Fracture-controlled nitrate and atrazine transport in four Iowa till units

Fractures in till may provide pathways for agricultural chemicals to contaminate aquifers and surface waters. This study was conducted to quantify the influence of fractures on solute fate and transport using three conservative and two nonconservative tracers. The conservative tracers were potassium bromide (KBr), pentafluorobenzoic acid (PFBA), and 1,4-piperazinediethanesulfonic acid disodium salt (PIPES); the nonconservative tracers were nitrate and atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine]. Three sites in Iowa were investigated, including four late Wisconsinan and Pre-Illinoian tills. Laboratory tracer experiments were conducted using eight large (0.4-0.45 m long by 0.43 m in diameter), undisturbed columns of till collected from depths of 1 to 28 m. The tills were densely fractured, with fracture spacing ranging from 3.8 to 10.4 cm. First arrival velocities of Br- ranged from 0.004 to 64.8 m d(-1), 10 to 100 times faster than predicted for unfractured media. Nitrate behaved as a conservative tracer in weathered till columns, but degraded during experiments using deeper tills. Sorption caused retardation of atrazine in the shallowest four columns. Atrazine degradation occurred in deeper columns as demonstrated by deviations between atrazine and the conservative tracers. Mobile-immobile model (MIM) simulations estimated first-order exchange coefficients (alpha) ranging from 1 x 10(-8) to 1.7 x 10(-2) s(-1), sorption coefficients (K(d)) for atrazine ranging from 2.6 x 10(-5) to 1 x 10(-3) m3 kg(-1), and degradation half-lives ranging from 0.24 to 67 d (nitrate) and 1.6 to 277 d (atrazine). This study suggests that aquifers and surface waters associated with thin, fractured till units may be vulnerable to contamination, yet deeper aquifers may be protected by these materials due to increased residence times provided by matrix diffusion.     

Influence of flow rate on transport of bacteriophage in shale saprolite

The objective of this study was to investigate the influence of flow rate on transport and retention of bacteriophage tracers in a fractured shale saprolite, which is a highly weathered, fine-grained subsoil that retains much of the fabric of the parent bedrock. Synthetic ground water containing PRD-1, MS-2, and bromide was passed through a saturated column of undisturbed shale saprolite at rates ranging from 0.0075 to 0.96 m d '. First arrival of the bacteriophage tracers in effluent samples in each of the experiments occurred within 0.01 to 0.04 pore volumes (PV) of the start of injection, indicating that bacteriophage were advectively transported mainly through fractures or macropores. Bacteriophage transport velocities, based on first arrival in the effluent, were very similar to fracture flow velocities calculated using the cubic law for flow in a fractured material. For MS-2, maximum concentration and mass of tracer recovered both increased steadily as flow rate increased. For PRD-1, these values initially increased, but were nearly constant at flow rates above 0.039 m d(-1), indicating that approximately 50% of the observed losses were independent of flow rate. Evaluation of the data indicates that physical straining and electrostatic or hydrophobic attachment to fracture or macropore walls were the dominant retention processes. Inactivation and gravitational settling playing secondary roles, except at the slowest flow rates. The study suggests that microbial contamination from sources such as septic fields and sewage ponds may pose a threat to the quality of ground water and surface water in areas with saprolitic subsoils.     

Direct and indirect hydrological controls on E. coli concentration and loading in midwestern streams

This study investigates hydrological controls on E. coli concentration and loading in two artificially drained agricultural watersheds (58 and 23 km(2)) of the U.S. Midwest. Stream E. coli concentrations are significantly (p < 0.02) lower at base flow than high flow; however, E. coli load is significantly higher at high flow than at low flow (p < 0.001). Although E. coli concentrations are not significantly higher (p = 0.253) in summer/fall (3269 MPN/100 mL) than in the winter/spring (2411 MPN/100 mL), E. coli load is significantly higher (p < 0.05) in winter/spring (346 MPN/day) than in summer/fall season (75 MPN/day). Correlation analysis indicates that discharge and precipitation are the best indicators of E. coli concentration and 7-d antecedent precipitation (7dP), the best indicator of E. coli loading in the watersheds studied regardless of flow conditions and location. However, E. coli concentration and loading best correlate to 7dP and turbidity at base flow. A spatial dependency is also observed at base flow with E. coli concentration and load correlating better to 7dP in the headwaters and to turbidity in the lower reaches of the watersheds studied. For high flow conditions, E. coli concentration and loading are poorly correlated to most variables, except stream water temperature and 7-d antecedent discharge. These results are consistent with those reported in the literature and suggest that, at least during base flow conditions, turbidity and 7dP may be usable in artificially drained landscapes of the Midwest to identify potential hot spots of E. coli contamination.     

USE OF CLIMATE PREDICTIONS TO DECIDE A WATER MANAGEMENT PROBLEM1

ABSTRACT: Seasonal precipitation predictions were utilized in a water management decision with major economic, societal, and political ramifications. A summer (1984) drought had created a situation calling for possible fall season use of state waters from two major multipurpose reservoirs with an ensuing effect on water price negotiations. Choices facing management and use of water from the reservoirs were to invoke expensive water restrictions with a 33 percent chance of being right, do nothing (66 percent chance of wrong outcome), or use the precipitation predictors (for above normal fall rain) having a 50 percent chance of error. Hydrologists chose to follow the precipitation predictions, which proved to be accurate for the fall of 1984, helping to reveal the long-term value of using well understood climate predictions in water management.     

Backwater Confluences of the Ohio River: Organic and Inorganic Fingerprints Explain Sediment Dynamics in Wetlands and Marinas

In the Ohio River (OR), backwater confluence sedimentation dynamics are understudied, however, these river features are expected to be influential on the system’s ecological and economic function when integrated along the river’s length. In the following paper, we test the efficacy of organic and inorganic tracers for sediment fingerprinting in backwater confluences; we use fingerprinting results to evidence sediment dynamics controlling deposition patterns in confluences used for wetland and marina functions; and we quantify the spatial extent of tributary drainages with wetland and marina features in OR confluences. Both organic and inorganic tracers statistically differentiate sediment from stream and river end‐members. Carbon and nitrogen stable isotopes produce greater uncertainty in fingerprinting results than inorganic elemental tracers. Uncertainty analysis of the nonconservative tracer term in the organic matter fingerprinting application estimates an apparent enrichment of the carbon stable isotopes during instream residence, and the nonconservativeness is quantified with a statistical approach unique to the fingerprinting literature. Wetland and marina features in OR confluences impact 42% and 11% of tributary drainage areas, respectively. Sediment dynamics show wetland and marina confluences experience deposition from river backwaters with longitudinally linear and nonlinear patterns, respectively, from sediment sources.     

CHARACTERISTICS OF LONG‐TERM FRESHWATER TRANSPORT IN APALACHICOLA BAY1

ABSTRACT: Long‐term freshwater transport is an important factor affecting estuarine aquatic ecosystems. In this study, a primitive equation, prognostic, three‐dimensional, hydrodynamic model was applied to Apalachicola Bay, Florida, for the summer and fall seasons of 1993. In response to the river freshwater discharge, tide, and wind forces, the model simulations were used to characterize the long‐term freshwater transport processes in the bay. Analysis of spatial distributions of seasonal average salinity and currents shows that the long‐term freshwater transport was strongly affected by the forcing functions of wind and density gradient in the bay. Average freshwater input was approximately the same in the summer and fall seasons of 1993. However, in the summer season, more freshwater moved to the east direction due to the predominant wind from the west, while in the fall season more freshwater moved to the west in response to the wind primarily from the east. The water column was strongly stratified near the river mouth, and it gradually changed to well mixing near the ocean boundaries. Vertical stratification in the bay changed due to wind‐induced mixing and mass transport. Due to the density gradient effect, surface residual currents carrying fresher water were in the direction from the river toward the Gulf, while the bottom residual currents with saltier water entered the bay from the Gulf of Mexico.     

Hydrology of Clay Settling Areas and Surrounding Landscapes in the Phosphate Mining District,Peninsular Florida1

Abstract: The objective of this study was to use applied and naturally occurring geochemical tracers to study the hydrology of clay settling areas (CSAs) and the hydrological connectivity between CSAs and surrounding hydrological landscapes. The study site is located on the Fort Meade Mine in Polk County, Florida. The CSA has a well‐developed, subangular‐blocky, clay‐rich surface layer with abundant desiccation cracks and other macropores, and a massive, clay‐rich sublayer that is saturated below ～1.0‐2.5 m. A bromide tracer was applied to study hydrological processes in the upper part of the CSA. Bromide infiltrated rapidly and perched on a massive, clay‐rich sublayer. Bromide concentrations decreased in the upper part of the profile without being transported vertically down through the lower part of the profile suggesting that bromide was lost to lateral rather than to vertical transport. Infiltration and lateral flow were rapid suggesting that preferential flow through desiccation cracks and other macropores likely dominates flow in the upper part of the CSA. Naturally occurring solute and stable isotope tracers were used to study the hydrological connectivity between the CSA and the surrounding hydrological landscape. Three‐end mass‐balance mixing model results indicate that shallow and/or deep CSA water can be found in all downgradient waters and must be as much as ～50% of some downgradient waters. Discharge from the CSA to the surrounding surface water‐bodies and surficial aquifer occurs laterally through the berms and/or vertically through the massive, clay‐rich sublayer. However, the precise flow paths from the CSA to the surrounding hydrological landscape are unclear and the fluxes remain unquantified, so the precise effects of CSAs on the hydrology of the surrounding hydrological landscape also remain unquantified.     

Dust deposition in a sub-tropical opencast coalmine area, India

This paper provides baseline information about the total annual dust fall, and its constituents and seasonal variation, from a sub-tropical opencast coalmine area in Bina, India. Dust samples were collected monthly for 2 years (June 2002-May 2004) from five sampling sites in the region and analyzed in the laboratory for water-soluble and -insoluble matter. Water-insoluble components constituted the major fraction of the total annual dust fall. Two-way ANOVA indicated significant variations in dust fall at different sites, over the months and in their interactions. The dust deposition rate was highest during summer (March-June), followed by winter (November-February) and lowest in the rainy season (July-October). Maximum dust fall was observed near the coal handling plant (at site 2) followed by the receiving pit of the coal handling plant (site 3), near the main sub-station (site 4), Jawahar colony (site 1) and Gharasari village (site 5). An inverse and significant relation was observed between dust fall and precipitation. Our studies have shown that the main residential areas are experiencing higher levels of dust fall which makes them unsuitable for living. We suggest that residential areas should be moved farther away from the mining area in the opposite direction of prevalent winds.     

Restoration of foothills rough fescue grassland following pipeline disturbance in southwestern Alberta

The effects of pipeline construction and reclamation techniques on the restoration of rough fescue plant communities following pipeline construction in southwestern Alberta, Canada were evaluated after 7–40 years. The pipeline construction right-of-way (ROW) sites varied from no recovery of rough fescue grassland to moderate recovery. The ROW sites had a higher proportion of introduced grasses and forbs, less topsoil, and poorer rangeland health than the adjacent undisturbed grassland. Within the ROW sites, less topsoil was present on those with larger diameter pipe and which had topsoil fully stripped from the ROW during construction. Introduced grasses, Festuca ovina (sheep fescue) and Poa compressa (Canada bluegrass), succeeded in establishment following seeding and persisted for at least 40 years. Poa pratensis (Kentucky bluegrass) dominated many of the ROW sites. Contributing factors to moderate recovery of rough fescue grassland were related to post-growing season pipeline construction, ideally, between August and March, summer or fall seeding, and minimum disturbance trench-only stripping. Reclamation practices appeared more important than time since restoration in the restoration of rough fescue grassland.     

Assessing drilling mud and technical fluid contamination in rock core and brine samples intended for microbiological monitoring at the CO2 storage site in Ketzin using fluorescent dye tracers

The CO₂SINK project in Ketzin represents a field laboratory for the storage of CO₂ in a 650-m deep saline aquifer. The project is accompanied by a microbiological monitoring programme to characterise the composition and activity of the autochthonous microbial community in rock and brine samples and their changes in response to CO₂ storage. A prerequisite of these studies is the acquisition of samples free of contamination from microorganisms and organic and inorganic components. Drilling mud and technical fluids are the main sources of contamination. This study describes the application of the fluorescent dye tracers fluorescein and rhodamine B as contamination controls for rock core and brine samples. Fluorescein was added to drilling mud that was used during the coring phase of the Ketzin wells Ktzi 200, 201 and 202. In addition, total organic carbon (TOC) concentrations, reflecting the carboxymethyl cellulose (CMC) component of the drilling mud, were determined to verify the tracer results. The fluorescence and TOC analyses revealed that drilling mud filtrate penetrated the outer 20 mm of mildly permeable sandstone cores. Rhodamine B was added to brines that were used to displace the drilling mud and to flush the wells after completion. The tracer monitoring during the discharge of drilling mud and displacement brines from the wells during hydraulic tests and nitrogen lifts enabled the quantification of reservoir fluid quality. After the production of 140–190 m³ (16–21 borehole volumes) of fluid, the drilling mud concentration was reduced to about 0.05%. The use of fluorescein emerged as a field-capable, sensitive and reliable method during the sampling of rock core and formation brine samples.     

Interrelationship of macropores and subsurface drainage for conservative tracer and pesticide transport

Macropore flow results in the rapid movement of pesticides to subsurface drains, which may be caused in part by a small portion of macropores directly connected to drains. However, current models fail to account for this direct connection. This research investigated the interrelationship between macropore flow and subsurface drainage on conservative solute and pesticide transport using the Root Zone Water Quality Model (RZWQM). Potassium bromide tracer and isoxaflutole, the active ingredient in BALANCE herbicide [(5-cyclopropyl-4-isoxazolyl) [2(methylsulfonyl)-4-(trifluoromethyl)phenyl] methanone], with average half-life of 1.7 d were applied to a 30.4-ha Indiana corn (Zea mays L.) field. Water flow and chemical concentrations emanating from the drains were measured from two samplers. Model predictions of drain flow after minimal calibration reasonably matched observations (slope = 1.03, intercept = 0.01, and R(2) = 0.75). Without direct hydraulic connection of macropores to drains, RZWQM under predicted bromide and isoxaflutole concentration during the first measured peak after application (e.g., observed isoxaflutole concentration was between 1.2 and 1.4 mug L(-1), RZWQM concentration was 0.1 mug L(-1)). This research modified RZWQM to include an express fraction relating the percentage of macropores in direct hydraulic connection to drains. The modified model captured the first measured peak in bromide and isoxaflutole concentrations using an express fraction of 2% (e.g., simulated isoxaflutole concentration increased to 1.7 mug L(-1)). The RZWQM modified to include a macropore express fraction more accurately simulates chemical movement through macropores to subsurface drains. An express fraction is required to match peak concentrations in subsurface drains shortly after chemical applications.     

Determining long-term (decadal) deep drainage rate using multiple tracers

The deep drainage rate is a critical hydrological parameter in understanding contamination mechanisms of soil and groundwater. Little research has been conducted on the temporal variations in deep drainage rate during the last century. The objective of this study was to determine the long-term deep drainage rate on a cultivated loamy soil in the Canadian Prairies. Three tracers were used: KCl applied in 1971, fallout tritium in 1963, and NO3* released during the initial cultivation of the field (1923). Two soil cores to a depth of 3.6 m were taken along a flat portion of the field, and soil Cl(-), 3H, and NO3* concentrations were measured as a function of depth. An additional four cores were taken for soil water content measurements between 2000 and 2003. Distinct peaks in the depth distribution of these three tracers were located at 1.27 m for Cl(-), 1.31 m for 3H, and 1.52 m for NO3*, 32, 40, and 80 yr after the application of Cl(-), 3H, and NO3*, respectively. The average deep drainage rates, calculated as the product of the estimated tracer velocity and volumetric soil water content below the active root zone, were 2.0 mm yr(-1) from the Cl(-) tracer, 2.2 mm yr(-1) from 3H, and 2.5 mm yr(-1) from the NO3* tracer. Therefore, there was little temporal variability in the groundwater recharge over the eight decades that the field has been cultivated. The recharge rates are less than 1% of the mean annual precipitation (333 mm).     

MANAGEMENT OF BASEFLOW AUGMENTATION: A REVIEW1

ABSTRACT: Baseflow augmentation refers to the temporary storage of subsurface water in floodplains, streambanks, and/or stream bottoms during the wet season, either by natural or artificial means, for later release during the dry season to increase the magnitude and permanence of low flows. Management strategies for baseflow augmentation fall into the following categories: (1) range management, (2) upland vegetation management, (3) riparian vegetation management, (4) upland runoff detention and retention, and (5) the use of instream structures. The benefits of a management strategy focused on baseflow augmentation are many, including: (1) increased summer flows, (2) healthier riparian areas, (3) increased channel and bank stability, (4) decreased erosion and sediment transport, (5) improved water quality, (6) enhanced fish and wildlife habitat, (7) lower stream temperatures, and (8) improved stream aesthetics. This review has shown that baseflow augmentation has been successfully accomplished in a few documented cases. Given its clear impact on soil and water conservation, particularly in the semiarid western U.S., it appears that baseflow augmentation is a concept whose time has come. Research is needed on how to successfully integrate baseflow augmentation within comprehensive resource management strategies.     

THERMAL AND DISSOLVED OXYGEN CHARACTERISTICS OF A SOUTH CAROLINA COOLING RESERVOIR1

ABSTRACT: Temperature and dissolved oxygen concentrations were measured monthly from January 1971 to December 1982 at 1-m depth intervals at 13 stations in Keowee Reservoir in order to characterize spatial and temporal changes associated with operation of the Oconee Nuclear Station. The reservoir water column was i to 4°C warmer in operational than in non-operational years. The thermo-dine was at depths of 5 to 15 m before the operation of Oconee Nuclear Station, but was always below the upper level of the intake (20 m) after the station was in full operation; this suggests that pumping by the Oconee Nuclear Station had depleted all available cool hypolimnetic water to this depth. As a result summer water temperatures at depths greater than 10 m were usually 10°C higher after plant operation began than before. By fall the reservoir was nearly homothemious to a depth of 27 m, where a thermocine developed. Seasonal temperature profiles varied with distance from the plant; a cool water plume was evident in spring and a warm water plume was present in the summer, fall, and winter. A cold water plume also developed in the northern section of the reservoir due to the operation of Jocassee Pumped Storage Station. Increases in the mean water temperature of the reservoir during operational periods were correlated with the generating output of the power plant. The annual heat load to the reservoir increased by one-third after plant operations began. The alteration of the thermal stratification of the receiving water during the summer also caused the dissolved oxygen to mix to greater depths.     

Instream sensor results suggest soil–plant processes produce three distinct seasonal patterns of nitrate concentrations in the Ohio River Basin

The Ohio River Basin (ORB) is responsible for 35% of total nitrate loading to the Gulf of Mexico yet controls on nitrate timing require investigation. We used a set of submersible ultraviolet nitrate analyzers located at 13 stations across the ORB to examine nitrate loading and seasonality. Observed nitrate concentrations ranged from 0.3 to 2.8 mg L⁻¹ N in the Ohio River's mainstem. The Ohio River experiences a greater than fivefold increase in annual nitrate load from the upper basin to the river's junction with the Mississippi River (74–415 Gg year⁻¹). The nitrate load increase corresponds with the greater drainage area, a 50% increase in average annual nitrate concentration, and a shift in land cover across the drainage area from 5% cropland in the upper basin to 19% cropland at the Ohio River's junction with the Mississippi River. Time-series decomposition of nitrate concentration and nitrate load showed peaks centered in January and June for 85% of subbasin-year combinations and nitrate lows in summer and fall. Seasonal patterns of the terrestrial system, including winter dormancy, spring planting, and summer and fall growing-harvest seasons, are suggested to control nitrate timing in the Ohio River as opposed to controls by river discharge and internal cycling. The dormant season from December to March carries 51% of the ORB's nitrate load, and nitrate delivery is high across all subbasins analyzed, regardless of land cover. This season is characterized by soil nitrate leaching likely from mineralization of soil organic matter and release of legacy nitrogen. Nitrate experiences fast transit to the river owing to the ORB's mature karst geology in the south and tile drainage in the northwest. The planting season from April to June carries 26% of the ORB's nitrate and is a period of fertilizer delivery from upland corn and soybean agriculture to streams. The harvest season from July to November carries 22% of the ORB's nitrate and is a time of nitrate retention on the landscape. We discuss nutrient management in the ORB including fertilizer efficiency, cover crops, and nitrate retention using constructed measures.     

SENSITIVITY OF A PRAIRIE WETLAND TO INCREASED TEMPERATURE AND SEASONAL PRECIPITATION CHANGES1

ABSTRACT: We assessed the potential effects of increased temperature and changes in amount and seasonal timing of precipitation on the hydrology and vegetation of a semi-permanent prairie wetland in North Dakota using a spatially-defined, rule-based simulation model. Simulations were run with increased temperatures of 2°C combined with a 10 percent increase or decrease in total growing season precipitation. Changes in precipitation were applied either evenly across all months or to individual seasons (spring, summer, or fall). The response of semi-permanent wetland P1 was relatively similar under most of the seasonal scenarios. A 10 percent increase in total growing season precipitation applied to summer months only, to fall months only, and over all months produced lower water levels compared to those resulting from the current climate due to increased evapotranspiration. Wetland hydrology was most affected by changes in spring precipitation and runoff. Vegetation response was relatively consistent across scenarios. Seven of the eight seasonal scenarios produced drier conditions with no open water and greater vegetation cover compared to those resulting from the current climate. Only when spring precipitation increased did the wetland maintain an extensive open water area (49 percent). Potential changes in climate that affect spring runoff, such as changes to spring precipitation and snow melt, may have the greatest impact on prairie wetland hydrology and vegetation. In addition, relatively small changes in water level during dry years may affect the period of time the wetland contains open water. Emergent vegetation, once it is established, can survive under drier conditions due to its ability to persist in shallow water with fluctuating levels. The model's sensitivity to changes in temperature and seasonal precipitation patterns accentuates the need for accurate regional climate change projections from general circulation models.     

Resolution and Analysis of Spatial Variations and Patterns in an Urban Lake with Rapid Profiling Instrumentation

Rapid response vertical profiling instrumentation was used to document spatial variability and patterns in a small urban lake, Onondaga Lake, associated with multiple drivers. Paired profiles of temperature, specific conductance (SC), turbidity (T_n), fluorometric chlorophyll a (Chl_f), and nitrate nitrogen (NO₃^?) were collected at >30 fixed locations (a “gridding”) weekly, over the spring to fall interval of several years. These gridding data are analyzed (1) to characterize phytoplankton (Chl_f) patchiness in the lake's upper waters, (2) to establish the representativeness of a single long‐term site for monitoring lake‐wide conditions, and (3) to resolve spatial patterns of multiple tracers imparted by buoyancy effects of inflows. Multiple buoyancy signatures were resolved, including overflows from less dense inflows, and interflows to metalimnetic depths and underflows to the bottom from the plunging of more dense inputs. Three different metrics had utility as tracers in depicting the buoyancy signatures as follows: (1) SC, for salinity‐enriched tributaries and the more dilute river that receives the lake's outflow, (2) T_n, for the tributaries during runoff events, and (3) NO₃^?, for the effluent of a domestic waste treatment facility and from the addition of NO₃^? solution to control methyl mercury. The plunging inflow phenomenon, which frequently prevailed, has important management implications.     

Using heat to characterize streambed water flux variability in four stream reaches

Estimates of streambed water flux are needed for the interpretation of streambed chemistry and reactions. Continuous temperature and head monitoring in stream reaches within four agricultural watersheds (Leary Weber Ditch, IN; Maple Creek, NE; DR2 Drain, WA; and Merced River, CA) allowed heat to be used as a tracer to study the temporal and spatial variability of fluxes through the streambed. Synoptic methods (seepage meter and differential discharge measurements) were compared with estimates obtained by using heat as a tracer. Water flux was estimated by modeling one-dimensional vertical flow of water and heat using the model VS2DH. Flux was influenced by physical heterogeneity of the stream channel and temporal variability in stream and ground-water levels. During most of the study period (April-December 2004), flux was upward through the streambeds. At the IN, NE, and CA sites, high-stage events resulted in rapid reversal of flow direction inducing short-term surface-water flow into the streambed. During late summer at the IN site, regional ground-water levels dropped, leading to surface-water loss to ground water that resulted in drying of the ditch. Synoptic measurements of flux generally supported the model flux estimates. Water flow through the streambed was roughly an order of magnitude larger in the humid basins (IN and NE) than in the arid basins (WA and CA). Downward flux, in response to sudden high streamflows, and seasonal variability in flux was most pronounced in the humid basins and in high conductivity zones in the streambed.     

The Use of Carbon and Nitrogen Isotopes to Study Watershed Erosion Processes1

Abstract:  Tracer studies are needed to better understand watershed soil erosion and calibrate watershed erosion models. For the first time, stable nitrogen and carbon isotopes (δ¹⁵N and δ¹³C) and the carbon to nitrogen atomic ratio (C/N) natural tracers are used to investigate temporal and spatial variability of erosion processes within a sub‐watershed. Temporal variability was assessed by comparing δ¹⁵N, δ¹³C, and C/N of eroded‐soils from a non‐equilibrium erosion event immediately following freezing and thawing of surface soils with two erosion events characterized by equilibrium conditions with erosion downcutting. Spatial variability was assessed for the equilibrium events by using the δ¹⁵N and δ¹³C signatures of eroded‐soils to measure the fraction of eroded‐soil derived from rill/interrill erosion on upland hillslopes as compared to headcut erosion on floodplains. In order to perform this study, a number of tasks were carried out including: (1) sampling source‐soils from upland hillslopes and floodplains, (2) sampling eroded‐soils with an in situ trap in the stream of the sub‐watershed, (3) isotopic and elemental analysis of the samples using isotope ratio mass spectrometry, (4) fractioning eroded‐soil to its upland rill/interrill and floodplain headcut end‐members using an unmixing model within a Bayesian Markov Chain Monte Carlo framework, and (5) evaluating tracer unmixing model results by comparison with process‐based erosion prediction models for rill/interrill and headcut erosion processes. Results showed that finer soil particles eroded during the non‐equilibrium event were enriched in δ¹⁵N and δ¹³C tracers and depleted in C/N tracer relative to coarser soil particles eroded during the equilibrium events. Correlation of tracer signature with soil particle size was explainable based on known biogeochemical processes. δ¹⁵N and δ¹³C were also able to distinguish between upland rill/interrill erosion and floodplain headcut erosion, which was due to different plant cover at the erosion sources. Results from the tracer unmixing model highlighted future needs for coupling rill/interrill and headcut erosion prediction models.     

TEMPORAL RESPONSES OF SURFACE‐WATER AND GROUND‐WATER TO PRECIPITATION IN ILLINOIS1

ABSTRACT: Illinois data from 168 months (1986–1999) were investigated to determine the responses of surface‐water and ground‐water resources to precipitation. Such responses were generally within the month of occurrence or one to two months later, with recovery being reached another one to three months into the future, depending on season of the year. Although the drought of 1988 immediately impacted surface‐water and ground‐water resources, the time of recovery was substantially longer compared to those of individual dry months, generally continuing for several months. The extremely wet summer of 1993 resulted in elevated responses in water resources almost immediately, but in this instance continued through the following fall and winter, into the spring of 1994.