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1.
通过对大连市工业区、居民区和城市背景区3种类型区域连续7个月大气样品的采集,分析PAHs在大气中的污染特征,并对其毒性进行评价。结果显示,城市工业区大气中PAHs含量最高,其次是居民区,城市背景区最低。3种类型采样点大气中PAHs的组成相似,菲是含量最多的物质,其次是荧蒽、芴和芘。16种PAHs基于苯并[a]芘的总毒性当量浓度为:工业区5.1 ng/m^3;居民区3.6 ng/m^3;城市背景区4.6 ng/m^3。3种类型功能区大气中PAHs的TEQ值都高于我国的《空气质量标准》(GB 3095-2012)中规定的大气中苯并[a]芘的年平均浓度(1 ng/m^3)或24 h平均浓度(2.5 ng/m^3)。  相似文献   

2.
Vehicular Contamination of Dust in Amman, Jordan   总被引:1,自引:0,他引:1  
Road dust from four traffic areas; the city center, tunnels, closed car parks and a residential area was collected from the urban part of Amman and analyzed for polycyclic aromatic hydrocarbons (PAH) and heavy metals content.Total PAH and selected heavy metals were in the range of a few gg–1. The distribution of PAH was controlled by the arid climatic conditions. PAH distribution in the street dust tended to be dominated by 4- and 6-ring PAHs with significantly less 2- and 3-ring PAH reflecting volatilization of the latter under the hot and dry climatic conditions. However, both PAH and heavy metal concentrations were affected by the densities and conditions of traffic activity at the various sites. Generally, the highest concentrations of both PAH and heavy metals were found in the tunnels and the lowest in the residential areas.Significant correlation between PAH and total organic matter (TOM), lead and cadmium indicated that PAH and heavy metals in street dust of heavily traffic areas are strongly affected by automobile exhaust emission and that those in the residential areas have another source, most probably street material erosion.  相似文献   

3.
Assessment and management of air quality for an opencast coal mining area   总被引:2,自引:0,他引:2  
A study for the assessment and management of the air quality was carried out at Lakhanpur area of Ib Valley Coalfield in Orissa state in India. The 24-h average concentrations of total suspended particulate (TSP) matter, respirable particulate matter (PM10), sulphur dioxide (SO2) and oxides of nitrogen (NOx) were monitored during 1 year period. Samplings were done at a regular interval through out the year at 13 monitoring stations in the residential areas and four monitoring stations in the mining/industrial areas. The 24-hr average TSP and PM10 concentrations ranged from 338.8 to 799.8 microg m(-3) and 102.5-425.6 microg m(-3) for industrial area, and 72.3-497.1 microg m(-3) and 40.8-171.9 microg m(-3) for residential area, respectively. During the study period 24-hr and annual average TSP and PM10 concentrations exceeded the respective standards set in the national ambient air quality standard (NAAQS) protocol at most residential and industrial areas. However, 24-hr and annual average concentrations of SO2 and NOx were well within the prescribed limit of NAAQS both in the residential and industrial areas. The annual and 24-hr average concentrations varied from 23.3 to 36.8 microg m(-3) and 16.0-55.2 microg m(-3) for SO2 and 23.9-41.9 microg m(-3) and 19.0-58.1 microg m(-3) for NOx, respectively. The temporal variations of TSP and PM10 fitted polynomial trend with an average correlation coefficient (R2) of 0.77 (+/-0.17) for TSP and 0.85 (+/-0.10) for PM10. On average the PM10 in the ambient air of the mining area constituted 31.94 (+/-1.76)% of the TSP. The linear regression correlation coefficient (R2) between TSP with PM10 and NOx with SO2 was 0.86 (+/-0.12) and 0.57 (+/-0.20), respectively. Maximal concentrations of TSP and PM10 occurred within the mining site based on the kriging technique. A management strategy is formulated for effective control of air pollution at source and other mitigative measures recommended including implementation of green belts around the sensitive areas where the concentration of air pollutants exceeded the standard limit.  相似文献   

4.
The demand for washed coal in India has led to the planning of washeries. The sources of air pollution in washeries are described is this paper. A number of new washeries are going to be installed within the vicinity of Jharia Coalfield in eastern India to fulfill the demand for washed coal. Air pollution monitoring was conducted at four coal washeries of Bharat Coking Coal Ltd. (BCCL). Methods adopted for selection of monitoring stations and sampling and analysis of ambient air quality are discussed. Suspended particulate matter (SPM) concentrations in an industrial area, a residential area, and a sensitive area such as a hospital were found to be high and to exceed the limit specified by the Indian Pollution Control Board. NOx and SO2 concentrations in some areas were also found to exceed the specified limits. A high percentage of respirable dust in SPM indicates a health hazard. Benzene-soluble material was found to be 40%, which can be fatal to human health. Suppression measures are discussed for dust, and control measures for air pollution in coal washeries are proposed.  相似文献   

5.
为了研究广元市房建施工扬尘排放特征,通过调研获取了广元市2010 ~2019年间的房建工地施工面积、抑尘措施及控制效率,按照自下而上的方法建立了房建施工扬尘排放清单,分析了2019年广元市房建施工扬尘的时空分布特征,并采用CALPUFF对广元市利州区某房建工地的排放进行了模拟.结果 表明:(1) 2010 ~2019年...  相似文献   

6.
We combined a natural experiment with field surveys and GIS to investigate the effects of dust from recreational trails and access roads on the federally threatened Valley elderberry longhorn beetle (“VELB,” Desmocerus californicus dimorphus) and its host plant, elderberry (Sambucus mexicana). Dust is listed in the species recovery plan as a threat to the VELB and unpaved surfaces are common throughout the riparian corridors where the VELB lives, yet the effects of dust on the VELB have been untested. We found that dust deposition varied among sites and was highest within 10 m of trails and roads, but was similar adjacent to dirt and paved surfaces within sites. Elderberry density did not differ with distance from dirt surfaces. Despite similar within-site dust levels, elderberry adjacent to paved surfaces were less stressed than those near dirt ones, possibly because increased runoff from paved surfaces benefited elderberry. Dust deposition across sites was weakly correlated with elderberry stress symptoms (e.g., water stress, dead stems, smaller leaves), indicating that ambient dust (or unmeasured correlates) influenced elderberry. Direct studies of the VELB showed that its distribution was not negatively affected by the proximity to dirt surfaces. Dust from low traffic dirt and paved access roads and trails, therefore, affected VELB presence neither directly nor indirectly through changed elderberry condition. These results suggest that the placement of VELB mitigation, restoration, and conservation areas can proceed independently of access roads if dust and traffic levels do not exceed those in our study site. Furthermore, dust control measures are likely to be unnecessary under such conditions. The potential effects of increased traffic and dust levels are addressed through a literature review.  相似文献   

7.
Human alteration of the landscape has an extensive influence on the biogeochemical processes that drive oxygen cycling in streams. We estimated trends from the mid-1990s to 2003, using the seasonal Mann-Kendall's test, for percent saturation dissolved oxygen (DO), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), and ammonia-nitrogen (NH(3)-N) for 12 sites in the Rock Creek watershed, northwest Oregon, USA. In order to understand the influence of landscape change, scale, and stormwater runoff management on dissolved oxygen trends, we calculated land cover change through aerial photo interpretation at full-basin, local (near sample point) basin, and 100m stream buffer scales, for the years 1994 and 2000. Significant (p < or = 0.05) trends occurred in DO (increasing at five sites), COD (decreasing at seven sites), TKN (decreasing at five sites, increasing at one site), and NH(3)-N (decreasing at one site, increasing at one site). Significant land cover change occurred in agricultural land cover (-8% for the entire basin area) and residential land cover (+10% for the entire basin area) (p < or = 0.05). Correlation results indicated that: (1) forest cover negatively influenced COD at the full basin scale and positively influences NH(3)-N at local scales, (2) residential land cover influenced oxygen demand variables at local scales, (3) agricultural land cover did not influence oxygen demand, (4) local topography negatively influenced TKN and NH(3)-N, and (5) stormwater runoff management infrastructure correlated positively with COD at the local scale. This study indicates that landscape factors influencing DO conditions for the study streams act at multiple scales, suggesting that better knowledge of scale-process interactions can guide watershed managers' decision making in order to maintain improving water quality conditions.  相似文献   

8.
Urbanization is one of the most important aspects of global change. The process of urbanization has a significant impact on the terrestrial ecosystem carbon cycle. The Yangtze Delta region has one of the highest rates of urbanization in China. In this study, carried out in Jiangyin County as a representative region within the Yangtze Delta, land use and land cover changes were estimated using Landsat TM and ETM+ imagery. With these satellite data and the BEPS process model (Boreal Ecosystem Productivity Simulator), the impacts of urbanization on regional net primary productivity (NPP) and annual net primary production were assessed for 1991 and 2002. Landsat-based land cover maps in 1991 and 2002 showed that urban development encroached large areas of cropland and forest. Expansion of residential areas and reduction of vegetated areas were the major forms of land transformation in Jiangyin County during this period. Mean NPP of the total area decreased from 818 to 699 gCm(-2)yr(-1) during the period of 1991 to 2002. NPP of cropland was only reduced by 2.7% while forest NPP was reduced by 9.3%. Regional annual primary production decreased from 808 GgC in 1991 to 691 GgC in 2002, a reduction of 14.5%. Land cover changes reduced regional NPP directly, and the increasing intensity and frequency of human-induced disturbance in the urbanized areas could be the main reason for the decrease in forest NPP.  相似文献   

9.
This study quantified nonpoint source nitrogen (NPS‐N) sources and sinks across the 14,582 km2 Neuse River Basin (NRB) located in North Carolina, to provide tabular data summaries and graphic overlay products to support the development of management approaches to best achieve established N reduction goals. First, a remote sensor derived, land cover classification was performed to support modeling needs. Modeling efforts included the development of a mass balance model to quantify potential N sources and sinks, followed by a precipitation event driven hydrologic model to effectively transport excess N across the landscape to individual stream reaches to support subsequent labeling of transported N values corresponding to source origin. Results indicated that agricultural land contributed 55 percent of the total annual NPS‐N loadings, followed by forested land at 23 percent (background), and urban areas at 21 percent. Average annual N source contributions were quantified for agricultural (1.4 kg/ha), urban (1.2 kg/ha), and forested cover types (0.5 kg/ha). Nonpoint source‐N contributions were greatest during the winter (40 percent), followed by spring (32 percent), summer (28 percent), and fall (0.3 percent). Seasonal total N loadings shifted from urban dominated and forest dominated sources during the winter, to agricultural sources in the spring and summer. A quantitative assessment of the significant NRB land use activities indicated that high (greater than 70 percent impervious) and medium (greater than 35 percent impervious) density urban development were the greatest contributors of NPS‐N on a unit area basis (1.9 and 1.6 kg/ha/yr, respectively), followed by row crops and pasture/hay cover types (1.4 kg/ha/yr).  相似文献   

10.
ABSTRACT: Field investigations were conducted at three sites in the Washington, D.C., area to detect the accumulation patterns of the trace metals, cadmium, copper, lead and zinc in the soils of roadside grassed swale drains that had been receiving urban stormwater runoff. Two sites were residential areas and one site was an intensively used highway. The research results seem to indicate that the use of swale drains to control urban stormwater runoff had few harmful effects to fine textured soils with respect to the study metals. With the exception of zinc, typical roadside patterns of decreasing metal concentrations with increasing distance from roads were observed for the upper 5 cm of study soils. Zinc accumulated in residential grassed swales due to leachate from galvanized curverts. Sampling to a depth of 60 cm revealed no evidence of subsurface trace metal enrichment in the study swales. Although the percentage of soil zinc in leachable form was as high as 20 percent of total zinc concentrations, the other study metals had small leachable components. Leachable lead was always less than 1 percent of the total lead.  相似文献   

11.
Three promising phytoextracting perennial weed species [ L. (ox-eye daisy), L. (curly dock), and L. (Canada goldenrod)] were planted in monoculture plots at two polychlorinated biphenyl (PCB)-contaminated sites in southern Ontario and followed over 2 yr to investigate the effects of plant age, contaminant characteristics, and species-specific properties on PCB uptake and accumulation patterns in plant tissues. Results from this study indicate that, for each of these weed species, shoot contaminant concentrations and total biomass are dependent on plant age and life cycle (vegetative and reproductive stages), which affects the total amount of PCBs phytoextracted on a per-plant basis. Even at suboptimal planting densities of 3 to 5 plants m, all three weed species extracted a greater quantity of PCBs per unit area (4800-10,000 μg m) than the known PCB-accumulator L. ssp (cv Howden pumpkins) (1500-2100 μg m) at one of the two sites. Calculated PCB extractions based on theoretical optimal planting densities were significantly higher at both sites and illustrate the potential of these weeds for site remediation. This study also demonstrates that plants may accumulate PCBs along the stem length in a similar manner as plants.  相似文献   

12.
A data analysis of three major Korean cities was conducted to assess roadside inhalable particulate matter 10 μm or smaller in aerodynamic diameter (PM10), including temporal and meteorological variations, over a recent period of 4 to 6 years. The yearly roadside PM10 concentrations presented a well-defined increasing trend or no trend depending on the roadside monitoring station. Most mean values exceeded or approximated the Korean standard of 70 μg/m3 per year for PM10. A representative roadside diurnal trend was characterized by a distinct morning maximum. In most cases, the Sunday roadside concentrations were similar to or somewhat lower than the weekday concentrations, and the PM10 concentrations presented a well-defined seasonal variation, with the maximum concentration in March. The monthly maximum concentrations observed in March were most likely attributable to Asian dust storms. In two metropolitan cities (Seoul and Busan), the frequency of days with roadside PM10 concentrations exceeding the standard of 150μg/m3 per 24 h was much lower for the roadside monitoring stations than for the residential monitoring station, whereas in the third city (Daegu), this result was reversed. Interestingly, the average maximum concentrations observed for the roadside sites in Seoul and Busan during March were higher than those for the residential sites, suggesting that the roadside concentrations responded more to the dust storms than the residential areas. The relationship between the pollutant concentrations and five important meteorological parameters (solar radiation, wind speed, air temperature, relative humidity, and precipitation) showed that the number and type of meteorological variables included in the equations varied according to the monitoring station or season. Finally, the current results confirmed that attention should be given to the PM10 exposure of residents living near roadways.  相似文献   

13.
The ratio of bioluminescent to total bacteria (bioluminescent ratio, BLR) as an indicator of a variety of types of anthropogenic contamination of estuarine ecosystems was evaluated through a series of laboratory and field studies. Laboratory studies indicated that the BLR of natural bacterioplankton communities was proportionally reduced in the presence of a number of contaminants including diesel fuel and saltmarsh sediments co-contaminated with mercury and polychlorinated biphenyls (PCBs). Bioluminescent ratio inhibition was observed after short-term exposure to a contaminant suggesting a physiological rather than a population response of native microbial communities. Simulated eutrophication did not suppress the BLR. Field observations of the BLR were conducted weekly for a 2-yr period in the Skidaway River estuary, Georgia, USA. These observations revealed considerable seasonal variability associated with the BLR. Bioluminescent ratios were highest during the summer (25 +/- 15%), lower in the fall (6 +/- 5%) and spring (3 +/- 2%), and near zero during the winter. Although the BLR was not significantly correlated to salinity at a single site (Skidaway River estuary), the BLR was significantly correlated with salinity when sites within the same estuary system were compared (r2 = 0.93). Variation in BLR was not correlated to standard bacteriological indicators of water quality including total and fecal coliform bacteria. Comparison of the BLR from impacted and pristine estuarine sites during the fall suggested that anthropogenically impacted sites exhibited lower BLR than predicted from salinity versus BLR relationships developed in pristine systems. These observations suggest that the BLR could be used as a simple and reliable initial indicator of chemical contamination of estuarine systems resulting from human activity.  相似文献   

14.
Movement of nutrients from livestock manure handling sites has the potential to negatively impact the environment. This study was conducted using electromagnetic induction (EMI) measurements to develop apparent soil electrical conductivity (EC(a)) maps to identify regions of nutrient buildup beneath an abandoned compost site. A trailer-mounted EM-38 coupled with a global positioning satellite system was towed across an area used for composting of feedlot manure. The resulting EC(a) maps were compared with known locations of compost rows confirming the alignment of row locations with high EC(a) regions. The identified rows were cored and compared with the region between the rows. The identified rows with a compost history demonstrated significant (P < 0.05) increases in soluble salts (1.6 times greater), NO3 (6.0 times greater), and Cl (2.0 times greater) compared with the area between the rows at a 1.5-m depth. Image processing techniques were used to display yearly changes that were associated with nutrient movement and transformations in the soil beneath the site. Correlations between EMI measurements and soil core analyses for NO3-N, Cl, and EC provided ancillary support for the EMI methods. The use of EMI for mapping of sites having a history of livestock waste application was effective in delineating high nutrient buildup areas and for observing spatial EC(a) changes over time.  相似文献   

15.
ABSTRACT: Geochemistry of fine-fraction streambed sediments collected from the upper illinois River basin was surveyed in the fall of 1987 as part of the U.S. Geological Survey National Water-Quality Assessment pilot projects. The survey included 567 samples analyzed for 46 elements. Three distinctive distribution patterns were found for seven U.S. Environmental Protection Agency priority pollutants surveyed, as well as for boron and phosphorus: (1) enrichment of elements in the Chicago urban area and in streams draining the urban area relative to rural areas, (2) enrichment in main stems relative to tributaries, and (3) enrichment in low-order streams at high-population-density sites relative to low-population-density sites. Significant differences in background concentrations, as measured by samples from low-order streams, were observed among five subbasins in the study area. Uncertain geochemical correspondence between low-order, background sites and high-order, generally metal enriched sites prevented determination of background levels that would be appropriate for high-order sites. The within-sample ratio of enriched elements was variable within the Chicago area but was constant in the Illinois River downstream from Chicago. Element ratios imply a composite fine-fraction sediment in the Illinois River of 35–40 percent Des Plaines River origin and 60–65 percent Kankakee River origin.  相似文献   

16.
Abstract: Runoff from urban catchments depends largely on the amount of impervious surface and the connectivity of these surfaces to the storm sewer drainage system. In residential areas, pervious lawns can be used to help manage stormwater runoff by intercepting and infiltrating runoff from impervious surfaces. The goal of this research was to develop and evaluate a simple method for estimating the reduction in stormwater runoff that results when runoff from an impervious surface (e.g., rooftop) is directed onto a pervious surface (e.g., lawn). Fifty‐two stormwater runoff reduction tests were conducted on six residential lawns in Madison, Wisconsin during the summer of 2004. An infiltration‐loss model that requires inputs of steady‐state infiltration rate, abstraction (defined here as surface storage, vegetation interception and cumulative total infiltration minus steady‐state infiltration during the period prior to steady‐state), and inundated area was evaluated using experimental data. The most accurate results were obtained using the observed steady‐state infiltration rates and inundated areas for each test, combined with a constant abstraction for all tests [root mean squared (RMS) difference = 1.0 cm]. A second case utilized lawn‐averaged steady‐state infiltration rates, a regression estimate of inundated area based on flow‐path length, and lawn‐specific abstractions based on infiltration rate (RMS difference = 2.2 cm). In practice, infiltration rates will likely be determined using double‐ring infiltration measurements (RMS difference = 3.1 cm) or soil texture (RMS difference = 5.7 cm). A generalized form of the model is presented and used to estimate annual stormwater runoff volume reductions for Madison. Results indicate the usefulness of urban lawns as a stormwater management practice and could be used to improve urban runoff models that incorporate indirectly connected impervious areas.  相似文献   

17.
ABSTRACT: Urban storm water data from four catchments near Miami, Florida, were collected and compiled by the U.S. Geological Survey and were used for testing the applicability of deterministic modeling for characterizing storm water flows from small land use areas. The four sites were:
    相似文献   

18.
Cost-effective methods are needed to identify the presence and distribution of tritium near radioactive waste disposal and other contaminated sites. The objectives of this study were to (i) develop a simplified sample preparation method for determining tritium contamination in plants and (ii) determine if plant data could be used as an indicator of soil contamination. The method entailed collection and solar distillation of plant water from foliage, followed by filtration and adsorption of scintillation-interfering constituents on a graphite-based solid phase extraction (SPE) column. The method was evaluated using samples of creosote bush [Larrea tridentata (Sessé & Moc. ex DC.) Coville], an evergreen shrub, near a radioactive disposal area in the Mojave Desert. Laboratory tests showed that a 2-g SPE column was necessary and sufficient for accurate determination of known tritium concentrations in plant water. Comparisons of tritium concentrations in plant water determined with the solar distillation-SPE method and the standard (and more laborious) toluene-extraction method showed no significant difference between methods. Tritium concentrations in plant water and in water vapor of root-zone soil also showed no significant difference between methods. Thus, the solar distillation-SPE method provides a simple and cost-effective way to identify plant and soil contamination. The method is of sufficient accuracy to facilitate collection of plume-scale data and optimize placement of more sophisticated (and costly) monitoring equipment at contaminated sites. Although work to date has focused on one desert plant, the approach may be transferable to other species and environments after site-specific experiments.  相似文献   

19.
The sharing of environmental cost by residents in various residential areas in the developing world is perceived to be unfair. This study therefore assessed residents’ experiences of environmental justice in Ile-Ife, Nigeria. Three residential areas were identified in the study area and samples were selected using systematic sampling. Using availability and condition of urban infrastructure, severity of environmental problems and residents’ involvement in environmental issues, the study examined environmental justice in the study area. The study established a variation in environmental issues across identified residential areas. The severity of environmental problem measured through an index tagged Severity of Environmental Problem (SEPI) revealed that environmental problems was most severe in the core (SEPI = 4.00), followed by the peripheral area (SEPI = 3.71) and least in the transition area (SEPI = 3.56). On the condition of available environmental infrastructure, the study revealed that the conditions of infrastructure were most improved in the peripheral area (ICI = 3.07), followed by the core (ICI = 2.67) and the least in the transition area (ICI = 2.42). The study concluded that residents’ experiences of environmental justice differ significantly across the different residential zones as reflected by residents’ socio-economic characteristics. Furthermore, it established that age, gender, educational status, and number of years spent in the area can be used to explain the differences in residents’ experience of environmental justice in the study area. To enhance the liveability, the study recommends adequate provision of environmental amenities needed by each category of people in the city.  相似文献   

20.
The structure and advancement of woody vegetation was studied in a semi-arid rangeland of southern Ethiopia under three land-use systems (communal land, a government ranch and a traditional grazing reserve enclosure) and along a distance gradient (near, middle and far) from water sources. A total of 54 woody plant species were identified. Based on the subjective opinions of the pastoralists, 85% of the identified woody plants have forage values to livestock. Cadaba farinsoa, Ormocarpum trichocarpum, Rhus natalensis, Acacia brevispica, Cordia gharaf and Hibiscus sparseaculeatus were reported to have fair to good palatability. Tree equivalent (TE) density of all woody plants combined was greater (P <0.01) in the government ranch (1) 188 TE ha(-1)) and the communal land (1083 TE ha(-1)) than in the traditional grazing reserve (419 TE ha(-1)), whereas this did not vary significantly (P >0.05) along the distance gradient from water. The most important encroaching woody plant species in the study areas were in descending order: Commiphora africana, Acacia drepanolobium, A. brevispica, Acacia. tortilis, Grewia tembensis and Lannea floccosa. The density of individual encroaching woody plant species along the distance gradient from water was not consistent. All encroaching woody species had the highest TE density in the communal land. The prevalence of these species followed the pattern of intensity of use within the communal grazing area. Most of the woody species had the highest abundance in the height class >0-2m regardless of land use and distance gradient from water. This study investigated the advance of severe woody encroachment in the communal and government sites as well as along the distance gradient from water. Some of the important contributing factors that can be suggested are heavy grazing pressure (in both the communal and government sites), expansion of cultivation and reduced mobility of livestock due to settlement of the pastoralists in the communal land.  相似文献   

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