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在阿维菌素精制工艺中 ,乙醇和甲苯被共用作溶剂及浸泡剂。乙醇与甲苯的混合液在常压下、温度为 76 .7℃时即共沸 (乙醇的沸点为 78.4℃ ,甲苯的沸点为 110 .8℃ ) ,这种残液如不处理则会带来严重的环保问题。此残液无法用普通精馏法分离 ,我们采用恒沸精馏法将其进行分离回收 ,取得了较好的效果。1 残液组成 以某生物农药厂阿维菌素精制工艺的废溶剂为试验原料 ,其中甲苯的质量分数为 12 %~ 16 %、乙醇的质量分数为 75 %~ 80 % ,其余为水和少量杂质。2 分离原理 通过在二元共沸物中引入第 3组分 (夹带剂 ) ,使其与乙醇、甲苯形成… 相似文献
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硫酸、磷肥生产废水的综合治理硫酸生产废水的处理主要是除砷。目前,除砷的主要方法有硫化法、铁盐法、交换吸附法、溶剂萃取法等。这些方法除砷效果很好,去除率可达99%以上,但处理成本高。磷肥生产排放的含氟废水,含氟浓度高,酸度大,直接用石灰中和并除氟,需消... 相似文献
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本文介绍了采用溶剂萃取法、蒸发浓缩法、吸附法和离子交换膜隔膜电解法对靛兰废水进行处理并回收碱的试验研究。试验结果表明,离子交换膜隔膜电解法具有工艺简单、操作和管理方便、碱回收率高、处理费用较低的特点,适于生产性应用。 相似文献
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Tsietsi Jefrey Pilusa Edison Muzenda Mukul Shukla 《Waste management (New York, N.Y.)》2013,33(6):1509-1515
This study investigated the recovery of oil from waste grease through the process of thermal degradation in an aqueous solution of potassium hydroxide (KOH) followed by solvent extraction. Waste high temperature metal bearing grease was dissolved in a 15 w/w% KOH solution at 80 °C while being agitated at 2000 rpm using a shear action agitator for a period of 15 min. Two distinct layers were observed after 8 min of settling time. The top layer being of dark brown oil and the bottom layer was a heterogeneous mixture. The two layers were separated by decantation. The bottom layer was cooled down to 45 °C followed by slow addition of toluene (C7H8) while agitating at 1200 rpm for 15 min to prevent solids settling and minimise rapid volatilisation of the organic compounds in the mixture. Two distinct layers were also formed, the top homogeneous mixture of light brown oil–toluene mixture and the bottom sludge layer. The solvent was recovered from the oil for re-use by fractional distillation of the homogenous mixture. It was observed that 15 w/w% potassium hydroxide solution can chemically degrade the soap matrix in the grease and extract up to 49 w/w% of the fuel oil when subjected to high shear stress at a temperature of 80 °C. The 26 w/w% extraction of oil in the remaining sludge was obtained by solvent extraction process with mass ratios of sludge to solvent of 2:1. Solvent recovery of 88% by mass was obtained via fractional distillation method. The combined extraction processes brought an overall oil yield of 75 w/w% from the waste grease. The fuel oil obtained from this process has similar properties to paraffin oil and can be blended with other oils as an alternative energy source. 相似文献
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The disposal of chromated copper arsenate (CCA)-treated wood is becoming a serious problem in many countries due to increasing levels of contamination by the hazardous elements, chromium, copper and arsenic. The present experiment was conducted as a preliminary step toward one-step solvent extraction of CCA-treated wood. Because chromium, copper and arsenic have different chemical characteristics, it is best to consider them separately prior to designing a one-step extraction process. As a basis, various two-step extraction processes were first designed and tested experimentally to determine feasibility. Among these combinations, the treatment combining oxalic acid as the 1st step and a sodium oxalate solution under acidic conditions (pH 3.2) as the 2nd step was found to be an effective way of extracting CCA elements from treated wood. Extraction efficiency reached 100% for arsenic and chromium and 95.8% for copper after a 3-h sodium oxalate treatment, following a 1-h pre-extraction process with oxalic acid. On the other hand, the same combination under alkaline conditions (pH 11.2) during the 2nd step was ineffective for copper removal, indicating that pH plays an important role in complexation with sodium oxalate solution. The present results suggest that the extraction of CCA elements using a combination of oxalic acid and acidic sodium oxalate solution is a promising basis for application to a one-step extraction method. 相似文献
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以稀土元素(简称稀土)用量较大的废FCC催化剂和废汽车尾气净化催化剂为研究对象,分析总结了两类废催化剂中稀土的成分和回收方法。从废催化剂中回收稀土普遍采用先浸出、后分离提纯的方法。浸出普遍采用无机酸(多为盐酸),分离方法包括溶剂萃取法、化学沉淀法等,最后经焙烧得到稀土氧化物。为从废催化剂中高效回收稀土,可着重考察新浸出机制的引入、分离方式的选择、分离试剂的应用,以及浸出和分离条件的优化,从而为实现工业化回收提供技术支持。 相似文献
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Bench‐scale solvent extraction and soil washing studies were performed on soil samples obtained from three abandoned wood preserving sites included in the National Priority List. The soil samples from these sites were contaminated with high levels of polyaromatic hydrocarbons (PAHs), pentachlorophenol (PCP), dioxins, and heavy metals. The effectiveness of the solvent extraction process was assessed using liquefied propane or dimethyl ether as solvents over a range of operating conditions. These studies have demonstrated that a two‐stage solvent extraction process using dimethyl ether as a solvent at a ratio of 1.61 per kg of soil could decrease dioxin levels in the soil by 93.0 to 98.9 percent, and PCP levels by 95.1 percent. Reduction percentages for benzo(a)pyrene (BaP) potency estimate and total detected PAHs were 82.4 and 98.6 percent, respectively. Metals concentrations were not reduced by the solvent extraction treatment. These removal levels could be significantly improved using a multistage extraction system. Commercial scale solvent extraction using liquefied gases costs about $220 per ton of contaminated soil. However, field application of this technology at the United Creosote site, Conroe, Texas, failed to perform to the level observed at bench scale due to the excessive foaming and air emission problem. Soil washing using surfactant solution and wet screening treatability studies were also performed on the soil samples in order to assess remediation strategies for sites. Although aqueous phase solubility of contaminants seemed to be the most important factor affecting removal of contaminants from soil, surfactant solutions (3 percent by weight) having nonionic surfactants with hydrophile‐lipophile balance (HLB) of about 14 (Makon‐12 and Igepal CA 720) reduced the PAH levels by an average of 71 percent, compared to no measurable change when pure deionized water was used. Large fractioza of clay and silt (<0.06mm), high le!ezielsof orgaizic contami‐ nants and hzimic acid can makesoil washing less applicable. 相似文献
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Pedram Ashtari Parviz Pourghahramani 《Journal of Material Cycles and Waste Management》2018,20(1):155-166
A large amount of hot filter cake (HFC) is annually generated in Iranian zinc plants. It contains 1% zinc, 16–30% manganese, 5–25% calcium and 1–4.5% cobalt. Usually, zinc is selectively leached by an alkaline medium and its residue is known as alkaline leached HFC (ALHFC). In the present study, the possibility of cobalt extraction from ALHFC was investigated using a creative hydrometallurgical process. At the first stage, zinc and cadmium were selectively removed with sulfuric acid. At the second stage, it was deeply focused on the possibility of selective reductive leaching of cobalt by H2O2 as a reductant in the presence of manganese. As results, several differences were found between the mechanism of cobalt and manganese leaching. Accordingly, cobalt leaching was more affected by acid concentration and manganese leaching was more affected by reductant concentration. Consequently, with manipulating these important parameters, it was made possible to selectively separate cobalt from manganese. Based on the obtained results, 90.9% of cobalt and only 10.04% of manganese were leached with 1% of H2O2. At the third stage, pregnant cobalt solution was successfully purified through a solvent extraction process with D2EHPA. Finally, cobalt hydroxide as our final product with a purity of more than 99% was precipitated from the pure pregnant solution at 70 °C. 相似文献
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以模拟低浓度含硝酸废水为研究对象,以煤油为稀释剂,考察了工艺条件对硝酸萃取和反萃效果的影响,并对萃取机理进行了探讨。实验结果表明:以10.0%(φ)Alamine336为萃取剂,在有机相与水相的体积比为1∶2、萃取温度为298 K的条件下,对初始硝酸质量浓度为2.00 g/L的含硝酸废水进行两级逆流萃取操作后,理论上水相硝酸质量浓度低于15 mg/L,达到GB 8987—1996中的一级标准;以0.05 mol/L氢氧化钠溶液为反萃剂,在有机相与水相的体积比为1∶2、反萃温度为298 K的条件下,对硝酸负载量为1.50 g/L的有机相进行两级反萃后,理论上有机相硝酸残余量小于0.005 g/L。机理研究表明Alamine336通过与硝酸形成离子对络合物来萃取硝酸。 相似文献
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Destruction of PAHS from soil by using pressurized hot water extraction coupled with supercritical water oxidation 总被引:4,自引:0,他引:4
Chemical processes utilizing water both as extraction solvent and reaction medium are promising "Green Chemistry" alternatives to conventional techniques. Equipment for on-line coupled hot water extraction and supercritical water oxidation was constructed to extract polyaromatic hydrocarbons and toluene from sea sand followed by oxidation using hydrogen peroxide. The effectiveness of the technique is based on the physico-chemical properties of heated and pressurized water. Extraction efficiency increased with temperature and time; the best results were obtained at 300 degrees C with 40 min extraction time. In the oxidation stage, conversion of the PAHs increased with reaction time and oxidant concentration and the best conversion (97.0-99.9%, depending on the compound) was obtained at 425 degrees C with 43 s reaction time. Benzaldehyde and benzoic acid were the most abundant reaction intermediates in the oxidation process. In addition, phenol, p-cresol, and benzyl alcohol were found as intermediates. The intermediates originated mainly from toluene, which was present in much greater concentration than PAHs in the reaction medium. 相似文献
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分别采用硫酸硝酸法、水平振荡法和醋酸缓冲溶液法制取气化炉渣的浸出液,考察了不同提取方式对浸出液中重金属质量浓度的影响。采用改进BCR连续提取法对气化炉渣中的重金属Cr,Zn,Cu,Pb,Ni,As,Cd的化学形态进行了分析。实验结果表明:煤气化工艺中的气化炉渣属第Ⅰ类一般工业固体废物;在3种提取方式中,醋酸缓冲溶液法的重金属浸出种类最多,且浸出量最大;Cd和Cr对环境具有较高的潜在危害性,Cu次之,Zn,Pb,Ni,As主要以残渣态形式存在,对环境的直接危害性较低。 相似文献
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Recovery of nickel oxide from spent catalyst 总被引:3,自引:0,他引:3
This study investigates the possibility of recovering nickel from the spent catalyst (NiO/Al2O3) resulting from the steam reforming process to produce water gas (H2/H2O) in many industries. In the extraction process, nickel is recovered as sulfate using sulfuric acid as a solvent. The considered parameters affecting nickel recovery were acid concentration, temperature and time of digestion solid:liquid ratio, particle size and stirring rate. Nickel was to be directly recovered as a sulfate salt by direct crystallization method. The conversion was 99% at 50% sulfuric acid concentration, solid: liquid ratio (1:12) by weight, particle size less than 500 micron for more than 5 h and 800 rpm at 100 degrees C. 相似文献