How green are the chemicals used as liquid fuels in direct liquid-feed fuel cells?

How green are the chemicals used as liquid fuels in the direct liquid-feed fuel cells intended to mobile, portable applications? Is there any risk of using such fuels? The present paper tries to give indications of answer to these questions while tackling the green chemistry concept, the liquid fuels (i.e. anodic oxidation, inherent hazards and renewability), the reaction products and by-products. The discussion especially focuses on green chemists' critical remarks and the green chemistry principles. Globally none of the liquid fuels appears to be green in terms of toxicity even if most could be produced from renewable raw materials. However this does not necessarily mean that the direct liquid-feed fuel cell technology is not green. The greenness of the direct liquid-feed fuel cell will also depend on its reliability and safety.     

Indicator framework for sustainable production planning and controlling

Production facilities serve to transform raw materials into products, usually with the goal of achieving a designated output, in terms of quantity and quality, with the minimum of cost and labour. With the aid of production planning and controlling (PPC) systems, raw material inputs, and labour can be planned to achieve a determined output of products. In general, the role of environmental and social aspects is neglected in production planning processes. Because of the growing pressure from politics and customers, sustainable production of products is becoming more important. One possibility for supporting sustainable manufacturing is, to integrate sustainable aspects in the production planning process. This paper presents input and output information for current PPC systems and discusses the need for additional information necessary for sustainable PPC. For this approach, a text review of cooperate social responsibility (CSR) reporting indicators provided by the GRI was performed. Based on the text review, an input-output model has been developed for conventional and another one for sustainable PPC systems. Through the comparison of the two input-output models, challenges and requirements for sustainable PPC systems have been defined as a basis for future work and analyses.     

Developing a fuzzy linear programming model for locating recovery facility in a closed loop supply chain

In this research a closed loop supply chain is designed which incorporates reverse logistics and forward logistic system simultaneously. In the design of reverse logistic system, recovery options are embedded in traditional supply chain for treating returned products. The recovery system includes collection centres, remanufacturing plants and disposal centres. Since the product return is supply driven, there is an uncertainty about it. In the proposed configuration for closed loop supply chain, the optimised configuration for supply chain in terms of locating recovery plants is developed. Accordingly, a fuzzy mixed integer linear programming model develops to deal with the uncertainty of returning products by customers. A general-purpose solver (LINGO 8.0) and a Meta heuristic approach (genetics algorithm) are implemented to solve the proposed model. The answers are compared by defining indexes and then the optimal answer, configuration and variables are identified. This solution will suggest a new design of supply chain network in which waste of materials is minimised and the new raw materials are necessary only when the used products may not be recovered by recovery options.     

Increased functionality of methyl oleate using alkene metathesis

A series of alkene cross-metathesis reactions were performed using a homogeneous ruthenium-based catalyst. Using this technology, a variety of functional groups can be incorporated into the bio-based starting material, methyl oleate. Trans-stilbene, styrene, methyl cinnamate and hexen-3-ol have all been shown to give desirable products. Using this technology, aromatics, alcohols or additional esters can be incorporated into the products. For example, the cross-metathesis reaction of methyl oleate with methyl cinnamate by the second-generation Grubbs catalyst showed 70% conversion of methyl oleate into products where half of the observed products contain an aromatic group and over one-third of the products contain an α,β-unsaturated methyl ester. This promising green route is versatile, and with an appropriate selection of starting materials, it is applicable to the synthesis of polymer precursors, industrial fluids or any other application where the upgrade of natural oils is necessary.     

Health and environmental impacts of a fertilizer plant--Part I: assessment of radioactive pollution

The aim of the first part of this investigation is to assess the radioactive pollution caused by a production plant of complex fertilizers (that is to say containing nitrogen, phosphorus and, in some cases, potassium). Firstly, the authors determine the concentrations of natural radioactivity present in raw materials, end products and wastes of the industrial plant. Then, they carry out an assessment of radioactive releases into the atmosphere, hydrosphere and lithosphere as well as of their significance from the environmental point of view. The second part of the investigation will be aimed at assessing the annual effective doses to plant workers and to members of the population surrounding the industrial site.     

Construction of Circular Economy Industrial System

It is difficult to realize the transformation from traditional economy industrial system to circular economy industrial system. Regarding primary raw materials as the indicators, the industrial system has been specified according to the divergence among the indicators and the circular utilization modes. In comparison with the association among industrial systems, the relationship among industrial sub-systems is named as industrial cross-linking in this paper. The industrial system which could completely utiLize and recycle the indicators shouM be increased and strengthened, and the circular economy industrial system with complete industrial association and industrial cross-linking should also be constructed. Taking the development of circular agricultural system basing on the traditional agricultural system as an example, the traditional agricultural products are regarded as the indicators which have been divided into foodstuff and crop straws which are used to produce food and articles for use, Like fertilizer, energy and papers etc. The way to construct the circular agricultural industrial system is to increase the industrial systems that could utilize the products generated from crop straws, feces and other castoffs and transform the wastewater and other trucks into environmental friendly products. It has also been pointed out that the construction of circular economy industrial system is conducive to the foundation of circular industrial economics and the establishment of the construction layout of circular economy and the application schemes. Suggestions to the theoretical and practical work of the next step have also been brought forward in this paper.     

Radon exhalation of cementitious materials made with coal fly ash: Part 1--scientific background and testing of the cement and fly ash emanation

Increased interest in measuring radionuclides and radon concentrations in fly ash, cement and other components of building products is due to the concern of health hazards of naturally occurring radioactive materials (NORM). The current work focuses on studying the influence of fly ash (FA) on radon-exhalation rate (radon flux) from cementitious materials. The tests were carried out on cement paste specimens with different FA contents. The first part of the paper presents the scientific background and describes the experiments, which we designed for testing the radon emanation of the raw materials used in the preparation of the cement-FA pastes. It is found that despite the higher (226)Ra content in FA (more than 3 times, compared with Portland cement) the radon emanation is significantly lower in FA (7.65% for cement vs. 0.52% only for FA).     

Construction of Circular Economy Industrial System

Abstract

It is difficult to realize the transformation from traditional economy industrial system to circular economy industrial system. Regarding primary raw materials as the indicators, the industrial system has been specified according to the divergence among the indicators and the circular utilization modes. In comparison with the association among industrial systems, the relationship among industrial sub-systems is named as industrial cross-linking in this paper. The industrial system which could completely utilize and recycle the indicators should be increased and strengthened, and the circular economy industrial system with complete industrial association and industrial cross-linking should also be constructed. Taking the development of circular agricultural system basing on the traditional agricultural system as an example, the traditional agricultural products are regarded as the indicators which have been divided into foodstuff and crop straws which are used to produce food and articles for use, like fertilizer, energy and papers etc. The way to construct the circular agricultural industrial system is to increase the industrial systems that could utilize the products generated from crop straws, feces and other castoffs and transform the wastewater and other trucks into environmental friendly products. It has also been pointed out that the construction of circular economy industrial system is conducive to the foundation of circular industrial economics and the establishment of the construction layout of circular economy and the application schemes. Suggestions to the theoretical and practical work of the next step have also been brought forward in this paper.     

Radon exhalation of hardening concrete: monitoring cement hydration and prediction of radon concentration in construction site

The unique properties of radon as a noble gas are used for monitoring cement hydration and microstructural transformations in cementitious system. It is found that the radon concentration curve for hydrating cement paste enclosed in the chamber increases from zero (more accurately - background) concentrations, similar to unhydrated cement. However, radon concentrations developed within 3 days in the test chamber containing cement paste were approximately 20 times higher than those of unhydrated cement. This fact proves the importance of microstructural transformations taking place in the process of cement hydration, in comparison with cement grain, which is a time-stable material. It is concluded that monitoring cement hydration by means of radon exhalation method makes it possible to distinguish between three main stages, which are readily seen in the time dependence of radon concentration: stage I (dormant period), stage II (setting and intensive microstructural transformations) and stage III (densification of the structure and drying). The information presented improves our understanding of the main physical mechanisms resulting in the characteristic behavior of radon exhalation in the course of cement hydration. The maximum value of radon exhalation rate observed, when cement sets, can reach 0.6 mBq kg(-1) s(-1) and sometimes exceeds 1.0 mBq kg(-1) s(-1). These values exceed significantly to those known before for cementitious materials. At the same time, the minimum ventilation rate accepted in the design practice (0.5 h(-1)), guarantees that the concentrations in most of the cases will not exceed the action level and that they are not of any radiological concern for construction workers employed in concreting in closed spaces.     

河流型水源地源水有机物种类分布特性及其与消毒副产物关系

研究了不同水文期条件下长三角某典型河流型水源地源水有机物种类分布特性及其与消毒副产物关系。结果表明，该水源地源水有机污染特性呈现出丰水期>平水期>枯水期的特点，水体腐殖化程度依次降低。经树脂富集分离后水样溶解性有机物(DOM)各组分占总有机碳(DOC)的比例有所不同。丰水期：疏水性有机酸(HPO A,38%)>亲水性有机物(HPI,26%)>过渡亲水性有机酸(TPI A,16%)>疏水性有机中性物质(HPO N,12%)>过渡亲水性中性物质(TPI N,8%)；平水期：HPO A(32%)>HPO N(22%)>TPI A(20%)>HPI(18%)>TPI N(8%)；枯水期：HPO A(28%)>TPI A(24%)>HPO N(20%)>HPI(19%)>TPI N(9%)。DOM中仅HPI组分比紫外吸光度值(SUVA)低于原水，其余均高于原水，其中HPO A组分SUVA值最高，是原水的177倍。各水文期条件下，疏水性有机物（疏水性有机酸和疏水性中性物质）对三卤甲烷和卤乙酸生成的贡献，分别超过全部有机物氯化后消毒副产物生成量的60%和65%，表明疏水性有机物是最主要的消毒副产物前体物，应当作为水处理工艺重点去除的有机物组分。各水文期源水有机物特性与消毒副产物生成潜能的关系变化不大，三卤甲烷生成潜能(STHMFP)与SUVA的线性相关度较高，卤乙酸生成潜能(SHAAFP)与SUVA的线性相关度一般。因此，可用水样SUVA值间接反映三卤甲烷生成潜能，以利于在实际生产中快速监控水中消毒副产物前体物的变化趋势     

Carbon Footprint Analysis for Baby Strollers

Abstract

The increasing awareness of climate change has led organizations to demand a standard procedure to measure and communicate greenhouse gas (GHG) emissions linked to their products or services. The publicly available specification PAS 2050 has been developed in response to broad community and industry desire for a consistent method-carbon footprint for assessing the life cycle GHG emissions of goods and services. Specifically, this paper illustrates the implementation of carbon footprint for a baby stroller in accordance with PAS 2050. A fial value of 321 kg per one stroller including package was calculated. Moreover, the study led to identify raw materials production of the stroller as the main source of GHS emissions where efforts need to focus for emission reduction opportunities. This case study is hoped to be a starting point for organizations to benefit from the increasing application of carbon footprint assessment.     

Playing with fire: the global threat presented by brominated flame retardants justifies urgent substitution

Few would now deny that the use of organobromine compounds to achieve fire retardancy in a diverse array of products and materials has led to contamination of the ecosphere on a widespread scale. This environmental prevalence and persistence of the brominated flame retardants, coupled with growing evidence of their potential for harm, present all too familiar parallels with the previous generation of persistent organic pollutants. Indeed, given the intrinsic properties of these brominated chemicals, the nature and extent of the current problem could well have been predicted in advance. The question is then whether we are prepared to let history repeat itself once more or to take precautionary action now to switch to more sustainable alternatives. The choice facing society is not between brominated flame retardants and unsafe products, but between fire safety leading to global contamination or fire safety achieved in less polluting ways. If we look beyond options for simple chemical-for-chemical substitution to alternative materials and designs, many of the solutions are already available. The remainder could undoubtedly be developed given the incentives to do so. However, a strong and clear policy approach, backed by legislative phase-outs within specified (and challenging) timeframes, will be necessary to break our current dependency on organobromine chemistry. This paper presents the justification for such an approach, reviews those initiatives already underway to replace brominated flame retardants and identifies pathways to the use of more sustainable products in the service of society.     

Industrial complexes and their relevance for pulp and paper mills

Advantages and disadvantages of the concept of an industrial complex are discussed. From an environmental standpoint an ideal industrial complex is one containing a group of compatible industrial plants utilizing completely each other's wastes and products as raw materials and manufacturing products with no adverse environmental impact and at a minimum of cost. A typical complex centering about a pulp and papermill is pictured in this paper. This complex produces six products for external sale and four products for internal use. In addition, all major wastes of suspended solids, cooking liquor, fillers, heat and bark are reused within the complex in the manufacture of these products. A literature review evolved typical concentrations of recoverable suspended solids in various process effluents. A mass balance was prepared assuming that the total production of fine paper is 907.2 kg × 10³ (1000 tons) per day. Little or no air or water pollution results from this complex. In addition, it is anticipated that no expensive waste-water treatment plant would be required for this complex. Ten additional practices are described which, when used, will reduce operating costs even further. A continuing study with more precise data on the production requirements for the service plants in the complex will yield a more balanced and realistic system.     

中国液态生物质燃料产业发展的间接社会收益分析

液态生物质燃料在发展过程中具有外部性,体现出的间接社会收益应得到中国政府的重视,也是该产业扩大发展的重要依据。提出液态生物质燃料产业发展的间接社会收益概念,分析该产业在原料搜集和种植、产品消费等过程中产生的额外经济价值,以度量对改善生态环境的直接作用。在分析生物质燃料原料分布和理清原料搜集的细节后,利用直接市场法测算了未来20年中国发展液态生物质燃料的间接社会收益,发现：到2015年,来自该产业的间接社会收益将达1 000亿元以上,到2030年将突破1万亿元。巨大的社会经济价值从另一个侧面折射出液态生物质燃料产业发展的必要性     

Optimal site selection for fluting paper mill from agricultural wastes in Golestan Province,Iran

Today, the issue of site selection for industrial units in developing countries which are poor in wood resources is considered as a vital matter and it is one of the key measures in the process of building industrial and giving service units. In every country there are some provinces and states which are more useful than other parts owing to primary infrastructures and facilities for industrialisation. As one of the suitable provinces of Iran, thanks to its lignocelluloses resources with 1,822,696 tons of exploitable waste, Golestan Province has a very good potential for building lignocelluloses products mills, such as fluting paper. For this end, in 2010, effective indices in fluting paper mill establishment were recognised in Golestan Province. Results showed that materials and products were the most important main indices and the preparation cost of raw materials was the most important sub-index. Finally, questionnaires were prepared for the best site selection and choices were evaluated according to the structure of interests and costs. The results of calculations performed through analytical hierarchy processes and in Expert Choice Software indicated that Gonbad City had the highest interest/cost ratio, and therefore, it is the best place for the establishment of floating paper mills from agricultural wastes in Golestan Province.     

Technological Progress,Structural Change and China’s Energy Efficiency

Abstract

China has witnessed rapid economic development since 1978, and during the time, energy production and consumption developed at a tremendous speed as well. Energy efficiency which can be measured by energy consumption per unit of GDP, however, experienced continuous decrease. Theoretically, the change of energy efficiency can be attributed to industry structural change and technological change. In order to explain the transformation of Chinese energy efficiency, we adopt logarithmic mean Divisia index techniques to decompose changes in energy intensity in the period of 1994–2005. We find that technological change is the dominant contributor in the decline of energy intensity, but the contribution has declined since 2001. The change in industry structure has decreased the energy intensity before 1998, but raised the intensity after 1998. Decomposed technological effects for all sectors indicate that technological progresses in high energy consuming industries such as raw chemical materials and chemical products, smelting and pressing of ferrous metals, manufacture of non-metallic mineral products and household contribute are the principal drivers of China’s declining energy intensity.     

Natural radioactivity in refractory manufacturing plants and exposure of workers to ionising radiation

This paper shows the results of a survey carried out at some refractory manufacturing plants. During the first part of the survey, the concentration of natural radioactivity in raw materials and end-products, coming from four plants, was assessed. Several raw materials and, as a consequence, some end-products as well have shown activity concentrations exceeding a few hundreds of Bq kg⁻¹ of ²³⁸U and ²³²Th. In some important raw materials, such as bauxite and corundums, a remarkable radioactive disequilibrium was observed; this is probably due to the high temperature processes undergone by these materials. The second part of the survey focussed on the measurements of ambient equivalent dose rates, airborne dust concentrations and radon indoor. On the basis of results obtained, the effective dose for the standard worker was estimated. Two different types of refractory plants were investigated. Effective doses for both plants were lower than 1 mSv y⁻¹.     

Natural radionuclide content in building materials and gamma dose rate in dwellings in Cuba

An extensive research project to investigate the radioactive properties of Cuban building materials was carried out because there is a lack of information on the radioactivity of such materials in Cuba. In the framework of this project 44 samples of commonly used raw materials and building products were collected in five Cuban provinces. The activity concentrations of natural radionuclides were determined by gamma ray spectrometry using a p-type coaxial high purity germanium detector and their mean values were in the ranges: 9-857Bqkg(-1) for (40)K; 6-57Bqkg(-1) for (226)Ra; and 1.2-22Bqkg(-1) for (232)Th. The radium equivalent activity in the 44 samples varied from 4Bqkg(-1) (wood) to 272Bqkg(-1) (brick). A high pressure ionisation chamber was used to measure the indoor absorbed dose rate in 543 dwellings and workplaces in five Cuban provinces. The average absorbed dose rates in air ranged from 43nGyh(-1) (Holguín) to 73nGyh(-1) (Camagüey) and the corresponding population-weighted annual effective dose due to external gamma radiation was estimated to be 145+/-40microSv. This value is 51% lower than the effective dose due to internal exposure from inhalation of decay products of (222)Rn and (220)Rn and it is 16% higher than the calculated value for the typical room geometry of a Cuban house.     

Quantification of the influence of life cycle parameters on the total environmental impact of steel-framed buildings

Due to the increased urgency with which environmental issues are currently being prioritized, business sectors such as construction, that have been identified as one of the largest consumers of raw materials and energy, are actively involved in research aiming to optimize construction processes and products in terms of environmental impact. Although researchers have pointed out various issues and aspects of a construction project’s delivery process that can significantly affect its environmental impact, the extent to which these issues can influence the total environmental impact of the project is unclear. The current research aims to investigate and eventually quantify the influence of a number of such parameters, utilizing an existing steel-framed building as the basis for the necessary calculations. The conclusions drawn illustrate the actual extent of the influence of the examined life cycle parameters, while also offering specific insight in regard to the determination of criteria that can be used as the basis for recommendations for similar projects.     

Recycling – the importance of understanding the complexity of the issue

Natural resources and raw materials such as metals and minerals are often taken for granted in today’s society. Without them, the offerings of an enormous variety of modern conveniences, including computers and mobile phones, would not be possible. The production of these everyday items depends on a secure, sustainable, and reliable supply of critical raw materials. In addition, product development also requires new hybrid materials when targeting lightweight structures, etc. However, the mandatory recyclability of new products or materials is not obligatory or even prevailing practice in present manufacturing business. Therefore, the main research question in this article is: “how to solve the challenge of recycling in industrial system?” In this article, a comprehensive approach to recycling based on the findings of research projects is presented. Simplified, this involves moving the challenge from the end of the product’s life cycle to the beginning, to the design or even to material development phases. Life cycle and system thinking and material know-how in the design phase are found to be essential elements of a new approach to recycling. This approach stems from the material development and market economy perspectives. Furthermore, the vulnerability of the industrial system to create uncertainty to recycling is also demonstrated.