Phosphorus resources,their depletion and conservation,a review

Yearly, about 22 × 10¹² g phosphorus (P) from mined fossil phosphate resources are added to the world economy. The size of remaining fossil phosphate resources is uncertain but practically finite. Thus, fossil P resources may become depleted by ongoing mining. Despite calls for resource conservation, fossil P resources have been depleted at an increasing rate. Geographically, fossil P supply and demand are distributed in an increasingly uneven way, which has geopolitical consequences and may well affect security of supply. Current use of P gives rise to negative environmental impacts due to P losses from the economy and contaminants derived from fossil P resources. There may also be negative impacts on human health. Reducing the demand for fossil phosphorus may reduce environmental burdens and may improve the future security of supply. Technically speaking, there is much scope for the reduction of current demand for fossil P resources. Limiting consumption of P to essential uses, increased efficiency of agricultural use and increased recycling of P may substantially contribute to the reduction of demand for fossil P resources. Recycling of P has to face concerns regarding the efficiency of P recovery, pathogenic organisms and contaminating substances. Much work remains to be done to effectively address those concerns.     

Rainfall conditions and rainwater harvesting potential in the urban area of Khartoum

Runoff water management is among the inherent challenges which face the sustainability of the development of arid urban centers. These areas are particularly at risk from flooding due to rainfall concentration in few heavy showers. On the other hand, they are susceptible to drought. The capital of Sudan (Khartoum) stands as exemplary for these issues. Hence, this research study aims at investigating the potential of applying rainwater harvesting (RWH) in Khartoum City Center as a potential urban runoff management tool. Rapid urbanization coupled with the extension of impervious surfaces has intensified the heat island in Khartoum. Consequently, increased frequency of heat waves and dust storms during the dry summer and streets flooding during the rainy season have led to environmental, economical, and health problems. The study starts with exposing the rainfall behavior in Khartoum by investigating rainfall variability, number of raindays, distribution of rain over the season, probability of daily rainfall, maximum daily rainfall and deficit/surplus of rain through time. The daily rainfall data show that very strong falls of >30 mm occur almost once every wet season. Decreased intra- and inter-annual rainfall surpluses as well as increased rainfall concentration in the month of August have been taking place. The 30-year rainfall variability is calculated at decade interval since 1941. Increasing variability is revealed with 1981–2010 having coefficients of variation of 66.6% for the annual values and 108.8–118.0% for the wettest months (July–September). Under the aforementioned rainfall conditions, this paper then explores the potential of RWH in Khartoum City Center as an option for storm water management since the drainage system covers only 40% of the study area. The potential runoff from the 6.5 km² center area is computed using the United States Natural Resources Conservation Services method (US-NRCS), where a weighted Curve Number (CN) of 94% is found, confirming dominant imperviousness. Rainfall threshold for runoff generation is found to be 3.3 mm. A 24,000 m³ runoff generated from a 13.1 mm rainfall (with 80% probability and one year return period) equals the drainage system capacity. An extreme rainfall of 30 mm produces a runoff equivalent to fourfold the drainage capacity. It is suggested that the former and latter volumes mentioned above could be harvested by applying the rational method from 18% and 80% rooftops of the commercial and business district area, respectively. Based on the above results, six potential sites can be chosen for RWH with a total roof catchment area of 39,558 m² and potential rooftop RWH per unit area of 0.033 m³. These results reflect the RWH potential for effective urban runoff management and better water resources utilization. RWH would provide an alternative source of water to tackle the drought phenomenon.     

Characterization of pollutants in Florida street sweepings for management and reuse

Disposal and beneficial-use options for street sweeping residuals collected as part of routine roadway maintenance activities in Florida, USA, were assessed by characterizing approximately 200 samples collected from 20 municipalities. Total concentrations (mg/kg or μg/kg) and leachable concentrations (mg/L or μg/L) of 11 metals and a number of organic pollutant groups (volatile organics, semi-volatile organics, pesticides, herbicides, carbamates) in the samples were measured. The synthetic precipitation leaching procedure (SPLP) was performed to evaluate the leachability of the pollutants. From the total metal analysis, several metals (e.g., arsenic, barium, chromium, copper, nickel, lead, and zinc) were commonly found above their detection limits. Zinc was found to have the highest mean concentration of all metals measured (46.7 mg/kg), followed by copper (10.7 mg/kg) and barium (10.5 mg/kg). The metal with the smallest mean concentration was arsenic (0.48 mg/kg). A small fraction of the total arsenic, barium, lead, and zinc leached in some samples using the SPLP; leached concentrations were relatively low. A few organic compounds (e.g., 4,4′-DDT, endrin, and endosulfan II) were detected in a limited number of samples. When the total and leaching results were compared to risk-based Florida soil cleanup target levels and groundwater cleanup target levels, the street sweepings were not found to pose a significant human-health risk via direct exposure or groundwater contamination.     

Design and implementation study of a Permanent Selective Collection Program (PSCP) on a University campus in Brazil

The selective collection and recycling of municipal solid waste are presented as stages of an integrated program of solid waste management to minimize the environmental impact of the treatment and final disposal of solid waste. Therefore, this program aims to save natural resources, such as energy and raw materials, in the manufacture of new products and to conserve areas for sites, such as to minimize the use of existing landfill sites, and to minimize the need for new waste treatment sites. A university is composed of educational professionals aware of their societal responsibilities, and, therefore, they play a fundamental role in the management of the university's solid waste. This study presents the design and implementation of a Permanent Selective Collection Program (PSCP) at the Federal University of Itajubá (Universidade Federal de Itajubá, UNIFEI), Itajubá-MG, Brazil. The material requirements for initiating the PSCP have been identified, and an action plan for continuous program improvement, which is initially based on the collection of performance indicator data for the PSCP campus, has been developed. Finally, the data from the PSCP performance indicators and software from the United States Environmental Protection Agency, the Landfill Gas Generation Model (LandGEM) and the Waste Reduction Model (WARM), were used to evaluate the impact of implementing PSCP in terms of energy and the generation of greenhouse gases (GHG). The results were promising, showing that there has been an improvement, since the inception of PSCP in 2006, in separating materials for selective collection, even though paper (41.00 wt%), plastic (6.00 wt%) and organic matter (26.00 wt%) are still highly generated wastes. The WARM simulations for a scenario in which 90% of the waste is sent for recycling resulted in an economy of −7 tCO₂ or −74.91 GJ (on an energy basis). The LandGEM (USEPA) simulations estimated 1424.60 kWh of energy in the peak production year.     

Informed and uninformed public opinions on CO2 capture and storage technologies in the Netherlands

Two research methods were used in this study to analyze the awareness and perception of the Dutch general public regarding Carbon dioxide Capture and Storage (CCS). In an Information-Choice Questionnaire (ICQ), a representative sample of the Dutch public (n = 995) was provided with all information on attributes of six CCS options, which experts deemed necessary to come to well-considered and well-informed opinions. A traditional questionnaire was used simultaneously (n = 327) to study uninformed evaluations of these technologies. The results showed that the Dutch public is mostly unaware of CCS and has little knowledge about how current energy use causes global warming. Uninformed respondents are still inclined to give their opinion however, which results in unpredictive, easily changeable opinions. ICQ respondents who processed information on attributes of CCS options were likely to base their option evaluations on this information, though not entirely. All in all, the results of the ICQ suggest that, after processing information deemed necessary by experts, Dutch people reluctantly agree with large scale implementation of each of the six CCS options.     

The potential for increased atmospheric CO2 emissions and accelerated consumption of deep geologic CO2 storage resources resulting from the large-scale deployment of a CCS-enabled unconventional fossil fuels industry in the U.S.

Desires to enhance the energy security of the United States have spurred renewed interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO₂) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO₂ storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO₂ from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO₂ capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO₂ emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3 MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000 and 7000 MtCO₂, in addition to storing potentially 900–5000 MtCO₂ in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000–5000 MtCO₂ emitted to the atmosphere in addition to potentially 21,000–22,000 MtCO₂ stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO₂ storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nation's CO₂ storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.     

Farmland damage and its impact on the overlapped areas of cropland and coal resources in the eastern plains of China

The subsidence caused by coal mining in areas where cropland and coal resources overlap in the eastern plains of China with high ground water levels has caused large amounts of water to collect in cropland, significant damage to cropland, and a sharp contradiction between people and land distribution within this region. Systematic analysis and calculation were conducted on these areas by using GIS spatial overlay analysis technology, subsidence and occupied cropland estimation models, and crop yield reduction prediction model to reveal the overlapped characteristics and extent of farmland damage, as well as to evaluate the effects of farmland damage to grain yield, farmland landscape, agricultural population, and dynamical equilibrium of the total cultivated land. Results showed that the overlapped areas of cropland and coal resources on the eastern plains of China occupied an area covering 1.33 × 10⁵ km², which accounted for 31.93% of the total cropland area. In 2020, the accumulative total area of destroyed cropland reached 3.83 × 10³ km², thus reducing grain yield by 9.63 × 10⁸ kg, and increasing the number of landless farmers to 1.91 × 10⁶. Furthermore, the quality and production capacity of cultivated land decreased, farmland landscape patterns changed, land patterns and structures were adjusted, the dynamical equilibrium of the total cultivated land was difficult to guarantee, and social instability increased in coal mining subsidence areas. These findings provided a scientific basis for relevant government departments to enact countermeasures for the coordinative production of coal and grain.     

Quantifying the impacts of primary metal resource use in life cycle assessment based on recent mining data

The quantification of impacts in the abiotic resource category in life cycle assessment is still controversial. However, this is a pertinent issue because of the growing dependence of our industrial society on these resources, particularly on metal resources. One of the important shortcomings of the existing assessment methods used today is that characterization factors are not based on actual mining practice data. In this paper, a new characterization factor derived from recent (1998–2010) and representative (more than 50% coverage of global primary metal production) mining data was established for nine metals: copper, zinc, lead, nickel, molybdenum, gold, silver, platinum and palladium. The quantification of this new characterization factor is based on the annual increase in mass of ore required per unit mass of metal in the ore. This quantification relies on the concept that the mining of resources is threatened not by lack of ores but by changing ore characteristics, e.g., the percentage of metal in the ore, mineral type and location. The characterization factors determined in this study ranged from below 0.1 kg ore kg⁻¹ y⁻¹ for zinc to more than 15,000 kg ore kg⁻¹ y⁻¹ for gold. These results indicate that in 1999, 370,000 kg of ore was required per kg of gold in the ore, whereas in 2008, 530,000 kg of ore was required per kg of gold in the ore (an increase of approximately 4% per annum). When comparing these results with traditional life cycle impact assessment methods, it was found that in all but one method gold, palladium and platinum have the highest characterization factors among the nine metals. In all methods based on ore grade changes lead and zinc are the metals with the lowest characterization factors. However, an important difference in the proposed method is that it assigns higher relative values to precious metals. This suggests that the supply of precious metals may be under more pressure than indicated by other methods, which in the framework of the proposed method implies greater efforts in mining and mineral processing. There is still scope for improvement of the proposed method if more data become readily available.     

Butyltin occurrence and risk assessment in the sediments of the Iberian Peninsula

The occurrence of butyltin (BT) compounds in more than 50 recent sediment samples of the Iberian Peninsula, collected in the harbours of the western Mediterranean Sea (Spain) and the North Atlantic Ocean (Portugal), including domestic and industrial sewage disposal sites, has been assessed. The highest levels of tributyltin (TBT) (7673 μg kg^?1 dry wt.) were detected in commercial harbours associated with inputs from large vessels. However, relatively high TBT values (about 2150 μg kg^?1 dry wt.) were also detected in fishing and recreational boating areas. Spanish marinas and harbours are more polluted in terms of TBT (5–7673 μg kg^?1 dry wt.) compared to those in Portugal (4–12 μg kg^?1 dry wt.). Generally, the Mediterranean sediments show a BT distribution characterized by the predominance of TBT over the degradation products dibutyl (DBT) and monobutyltin (MBT), indicating the presence of recent inputs, in contrast to the Portuguese coastal distribution. Calculation of butyltin degradation indexes (BDI) confirmed a different trend, depending on the area. Furthermore, a comparative study of the occurrence of BT in different sewage sludge disposal sites shows that domestic primary sewage sludge effluents can contribute to coastal BT pollution, but to a lesser extent when compared with harbours. Historical trends (1995–2003) for Barcelona harbour reveal that BT regulations on the use of TBT-based antifouling paints have not been fully effective. Finally, a comparison against the existing sediment quality guidelines (SQGs) indicated that acute toxic effects could only be expected for TBT in some Mediterranean harbours; conversely, in every North Atlantic Ocean station, a lesser environmental threat for the harbour benthic community is expected.     

Rainwater harvesting planning using geospatial techniques and multicriteria decision analysis

Growing water scarcity and global climate change call for more efficient alternatives of water conservation; rainwater harvesting (RWH) is the most promising alternative among others. However, the assessment of RWH potential and the selection of suitable sites for RWH structures are very challenging for the water managers, especially on larger scales. This study addresses this challenge by presenting a fairly robust methodology for evaluating RWH potential and identifying sites/zones for different RWH structures using geospatial and multicriteria decision analysis (MCDA) techniques. The proposed methodology is demonstrated using a case study. The remote sensing data and conventional field data were used to prepare desired thematic layers using ArcGIS© software. Distributed Curve Number method was used to calculate event-based runoffs, based on which annual runoff potential and runoff coefficient maps were generated in the GIS (geographic information system) environment. Thematic layers such as slope, drainage density, and runoff coefficient and their features were assigned suitable weights and then they were integrated in a GIS to generate a RWH potential map of the study area. Zones suitable for different RWH structures were also identified, together with suitable sites for constructing recharge structures (check dams and percolation tanks along the streams). It was found that the study area can be classified into three RWH potential zones: (a) ‘good’ (241 km²), (b) ‘moderate’ (476 km²), and (c) ‘poor’ (287 km²). About 3% of the study area (30 km²) is suitable for constructing farm ponds, while percolation tanks (on the ground) can be constructed in about 2.7% of the area (27 km²). Of the 83 sites identified for the recharge structures, 32 recharge sites are specially suited to the inhabitants because of their proximity. It is concluded that the integrated geospatial and MCDA techniques offer a useful and powerful tool for the planning of rainwater harvesting at a basin or sub-basin scale.     

Impacts of experimental trampling on tall alpine herbfields and subalpine grasslands in the Australian Alps

The Australian Alps, which are of high conservation value, are popular summer bushwalking destinations. Experimental trampling trials using a standardized methodology were conducted to determine the resistance and resilience of the two common vegetation types: tall alpine herbfield and subalpine grasslands. Vegetation parameters were measured in lanes subject to control (no trampling), 30, 100, 200, 500 and 700 passes at five sites prior to trampling, immediately post trampling, 2 weeks, 6 weeks and 1 year post trampling. Vegetation height, cover of graminoids and herbs, as well as net species richness all declined with trampling, while litter cover increased. Thresholds for damage varied between the two communities and among the different vegetation parameters. The resistance indices for the two communities (number of passes resulting in 50% reduction in vegetation cover), however, were similar at around 440–450 passes indicating that these two communities are among the most resistant of the 19 alpine–subalpine communities that have been tested around the world, but only of moderate resistance compared to non-alpine communities. The two communities showed limited recovery with damage still evident 1 year post trampling. This indicates that they have only moderate tolerance to damage due to moderate resistance, but low resilience.     

The use of recycled metal in dentistry: Evaluation of mechanical properties of titanium waste recasting

Environmental concerns are increasing rapidly, and the public and industry are concerned about natural resources. The products are produced to meet the customer's demand as to quality. However, today it is equally important to take into account cost, ecological factors in production and recycling of products. The same way, the dentistry must contribution with a recasting the alloys used to rehabilitation oral.This study evaluated the effect of the condition of Ti (as-received and re-cast) on its mechanical properties, microstructure and fractography. Castings (n = 6) with Ti in the as-received and once recast condition were made in a centrifugal casting machine using a high-purity argon gas. The ultimate tensile strength (UTS), proportional limit (PL) and elongation (EL) of the as-received specimens were evaluated in a universal testing machine at a crosshead speed of 1 mm/min. The fractured specimens were polished down for Vicker's microhardness (VHN) measurement (100 g/15 s) from 25 μm below the cast surface, then at depths of 50, 100, 200 and 500 μm. The microstructures of the alloys were also revealed. Scanning electron microscopy fractography was undertaken for the fractured surfaces after testing. The data from the mechanical tests and hardness were subjected to the Student's t-test and two-way repeated measures ANOVA, respectively. Tukey's test was used for pairwise comparison (α = 0.05). Higher UTS, PL and VHN and lower EL were observed for recast cp Ti. The microstructure was not influenced by recasting, but the mode of fracture was.The use of the recasting procedure can lower the costs of cp Ti castings and can be safely in dentistry.     

Calcium oxide for CO2 capture: Operational window and efficiency penalty in sorption-enhanced steam methane reforming

Calcium oxide (CaO) is a material that is being widely investigated in the context of CO₂ capture. One such application is as a CO₂ sorbent in the sorption-enhanced steam methane reforming processes (SERP). CO₂ is captured in an adsorption mode, where the conversion of CH₄ to H₂ is also enhanced, and released later in a separate desorption mode. This work presents an analysis of the relation between different process conditions and parameters during both adsorption and desorption modes. The interrelation between these conditions and the sorbent properties as well as the targeted carbon capture ratio is analysed. Conditions relevant for capturing 85% of carbon in the feed on CaO are determined and interlinked. A steam-to-carbon ratio of 4.2 has been determined to be relevant under 600 °C and 17 bar adsorption conditions. Similarly, process conditions relevant for regenerating the sorbent are determined and interlinked. For purge steam-to-CO₂ ratio of 1.8 at a desorption pressure of 1 bar, relevant desorption temperature has been calculated to be 820 °C. System simulations under these adsorption and desorption conditions resulted in a system efficiency of 50.8%. Effect of tuning process operating conditions on system efficiency as well as the efficiency penalty associated with the regeneration of the sorbent are investigated by process simulations using Aspen Plus^®. Possible system heat integration routes to reduce the efficiency penalty are proposed and the results of the process simulations are presented.     

Approaches for analyzing local carbon mitigation strategies: Tompkins County,New York,USA

A carbon budget was calculated for Tompkins County, NY, a semi-rural upstate county with a population density of 78 pp/km². The costs and potential for several carbon mitigation options were analyzed in four categories: terrestrial C sequestration, local power generation, transportation, and energy end-use efficiency. This study outlines a methodology for conducting this type of local-scale analysis, including sources and calculations adaptable to different localities. Effective carbon mitigation strategies for this county based on costs/Mg C and maximum potential include reforestation of abandoned agricultural lands, biomass production for residential heating and co-firing in coal power plants, changes in personal behavior related to transportation (e.g., public transportation), installation of residential energy efficient products such as programmable thermostats or compact fluorescent light bulbs, and development of local wind power. The total county emissions are about 340 Gg C/year, with biomass sequestration rates of 121 Gg C/year. The potential for mitigation, assuming full market penetration, amounts to about 234 Gg C/year (69%), with 100 Gg C/year (29%) at no net cost to the consumer. The development of local-scale C mitigation plans based on this sort of model of analysis is feasible and would be useful for guiding investments in climate change prevention.     

The value of post-combustion carbon dioxide capture and storage technologies in a world with uncertain greenhouse gas emissions constraints

By analyzing how the largest CO₂ emitting electricity-generating region in the United States, the East Central Area Reliability Coordination Agreement (ECAR), responds to hypothetical constraints on greenhouse gas emissions, the authors demonstrate that there is an enduring role for post-combustion CO₂ capture technologies. The utilization of pulverized coal generation with carbon dioxide capture and storage (PC + CCS) technologies is particularly significant in a world where there is uncertainty about the future evolution of climate policy and in particular uncertainty about the rate at which the climate policy will become more stringent. The paper's analysis shows that within this one large, heavily coal-dominated electricity-generating region, as much as 20–40 GW of PC + CCS could be operating before the middle of this century. Depending upon the state of PC + CCS technology development and the evolution of future climate policy, the analysis shows that these CCS systems could be mated to either pre-existing PC units or PC units that are currently under construction, announced and planned units, as well as PC units that could continue to be built for a number of decades even in the face of a climate policy. In nearly all the cases analyzed here, these PC + CCS generation units are in addition to a much larger deployment of CCS-enabled coal-fueled integrated gasification combined cycle (IGCC) power plants. The analysis presented here shows that the combined deployment of PC + CCS and IGCC + CCS units within this one region of the U.S. could result in the potential capture and storage of between 3.2 and 4.9 Gt of CO₂ before the middle of this century in the region's deep geologic storage formations.     

Evaluation of carbon dioxide storage potential for the Bohai Basin,north-east China

The storage potential of selected sites within the Bohai Basin was assessed for the COACH project. The Gangdong oilfield is considered to have a small potential storage capacity (23 Mt) and to be possibly suitable for an enhanced oil recovery or small-scale storage pilot rather than large-scale storage. The Shengli oilfield province is considered to have a great potential storage capacity (472 Mt in eight selected fields), however, these fields, like those of the Gangdong oilfield province, are compartmentalised by faulting and stratigraphy and likely to be quite challenging for injection. Unmineable coal seams in the Kailuan mining area were also considered for storage, the estimated capacity is 504 Gt adsorbed onto the coal and 38,100 Mt void storage capacity. However, the coals have low porosity and permeability, so they would be expected to have poor injectivity. This is also an active mining area and so any storage site would have to be chosen carefully to avoid affecting future energy resources. The Huimin sub-basin within the Jiyang Depression was identified for consideration as an aquifer storage site; the Guantao Formation has good porosity and permeability in this region, and the regional-level storage capacity of these areas was estimated to be 0.7 Gt. The aquifers in the Huimin sub-basin appear promising for storage, however, less data are available than for the oilfields and the sealing formations are not directly proven to trap buoyant fluids, though in adjacent oilfield in the Shengli oilfield province, the Minghuazhen Formation forms a regional seal for the Guantao Formation.     

Analytical solution for Joule–Thomson cooling during CO2 geo-sequestration in depleted oil and gas reservoirs

Mathematical tools are needed to screen out sites where Joule–Thomson cooling is a prohibitive factor for CO₂ geo-sequestration and to design approaches to mitigate the effect. In this paper, a simple analytical solution is developed by invoking steady-state flow and constant thermophysical properties. The analytical solution allows fast evaluation of spatiotemporal temperature fields, resulting from constant-rate CO₂ injection. The applicability of the analytical solution is demonstrated by comparison with non-isothermal simulation results from the reservoir simulator TOUGH2. Analysis confirms that for an injection rate of 3 kg s^?1 (0.1 MT yr^?1) into moderately warm (>40 °C) and permeable formations (>10^?14 m² (10 mD)), JTC is unlikely to be a problem for initial reservoir pressures as low as 2 MPa (290 psi).     

Shifting Priorities at the Department of Energy's Bomb Factories: Protecting Human and Ecological Health

More than 50 years of research, development, manufacture, and testing of nuclear weapons at Department of Energy (DOE) sites has left a legacy of on-site contamination that often spreads to surrounding areas. Despite substantial cleanup budgets in the last decade, the DOE's top-to-bottom review team concluded that relatively little actual cleanup has been accomplished, although milestones have been met and work packages completed. Rather than solely use regulatory constraints to direct cleanup, many people have suggested that human and ecological health should guide long-term stewardship goals of DOE-managed sites. The main questions are how ecological and human health considerations should be applied in deciding the extent of cleanup that contaminated sites should receive and how near-term and longer run considerations of costs and benefits should be balanced as cleanup decisions are made. One effort to protect ecological integrity is the designation of the largest sites as National Environmental Research Parks (NERPs). Recently, the Competitive Enterprise Institute (CEI) suggested isolating and conserving DOE sites as a policy priority because of their rich ecological diversity. A more effective long-term stewardship approach for former nuclear weapons complex sites may emerge if the guiding principles are to (1) reduce risks to human and ecological health, (2) protect cultural traditions, and (3) lower short- and long-term cleanup and remediation costs. A “net benefits” perspective that takes both near- and longer-term costs and consequences into account can help illuminate the trade-offs between expensive cleanup in the near term and the need to assure long-term protection of human health, cultural values, and high levels of biodiversity and ecological integrity that currently exist at many DOE sites.     

Nitrogen critical loads and management alternatives for N-impacted ecosystems in California

Empirical critical loads for N deposition effects and maps showing areas projected to be in exceedance of the critical load (CL) are given for seven major vegetation types in California. Thirty-five percent of the land area for these vegetation types (99,639 km²) is estimated to be in excess of the N CL. Low CL values (3–8 kg N ha^?1 yr^?1) were determined for mixed conifer forests, chaparral and oak woodlands due to highly N-sensitive biota (lichens) and N-poor or low biomass vegetation in the case of coastal sage scrub (CSS), annual grassland, and desert scrub vegetation. At these N deposition critical loads the latter three ecosystem types are at risk of major vegetation type change because N enrichment favors invasion by exotic annual grasses. Fifty-four and forty-four percent of the area for CSS and grasslands are in exceedance of the CL for invasive grasses, while 53 and 41% of the chaparral and oak woodland areas are in exceedance of the CL for impacts on epiphytic lichen communities. Approximately 30% of the desert (based on invasive grasses and increased fire risk) and mixed conifer forest (based on lichen community changes) areas are in exceedance of the CL. These ecosystems are generally located further from emissions sources than many grasslands or CSS areas. By comparison, only 3–15% of the forested and chaparral land areas are estimated to be in exceedance of the NO₃^? leaching CL. The CL for incipient N saturation in mixed conifer forest catchments was 17 kg N ha^?1 yr^?1. In 10% of the CL exceedance areas for all seven vegetation types combined, the CL is exceeded by at least 10 kg N ha^?1 yr^?1, and in 27% of the exceedance areas the CL is exceeded by at least 5 kg N ha^?1 yr^?1. Management strategies for mitigating the effects of excess N are based on reducing N emissions and reducing site N capital through approaches such as biomass removal and prescribed fire or control of invasive grasses by mowing, selective herbicides, weeding or domestic animal grazing. Ultimately, decreases in N deposition are needed for long-term ecosystem protection and sustainability, and this is the only strategy that will protect epiphytic lichen communities.