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Zhi-yuan Yu Min Gan Xu-ling Chen Qiang Chen Yun-song Huang 《Journal of the Air & Waste Management Association (1995)》2016,66(7):687-697
The primary goal of this paper is to reveal the reaction behavior of SO2 in the sinter zone, combustion zone, drying–preheating zone, and over-wet zone during flue gas recirculation (FGR) technique. The results showed that SO2 retention in the sinter zone was associated with free-CaO in the form of CaSO3/CaSO4, and the SO2 adsorption reached a maximum under 900ºC. SO2 in the flue gas came almost from the combustion zone. One reaction behavior was the oxidation of sulfur in the sintering mix when the temperature was between 800 and 1000ºC; the other behavior was the decomposition of sulfite/sulfate when the temperature was over 1000ºC. However, the SO2 adsorption in the sintering bed mainly occurred in the drying–preheating zone, adsorbed by CaCO3, Ca(OH)2, and CaO. When the SO2 adsorption reaction in the drying–preheating zone reached equilibrium, the excess SO2 gas continued to migrate to the over-wet zone and was then absorbed by Ca(OH)2 and H2O. The emission rising point of SO2 moved forward in combustion zone, and the concentration of SO2 emissions significantly increased in the case of flue gas recirculation (FGR) technique.
Implications: Aiming for the reuse of the sensible heat and a reduction in exhaust gas emission, the FGR technique is proposed in the iron ore sintering process. When using the FGR technique, SO2 emission in exhaust gas gets changed. In practice, the application of the FGR technique in a sinter plant should be cooperative with the flue gas desulfurization (FGD) technique. Thus, it is necessary to study the influence of the FGR technique on SO2 emissions because it will directly influence the demand and design of the FGD system. 相似文献
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Grochowalski A Lassen C Holtzer M Sadowski M Hudyma T 《Environmental science and pollution research international》2007,14(5):326-332
Background The aim of the project was to measure the actual emissions of PCDD/F, PCBs and HCB from 20 selected metallurgical installations
in Poland, in order to update the national inventory of dioxin emission from metallurgical industry for developing a strategy
for dioxins and furans emission abatement from the subject facilities (UNEP 2005).
Methods Sampling methodology used in this work was developed at the Cracow University of Technology because of the complexity of simultaneous
sampling and determining PCDFs, PCDDs, PCB and HCB. For the determination a GC-MS/MS system was used.
Results and Discussion Results from the work indicate that the highest dioxins and PCB concentrations were recorded for iron ore sintering plants
at 1.10–1.32 ng total1 TEQ/Nm3 followed by aluminium scrap melting at 0.03–0.66 ng total TEQ/Nm3. The highest HCB concentrations at 613–1491 ng/Nm3 were also recorded for iron ore sintering plants, whereas at aluminium plants the HCB concentrations were in the range of
only 10.1–22.7 ng/Nm3.
Conclusions The above investigations indicate that secondary aluminium production is the most significant dioxins source, if calculated
as emission factor values. However, iron ore sintering plants are operating at much higher production capacity, causing this
process to become the major source of dioxins, PCB and HCB pollution to the atmosphere in Poland.
Recommendations and Perspectives Based on the performed tests and the environmental reviews of selected plants several recommendations were formulated for
the reduction of generation or of emission of these pollutants from iron ore sintering plants, electric arc furnace steel
production processes, hot-blast furnace operations, secondary aluminium smelting and primary zinc production from zinc cathodes. 相似文献
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A laboratory-scale multi-layer system was developed for the adsorption of PCDD/Fs from gas streams at various operating conditions, including gas flow rate, operating temperature and water vapor content. Excellent PCDD/F removal efficiency (>99.99%) was achieved with the multi-layer design with bead-shaped activated carbons (BACs). The PCDD/F removal efficiency achieved with the first layer adsorption bed decreased as the gas flow rate was increased due to the decrease of the gas retention time. The PCDD/F concentrations measured at the outlet of the third layer adsorption bed were all lower than 0.1 ng I-TEQ Nm−3. The PCDD/Fs desorbed from BAC were mainly lowly chlorinated congeners and the PCDD/F outlet concentrations increased as the operating temperature was increased. In addition, the results of pilot-scale experiment (real flue gases of an iron ore sintering plant) indicated that as the gas flow rate was controlled at 15 slpm, the removal efficiencies of PCDD/F congeners achieved with the multi-layer reactor with BAC were better than that in higher gas flow rate condition (20 slpm). Overall, the lab-scale and pilot-scale experiments indicated that PCDD/F removal achieved by multi-layer reactor with BAC strongly depended on the flow rate of the gas stream to be treated. 相似文献
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Zhang Qin Chen Jiacheng Wu Yanan Liu Haipeng Gu Bin Hu Shen Yang Hongying 《Environmental science and pollution research international》2021,28(4):4307-4316
Environmental Science and Pollution Research - SO3 in the copper smelting flue gas not only causes serious corrosion in heat exchange and dust collection equipment but also increases the amount of... 相似文献
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为了开发除磷填料,以红壤为基本材料,并以烧结温度、粉煤灰添加量、外加剂A用量和外加剂B用量作为4个因素设计正交实验,制造了不同配方的红壤烧结填料,进行等温吸附实验并利用Langmuir模型拟合最大吸磷量进行比较。结果表明,通过烧结可使粉末状红壤成型,同时提高了其除磷能力;对填料理论吸磷量的影响因素主次顺序为外加剂B用量、外加剂A用量、粉煤灰用量及烧结温度;通过比较理论吸附量,同时考虑到成本,可以确定正交实验结果中较优填料配方组成为(重量比):61%红壤,30%粉煤灰,0%外加剂A,9%外加剂B,烧结温度1150℃,其最大理论的磷吸附量2.274mg/cm^2,单位除磷原料成本约0.047元/g. 相似文献
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应用聚丙烯腈基活性碳纤维(PAN-ACF)对模拟的工业烟气中的SO2和NO在烟气露点温度以上进行吸附脱除实验。通过改变固定床ACF装载量、反应温度、水蒸气体积分数和O2体积分数,研究了ACF脱硫效率和脱硝效率的变化规律,还研究了同时脱硫脱硝时入口SO2或NO浓度对脱除效率的影响。结果表明:PAN-ACF具有良好的脱硫性能和一定的脱硝能力,其脱硫效率和脱硝效率随着ACF装载量和O2体积分数的增大而升高,随着温度的升高而降低,随着水蒸气体积分数的增大先升高后降低;在同时脱硫脱硝时,SO2对ACF的脱硝反应有明显的抑制作用,而NO对ACF的脱硫反应影响不大。 相似文献
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通过对首钢烧结厂的污染结点、污染物特性、污染物控制技术措施和技术规范进行分析,提出了烧结厂PM10控制方案,对烧结厂采用高效除尘设备的PM10削减量及改造费用进行了估算,确定了烧结厂PM10治理技术方案排序,为钢铁企业烧结厂治理颗粒污染物的同时选择最为经济实用的除尘器类型提供理论依据。 相似文献
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Engineering and environmental properties of thermally treated mixtures containing MSWI fly ash and low-cost additives 总被引:9,自引:0,他引:9
An experimental work was carried out to investigate the feasibility of application of a sintering process to mixtures composed of Municipal Solid Waste Incinerator (MSWI) fly ash and low-cost additives (waste from feldspar production and cullet). The proportions of the three constituents were varied to adjust the mixture compositions to within the optimal range for sintering. The material was compacted in cylindrical specimens and treated at 1100 and 1150 degrees C for 30 and 60 min. Engineering and environmental characteristics including weight loss, dimensional changes, density, open porosity, mechanical strength, chemical stability and leaching behavior were determined for the treated material, allowing the relationship between the degree of sintering and both mixture composition and treatment conditions to be singled out. Mineralogical analyses detected the presence of neo-formation minerals from the pyroxene group. Estimation of the extent of metal loss from the samples indicated that the potential for volatilization of species of Pb, Cd and Zn is still a matter of major concern when dealing with thermal treatment of incinerator ash. 相似文献
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本文介绍了烟道式脱硫装置的特点及工艺原理 ,采用该装置处理某冶炼厂高浓度SO2 烟气 ,其脱硫率达 90 %以上 ,净化后的烟气可直接达标排放 ,并年产合格脱硫石膏近万吨。烟道式脱硫装置解决了常规脱硫除尘装置共同存在的结垢和堵塞问题 ,在冶炼烟气治理方面具有一定的推广应用价值。 相似文献
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Polychlorinated dibenzo-p-dioxins, dibenzofurans and 'dioxin-like' PCBs in flue gas emissions from municipal waste management plants 总被引:2,自引:0,他引:2
The aim of this work is to give representative data on polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated dibenzofurans (PCDFs) and polychlorinated biphenyl (PCBs) from stack gas emissions of an urban solid waste management plant which has to comply with the limit of 0.1 ng I-TEQ/Nm3. In particular, the study is focused on 29 target compounds, the seventeen 2,3,7,8-PCDDs/Fs, four non-ortho PCBs and eight mono-ortho PCBs which configure so-called 'dioxin-like' PCBs (DL-PCBs). To this end, emission measurements were performed during one year over the three operating combustion lines in a selected waste management plant. In general, accurate methodology allowed characterizing all target compounds in almost all the samples analyzed. In addition, a typical pattern for DL-PCBs is reported. The pattern presented PCB #118 to be the highest, nevertheless the figures demonstrated DL-PCBs contribution to the total TEQ around 3% being PCB #126 the most important congener due to its TEF of 0.1. Finally, remarkable differences were achieved in comparison with both environmental and biological samples such as soils, sediments, human milk or fish since these matrices may present DL-PCB contribution to the total TEQ up to 77%. 相似文献
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The aim of the project was to measure the actual emissions of polychlorinated dibenzodioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), dioxin-like polychlorinated biphenyls (dl-PCBs) and hexachlorobenzene (HCB) from four selected power plants in Poland in order to update the national inventory of PCDDs/PCDFs emission. Relatively low PCDDs/PCDFs as well as dl-PCBs concentrations in flue gas obtained in measurements in this study for four different circulated fluidized bed (CFB) boilers indicate practical absence of any hazards caused by PCDDs/PCDFs emission from these units. The results of PCDDs/PCDFs determination obtained in this study indicate that hard coal combustion in large CFB in the four central heating plants (CHP) is not a significant source of PCDDs/PCDFs emission to the environment even if operated by co-firing of waste coal. PCDDs/PCDFs concentration in flue gases as well as emission factors were recorded in the range of 0.012-0.060ngI-TEQ/m(n)(3) and 7.51-46.4mugI-TEQ/TJ, respectively. Dl-PCBs concentration was practically below the LOQ=0.006ng WHO-PCB TEQ/m(n)(3) in all experiments. HCB concentration as well as emission factors were recorded in the range of 11.5-42.0ng/m(n)(3) and 6.19-26.7mg/TJ, respectively, where the highest value was obtained for co-firing of waste coal, however. Obtained in this work emission factors will be used for national emission inventory purposes instead of the factors proposed by Toolkit or taken from previous measurements. However, consideration should be given to the fact that the measurements in most cases are related to single installations. Therefore, the need for further development of national factors for the power generation industry in Poland is desired. 相似文献
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