USING INFILTRATION ENHANCEMENT AND SOIL WATER MANAGEMENT TO REDUCE DIAZINON IN RUNOFF1

ABSTRACT: Pesticide runoff from dormant sprayed orchards is a major water quality problem in California's Central Valley. During the past several years, diazinon levels in the Sacramento and San Joaquin Rivers have exceeded water quality criteria for aquatic organisms. Orchard water management, via post‐application irrigation, and infiltration enhancement, through the use of a vegetative ground cover, are management practices that are believed to reduce pesticide loading to surface waters. Field experiments were conducted in Davis, California, to measure the effectiveness of these management practices in reducing the toxicity of storm water runoff. Treatments using a vegetative ground cover significantly reduced peak concentrations and cumulative pesticide mass in runoff for first flush experiments compared with bare soil treatments. Post‐application irrigation was found to be an effective means of reducing peak concentrations and cumulative mass in runoff from bare soil treatments, but showed no significant effect on vegetated treatments.     

Herbicide loading to shallow ground water beneath Nebraska's Management Systems Evaluation Area

Better management practices can counter deterioration of ground water quality. From 1991 through 1996 the influence of improved irrigation practices on ground water pesticide contamination was assessed at the Nebraska Management Systems Evaluation Area. Three 13.4-ha corn (Zea mays L.) fields were studied: a conventional furrow-irrigated field, a surge-irrigated field and a center pivot-irrigated field, and a center pivot-irrigated alfalfa (Medicago sativa L.) field. The corn fields received one identical banded application of Bicep (atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4,-diamine] + metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamidel) annually; the alfalfa field was untreated. Ground water samples were collected three times annually from 16 depths of 31 multilevel samplers. Six years of sample data indicated that a greater than 50% reduction in irrigation water on the corn management fields lowered average atrazine concentrations in the upper 1.5 m of the aquifer downgradient of the corn fields from approximately 5.5 to <0.5 microg L(-1). Increases in deethylatrazine (DEA; 2-chloro-4-amino-6-isopropylamino-s-triazine) to atrazine molar ratios indicated that reducing water applications enhanced microbial degradation of atrazine in soil zones. The occurrence of peak herbicide loading in ground water was unpredictable but usually was associated with heavy precipitation within days of herbicide application. Focused recharge of storm runoff that ponded in the surge-irrigated field drainage ditch, in the upgradient road ditch, and at the downgradient end of the conventionally irrigated field was a major mechanism for vertical transport. Sprinkler irrigation technology limited areas for focused recharge and promoted significantly more soil microbial degradation of atrazine than furrow irrigation techniques and, thereby, improved ground water quality.     

Contaminant Retention Potential of Forested Filter Strips Established as SMZs in the Piedmont of Georgia1

Abstract: It is common practice in the United States and elsewhere to maintain vegetated filter strips adjacent to streams to retain contaminants in surface runoff. Most research has evaluated contaminant retention in managed agricultural field strips, while relatively few studies have quantified retention in forested filter strips, particularly for dissolved contaminants. Plot‐scale overland flow experiments were conducted to evaluate the efficiency of natural forested filter strips established as streamside management zones (SMZs) for retaining phosphorus (P), atrazine, and picloram transported in runoff. Retention was evaluated for five different slope classes: 1‐2, 5‐7, 10‐12, 15‐17, and 20‐22%; two cover conditions: undisturbed forest floor (O horizon intact) and forest floor removed by raking; and two periods with contrasting soil moisture conditions: summer‐dry and winter‐wet season. Surface flow was collected at 0, 2, 4, 6, and 10 m within the filter strip to evaluate changes in solution concentration as it moved through the O horizon and the surface soil horizon mixing zone. On average, a 10 m length of forested SMZ with an undisturbed forest floor reduced initial solution concentration of total dissolved P by 51%, orthophosphate P by 49%, atrazine by 28%, and picloram by 5%. Percentages of mass retention through infiltration of water plus concentration reductions in runoff were 64% for total dissolved P, 62% for orthophosphate P, 47% for atrazine, and 28% for picloram for undisturbed forest floor conditions. Lower retention occurred following forest floor removal, particularly for P. Average dissolved P retention was 16% lower following forest floor removal. For undisturbed sites, differences in retention were more closely related to forest floor depth than to slope or antecedent soil moisture. These results indicate that forested SMZ filter strips provide a significant measure of surface water protection from dissolved P and herbicide delivery to surface water.     

Occurrence and fate of pesticides in four contrasting agricultural settings in the United States

Occurrence and fate of 45 pesticides and 40 pesticide degradates were investigated in four contrasting agricultural settings--in Maryland, Nebraska, California, and Washington. Primary crops included corn at all sites, soybeans in Maryland, orchards in California and Washington, and vineyards in Washington. Pesticides and pesticide degradates detected in water samples from all four areas were predominantly from two classes of herbicides--triazines and chloroacetanilides; insecticides and fungicides were not present in the shallow ground water. In most samples, pesticide degradates greatly exceeded the concentrations of parent pesticide. In samples from Nebraska, the parent pesticide atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine] was about the same concentration as the degradate, but in samples from Maryland and California atrazine concentrations were substantially smaller than its degradate. Simazine [6-chloro-N,N'-diethyl-1,3,5-triazine-2,4-diamine], the second most detected triazine, was detected in ground water from Maryland, California, and Washington. Metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] rarely was detected without its degradates, and when they were detected in the same sample metolachlor always had smaller concentrations. The Root-Zone Water-Quality Model was used to examine the occurrence and fate of metolachlor at the Maryland site. Simulations accurately predicted which metolachlor degradate would be predominant in the unsaturated zone. In analyses of relations among redox indicators and pesticide variance, apparent age, concentrations of dissolved oxygen, and excess nitrogen gas (from denitrification) were important indicators of the presence and concentration of pesticides in these ground water systems.     

Rethinking the contribution of drained and undrained grasslands to sediment-related water quality problems

Grass vegetation has been recommended for use in the prevention and control of soil erosion because of its dense sward characteristics and stabilizing effect on the soil. A general assumption is that grassland environments suffer from minimal soil erosion and therefore present little threat to the water quality of surface waters in terms of sediment and sorbed contaminant pollution. Our data question this assumption, reporting results from one hydrological year of observations on a field-experiment monitoring overland flow, drain flow, fluxes of suspended solids, total phosphorus (TP), and molybdate-reactive phosphorus (<0.45 mum) in response to natural rainfall events. During individual rainfall events, 1-ha grassland lysimeters yield up to 15 kg of suspended solids, with concentrations in runoff waters of up to 400 mg L(-1). These concentrations exceed the water quality standards recommended by the European Freshwater Fisheries Directive (25 mg L(-1)) and the USEPA (80 mg L(-1)) and are beyond those reported to have caused chronic effects on freshwater aquatic organisms. Furthermore, TP concentrations in runoff waters from these field lysimeters exceeded 800 mug L(-1). These concentrations are in excess of those reported to cause eutrophication problems in rivers and lakes and contravene the ecoregional nutrient criteria in all of the USA ecoregions. This paper also examines how subsurface drainage, a common agricultural practice in intensively managed grasslands, influences the hydrology and export of sediment and nutrients from grasslands. This dataset suggests that we need to rethink the conceptual understanding of grasslands as non-erosive landscapes. Failure to acknowledge this will result in the noncompliance of surface waters to water quality standards.     

Risk assessment of pesticide runoff from turf

The TurfPQ model was used to simulate the runoff of 15 pesticides commonly applied to creeping bentgrass (Agrostis stolonifera L.) fairways and greens on golf courses in the northeastern USA. Simulations produced 100-yr daily records of water runoff, pesticide runoff, and pesticide concentration in runoff for three locations: Boston, MA, Philadelphia, PA, and Rochester, NY. Results were summarized as annual and monthly means and annual maximum daily loads (AMDLs) corresponding to 10- and 20-yr return periods. Mean annual pesticide runoff loads did not exceed 3% of annual applications for any pesticide or site, and most losses were substantially less than 1% of application. However, annual or monthly mean concentrations of chlorothalonil, iprodione, and PCNB in fairway runoff often exceeded concentrations that result in 50% mortality of the affected species (LC50) for aquatic organisms. Concentrations of azoxystrobin, bensulide, cyfluthrin, and trichlorfon in extreme (1 in 10 yr or 1 in 20 yr) events often approached or exceeded LC50 levels. Concentrations of halofenozide, mancozeb, MCPP, oxadiazon, propiconazole, thiophanate-methyl, triadimefon, and trinexapac-ethyl were well below LC50 levels, and turf runoff of these chemicals does not appear to be hazardous to aquatic life in surface waters.     

Pesticide transport pathways from a sloped Litchi orchard to an adjacent tropical stream as identified by hydrograph separation

This study was performed to identify the transport pathways of pesticides from a sloped litchi ( Sonn.) orchard to a nearby stream based on a three-component hydrograph separation (baseflow, interflow, surface runoff). Dissolved silica and electrical conductivity were chosen as representative tracers. During the study period (30 d), 0.4 and 0.01% of the applied mass of atrazine and chlorpyrifos, respectively, were detected in the stream after 151 mm of rainfall. Baseflow (80-96%) was the dominant hydrological flow component, followed by interflow (3-18%) and surface runoff (1-7%). Despite its small contribution to total discharge, surface runoff was the dominant atrazine transport pathway during the first days after application because pesticide concentrations in the surface runoff flow component declined quickly within several days. Preferential transport with interflow became the dominant pathway of atrazine. Because chlorpyrifos was detected in the stream water only twice, it was not included in the hydrograph separation. A feature of the surface runoff pathway was the coincidence of pesticide and discharge peaks. In contrast, peak concentrations of pesticides transported by interflow occurred during the hydrograph recession phases. Stormflow generation and pesticide transport depended on antecedent rainfall. The combination of high-resolution pesticide concentration measurements with a three-component hydrograph separation has been shown to be a suitable method to identify pesticide transport pathways under tropical conditions.     

ATRAZINE IN SPRING RUNOFF AS RELATED TO ENVIRONMENTAL SETTING EBRASKA, 19921

ABSTRACT: A synoptic sampling of five surface-water sites in central Nebraska was conducted by the U.S. Geological Survey as part of its National Water-Quality Assessment Program during storm runoff in May 1992 to relate transport, yields, and concentrations of atrazine to environmental setting. Atrazine was the most extensively applied pesticide in the study unit. Atrazine transport was related to the size of contributing drainage area, quantity of atrazine applied, amount of precipitation, and volume of stream-flow. Estimated yields and mean concentrations of atrazine were related to the percentage of cropland in a drainage area. The largest estimated yields and mean concentrations of atrazine in surface water were associated from drainage areas with the highest percentage of cropland, and the smallest was associated with the smallest amount of cropland. Atrazine concentrations increased as streamflow increased but decreased at or near the time of peak streamflows, perhaps due to dilution. Atrazine concentrations then increased and remained elevated far into the stream recession. Atrazine is a regulated contaminant in finished public-water supplies. Large concentrations of atrazine could affect the management of public-water supplies because atrazine remains in solution in contrast to many other pesticides that are more easily removed.     

Behavior of pesticide residues in agricultural soil and adjacent River Kuywa sediment and water samples from Nzoia sugarcane belt in Kenya

An inventory survey conducted to determine pesticide usage in a sub-catchment of the Nzoia sugarcane belt found a variety of pesticides used in the sub-catchment, which are reported in this paper. Analysis of soil samples from seven fallow experimental field plots left uncultivated for various periods from 3 to 96?months after cultivation with pesticide application indicated persistence of high concentrations of pesticide residues in the soil, with estimated soil half-lives (in years) ranging from 0.72 to 57.75 for organochlorines and from 1.13 to 8.25 for herbicides. The mean water concentrations (in ??g/L) of the pesticide residues in River Kuywa, which flows through the Nzoia Nucleus Estate sugarcane farms, ranged from 0.12 (lindane) to 1.36 (p,p??-DDT) for organochlorines and from 0.14 (atrazine) to 1.75 (diuron) for herbicides during the heavy rains period in August 2008 while the mean sediment concentrations (in ??g/g) ranged from 0.28 (lindane) to 1.87 (endrin) for organochlorines and 0.39 (hexazinone) to 4.61 (alachlor) for herbicides. The mean concentrations of residues in water during the light rain period in December 2008 ranged from 0.17 (p,p??-DDT) to 0.71 (aldrin) for organochlorines and 0.01 (atrazine) to 1.74 (alachlor) for herbicides while the sediment concentrations ranged from 0.38 (p,p??-DDT) to 1.145 (aldrin) for organochlorines and 0.74 (atrazine) to 1.98 (alachlor) for herbicides. Although DDT, aldrin, dieldrin, and endrin were not reported in the survey, their presence in the fallow experimental field plot soils and in River Kuywa water and sediment could indicate previous application, lack of recorded data or illegal usage since 1997 when they were banned. Notably, the concentrations of alachlor, diuron, cypermethrin, and hexazinone in the water column were substantial indicating their extensive usage and residual persistence in the sub-catchment, with subsequent wash-off and leaching into River Kuywa. The concentration levels of some of the individual pesticides exceeded the EU limit requirements for drinking water and indicated potential risk to humans and cattle if the water is used without treatment.     

Simulating endosulfan transport in runoff from cotton fields in Australia with the GLEAMS model

Endosulfan (6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9methano-2,4,3-benzodioxathiepin 3-oxide), a pesticide that is highly toxic to aquatic organisms, is widely used in the cotton (Gossypium hirsutum L.) industry in Australia and is a risk to the downstream riverine environment. We used the GLEAMS model to evaluate the effectiveness of a range of management scenarios aimed at minimizing endosulfan transport in runoff at the field scale. The field management scenarios simulated were (i) Conventional, bare soil at the beginning of the cotton season and seven irrigations per season; (ii) Improved Irrigation, irrigation amounts reduced and frequency increased to reduce runoff from excess irrigation; (iii) Dryland, no irrigation; (iv) Stubble Retained, increased soil cover created by retaining residue from the previous crop or a specially planted winter cover crop; and (v) Reduced Sprays, a fewer number of sprays. Stubble Retained was the most effective scenario for minimizing endosulfan transport because infiltration was increased and erosion reduced, and the stubble intercepted and neutralized a proportion of the applied endosulfan. Reducing excess irrigation reduced annual export rates by 80 to 90%, but transport in larger storm events was still high. Reducing the number of pesticide applications only reduced transport when three or fewer sprays were applied. We conclude that endosulfan transport from cotton farms can be minimized with a combination of field management practices that reduce excess irrigation and concentration of pesticide on the soil at any point in time; however, discharges, probably with endosulfan concentrations exceeding guideline values, will still occur in storm events.     

MOBILITY AND AQUATIC TOXICITY OF COPPER IN AN URBAN WATERSHED1

ABSTRACT: Abundant use of copper based products has resulted in increased violation of copper water quality criteria in runoff from urban storm water systems. The objectives of this work were to understand the mobility and toxicity of copper in an urban watershed and to apportion the amount of copper entering the freshwater receiving stream from different urban land covers using a mass balance approach. Sixteen rainfall events collected from the University of Connecticut study watershed between August 1998 and September 2000 were analyzed to assess copper flux in an urban storm water system. Mean flow weighted dissolved copper concentrations observed in the study for copper based architectural material runoff, pervious area runoff, impervious area runoff, and in the receiving stream were 1210 ± 840, 9 ± 3, 8 ± 2, and 14 ± 7 μg/L, respectively. Mean dissolved copper concentrations in the receiving stream exceeded Connecticut's water quality criteria. Despite exceeding the dissolved concentration based criteria, cupric ion concentrations at the system outlet remained below 0.05 μg/L for all storms analyzed, and no acute toxicity (using Daphnia pulex as the test organism) was measured in samples collected from the stream.     

INPUTS OF COPPER‐BASED CROP PROTECTANTS TO COASTAL CREEKS FROM PASTICULTURE RUNOFF1

ABSTRACT: Inputs of copper‐based crop protectants from tomato fields grown under plastic mulch agriculture (plasticulture) to an estuarine creek were investigated. Copper was measured in runoff from diverse land‐uses including conventional agriculture, plasticulture, residences, and natural areas. Water column and sediment copper concentrations were measured in plasticulture and control (nonagriculture) watersheds. Copper concentrations in plasticulture‐impacted creeks exceeded background levels episodically. High concentrations occurred during or immediately after runoff‐producing rains. Concentrations of 263 μg/L total copper and 126 μg/L dissolved copper were measured in a tidal creek affected by plasticulture; concentrations exceeded the shellfish LC₅₀ values and the water quality criteria of 2.9 μg/L dissolved copper. Control watersheds indicated background water column levels of ≤ 4 μg/L dissolved copper with similar copper levels during periods with and without rain. The copper concentrations in tomato plasticulture field runoff itself contained up to 238 μg/L dissolved copper. Copper concentrations in runoff from other land‐uses were less than 5 μg/L dissolved copper. Creek sediment samples adjacent to a plasticulture field contained significantly higher copper concentrations than sediments taken from nonplasticulture watersheds.     

Vegetative Buffer Strips for Reducing Herbicide Transport in Runoff: Effects of Buffer Width,Vegetation, and Season

The effectiveness of vegetative buffer strips (VBS) for reducing herbicide transport has not been well documented for runoff prone soils. A multi‐year plot‐scale study was conducted on an eroded claypan soil with the following objectives: (1) assess the effects of buffer width, vegetation, and season on runoff transport of atrazine (ATR), metolachlor (MET), and glyphosate; (2) develop VBS design criteria for herbicides; and (3) compare differences in soil quality among vegetation treatments. Rainfall simulation was used to create uniform antecedent soil water content and to generate runoff. Vegetation treatment and buffer width impacted herbicide loads much more than season. Grass treatments reduced herbicide loads by 19‐28% and sediment loads by 67% compared to the control. Grass treatments increased retention of dissolved‐phase herbicides by both infiltration and adsorption, but adsorption accounted for the greatest proportion of retained herbicide load. This latter finding indicated VBS can be effective on poorly drained soils or when the source to buffer area ratio is high. Grass treatments modestly improved surface soil quality 8‐13 years after establishment, with significant increases in organic C, total N, and ATR and MET sorption compared to continuously tilled control. Herbicide loads as a function of buffer width were well described by first‐order decay models which indicated VBS can provide significant load reductions under anticipated field conditions.     

Evaluation of Three Watershed‐Scale Pesticide Environmental Transport and Fate Models1

Abstract: The U.S. Environmental Protection Agency (USEPA) Office of Pesticide Programs (OPP) has completed an evaluation of three watershed‐scale simulation models for potential use in Food Quality Protection Act pesticide drinking water exposure assessments. The evaluation may also guide OPP in identifying computer simulation tools that can be used in performing aquatic ecological exposure assessments. Models selected for evaluation were the Soil Water Assessment Tool (SWAT), the Nonpoint Source Model (NPSM), a modified version of the Hydrologic Simulation Program‐Fortran (HSPF), and the Pesticide Root Zone Model‐Riverine Water Quality (PRZM‐RIVWQ) model. Simulated concentrations of the pesticides atrazine, metolachlor, and trifluralin in surface water were compared with field data monitored in the Sugar Creek watershed of Indiana’s White River basin by the National Water Quality Assessment (NAWQA) program. The evaluation not only provided USEPA with experience in using watershed models for estimating pesticide concentration in flowing water but also led to the development of improved statistical techniques for assessing model accuracy. Further, it demonstrated the difficulty of representing spatially and temporally variable soil, weather, and pesticide applications with relatively infrequent, spatially fixed, point estimates. It also demonstrated the value of using monitoring and modeling as mutually supporting tools and pointed to the need to design monitoring programs that support modeling.     

Simulating pesticide leaching and runoff in rice paddies with the RICEWQ-VADOFT model

There is a current need to simulate leaching and runoff of pesticide from rice (Oryza sativa L.) paddies for assessing environmental impacts on a valuable agricultural system. The objective of this study was to develop a model for determining predicted environmental concentration (PEC) in soil, runoff, and ground water through the linkage of two models, rice water quality model (RICEWQ) and vadose zone transport model (VADOFT), to simulate pesticide fate and transport within a rice paddy and underlying soil profile. Model performance was evaluated with a field data set obtained from a 2-yr field experiment in 1997 and 1998 in northern Italy. The predictions of amount of pesticide running off from the paddy field and accumulating in the paddy sediment were in agreement with measured values. Leaching into the vadose zone accounted for approximately 19% of the applied dose, but only a small amount of chemical (<0.1%) was predicted to reach ground water at a 5-m depth due to sorption and transformation in the soil. The permeability of the soil and the water management practices in the paddy field were shown to have a strong influence on pesticide fate. These factors need to be well characterized in the field if model predictions are to be successful. The combined model developed in this work is an effective tool for exposure assessments for soil, surface water, and ground water, in the particular conditions of rice cultivation.     

Herbicide Transport in Goodwater Creek ExperimentalWatershed: I. Long‐Term Research on Atrazine1

Lerch, R.N., E.J. Sadler, K.A. Sudduth, C. Baffaut, and N.R. Kitchen, 2010. Herbicide Transport in Goodwater Creek Experimental Watershed: I. Long‐Term Research on Atrazine. Journal of the American Water Resources Association (JAWRA) 1‐15. DOI: 10.1111/j.1752‐1688.2010.00503.x Abstract: Atrazine continues to be the herbicide of greatest concern relative to contamination of surface waters in the United States (U.S.). The objectives of this study were to analyze trends in atrazine concentration and load in Goodwater Creek Experimental Watershed (GCEW) from 1992 to 2006, and to conduct a retrospective assessment of the potential aquatic ecosystem impacts caused by atrazine contamination. Located within the Central Claypan Region of northeastern Missouri, GCEW encompasses 72.5 km² of predominantly agricultural land uses, with an average of 21% of the watershed in corn and sorghum. Flow‐weighted runoff and weekly base‐flow grab samples were collected at the outlet to GCEW and analyzed for atrazine. Cumulative frequency diagrams and linear regression analyses generally showed no significant time trends for atrazine concentration or load. Relative annual loads varied from 0.56 to 14% of the applied atrazine, with a median of 5.9%. A cumulative vulnerability index, which takes into account the interactions between herbicide application, surface runoff events, and atrazine dissipation kinetics, explained 63% of the variation in annual atrazine loads. Based on criteria established by the U.S. Environmental Protection Agency, atrazine reached concentrations considered harmful to aquatic ecosystems in 10 of 15 years. Because of its vulnerability, atrazine registrants will be required to work with farmers in GCEW to implement practices that reduce atrazine transport.     

Herbicides in ground water beneath Nebraska's Management Systems Evaluation Area

Profiles of ground water pesticide concentrations beneath the Nebraska Management Systems Evaluation Area (MSEA) describe the effect of 20 yr of pesticide usage on ground water in the central Platte Valley of Nebraska. During the 6-yr (1991-1996) study, 14 pesticides and their transformation products were detected in 7848 ground water samples from the unconfined water table aquifer. Triazine and acetamide herbicides applied on the site and their transformation products had the highest frequencies of detection. Atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4,-diamine] concentrations decreased with depth and ground water age determined with 3H/3He dating techniques. Assuming equivalent atrazine input during the past 20 yr, the measured average changes in concentration with depth (age) suggest an estimated half-life of >10 yr. Hydrolysis of atrazine and deethylatrazine (DEA; 2-chloro-4-amino-6-isopropylamino-s-triazine) to hydroxyatrazine [6-hydroxy-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine] appeared to be the major degradation route. Aqueous hydroxyatrazine concentrations are governed by sorption on the saturated sediments. Atrazine was detected in the confined Ogallala aquifer in ultra-trace concentrations (0.003 microg L(-1)); however, the possibility of introduction during reverse circulation drilling of these deep wells cannot be eliminated. In fall 1997 sampling, metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] was detected in 57% of the 230 samples. Metolachlor oxanilic acid [(2-ethyl-6-methylphenyl)(2-methoxy-1-methylethyl) amino]oxo-acetic acid] was detected in most samples. In ground water profiles, concentrations of metolachlor ethane sulfonic acid [2-[(ethyl-6-methylphenyl)(2-methoxy-1-methylethyl)amino]-2-oxo-ethanesulfonic acid] exceeded those of deethylatrazine. Alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide] was detected in <1% of the samples; however, alachlor ethane sulfonic acid [2-[(2,6-diethylphenyl)(methoxymethyl)amino]-2-oxoethanesulfonic acid] was present in most samples (63%) and was an indicator of past alachlor use.     

PRELIMINARY OBSERVATIONS ON WATER QUALITY OF STORM RUNOFF FROM FOUR SELECTED RESIDENTIAL ROOFS1

ABSTRACT: Storm runoff from four characteristic types of residential roofs and incident rainwater were monitored for 47 storm events over a six-month period at Nacogdoches, Texas, to study water quality conditions for 20 element and four chemical variables. The total element concentration in storm runoff from each roof type was greater than that of rainwater in the open. Differences in element concentrations in storm runoff among the four roof types were statistically significant (α≤ 0.05) with the differences for the wood shingle roof being the greatest and that for terra cotta clay roof being the least. The median concentrations of four element variables exceeded the Texas surface water quality standards, while 12 variables exceeded the standards at least one time in all samples collected. Zinc concentrations violated the Standard ranging from 85.7 percent of the samples for the wood shingle roof to 66.0 percent for the composite shingle, the greatest exceedances of all 24 variables studied. Storm characteristics and gutter maintenance level had some effects on these water quality conditions. The study suggested that roof types can be important to water pollution management programs. More detailed studies on roof water quality in major municipalities are required.     

FACTORS AFFECTING PESTICIDE OCCURRENCE AND TRANSPORT IN A LARGE MIDWESTERN RIVER BASIN1

ABSTRACT: Several factors affect the occurrence and transport of pesticides in surface waters of the 29,400 km² White River Basin in Indiana. A relationship was found between pesticide use and the average annual concentration of that pesticide in the White River, although this relationship varies for different classes of pesticides. About one percent of the mass applied of each of the commonly used agricultural herbicides was transported from the basin via the White River. Peak pesticide concentrations were typically highest in late spring or early summer and were associated with periods of runoff following application. Concentrations of diazinon were higher in an urban basin than in two agricultural basins, corresponding to the common use of this insecticide on lawns and gardens in urban areas. Concentrations of atrazine, a corn herbicide widely used in the White River Basin, were higher in an agricultural basin with permeable, well‐drained soils, than in an agricultural basin with less permeable, more poorly drained soils. Although use of butylate and cyanazine was comparable in the White River Basin between 1992 and 1994, concentrations in the White River of butylate, which is incorporated into soil, were substantially less than for cyanazine, which is typically applied to the soil surface.