两级串联水力旋流器原位处理疏浚泥水

采用两级串联水力旋流器进行疏浚泥水原位处理技术在实现高效固液分离的同时,出水SS满足GB 8978—1996《污水综合排放标准》Ⅲ级标准,可直接排入水体。实验条件下,一、二级水力旋流器最佳锥角分别为8°和5°,一级水力旋流器最佳分流比为0. 12。PAM的混凝作用一方面可以提高二级水力旋流器固液分离效率,降低二级出水SS;另一方面可以提高一级水力旋流器底流体积浓度,降低一级分流比。二级水力旋流器PAM投加量为4 mg/g干污泥时,出水ρ(SS)为(301. 5±54. 1) mg/L,满足GB 8978—1996排放标准;一级水力旋流器PAM投加量为1 mg/g干污泥时,分离效率为60%时,分流比由0. 15降至0. 05。该技术有望在疏浚泥水原位处理中得到推广应用。     

PE微孔管用于旋流分离的理论分析及实验研究

对PE微孔管应用在水力旋流器领域的可能性及其工作原理进行了理论分析,并用PE微孔管将常规液-液水力旋流器的尾管段替换,在后者的结构基础上研制了一种改进结构的水力旋流器,并利用该旋流器对油水混合液进行了分离实验研究,测定和分析了相关效率,对于微孔管与旋流器的结合应用具有一定的意义。     

水力旋流分离器在水处理领域的应用研究进展

水力旋流分离器具有分离效率高、简单可靠、绿色经济等优点,被广泛应用于各种分离场景,特别是近年来在水处理领域得到诸多关注。概述了运行操作参数（进料流速、进料浓度、进料压力）、结构设计参数（溢流管插入深度、底流管直径、回流角）、旋流器构型种类（W型、抛物线型、圆柱形）对水力旋流器分离性能的影响。优化操作参数可增强水力旋流器分离效率;溢流管插入深度与圆柱体横截面直径比值（L₀/D）为1.0时产生的流场更有利于分离;底流管直径存在最佳设计范围;旋流分离器与水源热泵联用吸入角为90°时效果最好。水力旋流器的分离作用在水处理过程中可以起到改善微生物聚集体性能（如提高污泥水解速率、提升沉降性能）、分离特定颗粒态微生物（如厌氧氨氧化菌颗粒污泥）、去除或回收特定密度物质（如悬浮有机物、泥砂、金属颗粒）等诸多作用,为水力旋流器在水处理领域的应用拓展了新的前景。     

除油水力旋流器在九江石化厂的应用

除油水力旋流器是一种管道式油水分离设备 ,它具有体积小 ,无须特殊维护等特点。针对炼油装置的具体特点 ,提出了旋流器的配置流程 ,并结合在九江石化总厂的使用经验 ,验证了旋流器在炼油装置应用的可行性 ,同时提出了具体使用时应注意的问题。     

柱型水力旋流器对硅切割废砂浆分离性能的研究

为了研究废砂浆中碳化硅粉和硅粉的分离情况,选用混合模型对柱型水力旋流器多相流流场进行数值模拟。模拟结果表明:柱型水力旋流器的分离效率与入口速度、进口浓度等因素有关,并分析出一定条件下当主、次相的入口速度均为1.1m/s时颗粒分离效果较好,分离效率较高,实验检测分离性能较好,为进一步实验研究提供一定的指导。     

离心气浮技术及在含油污水处理中的应用

针对含油污水处理将朝着低污染、低成本、易操作、结构紧凑、高效处理方向发展的要求,围绕离心气浮处理技术进行综述。将迄今各种含油污水离心气浮处理技术分为:基于充气水力旋流器的气浮旋流组合、气浮与常规水力旋流器单体组合、气浮与低强度旋流离心力场组合三大类,并对其特点进行了详细分析。国外采油污水处理的最新进展表明,紧凑型旋流气浮组合技术具有广阔的应用前景。     

渤西油田钻井平台含油废水处理系统存在问题及改进对策

针对渤西油田QK18-1钻井平台含油废水处理系统存在的主要问题,即原油缓冲罐因进水质、水量变化较大造成罐体液位波动、后段水力旋流器供压不稳定、除油效果差、出水超标等,通过系统优化提出了稳流、稳压的改进措施,实践表明：在水力旋流器前配置稳压罐、增设回流管阀和在线液位控制,极大地提高了除油效果,使出水石油类稳定达到国家排放标准,同时提高了系统的处理能力。     

旋流分离技术在水处理方面的应用及优化设计

确定了用于沙、水分离的水力旋流器的几何构造，并对结构参数进行优化设计进而得出各个结构参数，在此基础上制造出一台样机，以不同参数（入口流速，含沙量）对分离效率的影响，得出一些有益的结论。     

典型气浮净水设备评述

文章主要从气浮设备的原理与结构、优缺点、应用情况等方面评述了加压溶气气浮设备、涡凹气浮设备、浅层气浮设备、电气浮设备、充气水力旋流器、多段环流气浮塔和旋流-充气气浮系统等气浮设备,并讨论了气浮设备的研究和应用发展趋势。     

锰矿石选矿工艺的改革

一、问题的提出: 遵义铁合金厂选矿车间原生产采用单一的浮选流程。原矿经破碎洗矿后进入二段球磨机连续磨矿,使其85％的粒度小于200目,再经φ125mm水力旋流器脱泥后进行浮碳、浮硫再浮选锰矿石。其工艺流程如图一。     

基于电子鼻土壤与地下水污染修复现场TVOC和恶臭的评估

根据上海某土壤与地下水污染修复现场情况,应用自主研发的电子鼻系统(iSA-M1)分别对未修复及修复过程中的土壤和地下水、修复场地上空及周边空气中的VOCs和恶臭类气体进行检测.结合前期研究所得TPI和OPI公式,求得各点的值,并将其用图表示.结果表明:①修复后TVOC和恶臭的浓度总体呈下降趋势;②在土壤和地下水修复过程中,VOCs和恶臭的挥发受气象要素和作业的影响,其浓度在总体下降的过程中伴随着阶段性上升现象;③结合GIS技术,电子鼻能初步用于评估土壤和地下水修复现场造成的空间污染情况及对周围居民产生的影响.但造成影响程度的具体细化分级还需要进一步研究.     

军工材料环境适应性工程化验证和研究发展战略探讨

通过对国内外发展现状分析,讨论了环境适应性工程化验证和研究在军工材料开发、应用及其在武器装备发展中的地位和作用。提出了军工材料环境适应性工程化验证的技术内涵、试验与研究的模式和军工材料开发到武器装备应用各个阶段的任务和目标。在此基础上。探讨了发展军工关键材料环境适应性工程化验证试验与研究的总体战略和目标。结合国情。提出了军工关键材料环境适应性工程化验证与研究和关键材料体系环境适应性数据完善．军工关键材料环境适应性工程化验证自主保障能力建设．军工关键材料环境适应性工程化验证技术的提升等3方面重点发展和研究内容的构想与建议。     

Experimental investigation of the effect of sediment transport patterns on the adsorption of cadmium ions onto sediment particles

The mechanism of flow turbulence, sediment supply conditions, and sediment transport patterns that affect the adsorption of cadmium ions onto sediment particles in natural waters are experimentally simulated and studied in this study both in batch reactors and in a turbulence simulation tank. By changing the agitation conditions, the sediment transport in batch reactors can be categorized into bottom sediment-dominated sediment and suspended sediment-dominated sediment. It is found that the adsorption rate of bottom sediment is much less than that of suspended sediment, but the sediment transport pattern does not affect the final (equilibrium) concentration of dissolved cadmium. This result indicates that the parameters of an adsorption isotherm are the same regardless of the sediment transport pattern. In the turbulence simulation tank, the turbulence is generated by harmonic grid-stirred motions, and the turbulence intensity is quantified in terms of eddy diffusivity, which is equal to 9.84F(F is the harmonic vibration frequency) and is comparable to natural surface water conditions.When the turbulence intensity of flow is low and sediment particles stay as bottom sediment, the adsorption rate is significantly low, and the adsorption quantity compared with that of suspended sediment is negligible in the 6 h duration of the experiment. This result greatly favors the simplification of the numerical modeling of heavy metal pollutant transformation in natural rivers. When the turbulence intensity is high but bottom sediment persists, the rate and extent of descent of the dissolved cadmium concentration in the tank noticeably increase, and the time that is required to reach adsorption equilibrium also increases considerably due to the continuous exchange that occurs between the suspended sediment and the bottom sediment.A comparison of the results of the experiments in the batch reactor and those in the turbulence simulation tank reveals that the adsorption ability of the sediment, and in particular the adsorption rate, is greatly over-estimated in the batch reactor.     

MFI型沸石吸附分离水体中混合硝基氯苯的研究

采用MFI型沸石(HZSM-5与Silicalite-1沸石)为吸附剂分别吸附水体中的对硝基氯苯和邻硝基氯苯,研究了温度与沸石的结构特性对硝基氯苯吸附的影响,以及2种硝基氯苯分子在MFI型沸石中的扩散行为．结果表明,在不同温度下,对硝基氯苯与邻硝基氯苯在HZSM-5与Silicalite-1沸石中的吸附行为明显不同;对硝基氯苯在2种MFI型沸石中的扩散系数都显高于邻硝基氯苯．对硝基氯苯与邻硝基氯苯在吸附量与扩散性上的差异导致HZSM-5与Silicalite-1沸石对对硝基氯苯的吸附具有良好的选择性．尤其HZSM-5沸石在低温下更有利于从水体中选择性吸附分离混合硝基氯苯。     

Adsorption of phenolic compounds from aqueous solutions by aminated hypercrosslinked polymers

Two novel polymers （NJ-1 and N J-2） were synthesized by chemically modified a hypercrosslinked polymer NJ-0 with dimethylamine and trimethylamine, respectively. The comparison of the adsorption properties of the three polymers toward phenol, resorcin and phloroglucin was made. The study focused on the static equilibrium adsorption behaviors and the adsorption thermodynamics. Freundlich equation was found to fit the adsorption results well. The effect of amino groups introduced onto the surface of the resin and the structure of phenolic compounds on the adsorption were also studied. The hydrogen-bonding interaction and electrostatic interaction could happen between the amino groups and the adsorbates. The adsorption impetus increased as quantity of hydroxyl groups increased, but the adsorption capacity decreased due to the drop of the matching degree of the aperture of resins and the diameter of adsorbate molecules.     

Sorption and cosorption of the nonionic herbicide mefenacet and heavy metals on soil and its components

Sorption and cosorption of the nonionic herbicide mefenacet and two typical metals (copper and silver) on black soil and its components (kaolinite and humic acid) were investigated. It was found that because of their different valences and properties, Cu²⁺and Ag⁺ presented different effects on the sorption of mefenacet. Due to the competition of Cu²⁺, along with the shells of dense water formed by its surface complexation, for sorption surface area with mefenacet, the addition of Cu²⁺ decreased the sorption amount of mefenacet on soil and its components, especially on humic acid. However, the addition of Ag⁺ significantly enhanced the sorption of mefenacet, which was attributed to the softness of the cation that weakened the hydrophilicity of the local region around Ag⁺-complexed functionalities, and thus mitigated the competitive sorption of water. In addition, the sorption of mefenacet on soil with or without the two metals was generally decreased with increasing pH, which was caused by the hydrolysis of carbonyl and carboxyl groups on the surface of the sorbents, π-π interaction between mefenacet and the soil organic matter, and so on. On the other hand, the presence of mefenacet seemed to have little effect on the sorption of Cu²⁺ and Ag⁺, indicating that Cu²⁺ and Ag⁺ might be sorbed strongly on the tested sorbents and the mefenacet added was too low in concentration to affect the sorption of the metals.     

厌氧氨氧化过程中COD及pH与基质浓度之间的关系

分析了上向流厌氧氨氧化生物滤池中氮素化合物浓度、COD和pH变化规律以及ANAMMOX活性和生物量的分布规律,利用数理统计的方法研究了厌氧氨氧化过程中COD和pH与氮素基质浓度之间的关系.结果表明,溶解氧和氮负荷的共同作用使得ANAMMOX活性和生物量的分布沿滤层深度呈"山脊"状不均匀分布;异养反硝化的存在和H+的消耗使得厌氧氨氧化过程中COD和pH分别呈降低和升高趋势;100 mg/L以下的有机物浓度对厌氧氨氧化菌的影响不大,且COD和pH与基质NH4+-N浓度之间呈良好的线性相关关系.本试验中COD-NH4+-N和pH-NH4+-N拟合直线的斜率分别为1.113 8±0.052 2和-0.111 3±0.001 2,置信度为95%,平均相关系数R2分别为0.982 3和0.985 0.     

持续水动力作用下湖泊底泥胶体态氮、磷的释放

为揭示水动力扰动及其后续沉淀效应对湖泊内源氮、磷营养盐释放的作用,通过室内试验模拟了水体在受到持续扰动后又长时间静置沉淀的整个过程. 结果表明,水动力扰动初期可引起底泥颗粒态和胶体态氮、磷向水体大量释放. 在连续扰动0.5 d时,水体总氮(TN)和总磷(TP)浓度分别达最高值2.106 mg/L和0.272 mg/L; 连续扰动1 d时,水体中胶体氮(CN)和胶体磷(CP)含量分别达最高值0.452 mg/L和0.052 mg/L; 之后虽继续扰动,因颗粒物和胶体物质的凝聚沉淀作用超过了其悬浮量,TN、TP、CN、CP的含量却转而降低.在停止扰动后的静置过程中,大颗粒悬浮物迅速沉淀,而胶体物质沉降缓慢,静置时间超过1 d后,CN和CP含量才开始因絮凝沉淀而降低.真溶解态氮(UDN) 和真溶解态磷(UDP)含量在扰动阶段升高较少而在静置1　d之后有持续大幅度升高,说明胶体的吸附作用在扰动阶段限制了水体溶解态氮磷含量的升高,且延长了其悬浮后在水柱中的停留时间,在扰动后的静置阶段,胶体又会将吸附的氮磷解吸释放到水体中,从而延缓了营养盐去除和水质的改善.     

汽车排气尾流中微粒分布及其变化特性的研究

根据微粒核化、凝并及凝结模型对汽车排气尾流中微粒分布的变化特性进行了分析.结果表明,微粒的核化增加了排气尾流中超细微粒的数量;微粒的凝并和凝结将改变排气尾流中的微粒分布.在核化、凝并及凝结过程同时存在时,核化对微粒分布的影响相对较小,微粒分布的变化主要受凝并和凝结的作用.在排气管出口处,微粒的核化、凝并及凝结过程比较剧烈,微粒分布变化较大;随着距排气管出口距离的增加,微粒演变逐渐减弱.研究工作可以为汽车排放控制策略的确定以及汽车微粒对人体健康影响的研究提供依据.     

中国产区苹果越冬冻害的风险评估

越冬期冻害是影响苹果种植分布和质量形成的主要气象灾害之一。论文利用1961-2014年2 084个气象站点资料和冻害调查数据,基于二分类Logistic回归分别建立了越冬期初冬冻害和极端低温冻害发生的概率预测模型,并按照风险极低、低、中度、高、极高等5个等级进行了空间划分。结果表明：建立的初冬冻害和极端低温冻害风险概率预测模型均通过了Hosmer-Losmer检验,独立样本的预测准确率分别达到了83.6%和91.4%。中国产区苹果的越冬冻害主要以初冬冻害为主,覆盖了除黄河故道和云南产区外的大部分果区,而极端低温冻害主要分布在纬度或海拔较高的环渤海湾北部产区、黄土高原西北部和北疆。两种冻害的高风险区域面积基本相当,中度以上风险面积较大的省份依次为甘肃、辽宁、河北和山西,但苹果种植面积最大的陕西和山东遭遇两种冻害特别是极端低温冻害的风险概率总体较低。