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1.
Wood products are easy to produce dust in the production and processing process, and have a serious explosion risk. In order to improve the safety of wood products production, the inhibiting effects of magnesium hydroxide (MTH), SiO2, melamine polyphosphate (MPP) on the minimum ignition energy (MIE) and minimum ignition temperature (MIT) of wood dust were experimentally studied. The results showed that the inhibiting effects of inhibitors on the MIE of wood dust show the order of MPP > SiO2>MTH. The order of the inhibiting effects on the MIT of wood dust was MPP > MTH > SiO2. When 10% MPP was added to wood dust, the time when the flame appears (Tappear) and the time when the flame reaches the top of the glass tube (Ttop) obviously rose to 80, 140 ms. Therefore, MPP had the best inhibiting effect on the ignition sensitivity of wood dust.According to thermogravimetry (TG), differential scanning calorimetry (DSC) tests, the introduction of MPP leaded to lower maximum mass loss rate (MMLR), higher temperature corresponding to mass loss of 90% (T0.1), residual mass and heat absorption. In addition, thermogravimetric analysis/infrared spectrometry (TG-IR) results showed that MPP produced H2O (g) and NH3 (g) during the thermal decomposition process, which diluted the oxygen.  相似文献   

2.
The explosion characteristic parameters of polyethylene dust were systematically investigated. The variations in the maximum explosion pressure (Pmax), explosion index (Kst), minimum ignition energy (MIE), minimum ignition temperature (MIT), and minimum explosion concentration (MEC) of dust samples with different particle sizes were obtained. Using experimental data, a two-dimensional matrix analysis method was applied to classify the dust explosion severity based on Pmax and Kst. Then, a three-dimensional matrix was used to categorize the dust explosion sensitivity based on three factors: MIE, MIT, and MEC. Finally, a two-dimensional matrix model of dust explosion risk assessment was established considering the severity and sensitivity. The model was used to evaluate the explosion risk of polyethylene dust samples with different particle sizes. It was found that the risk level of dust explosion increased with decreasing particle size, which was consistent with the actual results. The risk assessment method can provide a scientific basis for dust explosion prevention in the production of polyethylene.  相似文献   

3.
Explosibility of micron- and nano-titanium was determined and compared according to explosion severity and likelihood using standard dust explosion equipment. ASTM methods were followed using a Siwek 20-L explosion chamber, MIKE 3 apparatus and BAM oven. The explosibility parameters investigated for both size ranges of titanium include explosion severity (maximum explosion pressure (Pmax) and size-normalized maximum rate of pressure rise (KSt)) and explosion likelihood (minimum explosible concentration (MEC), minimum ignition energy (MIE) and minimum ignition temperature (MIT)). Titanium particle sizes were ?100 mesh (<150 μm), ?325 mesh (<45 μm), ≤20 μm, 150 nm, 60–80 nm, and 40–60 nm. The results show a significant increase in explosion severity as the particle size decreases from ?100 mesh with an apparent plateau being reached at ?325 mesh and ≤20 μm. Micron-size explosion severity could not be compared with that for nano-titanium due to pre-ignition of the nano-powder in the 20-L chamber. The likelihood of an explosion increases significantly as the particle size decreases into the nano range. Nano-titanium is very sensitive and can self-ignite under the appropriate conditions. The explosive properties of the nano-titanium can be suppressed by adding nano-titanium dioxide to the dust mixture. Safety precautions and procedures for the nano-titanium are also discussed.  相似文献   

4.
In this study, a physical model of the dust cloud ignition process is developed for both cylindrical coordinates with a straight-line shaped ignition source and spherical coordinates with a point shaped ignition source. Using this model, a numerical algorithm for the calculation of the minimum ignition energy (MIE) is established and validated. This algorithm can evaluate MIEs of dusts and their mixtures with different dust concentrations and particle sizes. Although the average calculated cylindrical MIE (MIEcylindrical) of the studied dusts only amounts to 63.9% of the average experimental MIE value due to reasons including high idealization of the numerical model and possible energy losses in the experimental tests, the algorithm with cylindrical coordinates correctly predicts the experimental MIE variation trends against particle diameter and dust concentration. There is a power function relationship between the MIE and particle diameter of the type MIE ∝ dpk with k being approximately 2 for cylindrical coordinates and 3 for spherical coordinates. Moreover, as dust concentration increases MIE(conc) first drops because of the decreasing average distance between particles and, at fuel-lean concentrations the increasing dust cloud combustion heat; however, after the dust concentration rises beyond a certain value, MIE(conc) starts to increase as a result of the increasingly significant heat sink effect from the particles and, at fuel-rich concentrations the no longer increasing dust cloud combustion heat.  相似文献   

5.
To forestall, control, and mitigate the detrimental effects of aluminium dust, a 20-L near-spherical dust explosion experimental system and an HY16429 type dust-cloud ignition temperature test device were employed to explore the explosion characteristics of micron-sized aluminium powder under different ignition energies, dust particle sizes, and dust cloud concentration (Cdust) values; the minimum ignition temperature (MIT) values of aluminium powder under different dust particle sizes and Cdust were also examined. Flame images at different times were photographed by a high-speed camera. Results revealed that under similar dust-cloud concentrations and with dust particle size increasing from 42.89 to 141.70 μm, the MIT of aluminium powder increased. Under various Cdust values, the MIT of aluminium dust clouds attained peak value when concentrations enhanced. Furthermore, the increase of ignition energy contributed to the increase of the explosion pressure (Pex) and the rate of explosion pressure rise [(dP/dt)ex]. When dust particle size was augmented gradually, the Pex and (dP/dt)ex attenuated. Decreasing particle size lowered both the most violent explosion concentration and explosive limits.  相似文献   

6.
The current research is aimed at investigating the explosion behavior of hazardous materials in relation to aspects of particulate size. The materials of study are flocculent (fibrous) polyamide 6.6 (nylon) and polyester (polyethylene terephthalate). These materials may be termed nontraditional dusts due to their cylindrical shape which necessitates consideration of both particle diameter and length. The experimental work undertaken is divided into two main parts. The first deals with the determination of deflagration parameters for polyamide 6.6 (dtex 3.3) for different lengths: 0.3 mm, 0.5 mm, 0.75 mm, 0.9 mm and 1 mm; the second involves a study of the deflagration behavior of polyester and polyamide 6.6 samples, each having a length of 0.5 mm and two different values of dtex, namely 1.7 and 3.3. (Dtex or decitex is a unit of measure for the linear density of fibers. It is equivalent to the mass in grams per 10,000 m of a single filament, and can be converted to a particle diameter.) The explosibility parameters investigated for both flocculent materials include maximum explosion pressure (Pmax), size-normalized maximum rate of pressure rise (KSt), minimum explosible concentration (MEC), minimum ignition energy (MIE) and minimum ignition temperature (MIT). ASTM protocols were followed using standard dust explosibility test equipment (Siwek 20-L explosion chamber, MIKE 3 apparatus and BAM oven). Both qualitative and quantitative analyses were undertaken as indicated by the following examples. Qualitative observation of the post-explosion residue for polyamide 6.6 indicated a complex interwoven structure, whereas the polyester residue showed a shiny, melt-type appearance. Quantitatively, the highest values of Pmax and KSt were obtained at the shortest length and finest dtex for a given material. For a given length, polyester displayed a greater difference in Pmax and KSt at different values of dtex than polyamide 6.6. Long ignition delay times were observed in the BAM oven (MIT measurements) for polyester, and video framing of explosions in the MIKE 3 apparatus (MIE measurements) enabled observation of secondary ignitions caused by flame propagation after the initial ignition occurring at the spark electrodes.  相似文献   

7.
This paper experimentally investigated the relation between the minimum ignition energy (MIE) of magnesium powders as well as the effect of inert nitrogen (N2) on the MIE. The modified Hartmann vertical-tube apparatus and four kinds of different-sized pure magnesium powders (median particle size, D50; 28.1 μm–89.8 μm) were used in this study. The MIE of the most sensitive magnesium powder was 4 mJ, which was affected by the powder particle size (D50; 28.1 μm). The MIE of magnesium powder increased with an increase in the N2 concentration for the inerting technique. The magnesium dust explosion with an electrostatic discharge of 1000 mJ was suppressed completely at an N2 concentration range of more than 98%. The experimental data presented in this paper will be useful for preventing magnesium dust explosions generated from electrostatic discharges.  相似文献   

8.
In order to prevent dust explosions due to electrostatic discharges (ESD), this paper reports the minimum ignition energy (MIE) of aluminum powders in the air and the effective nitrogen (N2) concentration for the inert technique. The Hartman vertical-tube apparatus and five kinds of different sized pure aluminum powders (median particle size, D50; 8.53 μm–51.2 μm) were used in this study. The statistic minimum ignition energy (MIEs) of the most sensitive aluminum powder used in this study was 5 mJ, which was affected by the powder particle size (D50; 8.53 μm). In the case of aluminum powder, the inerting effects of N2 were quite different from the polymer powders. The MIE of aluminum powder barely changed until the N2 concentration was 89% in comparison with that of the normal air. When the N2 concentration was 90%, the MIE of aluminum powders suddenly exceeded 1000 mJ, which does not occur easily with ESD in the industrial process.  相似文献   

9.
针对某不饱和聚酯树脂钮扣厂在除尘设备维修过程中发生的粉尘爆炸事故,探究静电引起此次事故的可能性并提出防护措施。通过实验测定不饱和聚酯树脂钮扣粉尘的爆炸特性参数,进而确定其静电爆炸敏感性。结果发现:不饱和聚酯树脂钮扣粉尘云最小点火能MIE为4~10 mJ、最低着火温度MIT为480 ℃、粉尘层最低着火温度LIT>400 ℃。表明,此粉尘属易燃粉尘,其粉尘爆炸敏感度极高,被静电火花点燃的可能性极大,在生产过程中,应采取静电防护措施。  相似文献   

10.
The Mediterranean area is responsible for about 98% of the olive oil worldwide production, with 900 million olive trees occupying 10 million hectares. However, the processing of 100 kg of olives leads to the production of 40 kg of wastes, mainly constituted by olive pomace, which is potentially recoverable as energetic or material source. In general, in the past 20 years, the exploitation of olive pomace has increased, but along with it, the need for further information about its chemical-physical characterization and the related hazard in industry. Thus, a risk analysis assessment was conducted. When pelletized or in chunks, olive pomace does not pose any greater hazard than a pile of woody material, but when pulverized, it might become dangerous. Two parallel series of experiments were carried out at Dalhousie University (Lab 1) and at Polytechnic of Turin (Lab 2) using the same olive pomace sample, according to slightly different experimental procedures. Olive pomace dust explosibility and flammability parameters were measured: minimum ignition energy (MIE), minimum ignition temperature (MIT), maximum pressure rise rate ((dP/dt)max and KSt), maximum pressure (Pmax), and minimum explosible concentration (MEC). Moreover, the chemical and physical characterization of olive pomace was carried out: moisture content, particle size analysis, Scanning Electronic Microscope (SEM) investigation, thermo-gravimetric analysis (TGA), solid-state Nuclear Magnetic Resonance (NMR), mass spectrometry, calorific value, and bulk density estimation. Different thermal behaviors were observed according to the sieving/grinding pre-treatment. As concern flammability tests, samples seemed not to be sensitive to electric arc ignition (a value of MIE could not be measured), while coarser samples demonstrated higher ignition sensitivity to hot environment sources (MIT furnace) than finer ones. On the other hand, explosion violence parameters were enhanced by decreasing the particle size, while peak pressures were significantly influenced by the heat of combustion and the moisture content. Finally, a new test was developed to quantify the propensity of the raw material to produce fines by abrasion. It is defined “Abrasion by Rolling Test” (ART). The properties of the fines produced were measured as well.  相似文献   

11.
We investigate the PAN dust explosion inhibition behaviors of NaHCO3 and Al(OH)3 in a 20 L spherical explosion system and a transparent pipe explosion propagation test system. The results show that, in the standard 20 L spherical explosion system, the highest PAN dust explosion concentration is 500 g/m3, the maximum explosion pressure is 0.661 MPa, and the maximum explosion pressure increase rate is 31.64 MPa/s; adding 50% NaHCO3 and 60% Al(OH)3 can totally inhibit PAN dust explosion. In the DN0.15 m transparent pipe explosion propagation test system, for 500 g/m3 PAN dust, the initial explosion flame velocity is 102 m/s, the initial pressure is 0.46 MPa, and the initial temperature is 967 °C; adding 60% NaHCO3 and 70% Al(OH)3 can totally inhibit PAN dust explosion flames. Through FTIR and TG analyses, we obtain the explosion products and pyrolysis patterns of the explosion products of PAN dust, NaHCO3, and Al(OH)3. On this basis, we also summarize the PAN dust explosion inhibition mechanisms of NaHCO3 and Al(OH)3.  相似文献   

12.
Explosibility of polyurethane dusts produced in the recycling process of refrigerator and the ways to prevent the dust explosion were studied. In recent years, cyclopentane is often used as the foaming agent and this produces explosive atmosphere in the shredding process. The minimum explosive concentration of polyurethane dust, influence of coexisting cyclopentane gas on the explosibility, effect of relative humidity on the minimum explosive concentration of polyurethane dusts, the minimum ignition energy, influence of cyclopentane mixture on the explosion severity, etc. were investigated.The minimum explosive dust concentration decreased with the increase of cyclopentane concentration and increased with the increase of relative humidity. The minimum ignition energy was about 11 mJ. The ignition energy decreased with the increase of the cyclopentane gas concentration. The cyclopentane gas concentration up to about 5300 ppm did not influence too much on the explosion index (Kst) and maximum explosion pressure. From these, it would be a good way to increase the relative humidity and to regulate the cyclopentane concentration in the shredding process to prevent the dust explosion hazard.  相似文献   

13.
In general terms, the purpose of any safety standard is to define borderlines between safe and unsafe conditions, with reasonable safety margins. The electrical spark ignition sensitivity of dust clouds (MIE) varies over at least eight orders of magnitude. Therefore, in the case of intrinsically safe electrical apparatus to be used in the presence of explosive dust clouds, substantial differentiation of the minimum requirements to prevent ignition by electrical sparks is needed. The present paper proposes a method by which adequate differentiation of required maximum permissible currents and/or voltages in intrinsically safe electrical circuits to be used in explosive dust clouds can be achieved. In essence, the concept is to use conservative first-order ignition curves, calculated or estimated from the experimental MIE value of clouds in air of the actual dust. Charts to be used for design purposes are given in the paper. Internationally standardised test methods allow MIE for clouds of any dust to be determined, at least down to the range of a few mJ. There is, however, a need for a supplementary method covering the range of lower energies, down to 0.01 mJ.  相似文献   

14.
6氨基青霉烷酸(6-APA)是生产阿莫西林的重要中间体,在生产过程的离心机分离及干燥等环节存在粉体燃烧爆炸的危险。利用Hartmann管式粉尘最小点火能测试装置,研究6-APA干粉状态及丙酮存在环境粉体最小点火能变化规律。实验结果表明,6-APA粉体在分散质量为0.6g时,最小点火能为14mJ,参照VDI2263的规定,属于一般着火敏感性粉尘。向粉体中加入丙酮溶剂模拟实际生产环境,实验结果显示粉尘云最小点火能下降明显,且混合物着火能力增强。质量为1g的6-APA粉体与0.5mL丙酮溶剂配比条件下,混合物分散质量为0.6g时,最小点火能为6mJ,在此环境中混合粉体属于特别着火敏感性粉尘。实验结果阐明了6-APA在丙酮存在环境条件下混合粉体燃烧的爆炸危险性,为采取相应的爆炸防护措施提供了实验依据。  相似文献   

15.
Current standard test methods for electric-spark minimum ignition energies (MIEs) of dust clouds in air require that a series inductance of at least 1–2 mH be included in the electric-spark discharge circuit. The reason is to prolong the spark discharge duration and thus minimize the spark energy required for ignition. However, when assessing the minimum electrostatic energy ½CU2 for dust cloud ignition by accidental electrostatic-spark discharges, current testing standards require that the series inductance of at least 1–2 mH be removed from the spark discharge circuit. No other changes of apparatus and test procedure are required. The present paper questions whether this simple approach is always adequate. The reason is that in practice in industry accidental electrostatic-spark discharge circuits may contain large ohmic resistances due to corrosion, poor electrical grounding connections, poorly electrically conducting construction materials etc. The result is increased spark discharge durations and reduced mechanical disturbance of the dust cloud by the blast wave emitted by the spark. Therefore, testing for minimum ½CU2 for ignition by accidental electrostatic spark discharges may not only require removal of the series inductance of 1–2 mH from the standard MIE spark discharge circuit. Additional tests may be needed with one or more quite large series resistances Rs inserted into the spark discharge circuit. The present paper proposes a modified standard test procedure for measurement of the minimum electrostatic-spark ignition energy of dust clouds that accounts for these effects.  相似文献   

16.
An experimental program has been undertaken to investigate the explosibility of selected organic dusts. The work is part of a larger research project aimed at examination of a category of combustible dusts known as marginally explosible. These are materials that appear to explode in laboratory-scale test chambers, but which may not produce appreciable overpressures and rates of pressure rise in intermediate-scale chambers. Recent work by other researchers has also demonstrated that for some materials, the reverse occurs – i.e., values of explosion parameters are higher in a 1-m3 chamber than one with a volume of 20 L. Uncertainties can therefore arise in the design of dust explosion risk reduction measures.The following materials were tested in the current work: niacin, lycopodium and polyethylene, all of which are well-known to be combustible and which cover a relatively wide range of explosion consequence severity. The concept of marginal explosibility was incorporated by testing both fine and coarse fractions of polyethylene. Experiments were conducted at Dalhousie University using the following equipment: (i) Siwek 20-L explosion chamber for determination of maximum explosion pressure (Pmax), volume-normalized maximum rate of pressure rise (KSt), and minimum explosible concentration (MEC), (ii) MIKE 3 apparatus for determination of minimum ignition energy (MIE), and (iii) BAM oven for determination of minimum ignition temperature (MIT). Testing was also conducted at Fauske & Associates, LLC using a 1-m3 explosion chamber for determination of Pmax, KSt and MEC. All equipment were calibrated against reference dusts, and relevant ASTM methodologies were followed in all tests.The explosion data followed known trends in accordance with relevant physical and chemical phenomena. For example, Pmax and KSt values for the fine sample of polyethylene were higher than those for the coarse sample because of the decrease in particle size. MEC values for all samples were comparable in both the 20-L and 1-m3 chambers. Pmax and KSt values compared favorably in the different size vessels except for the coarse polyethylene sample. In this case, KSt determined in a volume of 1 m3 was significantly higher than the value from 20-L testing. The fact that the 20-L KSt was low (23 bar m/s) does not indicate marginal explosibility of the coarse polyethylene. This sample is clearly explosible as evidenced by the measured values of MEC, MIE, MIT, and 1-m3 KSt (at both 550 and 600 ms ignition delay times).  相似文献   

17.
The knowledge of the ignition behavior of dust–air mixtures due to electrical sparks (MIE, Minimum Ignition Energy) and hot surfaces (MIT, Minimum Ignition Temperature) is important for risk assessments in chemical production plants. The ignition behavior determines the extent and hence the cost of preventive protection measures.This paper describes the use of the minimum ignition energy and minimum ignition temperature as very important safety indexes in practice.  相似文献   

18.
为准确评价高密度聚乙烯(HDPE)粉尘爆炸敏感性和开展有效的粉尘防爆工作,采用Godbert-Greenwald恒温炉标准实验装置研究了典型HDPE粉尘云最低着火温度的分布特性,着重探讨了粉尘云浓度对不同喷尘压力条件下HDPE粉尘云最低着火温度的影响规律。研究表明:测试条件下HDPE粉尘云最低着火温度的变化处于360~445 ℃范围,随粉尘云浓度的增加呈现先降低后升高的总体趋势,粉尘云浓度为1.111 kg/m3时出现拐点,且粉尘云最低着火温度随喷尘压力的增加而降低。  相似文献   

19.
Powdery materials such as metallic or polymer powders play a considerable role in many industrial processes. Their use requires the introduction of preventive safeguard to control the plants safety. The mitigation of an explosion hazard, according to the ATEX 137 Directive (1999/92/EU), requires, among other things, the assessment of the dust ignition sensitivity. PRISME laboratory (University of Orléans) has developed an experimental set-up and methodology, using the Langlie test, for the quick determination of the explosion sensitivity of dusts. This method requires only 20 shots and ignition sensitivity is evaluated through the E50 (energy with an ignition probability of 0.5). A Hartmann tube, with a volume of 1.3 l, was designed and built. Many results on the energy ignition thresholds of partially oxidised aluminium were obtained using this experimental device (Baudry, 2007) and compared to literature. E50 evolution is the same as MIE but their respective values are different and MIE is lower than E50 however the link between E50 and MIE has not been elucidated.In this paper, the Langlie method is explained in detail for the determination of the parameters (mean value E50 and standard deviation σ) of the associated statistic law. The ignition probability versus applied energy is firstly measured for Lycopodium in order to validate the method. A comparison between the normal and the lognormal law was achieved and the best fit was obtained with the lognormal law.In a second part, the Langlie test was performed on different dusts such as aluminium, cornstarch, lycopodium, coal, and PA12 in order to determine E50 and σ for each dust. The energies E05 and E10 corresponding respectively to an ignition probability of 0.05 and 0.1 are determined with the lognormal law and compared to MIE find in literature. E05 and E10 values of ignition energy were found to be very close and were in good agreement with MIE in the literature.  相似文献   

20.
Explosion characteristics of micron- and nano-size magnesium powders were determined using CSIR-CBRI 20-L Sphere, Hartmann apparatus and Godbert-Greenwald furnace to study influence of particle size reduction to nano-range on these. The explosion parameters investigated are: maximum explosion pressure (Pmax), maximum rate of pressure-rise (dP/dt)max, dust explosibility index (KSt), minimum explosible concentration (MEC), minimum ignition energy (MIE), minimum ignition temperature (MIT), limiting oxygen concentration (LOC) and effect of reduced oxygen level on explosion severity. Magnesium particle sizes are: 125, 74, 38, 22, 10 and 1 μm; and 400, 200, 150, 100, 50 and 30 nm. Experimental results indicate significant increase in explosion severity (Pmax: 7–14 bar, KSt: 98–510 bar·m/s) as particle size decreases from 125 to 1 μm, it is maximum for 400 nm (Pmax: 14.6 bar, KSt: 528 bar·m/s) and decreases with further decrease of particle size to nano-range 200–30 nm (Pmax: 12.4–9.4 bar, KSt: 460–262 bar·m/s) as it is affected by agglomeration of nano-particles. MEC decreases from 160 to 30 g/m3 on decreasing particle size from 125 to 1 μm, its value is 30 g/m3 for 400 and 200 nm and 20 g/m3 for further decrease in nano-range (150–30 nm). MIE reduces from 120 to 2 mJ on decreasing the particle size from 125 to 1 μm, its value is 1 mJ for 400, 200, 150 nm size and <1 mJ for 50 and 30 nm. Minimum ignition temperature is 600 °C for 125 μm magnesium, it varies between 570 and 450 °C for sizes 38–1 μm and 400–350 °C for size range 400–30 nm. Magnesium powders in nano-range (30–200 nm) explode less violently than micron-range powder. However, likelihood of explosion increases significantly for nano-range magnesium. LOC is 5% for magnesium size range 125–38 μm, 4% for 22–1 μm, 3% for 400 nm, 4% for 200, 150 and 100 nm, and 5% for 50 and 30 nm. Reduction in oxygen levels to 9% results in decrease in Pmax and KSt by a factor of 2–3 and 4–5, respectively, for micron as well as nano-sizes. The experimental data presented will be useful for industries producing or handling similar size range micron- and nano-magnesium in order to evaluate explosibility of their magnesium powders and propose/design adequate safety measures.  相似文献   

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