Use of water spray curtain to disperse LNG vapor clouds

Effective safety measures to prevent and mitigate the consequences of an accidental release of flammable LNG are critical. Water spray curtain is currently recognized as an effective technique to control and mitigate various hazards in the industries. It has been used to absorb, dilute and disperse both toxic and flammable vapor cloud. It is also used as protection against heat radiation, in case of fighting vapor cloud fire. Water curtain has also been considered as one of the most economic and promising LNG vapor cloud control techniques. Water curtains are expected to enhance LNG vapor cloud dispersion mainly through mechanical effects, dilution, and thermal effects. The actual phenomena involved in LNG vapor and water curtain interaction were not clearly established from previous research. LNG spill experiments have been performed at the Brayton Fire Training Field at Texas A&M University (TAMU) to understand the effect of water curtain in controlling and dispersing LNG vapor cloud. This paper summarizes experimental methodology and presents data from two water curtain tests. The analysis of the test results are also presented to identify the effectiveness of these two types of water spray curtains in enhancing the LNG vapor cloud dispersion.     

Forced dispersion of LNG vapor with water curtain

Installation of effective safety measures to prevent and mitigate an accidental LNG release is critical. Water curtains are usually inexpensive, simple and reliable and currently have been recognized as an efficient technique to control and mitigate various hazards in the process industries including LNG industry. Actions of a water spray consist of a combination of several physical mechanisms. Detailed analysis of the complex mechanisms and the effects of water spray features to control and mitigate potential LNG vapor cloud are still unclear. This paper discusses the experimental research conducted by MKOPSC to study the physical phenomena involved and the effect of different types of water curtains parameters when applied for LNG vapor. The data from medium scale out-door experiments at the Brayton Fire Training School (BFTF), Texas, are summarized here to understand the relative importance of induced mechanical mixing effects, dilution with air, and heat transfer between water droplets and the LNG vapor. Field test results have determined that water curtains can reduce the concentration of the LNG vapor cloud. Due to the water curtain mechanisms of entrainment of air, dilution of vapor with entrained air, transfer of momentum and heat to the gas cloud, water curtain can disperse LNG vapor cloud to some extent.     

LNG accident dynamic simulation: Application for hazardous consequence reduction

The evaluation of exclusion (hazard) zones around the LNG stations is essential for risk assessment in LNG industry. In this study, computational fluid dynamics (CFD) simulations have been conducted for the two potential hazards, LNG flammable vapor dispersion and LNG pool fire radiation, respectively, to evaluate the exclusion zones. The spatial and temporal distribution of hazard in complex spill scenario has been taken into account in the CFD model. Experimental data from Falcon and Montoir field tests have been used to validate the simulation results. With the valid CFD model, the mitigation of the vapor dispersion with spray water curtains and the pool fire with high expansion foam were investigated. The spray water curtains were studied as a shield to prevent LNG vapor dispersing, and two types of water spray curtain, flat and cone, were analyzed to show their performance for reduction and minimization of the hazard influencing distance and area. The high expansion foam firefighting process was studied with dynamic simulation of the foam action, and the characteristics of the foam action on the reduction of LNG vaporization rate, vapor cloud and flame size as well as the thermal radiation hazard were analyzed and discussed.     

Influence of active mitigation barriers on LNG dispersion

In recent years, particular interest has been direct to the issues of risk associated with the storage, transport and use of Liquefied Natural Gas (LNG) due to the increasing consideration that it is receiving for energy applications. Consequently, a series of experimental and modeling studies to analyze the behavior of LNG have been carried out to collect an archive of evaporation, dispersion and combustion information, and several mathematical models have been developed to represent LNG dispersion in realistic environments and to design mitigation barriers.This work uses Computational Fluid Dynamics codes to model the dispersion of a dense gas in the atmosphere after accidental release. In particular, it will study the dispersion of LNG due to accidental breakages of a pipeline and it will analyze how it is possible to mitigate the dispersing cloud through walls and curtains of water vapor and air, also providing a criterion for the design of such curtains.     

Quantification of source-level turbulence during LNG spills onto a water pond

The use of computational fluid dynamics (CFD) models to simulate LNG vapor dispersion scenarios has been growing steadily over the last few years, with applications to LNG spills on land as well as on water. Before a CFD model may be used to predict the vapor dispersion hazard distances for a hypothetical LNG spill scenario, it is necessary for the model to be validated with respect to relevant experimental data. As part of a joint-industry project aimed at validating the CFD methodology, the LNG vapor source term, including the turbulence level associated with the evaporation process vapors was quantified for one of the Falcon tests.This paper presents the method that was used to quantify the turbulent intensity of evaporating LNG, by analyzing the video images of one of the Falcon tests, which involved LNG spills onto a water pond. The measured rate of LNG pool growth and spreading and the quantified turbulence intensity that were obtained from the image analysis were used as the LNG vapor source term in the CFD model to simulate the Falcon-1 LNG spill test. Several CFD simulations were performed, using a vaporization flux of 0.127 kg/m² s, radial and outward spreading velocities of 1.53 and 0.55 m/s respectively, and a range of turbulence kinetic energy values between 2.9 and 28.8 m²/s². The resulting growth and spread of the vapor cloud within the impounded area and outside of it were found to match the observed behavior and the experimental measured data.The results of the analysis presented in this paper demonstrate that a detailed and accurate definition of the LNG vapor source term is critical in order for any vapor cloud dispersion simulation to provide useful and reliable results.     

Numerical simulation of water curtain application for ammonia release dispersion

Using water curtain system to forced mitigate ammonia vapor cloud has been proven to be an effective measure. Currently, no engineering guidelines for designing an effective water curtain system are available, due to lack of understanding of complex interactions between ammonia vapor cloud and water droplets, especially the understanding of ammonia absorption into water droplets. This paper presents numerical calculations to reproduce the continuous ammonia release dispersion with and without the mitigating influence of a downwind water curtain using computational fluid dynamic (CFD) software ANSYS Fluent 14.0. The turbulence models k–ɛ and RNG were used to simulate the ammonia cloud dispersion without downwind water curtain. The simulated results were compared with literature using the statistical performance indicators. The RNG model represents better agreement with the experimental data and the k–ɛ model generates a slightly lesser result. The RNG model coupled with Lagrangian discrete phase model (DPM) was used to simulate the dilution effectiveness of the water curtain system. The ammonia absorption was taken into account by means of user-defined functions (UDF). The simulated effectiveness of water curtains has good agreements with the experimental results. The effectiveness of water mitigation system with and without the ammonia absorption was compared. The results display that the effectiveness mainly depends on the strong air entrainment enhanced by water droplets movement and the ammonia absorption also enhances the effectiveness of water curtain mitigation system. The study indicates that the CFD code can be satisfactorily applied in design criteria for an effective mitigation system.     

Validation of FLACS against experimental data sets from the model evaluation database for LNG vapor dispersion

The siting of facilities handling liquefied natural gas (LNG), whether for liquefaction, storage or regasification purposes, requires the hazards from potential releases to be evaluated. One of the consequences of an LNG release is the creation of a flammable vapor cloud, that may be pushed beyond the facility boundaries by the wind and thus present a hazard to the public. Therefore, numerical models are required to determine the footprint that may be covered by a flammable vapor cloud as a result of an LNG release. Several new models have been used in recent years for this type of simulations. This prompted the development of the “Model evaluation protocol for LNG vapor dispersion models” (MEP): a procedure aimed at evaluating quantitatively the ability of a model to accurately predict the dispersion of an LNG vapor cloud.This paper summarizes the MEP requirements and presents the results obtained from the application of the MEP to a computational fluid dynamics (CFD) model – FLACS. The entire set of 33 experiments included in the model validation database were simulated using FLACS. The simulation results are reported and compared with the experimental data. A set of statistical performance measures are calculated based on the FLACS simulation results and compared with the acceptability criteria established in the MEP. The results of the evaluation demonstrate that FLACS can be considered a suitable model to accurately simulate the dispersion of vapor from an LNG release.     

Underwater LNG release: Does a pool form on the water surface? What are the characteristics of the vapor released?

One of the scenarios of concern in assessing the safety issues related to transportation of LNG in a marine environment (ship or underwater pipeline) is the release of LNG underwater. This scenario has not been given the same level of scientific attention in the literature compared to surface releases and assessment of consequences therefrom. This paper addresses questions like, (1) does an LNG spill underwater form a pool on the water surface and subsequently evaporate like an LNG spill “on the surface” producing cold, heavier than air vapors?, and (2) what is the range of expected temperatures of the vapor, generated by LNG release due to heat transfer within the water column, when it emanates from the water surface?Very limited data from two field tests of LNG underwater release are reviewed. Also presented are the results from tests conducted in other related industries (metal casting, nuclear fission and fusion, chemical processing, and alternative fuel vehicles) where a hot (or cold) liquid is injected into a bulk cold (or hot) liquid at different depths.A mathematical model is described which calculates the temperature of vapor emanating at the water surface, and the liquid fraction of released LNG that surfaces, if any, to form a pool on the water surface. The model includes such variables as the LNG release rate, diameter of the jet at release, depth of release and water body temperature. Results obtained from the model for postulated release conditions are presented. Comparison of predicted results with available LNG underwater release test data is also provided.     

Numerical simulation of LNG dispersion under two-phase release conditions

The use of LNG (liquefied natural gas) as fuel brings up issues regarding safety and acceptable risk. The potential hazards associated with an accidental LNG spill should be evaluated, and a useful tool in LNG safety assessment is computational fluid dynamics (CFD) simulation. In this paper, the ADREA-HF code has been applied to simulate LNG dispersion in open-obstructed environment based on Falcon Series Experiments. During these experiments LNG was released and dispersed over water surface. The spill area is confined with a billboard upwind of the water pond. FA1 trial was chosen to be simulated, because its release and weather conditions (high total spill volume and release rate, low wind speed) allow the gravitational force to influence the cold, dense vapor cloud and can be considered as a benchmark for LNG dispersion in fenced area. The source was modeled with two different approaches: as vapor pool and as two phase jet and the predicted methane concentration at sensors' location was compared with the experimental one. It is verified that the source model affect to a great extent the LNG dispersion and the best case was the one modeling the source as two phase jet. However, the numerical results in the case of two phase jet source underestimate the methane concentration for most of the sensors. Finally, the paper discusses the effect of neglecting the ?9.3° experimental wind direction, which leads to the symmetry assumption with respect to wind and therefore less computational costs. It was found that this effect is small in case of a jet source but large in the case of a pool source.     

Key parametric analysis on designing an effective forced mitigation system for LNG spill emergency

Concerns over public safety and security of a potential liquefied natural gas (LNG) spill have promoted the need for continued improvement of safety measures for LNG facilities. The mitigation techniques have been recognized as one of the areas that require further investigation to determine the public safety impact of an LNG spill. Forced mitigation of LNG vapors using a water curtain system has been proven to be effective in reducing the vapor concentration by enhancing the dispersion. Currently, no engineering criteria for designing an effective water curtain system are available, mainly due to a lack of understanding of the complex droplet–vapor interaction. This work applies computational fluid dynamics (CFD) modeling to evaluate various key design parameters involved in the LNG forced mitigation using an upwards-oriented full-cone water spray. An LNG forced dispersion model based on a Eulerian–Lagrangian approach was applied to solve the physical interactions of the droplet–vapor system by taking into account the various effects of the droplets (discrete phase) on the air–vapor mixture (continuous phase). The effects of different droplet sizes, droplet temperatures, air entrainment rates, and installation configurations of water spray applications on LNG vapor behavior are investigated. Finally, the potential of applying CFD modeling in providing guidance for setting up the design criteria for an effective forced mitigation system as an integrated safety element for LNG facilities is discussed.     

Investigation of pool spreading and vaporization behavior in medium-scale LNG tests

A failure of a Liquefied Natural Gas (LNG) tanker can occur due to collision or rupture in loading/unloading lines resulting in spillage of LNG on water. Upon release, a spreading liquid can form a pool with rapid vaporization leading to the formation of a flammable vapor cloud. Safety analysis for the protection of public and property involves the determination of consequences of such accidental releases. To address this complex pool spreading and vaporization phenomenon of LNG, an investigation is performed based on the experimental tests that were conducted by the Mary Kay O'Connor Process Safety Center (MKOPSC) in 2007. The 2007 tests are a part of medium-scale experiments carried out at the Brayton Fire Training Field (BFTF), College Station. The dataset represents a semi-continuous spill on water, where LNG is released on a confined area of water for a specified duration of time. The pool spreading and vaporization behavior are validated using empirical models, which involved determination of pool spreading parameters and vaporization rates with respect to time. Knowledge of the pool diameter, pool height and spreading rate are found to be important in calculating the vaporization rates of the liquid pool. The paper also presents a method to determine the vaporization mass flux of LNG using water temperature data that is recorded in the experiment. The vaporization rates are observed to be high initially and tend to decrease once the pool stopped spreading. The results of the analysis indicated that a vaporization mass flux that is varying with time is required for accurate determination of the vaporization rate. Based on the data analysis, sources of uncertainties in the experimental data were identified to arise from ice formation and vapor blocking.     

Application of fire suppression materials on suppression of LNG pool fires

An LNG pool fire is considered one of the main hazards of LNG, together with LNG vapor dispersion. Suppression methods are designed to reduce the hazard exclusion zones, distance to reach radiant heat of 5 kW/m², when an LNG pool fire is considered. For LNG vapor dispersion, the hazard exclusion zone is the distance travelled by the LNG vapor to reach a concentration of 2.5% v/v (half of the LNG lower flammability limit).Warming the LNG vapor to reach positive buoyancy faster is one way to suppress LNG vapor dispersion and reduce evaporation rate (thus fire size and its associated radiant heat) and that is the main objective in LNG pool fire suppression. Based on previous research, the use of high expansion foam has been regarded as the primary method in suppressing LNG pool fires. However, in 1980, another method was introduced as an alternative pool fire suppression system, Foamglas^®. The research concluded that 90% of the radiant heat was successfully reduced. Currently-called Foamglas^® pool fire suppression (Foamglas^® PFS) is a passive mitigation system and is deployed after the leak occurs. Foamglas^® PFS is non-flammable, and has a density one-third of the density of LNG, thus floats when an LNG pool is formed.This paper describes the study and confirmation of Foamglas^®PFS effectiveness in suppressing LNG pool fires. In addition, while Foamglas^® PFS is not expected to suppress LNG vapor dispersion, further investigation was conducted to study the effect of Foamglas^®PFS on LNG vapor dispersion. An LNG field experiment was conducted at Brayton Fire Field. The experimental development, procedures, results and findings are detailed in this paper.     

Underwater LNG release test findings: Experimental data and model results

An underwater LNG release test was conducted to understand the phenomena that occur when LNG is released underwater and to determine the characteristic of the vapor emanating from the water surface. Another objective of the test was to determine if an LNG liquid pool formed on the water surface, spread and evaporated in a manner similar to that from an on-the-surface release of LNG.A pit of dimensions 10.06 m × 6.4 m and 1.22 m depth filled with water to 1.14 m depth was used. A vertically upward shooting LNG jet was released from a pipe of 2.54 cm diameter at a depth of 0.71 m below the water surface. LNG was released over 5.5-min duration, with a flow rate of 0.675 ± 0.223 L/s. The wind speed varied between 2 m/s and 4 m/s during the test.Data were collected as a function of time at a number of locations. These data included LNG flow rate, meteorological conditions, temperatures at a number of locations within the water column, and vapor temperatures and concentrations in air at different downwind locations and heights. Concentration measurements were made with instruments on poles located at 3.05 m, 6.1 m and 9.14 m from the downwind edge of the pit and at heights 0.46 m, 1.22 m, and 2.13 m. The phenomena occurring underwater were recorded with an underwater video camera. Water surface and in-air phenomena including the dispersion of the vapor emanating from the water surface were captured on three land-based video cameras.The lowest temperature recorded for the vapor emanating from the water surface was −1 °C indicating that the vapor emitted into air was buoyant. In general the maximum concentration observed at each instrument pole was progressively at higher and higher elevations as one traveled downwind, indicating that the vapor cloud was rising. These findings from the instrument recorded data were supported by the visual record showing the “white” cloud rising, more or less vertically, in air. No LNG pool was observed on the surface of water. Discussions are provided on the test findings and comparison with predictions from a previously published theoretical model.     

Highlights of LNG risk technology

The authors have recently undertaken a major review of LNG consequence modeling, compiling a wide range of historical information with more recent experiments and modeling approaches in a book entitled “LNG Risk-Based Safety: Modeling and Consequence Analysis”. All the main consequence routes were reviewed – discharge, evaporation, pool and jet fire, vapor cloud explosions, rollover, and Rapid Phase Transitions (RPT’s). In the book, experimental data bases are assembled for tests on pool spread and evaporation, burn rates, dispersion, fire and radiation and effects on personnel and structures. The current paper presents selected highlights of interest: lessons learned from historical development and experience, comparison of predictions by various models, varying mechanisms for LNG spread of water, a modeling protocol to enable acceptance of newer models, and unresolved technical issues such as cascading failures, fire engulfment of a carrier, the circumstances for a possible LNG BLEVE, and accelerated evaporation by LNG penetration into water.     

Methodology for consequence analysis of LNG releases at deepwater port facilities

A methodology to perform consequence analysis associated with liquefied natural gas (LNG) for a deepwater port (DWP) facility has been presented. Analytical models used to describe the unconfined spill dynamics of LNG are discussed. How to determine the thermal hazard associated with a potential pool fire involving spilled LNG is also presented. Another hazard associated with potential releases of LNG is the dispersion of the LNG vapor. An approach using computational fluid dynamics tools (CFD) is presented. The CFD dispersion methodology is benchmarked against available test data. Using the proposed analysis approach provides estimates of hazard zones associated with newly proposed LNG deepwater ports and their potential impact to the public.     

Development of heat transfer and evaporation model of LNG covered by Hi-Ex foam

Natural gas is a kind of clean, efficient green energy source, which is used widely. Liquefied natural gas (LNG) is produced by cooling natural gas to −161 °C, at which it becomes the liquid. Once LNG was released, fire or explosion would happen when ignition source existed nearby. The high expansion foam (Hi-Ex foam) is believed to quickly blanket on the top of LNG spillage pool and warm the LNG vapor to lower the vapor cloud density at the ground level and raising vapor buoyancy. To identify the physical structure after it contacted with LN₂ and to develop heat transfer model, the small-scale field test with liquid nitrogen (LN₂) was designed. In experiment, three layers including frozen ice layer, frozen Hi-Ex layer and soft layer of Hi-Ex foam were observed at the steady state. By characterizing physical structure of the foam, formulas for calculating the surface of single foam bubble and counting foam film thickness were deduced. The micro heat transfer and evaporation model between cryogenic liquid and Hi-Ex foam was established. Indicating the physical structure of the frozen ice layer, there were a certain number of icicles below it. The heat transfer and evaporation mathematical model between the frozen ice layer and LNG was derived. Combining models above with the heat transfer between LNG, ground and cofferdam, the heat transfer and evaporation mathematical model of LNG covered by Hi-Ex foam was developed eventually. Finally, LN₂ evaporation rate calculated by this model was compared with the measured evaporation rate. The calculated results are 1.2–2.1 times of experimental results, which were acceptable in engineering and proved the model was reliable.     

Developing a CFD heat transfer model for applying high expansion foam in an LNG spill

Liquefied natural gas (LNG) is widely used to cost-effectively store and transport natural gas. However, a spill of LNG can create a vapor cloud, which can potentially cause fire and explosion. High expansion (HEX) foam is recommended by the NFPA 11 to mitigate the vapor hazard and control LNG pool fire. In this study, the parameters that affect HEX foam performance were examined using lab-scale testing of foam temperature profile and computational fluid dynamics (CFD) modeling of heat transfer in vapor channels. A heat transfer model using ANSYS Fluent® was developed to estimate the minimum HEX foam height that allows the vapors from LNG spillage to disperse rapidly. We also performed a sensitivity analysis on the effect of the vaporization rate, the diameter of the vapor channel, and the heat transfer coefficient on the required minimum height of the HEX foam. It can be observed that at least 1.2 m of HEX foam in height are needed to achieve risk mitigation in a typical situation. The simulation results can be used not only for understanding the heat transfer mechanisms when applying HEX foam but also for suggesting to the LNG facility operator how much HEX foam they need for effective risk mitigation under different conditions.     

Experimental research of LNG accidental underwater release and combustion behavior

Evaluating potential hazards caused by accidental LNG release from underwater pipelines or vessels is a significant consideration in marine transportation safety. The aim of this study was to capture the dynamic behavior of LNG jet released under water and to analyze its vapor dispersion characteristics and combustion characteristics on the water surface during different release scenarios. Controlled experiments were conducted where LNG was jet released from a cryogenic storage tank. The dynamic process of LNG being jet released from orifices of different sizes and shapes, as well as the rising plume structure, were captured by a high-speed camera. The leakage flow rate and pipeline pressure were recorded by a flow meter and pressure gauge, respectively. The concentration distribution that emanated from the water surface was measured utilizing methane sensors in different positions with various wind speeds. The flame combustion characteristics of LNG vapor clouds, which immediately ignited upon the enclosed water tank, were also recorded. Additionally, the mass burning rate of the flame on the water surface was evaluated, and a new correlation between the ratio of flame length and width was established. The results indicated a large dimensionless heat release rate (Q*) and a continuous release flow rate in a limited burning area. This study could provide greater understanding of the mechanisms of LNG release and combustion behavior under water.     

水面LNG液池扩展模型的分析与对比研究

为了评价在开阔水面上的液化天然气（LNG）火灾和蒸气云爆炸灾害后果,分析了LNG水面扩展动态过程;对比分析了Fay模型、FERC模型和计算流体力学软件FLACS的计算结果,探讨了LNG液池面积随时间的动态变化过程,分析了泄漏量、泄漏速率等参数对LNG液池扩展半径的影响;根据液池扩展模型的计算结果,确定了LNG液池的最大面积,并以此分析了LNG流淌火灾的辐射危害。研究结果表明:对于相同的泄漏条件,3种方法模拟的泄漏LNG水面扩展动态过程相似,一般情况下,FLACS模型,FERC模型和Fay模型所计算的最大液池半径依次增大;由于FERC模型与FLACS软件的模拟结果接近且偏于保守,故此在一般的工程应用时,采用FERC模型即可方便快捷地获得较为准确的结果。     

Modeling the vapor source term associated with the spill of LNG into a sump or impoundment area

The recent publication of evaluation protocols for vapor source term models and vapor dispersion models have influenced the modeling approaches that can be used for approval of new and expansion projects at LNG receiving terminals. In the past few years the scientific basis of integral vapor source term models has been questioned with growing concerns regarding their validity. In this paper, the shallow water equations (SWEs) were solved to study the characteristics of the evaporating LNG pool associated with a constant flow rate spill of LNG into a concrete sump. In the early stages of pool spreading, the leading edge thickness profile of the SWE model scales with the square root of the distance from the leading edge as the pool spreads. After the edge of the pool reaches the wall, the reflected wave forms a hydraulic jump that travels back towards the center of the pool at a speed that is considerably slower than the initial spreading of the pool. Once the hydraulic jump reaches the center, the pool assumes a nearly flat free surface for the rest of the spill. The pool spreading and the rate of evaporation from the SWEs were then compared to the solution provided by the integral model, PHAST. The two approaches were found to agree well with one another. The SWE model was also used to demonstrate the influence of an elevated spill source. With an elevated source, the LNG pool spreads faster, significantly increasing the initial rate of vaporization and peak vaporization rate. This increase in the initial rate of vaporization could lead to an increase in the vapor cloud hazard distance. The SWE model was also used to demonstrate the influence of an inclined sump floor in the shape of an inverted cone where the spilling LNG accumulates in the low vertex of the cone. Inclined sump floors can be used to significantly reduce the cumulative evaporation, making them attractive as a possible mitigation approach in cases where a containment sump is located close to a property boundary.