分光光度法测定COD_(Cr)的试验条件选择

用分光光度法测定水中化学需氧量ＣＯＤＣｒ,通过正交试验选择氧化的最佳选择。试验结果表明对ＣＯＤＣｒ值为５０～１０００ｍｇ／Ｌ的水样：氧化剂Ｋ２Ｃｒ２Ｏ７用量为０．２０～０．４０ｍｏｌ／Ｌ,催化剂Ａｇ２ＳＯ４用量为１０ｇ／ＬＨ２ＳＯ４,消解时间１０ｍｉｎ,加热温度１８０℃。用ＣＯＤＣｒ为１３８ｍｇ／Ｌ的质控标样进行验证试验,其绝对误差为０．５～３．０ｍｇ／Ｌ。与标准方法相比用分光光度法测定ＣＯＤＣｒ具有分析误差小,省时、省力,节约药剂的特点。     

COD_(Cr)测定中排除氯离子干扰的进一步探讨

废水中化学需氧量的测定采用重铬酸钾法［１］,大多数情况下都存在Ｃｌ－干扰,其排除方法用ＨｇＳＯ４掩蔽,通过实验探讨不用剧毒药品ＨｇＳＯ４掩蔽Ｃｌ－的干扰,而用ＣＯＤＣｒ总量减去Ｃｌ－的量。实验结果表明：当测定化学需氧量较低而Ｃｌ－含量高的水样时,即使采用掩蔽Ｃｌ－也会产生较大的误差,而用测定值减去０．２２６［Ｃｌ－］之值更接近真值。     

奶牛场废水处理技术研究

本文对奶牛场废水处理工艺进行了研究。结果表明,奶牛场废水经混凝处理后,ＣＯＤｃｒ 从２０１０ ｍｇ／Ｌ 下降到５６３ｍｇ／Ｌ～６９１ ｍｇ／Ｌ,ＮＨ３ － Ｎ 可从７１ ｍｇ／Ｌ 下降到２５ ｍｇ／Ｌ～３３ ｍｇ／Ｌ,ＣＭ 从１８０ 度下降到４０ 度～７０ 度。如采用混凝表面曝气处理工艺,可使奶牛场废水达到国家排放标准,且处理工艺简单、投资少、运行费低、易操作管理     

人工湿地系统植物床内CODcr动态变化规律探讨

人工湿地处理污水系统植物床内各监测点的上、下层 Ｃ Ｏ Ｄｃｒ值虽有一定的差别,但经过成对平均数比较分析发现这种差别并未形成明显的趋势。污水在植物床基质中流动时,随着迁移距离的延长,其中的 Ｃ Ｏ Ｄｃｒ的降解速率呈现先快后慢的趋势,根据形成的动态变化曲线,建立了 Ｃ Ｏ Ｄｃｒ在植物床内沿程动态变化模型： Ｃ Ｌ＝ Ｃｏｅｘｐ（４６２９×１０－ ５ Ｌ２－ ００１５６７ Ｌ,０≤ Ｌ≤１００）。经验证,模型预测值与实际监测值呈非常显著相关（ｄｆ＝ ４,ｒ≥０９９４６＞ ｒ００００５（４）,ｒ００００５（４）＝ ０９７４１）。     

测定污水中CODCr回流时间的探讨

测定污水中ＣＯＤｃｒ回流时间的探讨肖建寅，吴平胜（珠海市政管理处，珠海５１９０１５）化学需氧量（ＣｈｇｇｉＣＣＩＯＸｙｇｅｎＤｅｍａｎｄ，简称ＣＯＤ）是指水体中易被强氧化剂氧化的还原性物质所消耗氧化剂的量，结果折算成氧的量（以ｍｇ／Ｌ计）。而以酸性介...     

UASB—Fe反应器处理城市污水中试研究

本文对ＵＡＳＢ－Ｆｅ装置处理城市污水进行了中试研究，结果表明，当厌氧ＨＲＴ３－４小时，进水浓度总ＣＯＤｃｒ为２４１．２－４０２．３ｍｇ／ｌ，溶ＢＯＤ５为８０．６－１３６．８ｍｇ／ｌ，ＳＳ为１７０．８－１８９．８ｍｇ／ｌ时，其平均去除率依次为４２．１－５６．６％，６４．０－３９．８％和７２．９－６５．４％。讨论了厌氧ＨＲＴ，进水浓度，温度等因子对厌氧处理效果的影响情况。浅析了铁填料层在城市污水处理中     

无污泥化生物技术在真丝染色综合废水处理中的研究及应用

本文主要对真丝染色综合废水Ａ／Ｏ处理中所产生的污泥进行无污泥化生物处理的研究,并把技术运用在日处理９００ｔ／ｄ的综合废水生化处理装置上,设施经四年连续运行表明：出水ｐＨ＝７． ３６,ＳＳ＝４８ｍｇ／１,ＣＯＤｃｒ＝９５ｍｇ／１,ＢＯＤ５＝３８ｍｇ／１,ＮＨ３－Ｎ＝１８ ．８ｍｇ／１,出水水质指标全部达到国家规定的排放标准,该技术不仅解决了污泥的难治理问题,而且利用生物技术彻底解决了污泥的二次污染问题,还节约了可观的运行费用和投资费用,并提高了Ａ／Ｏ的处理效果。     

COD分光光度法与标准方法对比实验

ＣＯＤｃｒ分光光度快速测定法具有简便，快速，节能，省试剂等优点。其测定结果与标准方法之间有良好的可比性，最低检测限为５．０ｍｇ／ｌ 。     

工业燃煤锅炉大气污染物控制技术

工业燃煤锅炉大气污染物控制技术ＰＯＬＬＵＴＩＯＮＣＯＮＴＲＯＬＦＯＲＩＮＤＵＳＴＲＩＡＬＣＯＡＬ－ＦＩＲＥＤＢＯＩＬＥＲＳＳｉｇｎｉｆｉｃａｎｔｐｒｏｇｒｅｓｓｈａｓｂｅｅｎｍａｄｅｉｎｃｏｎｔｒｏｌｌｉｎｇａｉｒｐｏｌｌｕｔｉｏｎ（ｅ．ｇ．ｐａｒｔ...     

新型防锈、防垢、防污水处理器－ION－CLEAN

新型防锈、防垢、防污水处理器一ＩＯＮ一ＣＬＥＡＮＮｃｗＡｎｔｉ－Ｒｕｓｔ．Ａｎｈ－ＳｃａｌｅａｎｄＡｎｔｉ－ＳｅｗａｔｅＤｅｖｉｓｅ－Ｄｅｖｉｃｅ－ＩＯＮ－ＣＬＥＡＮ日本ＳＶＮ－ＷＡＲＤ公司日前在北京作了关于ＩＯＮ－ＣＬＥＡＮ水处理器的技术介绍。该处...     

重铬酸钾法测定化学需氧量的实验条件优化

以降低成本、减少二次污染、提供多元化实验条件为主要出发点,开展GB 11914-89中氯离子掩蔽剂加入量和催化剂种类等优化实验研究。结果表明:采用按比例加入的方式可以降低硫酸汞使用量,m[HgSO4]:m[Cl-]=10∶1即可达到有效掩蔽效果;在标准样品、地表水和一般废水的COD测定中,硫酸镍、硫酸铝钾和磷酸二氢锰作为硫酸银的替代物具有一定的可行性,建议最低加入量为4g/L。     

微生物菌剂在酿酒废水处理中的应用研究

采用厌氧－好氧工艺,结合微生物菌剂对酿酒废水进行了处理研究。进水CODCr浓度可达到8,456.3-22,442.0mg/L,BOD55,040.0-9.557.1mg/L,pH3-4,可不调pH,采用微生物菌剂接种可启动厌氧反应器,COD有机负荷最高达到10.2gCOD/Ld,COD去除率稳定在91－95％,BOD去除率90－94％,出水pH6.6-7.1,出水CODCr在2,000mg/L以下,BOD5800mg/L以下。厌氧污泥可全部颗粒化。好氧处理系统中接种微生物菌剂,曝气10－12小时,可保证出水中CODCr在230mg/L以下,甚至直接达到国家一级排放标准。微生物菌剂的应用是取得该处理效果的关键。     

Treatment of low-strength soluble wastewater using an anaerobic baffled reactor (ABR)

Treatment of low-strength soluble wastewater (COD approximately 500 mg/L) was studied using an eight chambered anaerobic baffled reactor (ABR). At pseudo steady-state (PSS), the average total and soluble COD values (COD(T) and COD(S)) at 8h hydraulic retention time (HRT) were found to be around 50 and 40 mg/L, respectively, while at 10h HRT average COD(T) and COD(S) values were of the order of 47 and 37 mg/L, respectively. COD and BOD (3 day, 27 degrees C) removal averaged more than 90%. Effluent conformed to Indian standards laid down for BOD (less than 30 mg/L). Reactor effluent characteristics exhibited very low values of standard deviation indicating excellent reactor stability at PSS in terms of effluent characteristics. Based on mass balance calculations, more than 60% of raw wastewater COD was estimated to be recovered as CH(4) in the gas phase. Compartment-wise profiles indicated that most of the BOD and COD got reduced in the initial compartments only. Sudden drop in pH (7.8-6.7) and formation of volatile fatty acids (VFA) (53-85 mg/L) were observed in the first compartment due to acidogenesis and acetogenesis. The pH increased and VFA concentration decreased longitudinally down the reactor. Residence time distribution (RTD) studies revealed that the flow pattern in the ABR was neither completely plug-flow nor perfectly mixed. Observations from scanning electron micrographs (SEM) suggest that distinct phase separation takes place in an ABR.     

车载巡回式UV／Fenton装置处理小城镇垃圾渗滤液

为了研究车载巡回处理装置对小城镇垃圾渗滤液的处理效果,采用自制的UV-Fenton试验装置研究了pH值、FeSO_4剂量、反应时间等因素对处理效果的影响,结果表明:最佳pH值为4.0,进水中COD为825 mg/L时,FeSO_4和H_2O_2的投加量分别为0.008 mol/L和0.08 mol/L,此时COD去除率72.22%,出水COD为216 mg/L;随着FeSO_4投加量缓慢增加到一定程度后转而下降,FeSO_4最佳投加量为0.008 mol/L;不同H_2O_2和Fe~(2+)配比对COD去除效果具有影响,(10:1)时为最佳配比。经过氨吹脱和混凝沉淀预处理的渗滤液采用UV/Fenton处理工艺,出水中COD可以达到《生活垃圾填埋场污染控制标准》(GB 16889-1997)中二级标准。     

Use of constructed wetland systems with Arundo and Sarcocornia for polishing high salinity tannery wastewater

Treatment of tannery wastewater is problematic due to high and variable concentrations of complex pollutants often combined with high salinity levels. Two series of horizontal subsurface flow constructed wetlands (CWs) planted with Arundo donax and Sarcocornia fruticosa were set up after a conventional biological treatment system operating at a tannery site. The aim of the CWs was polishing organics and nitrogen from the high salinity effluent (2.2-6.6?g Cl(-)?L(-1)). Both plant species established and grew well in the CW. Arundo, however, had more vigorous growth and a higher capacity to take up nutrients. The CWs were efficient in removing COD and BOD(5) with removal efficiencies varying between 51 and 80% for COD (inlet: 68-425?mg?L(-1)) and between 53 and 90% for BOD(5) (inlet: 16-220?mg?L(-1)). Mass removal rates were up to 615?kg COD ha(-1)?d(-1) and 363 BOD(5) kg?ha(-1)?d(-1). Removal efficiencies were 40-93% for total P, 31-89% for NH(4)(+) and 41-90% for Total Kjeldahl Nitrogen. CW systems planted with salt tolerant plant species are a promising solution for polishing saline secondary effluent from the tannery industry to levels fulfilling the discharge standards.     

硫酸盐生物还原的限制性生态因子的影响研究

利用厌氧颗粒污泥对烟气中SO2吸收生成的硫酸盐或亚硫酸盐废水进行处理，考察起始SO4^2-质量浓度、初始COD／SO4^2-、初始pH、接种污泥质量、亚铁离子等限制性生态因子对硫酸盐还原的影响。结果表明：在起始SO4^2-质量浓度800mg／L，初始COD／SO4^2-为3．0，pH值为7．0，接种污泥质量为31．10gVSS／L，添加亚铁离子的条件下，进行半连续试验，硫酸根去除率可迭70％。表明在COD／SO4^2-较低的条件下，各生态因子综合作用下，硫酸盐还原可得较好效果。     

Application of Eichhornia crassipes and Pistia stratiotes for treatment of urban sewage in Israel

The effectiveness of sewage purification by aquatic plants, such as water hyacinth (Eichhornia crassipes) and water lettuce (Pistia stratiotes), was tested on laboratory and pilot scales. Cascade and semi-continuous pilot experiments verified that the plants are capable of decreasing all tested indicators of water quality to levels that permit the use of the purified water for irrigation of tree crops. This applies to biochemical oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), and turbidity. The laboratory-scale tests confirm the capacity of the plants to reach and hold reasonably low levels of BOD (5-7 mg L(-1)) and COD (40-50 mg L(-1)) and very low levels of TSS (3-5 mg L(-1)) and turbidity (1-2 NTU). In the experimental pilot setup, with circulation, COD decreased from 460 to 100 mg L(-1) after 2.5-4 days of treatment, while 6-7 days were required to this end without circulation. This doubled the active pond area and provided a two-level hydraulic loading (8 and 12 L min(-1)) with circulation that proved to be effective during the summer as well as the winter season. The outflow concentrations were 50-85 mg L(-1) of COD and 4-6 mg L(-1) of BOD. The results show that the use of this free water surface flow system (FWS) and its low maintenance system for treatment of urban and agricultural sewage is a viable option.     

新型除磷混凝剂的研制与应用＊

实验以处理金属表面所产生的磷化废水为研究对象,系统地分析了在新型混凝剂的使用过程中,pH值、温度、石灰投入量、沉降时间、助剂A等因素对脱磷效果的影响。结果表明,含磷量为18mg/L、COD为300mg/L、SS为150mg/L、pH值为5.7～6.5的废水,石灰投入量为300mg/L、沉降时间为10min左右、温度为25℃、pH值调节至9.0、加入5mL助剂A处理后,废水中磷含量为0.25～0.35mg/L、COD为80mg/L、SS为60mg/L,满足《污水综合排放标准》(GB8978—1996)中的一级标准。