Attenuation of N2O emission rates from agricultural soil at different dicyandiamide concentrations

An experiment was conducted to assess the role of different concentrations of dicyandiamide (DCD), a potent nitrification inhibitor, on temporal changes in nitrous oxide emission from sandy loam agricultural soil. It was found that with increasing concentration of DCD i.e. from 6 to 12% of nitrogen applied in the form of urea, there was a decrease in the both average and peak N₂O emissions. However, from 14% DCD treated soil, there was a non-significant alteration in the N₂O emission. Maximum average N₂O efflux of 217.55 μg m⁻² h⁻¹ was noted from control plots. As compared to control, there was an attenuation of 50, 58, 65, and 91% average N₂O efflux from 6, 8, 10 and 12% DCD applied pots, respectively, whereas, there was a negative average of N₂O efflux from the soil with 14% DCD treatment. The soil N content also showed a significant correlation with N₂O emission. Therefore, 12% DCD treatment has been found to be the best with regard to attenuation of nitrous oxide from sandy loam agricultural soils.     

Nitrous oxide emission out of grassland

Grazed grassland which received 295 kg ha^–1 N-fertilizer (NH₄NO₃), split-applied, was used to measure nitrous oxide emission. The closed box method was used. At the same time, also soil cores were taken for incubation in the presence of acetylene. During 280 days in 1992, a total emission of 8.4 kg N₂O-N ha^–1 was found. This was close to 50 % of the total denitrification, which was 18.7 kg (N₂O+N₂)-N ha^–1 over 280 days. A variability study on N₂O emission was carried out on a surface of 1, 100 and 10,000 m², respectively. This study confirmed the lognormal distribution of data with variation coefficients of 20 to 25%. It was also found that the effect of application of 200 kg KNO₃-N on N₂O emission was limited to 2 weeks upon fertilization. It more than doubled the emission rate during this period.     

Greenhouse gas mitigation in rice–wheat system with leaf color chart-based urea application

Conventional blanket application of nitrogen (N) fertilizer results in more loss of N from soil system and emission of nitrous oxide, a greenhouse gas (GHG). The leaf color chart (LCC) can be used for real-time N management and synchronizing N application with crop demand to reduce GHG emission. A 1-year study was carried out to evaluate the impact of conventional and LCC-based urea application on emission of nitrous oxide, methane, and carbon dioxide in a rice–wheat system of the Indo-Gangetic Plains of India. Treatments consisted of LCC scores of ≤4 and 5 for rice and wheat and were compared with conventional fixed-time N splitting schedule. The LCC-based urea application reduced nitrous oxide emission in rice and wheat. Application of 120 kg N per hectare at LCC ≤ 4 decreased nitrous oxide emission by 16% and methane by 11% over the conventional split application of urea in rice. However, application of N at LCC ≤ 5 increased nitrous oxide emission by 11% over the LCC ≤ 4 treatment in rice. Wheat reduction of nitrous oxide at LCC ≤ 4 was 18% as compared to the conventional method. Application of LCC-based N did not affect carbon dioxide emission from soil in rice and wheat. The global warming potential (GWP) were 12,395 and 13,692 kg CO₂ ha⁻¹ in LCC ≤ 4 and conventional urea application, respectively. Total carbon fixed in conventional urea application in rice–wheat system was 4.89 Mg C ha⁻¹ and it increased to 5.54 Mg C ha⁻¹ in LCC-based urea application (LCC ≤ 4). The study showed that LCC-based urea application can reduce GWP of a rice–wheat system by 10.5%.     

Emissions of NO and N2O from soils

Nitric oxide (NO) and nitrous oxide (N₂O) fluxes were measured from agricultural, forest and moorland environments, using chamber techniques. Maximum emissions of NO and N₂O were measured from the agricultural soils shortly after fertiliser application (7 ng NO-N m^–2 s^–1 and 91 ng N₂O-N m^–2 s^–1). For the non-agricultural soils the NO flux ranged from –0.3 to 0.5 ng NO-N m^–2 s^–1 and the N₂O flux ranged from 1 to 2.7 ng N₂O-N m^–2 s^–1. Emissions, however, were increased 2 to 7 fold when N deposition (uplands) and N fixation (alder plantations) contributed to the pool of soil available N. The best predictors of the NO emission were soil NO ₃ ^– and soil temperature, accounting for 60% of the variability observed. The prediction of N₂O was less successful. Only 30% of the variability could be explained by the soil NO ₃ ^– and the soil moisture content, soil temperature did not have a significant effect on the N₂O emission.     

Formation and Emission of N2O and CH4 from Compost Heaps of Organic Household Waster

Composting can be a source of N₂O andCH₄ production. In this investigation, differentcompost heaps of organic household waste weremonitored with the focus on potential formation ofCH₄ and N₂O in the heaps and emission ofthese gases from the heaps. The studied compost heapshad different compost ages, turning intervals andcompost sizes. The analysed compost gases containedbetween 1–3421 L of N₂O-N L^-1 and 0–470 mL of CH₄ L^-1. The emission rates ofN₂O and CH₄ from the compost heaps werebetween 1–1464 mg N₂O m^-2 day^-1 and0–119 000 mg CH₄ m^-2 day^-1. These verylarge differences in compost gas composition andemission indicate the importance of compostmanagement. The results also give an understanding ofwhere in the composting process an increasing emissionof N₂O and CH₄ can occur.     

Assessment of private economic benefits and positive environmental externalities of tea plantation in China

Tea plantations are rapidly expanding in China and other countries in the tropical and subtropical zones, driven by relatively high private economic benefit. However, the impact of tea plantations on the regional environment, including ecosystem services and disservices are unclear. In this study, we developed an assessment framework for determining the private economic benefits and environmental externalities (the algebraic sum of the regulating services and disservices) of tea plantations in China. Our results showed that tea plantations provided private economic benefits of 5,652 yuan ha^?1 year^?1 (7.6 yuan?=?1 USD in 2007) for tea farmers, plus positive environmental externalities of 6,054 yuan ha^?1 year^?1 for the society. The environmental externalities were calculated as the sum of the value of four regulating services, including carbon sequestration (392 yuan ha^?1 year^?1); soil retention (72 yuan ha^?1 year^?1); soil fertility protection (3,189 yuan ha^?1 year^?1) and water conservation (2,685 yuan ha^?1 year^?1), and three disservices, including CO₂ emission (?39 yuan ha^?1 year^?1), N₂O emission (?137 yuan ha^?1 year^?1) and nonpoint source pollution (?108 yuan ha^?1 year^?1). Before the private optimal level, the positive environmental externalities can be maintained by private economic benefits; if a social optimal level is required, subsidies from government are necessary.     

Laboratory study of the emission of NO and N2O from some Belgian soils

The NO, NO₂ and N₂O emission was measured, upon application of nitrate, ammonium and both, to four Belgian soils with different characteristics. The addition of NH ₄ ⁺ caused higher NO and N₂O emissions than the addition of no nitrogen, or the addition of NO ₃ ^– . In contrast to the two soils with a pH of approximately 8 the two soils with a pH around 6 showed a considerable delay in production of both NO and N₂O upon the application of the ammonium, probably due to the lag-period of nitrification. The soils with a pH of 8 gave higher emissions on the application of NH ₄ ⁺ than the soils with a pH of 6. The emission of NO₂ was found to be considerably lower than the NO emission from the soils. The NO/NO₂ ratio varied between 5–25 at considerable NO emissions (>50 nmol kg^–1). In the controls of soil 1 and soil 2, which showed very low NO emissions ratios of <1 were observed. The N₂O/NO ratios varied between 5–20 when NO emissions were considerable (>50 nmol kg^–1). Soil 3 and 4 gave lower N₂O/NO ratios than soil 1 and 2. In the controls of soil 1 and soil 2, at low NO emissions, N₂O/NO ratios of >300 were observed. Soil 3 and 4 gave higher NO/NO₂ and lower N₂O/NO ratios than soil 1 and 2.     

Adaptive nitrogen and integrated weed management in conservation agriculture: impacts on agronomic productivity,greenhouse gas emissions,and herbicide residues

Increasing nitrogen (N) immobilization and weed interference in the early phase of implementation of conservation agriculture (CA) affects crop yields. Yet, higher fertilizer and herbicide use to improve productivity influences greenhouse gase emissions and herbicide residues. These tradeoffs precipitated a need for adaptive N and integrated weed management in CA-based maize (Zea mays L.)—wheat [Triticum aestivum (L.) emend Fiori & Paol] cropping system in the Indo-Gangetic Plains (IGP) to optimize N availability and reduce weed proliferation. Adaptive N fertilization was based on soil test value and normalized difference vegetation index measurement (NDVM) by GreenSeeker? technology, while integrated weed management included brown manuring (Sesbania aculeata L. co-culture, killed at 25 days after sowing), herbicide mixture, and weedy check (control, i.e., without weed management). Results indicated that the ‘best-adaptive N rate’ (i.e., 50% basal + 25% broadcast at 25 days after sowing + supplementary N guided by NDVM) increased maize and wheat grain yields by 20 and 14% (averaged for 2 years), respectively, compared with whole recommended N applied at sowing. Weed management by brown manuring (during maize) and herbicide mixture (during wheat) resulted in 10 and 21% higher grain yields (averaged for 2 years), respectively, over the weedy check. The NDVM in-season N fertilization and brown manuring affected N₂O and CO₂ emissions, but resulted in improved carbon storage efficiency, while herbicide residuals in soil were significantly lower in the maize season than in wheat cropping. This study concludes that adaptive N and integrated weed management enhance synergy between agronomic productivity, fertilizer and herbicide efficiency, and greenhouse gas mitigation.     

Dynamics of Organic Carbon and Microbial Biomass in Alluvial Soil With Tillage and Amendments in Rice-wheat Systems

Rice-wheat cropping systems of the Indo-Gangetic plains (IGP) occupying 12 million ha of productive land are important for the food security of South Asia. There are, however, concerns that yield and factor productivity trends in these systems are declining/stagnating in recent years. Decrease in soil organic carbon is often suggested as a reason for such trends. A field experiment was conducted to study the soil organic carbon (SOC) and soil microbial biomass carbon (MBC) dynamics in the rice-wheat systems. Use of organic amendments and puddling of soil before rice transplanting increased SOC and MBC contents. Microbial biomass carbon showed a seasonal pattern. It was low initially, reached its peak during the flowering stages in both rice and wheat and declined thereafter. Microbial biomass carbon was linearly related to SOC in both rice and wheat indicating that SOC could be used as a proxy for MBC.     

Inspection of non-CO2 greenhouse gases from emission sources and in ambient air by Fourier-transform-infrared-spectrometry: Measurements with FTIS-MAPS

Infrared spectrometry is a versatile basis to analyse greenhouse gases in the atmosphere. A multicomponent air pollution software (MAPS) was developed for retrieval of gas concentrations from radiation emission as well as absorption measurements. Concentrations of CO, CH₄, N₂O, and H₂O as well as CO₂, NO, NO₂, NH₃, SO₂, HCl, HCHO, and the temperature of warm gases are determined on-line. The analyses of greenhouse gases in gaseous emission sources and in ambient air are performed by a mobile remote sensing system using the double-pendulum interferometer K300 of the Munich company Kayser-Threde. Passive radiation measurements are performed to retrieve CO, N₂O, and H₂O as well as CO₂, NO, SO₂, and HCl concentrations in smoke stack effluents of thermal power plants and municipal incinerators and CO and H₂O as well as CO₂ and NO in exhausts of aircraft engines. Open-path radiation measurements are used to determine greenhouse gas concentrations at different ambient air conditions and greenhouse gas emission rates of diffusive sources as garbage deposits, open coal mining, stock farming together with additional compounds (e.g. NH₃), and from road traffic together with HCHO. Some results of measurements are shown. A future task is the verification of emission cadastres by these inspection measurements.     

Effect of pendimethalin and quizalofop on N<Subscript>2</Subscript>-fixing bacteria in relation to availability of nitrogen in a <Emphasis Type="Italic">Typic Haplustept</Emphasis> soil of West Bengal,India

An experiment was conducted under laboratory conditions to investigate the effect of two systemic herbicides viz., pendimethalin and quizalofop, at their recommended field rates (1.0 kg and 50 g active ingredient ha^− 1, respectively) on the growth and activities of non-symbiotic N₂-fixing bacteria in relation to mineralization and availability of nitrogen in a Typic Haplustept soil. Both the herbicides, either singly or in a combination, stimulated the growth and activities of N₂-fixing bacteria resulting in higher mineralization and availability of nitrogen in soil. The single application of quizalofop increased the proliferation of aerobic non-symbiotic N₂-fixing bacteria to the highest extent while that of pendimethalin exerted maximum stimulation to their N₂-fixing capacity in soil. Both the herbicides, either alone or in a combination, did not have any significant difference in the stimulation of total nitrogen content and availability of exchangeable NH₄ ⁺ while the solubility of NO₃ ⁻ was highly manifested when the herbicides were applied separately in soil.     

Persistence behaviour of imidacloprid and its metabolites in soil under sugarcane

The persistence and metabolism of imidacloprid in soil under sugarcane were studied following application of imidacloprid at 20 and 80 g active ingredient (a.i.) ha^?1. Soil samples were collected at different time intervals (7, 15, 30, 45, 60 and 90 days after application), and the residues of imidacloprid and its metabolites (6-chloronicotinic acid, nitrosimine, imidacloprid-NTG, olefin, urea and 5-hydroxy) were quantified by high-performance liquid chromatography. In soil, the total imidacloprid residues were mainly constituted by the parent compound followed by 6-chloronicotinic acid, nitrosimine and imidacloprid-NTG metabolites. Maximum residues of imidacloprid and its metabolites were 4.29 and 7.81 mg kg^?1 in soil samples collected 7 days after the application of imidacloprid at 20 and 80 g a.i. ha^?1, respectively. At both doses, these residues declined to below the detectable limit in soil after 90 days of application. Olefin, urea and 5-hydroxy metabolites were not detected in soil. Dissipation of total imidacloprid residues did not follow the first-order kinetics with a coefficient of determination value of 0.883 and 0.838 for the recommended dose and four times the recommended dose, respectively. The half-life (T _1/2) value of total imidacloprid was observed to be 10.64 and 10.10 days for the recommended dose and four times the recommended dose, respectively.     

Separate estimation of N export into baseline N leakage without disturbance and N loss due to insect defoliation in a pine forest watershed in central Japan

Pine wilt disease (PWD) is caused by a non-native pest that has spread extensively throughout Japan. Previous research has indicated that most infected trees have died and the litter deposited has resulted in changes to stream-water chemistry, particularly increased nitrate (NO ₃ ^? ) concentrations. In this study, we divided stream nitrogen (N) export into N loss due to PWD and baseline N leakage without disturbance based on long-term monitoring. The annual N export was 110.0 mol N ha^?1 year^?1 in 1990 and 749.8 mol N ha^?1 year^?1 in 1997, and had decreased to 37.0 mol N ha^?1 year^?1 in 2005. N export under PWD influence was estimated to be 3697 mol N ha^?1, and N loss due to PWD was 2810 mol N ha^?1. N loss due to PWD was three times larger than baseline N leakage for the disturbed period. These changes in plant–herbivore relationships could affect N status in a forest ecosystem. So-called “semi-natural” disturbances related to non-native species invasion and increases of atmospheric N deposition caused by human activity will increase. Long-term monitoring studies of various aspects are necessary to offer insight into this ecosystem.     

Carbon density and accumulation in agroecosystem of Indo-Gangetic Plains and Vindhyan highlands,India

In agroecosystems, the annual carbon (C) inputs to soil are one of the most promising greenhouse gas mitigation options. Net primary productivity (NPP) provides the inputs of C in ecosystems that can potentially be sequestered in soil organic matter. In this study, we estimates the C density and accumulation rate in rice–wheat agroecosystem at four sites of Indo-Gangetic Plains and Vindhyan highlands through amalgamation of ground truth (GT) and remote sensing (RS) approach. In addition to this, we validated field-measured aboveground net production (ANP) with remotely sensed SPOT-Vegetation data. ANP of the sites ranged from 6.8 to 11.1 and 3.3 to 8.8 t-C ha^?1 year^?1 for GT and RS, respectively. Both estimates (GT and RS) were linearly and significantly related with each other (y?=?1.33x???5.82, R ²?=?0.93, P?=?0.04; where x?=?GT ANP and y?=?RS ANP). For the whole region, total NPP (rice?+?wheat) was ranged from 7.9 to 12.5 t-C ha^?1 year^?1. The C accumulation potential of the present agroecosystems was 9.1 and 1.9 t-C ha^?1 year^?1 in the form of ANP and belowground NPP (BNP), respectively. The aboveground C stock of agroecosystem allocated in foliage (7.8 %), stem (57.6 %), and grain (35.1 %). Survey about the fate of post-harvested materials indicated that aboveground portion of the crop is almost used completely within the year for different purposes including human consumption and cattle feeding. Therefore, only BNP and litter contribute to long-term C sequestration. Since agroecosystem has enormous potential to sequester C, better management of aboveground portion NPP of the crop may enhance C sequestration potential of agroecosystem.     

Long-term spatiotemporal patterns of CH4 and N2O emissions from livestock and poultry production in Turkey

This study quantified spatiotemporal patterns of CH₄ and N₂O emissions from livestock and poultry production in Turkey between 1961 and 2007. CH_4(enteric) (from enteric fermentation), CH_4(manure) (from manure management), and N₂O_(AWM) (from animal waste management) emissions in Turkey were estimated at 1,164, 216, and 55 Gg in 1961 and decreased to 844, 187, and 39 Gg in 2007, contributing a share of roughly 2% to the global livestock-related CH₄ emissions and %1.5 to the global N₂O_(AWM) emissions, respectively. Total CO₂-eq emissions were estimated at 50.7 Tg in 1961 and declined from a maximum value of 60.7 Tg in 1982 to a minimum value of 34.5 Tg in 2003, with a mean emission rate of 48 Tg year^???1 due to a significant reduction in the number of ruminant livestock. The highest mean share of emissions belonged to West Black Sea (14% and 16%) for CH_4(enteric) and CH_4(manure) and to North East Anatolia (12% and %13) for N₂O_(AWM) and total CO₂-eq emissions, respectively. The highest emission density was 1.7 Mg km^???2 year^???1 for CH_4(enteric), 0.3 Mg km^???2 year^???1 for CH_4(manure), and 0.07 Mg km^???2 year^???1 for the total CO₂-eq emissions in the West and North East Anatolia regions and 0.09 Mg km^???2 year^???1 for N₂O_(AWM) in the East Marmara region. Temporal and spatial variations in CH_4(enteric), CH_4(manure), and N₂O_(AWM) emissions in Turkey were estimated using regression models and ordinary kriging at a 500-m resolution, respectively.     

Methane fluxes in aerobic soils

Aerobic soils are an important sink for methane (CH₄), contributing up to 15% of global CH₄ destruction. However, the sink strength is significantly affected by land management, nitrogen (N) fertilizers and acidity. The rates of uptake from the atmosphere of both enhanced (10 ppmv) and ambient (2 ppmv) concentrations of CH₄ were measured in laboratory incubations of soil cores under controlled conditions taken from sites in the U.K. and Germany. The most rapid rates of uptake were measured in soil from deciduous woodland at pH 4 (measured in water). Extended (150 years) cultivation of land for arable crops reduced uptake rate by 85% compared to that in the same soil under an adjacent woodland. The long-term application of ammonium (NH₄)-based fertilizer, but not nitrate (NO₃)-based fertilizer, completely inhibited CH₄ uptake, but the application for the same period of farmyard manure (FYM) that contained more N than the fertilizer had no inhibitory effect. Where a combination of FYM and inorganic fertilizer was applied there was a reduction in methane uptake rate compared to plots receiving solely FYM.Autoclaving showed that the uptake of CH₄ was microbially mediated. The most likely causes of the inhibitory effects seen are (i) insufficient concentrations of CH₄ in situ to activate methane monooxygenase; (ii) the direct inhibition of CH₄ oxidation by NH _inf4 ^sup+ ions; (iii) the suppression of methanotrophs by NH₄-based fertilizers; (iv) the requirement of methanotrophs for a stable soil architecture which is incompatible with the disturbance caused by regular arable cultivation.     

Estimation of green house gas emissions from Koteshwar hydropower reservoir,India

The emissions of greenhouse gas (GHG) from soils are of significant importance for global warming. The biological and physico-chemical characteristics of soil affect the GHG emissions from soils of different land use types. Methane (CH₄), nitrous oxide (N₂O), and carbon dioxide (CO₂) production rates from six forest and agricultural soil types in the Koteshwar hydropower reservoir catchments located in the Uttarakhand, India, were estimated and their relations with physico-chemical characteristics of soils were examined. The samples of different land use types were flooded and incubated under anaerobic condition at 30 °C for 60 days. The cumulative GHG production rates in reservoir catchment are found as 1.52 ± 0.26, 0.13 ± 0.02, and 0.0004 ± 0.0001 μg g soil^?1 day^?1 for CO₂, CH₄, and N₂O, respectively, which is lower than global reservoirs located in the same eco-region. The significant positive correlation between CO₂ productions and labile organic carbon (LOC), CH₄ and C/N ratio, while N₂O and N/P ratio, while pH of soils is negatively correlated, conforms their key role in GHG emissions. Carbon available as LOC in the reservoir catchment is found as 3–14% of the total ?C” available in soils and 0–23% is retained in the soil after the completion of incubation. The key objective of this study to signify the C, N, and P ratios, LOC, and pH with GHG production rate by creating an incubation experiment (as in the case of benthic soil/sediment) in the lab for 60 days. In summary, the results suggest that carbon, as LOC were more sensitive indicators for CO₂ emissions and significant C, N, and P ratios, affects the GHG emissions. This study is useful for the hydropower industry to know the GHG production rates after the construction of reservoir so that its effect could be minimized by taking care of catchment area treatment plan.     

Anthropogenic emissions of methane and nitrous oxide in the Federal Republic of Germany

The anthropogenic emission sources of methane (CH₄) and nitrous oxide (N₂O) in the Federal Republic of Germany were investigated. The object of the recently completed first phase of this research project was to summarize the present knowledge about the emission sources, make a first rough estimate of the emissions, identify the need for further research in the field, and - as far as possible - discuss the existing possibilities to reduce emissions. The main CH₄ emission sources identified are the landfills, stock farming and pit mining, the main N₂O sources are agriculture (including a minor contribution from animal wastes) and the production of adipic acid, the latter possibly being reducible by means of a new catalytic process. The total anthropogenic emissions of CH₄ from Germany are estimated at 5.4 – 7.7 million tonnes per year, contributing a share of roughly 2 % to the world-wide anthropogenic emissions (350 million t/a). Those of N₂O are estimated at 200 000 – 280 000 tonnes per year (world-wide 1.4 – 6.5 million t/a).     

Three-year monitoring results of nitrate and ammonium wet deposition in Thailand

Wet deposition is one of the important sources of nitrogen input into the ecosystem. It also contributes to rain acidity in some environments. In this study we reported the annual as well as seasonal trends of nitrogen wet deposition at three locations in Thailand: Bangkok, Chiang Mai and Nan. Comparison of nitrogen wet deposition between in rural and in the urban areas was also made. Daily rainfall was measured and monthly rainwater was collected for nitrogen analysis during 1999–2002. The average NO₃ ^– concentration in rainwater collected from the rural sites (60 km from urban area) was around 0.2–0.3 mg L^–1, while that from the urban areas of Chiang Mai and Nan cities it was 0.4–0.5 mg L^–1. NH₄ ⁺ concentration in rainwater showed the similar ranges to that of NO₃ ^– , except at Nan where concentration was not significantly different between the urban and rural sites. On the other hand, the average concentrations of NO₃ ^– were higher at Bangkok site than other sites, while concentration of NH₄ ⁺ was almost the same between Chiang Mai and Bangkok. Wet deposition of NO₃ ^– at the rural sites of Chiang Mai and Nan ranged from 2.1 to 3.2 kg N ha^–1 yr^–1, while at the urban sites this ranged from about 6 kg N ha^–1 yr^–1 in Chiang Mai and Nan Cities to 8.6 kg N ha^–1 yr^–1 in Bangkok. Wet deposition of NH₄ ⁺ at the rural sites of Chiang Mai and Nan was about 2.4 to 3.6 kg N ha^–1 yr^–1 and at the urban sites of Chiang Mai, Nan and Bangkok this was 7.7, 4.9 and 8.1 kg N ha^–1 yr^–1, respectively. Thus, it was concluded that wet deposition of both nitrogen species was significantly higher at the urban sites than at the rural sites.     

Persistent Organochlorine Pesticide Residues in Soil and Surface Water of Northern Indo-Gangetic Alluvial Plains

This study reports the concentration levels and distribution pattern of the organochlorine pesticide (OCPs) residues in the soil and surface water samples collected from the northern Indo-Gangetic alluvial plains. A total of 31 soil and 23 surface water samples were collected from the study region in Unnao district covering an area of 2150 km² and analyzed for aldrin, dieldrin, endrin, HCB, HCH isomers, DDT isomers/metabolites, endosulfan isomers (α and β), endosulfan sulfate, heptachlor and its metabolites, α-chlordane, γ-chlordane and methoxychlor. In both the soil and surface water samples β- and δ-isomers of HCH were detected most frequently, whereas, methoxychlor was the least detected pesticide. The results showed contamination of soil and surface water of the region with several persistent organic pesticides. The total OCPs level ranged from 0.36–104.50 ng g^–1 and 2.63–3.72 μg L^–1 in soil and surface water samples, respectively.