Assessment of regional climatic changes in the Eastern Himalayan region: a study using multi-satellite remote sensing data sets

In this study, an attempt has been made to capture the sensitivity of a mountainous region to elevation-dependent warming and the response of a glacier-laden surface to increasing greenhouse gases (GHGs) and aerosol concentration. Some of the changes Sikkim has undergone due to urban sprawl are as follows: an increase of ~0.7?±?0.46 °C temperature in the past 40 years at an altitude of 5.5 km; a 2.21 km²/year rate of loss of glacierised area in the past 33 years; an increase in absorbed longwave radiation (6?±?2.41 W/m²); an increase in heat fluxes (2?±?0.97 W/m²); a decrease in albedo during the last 30 years; an increase in the concentrations of carbon dioxide (4.42 %), methane (0.61 %), ozone (0.67 %) and black carbon column optical depth (7.19 %); a decrease in carbon monoxide (2.61 %) and an increase in aerosol optical depth (19.16 %) during the last decade; a decrease in precipitation, water yield, discharge and groundwater; and an increase in evapotranspiration during 1971–2005. Detection of three climate signals (1976, 1997 and 2005) in the entire analysis is the quantification of the fact that the climate of Sikkim is moving away from its inter-annual variability. An increase in temperature (0.23 °C/decade) at higher altitude (~5.5 km), suppression of precipitation, decreasing water availability and rapid loss of glacierised area are the evidences of the fact that air pollution is playing a significant role in bringing about regional climatic changes in Sikkim. In this study, change detection method has been used for the first time for the estimation of change in a glacierised area of the region.     

Spatio-temporal footprints of urbanisation in Surat, the Diamond City of India (1990–2009)

Urbanisation is a ubiquitous phenomenon with greater prominence in developing nations. Urban expansion involves land conversions from vegetated moisture-rich to impervious moisture-deficient land surfaces. The urban land transformations alter biophysical parameters in a mode that promotes development of heat islands and degrades environmental health. This study elaborates relationships among various environmental variables using remote sensing dataset to study spatio-temporal footprint of urbanisation in Surat city. Landsat Thematic Mapper satellite data were used in conjugation with geo-spatial techniques to study urbanisation and correlation among various satellite-derived biophysical parameters, [Normalised Difference Vegetation Index, Normalised Difference Built-up Index, Normalised Difference Water Index, Normalised Difference Bareness Index, Modified NDWI and land surface temperature (LST)]. Land use land cover was prepared using hierarchical decision tree classification with an accuracy of 90.4 % (kappa?=?0.88) for 1990 and 85 % (kappa?=?0.81) for 2009. It was found that the city has expanded over 42.75 km² within a decade, and these changes resulted in elevated surface temperatures. For example, transformation from vegetation to built-up has resulted in 5.5?±?2.6 °C increase in land surface temperature, vegetation to fallow 6.7?±?3 °C, fallow to built-up is 3.5?±?2.9 °C and built-up to dense built-up is 5.3?±?2.8 °C. Directional profiling for LST was done to study spatial patterns of LST in and around Surat city. Emergence of two new LST peaks for 2009 was observed in N–S and NE–SW profiles.     

Receptor model-based source apportionment of particulate pollution in Hyderabad, India

Air quality in Hyderabad, India, often exceeds the national ambient air quality standards, especially for particulate matter (PM), which, in 2010, averaged 82.2?±?24.6, 96.2?±?12.1, and 64.3?±?21.2 μg/m³ of PM₁₀, at commercial, industrial, and residential monitoring stations, respectively, exceeding the national ambient standard of 60 μg/m³. In 2005, following an ordinance passed by the Supreme Court of India, a source apportionment study was conducted to quantify source contributions to PM pollution in Hyderabad, using the chemical mass balance (version 8.2) receptor model for 180 ambient samples collected at three stations for PM₁₀ and PM_2.5 size fractions for three seasons. The receptor modeling results indicated that the PM₁₀ pollution is dominated by the direct vehicular exhaust and road dust (more than 60 %). PM_2.5 with higher propensity to enter the human respiratory tracks, has mixed sources of vehicle exhaust, industrial coal combustion, garbage burning, and secondary PM. In order to improve the air quality in the city, these findings demonstrate the need to control emissions from all known sources and particularly focus on the low-hanging fruits like road dust and waste burning, while the technological and institutional advancements in the transport and industrial sectors are bound to enhance efficiencies. Andhra Pradesh Pollution Control Board utilized these results to prepare an air pollution control action plan for the city.     

Simultaneous measurement of ventilation using tracer gas techniques and VOC concentrations in homes, garages and vehicles

Air exchange rates and interzonal flows are critical ventilation parameters that affect thermal comfort, air migration, and contaminant exposure in buildings and other environments. This paper presents the development of an updated approach to measure these parameters using perfluorocarbon tracer (PFT) gases, the constant injection rate method, and adsorbent-based sampling of PFT concentrations. The design of miniature PFT sources using hexafluorotoluene and octafluorobenzene tracers, and the development and validation of an analytical GC/MS method for these tracers are described. We show that simultaneous deployment of sources and passive samplers, which is logistically advantageous, will not cause significant errors over multiday measurement periods in building, or over shorter periods in rapidly ventilated spaces like vehicle cabins. Measurement of the tracers over periods of hours to a week may be accomplished using active or passive samplers, and low method detection limits (<0.025 microg m(-3)) and high precisions (<10%) are easily achieved. The method obtains the effective air exchange rate (AER), which is relevant to characterizing long-term exposures, especially when ventilation rates are time-varying. In addition to measuring the PFT tracers, concentrations of other volatile organic compounds (VOCs) are simultaneously determined. Pilot tests in three environments (residence, garage, and vehicle cabin) demonstrate the utility of the method. The 4 day effective AER in the house was 0.20 h(-1), the 4 day AER in the attached garage was 0.80 h(-1), and 16% of the ventilation in the house migrated from the garage. The 5 h AER in a vehicle traveling at 100 km h(-1) under a low-to-medium vent condition was 92 h(-1), and this represents the highest speed test found in the literature. The method is attractive in that it simultaneously determines AERs, interzonal flows, and VOC concentrations over long and representative test periods. These measurements are practical, cost-effective, and helpful in indoor air quality and other investigations.     

Evaluating the urban climate of a typically tropical city of northeastern Brazil

This study attempted to assess a bioclimate index and the occurrence of an urban heat island in the city of Campina Grande, northeastern Brazil, using data taken from mobile measurements and Automatic Weather Stations (AWS). The climate data were obtained during two representative months, one for the dry season (November 2005) and one for the rainy season (June 2006) at seven points in an urban area. Ten-minute air temperatures recorded by an AWS installed in urban areas were compared to those from a similar station located in a suburban area to assess the urban heat island (UHI). The data were collected using a 23X data logger (Campbell Scientific, Inc.) programmed for collecting data every second. The thermal discomfort level was analyzed by Thom’s discomfort index (DI), and an analysis of variance was applied for assessing if there was any statistically significant difference at the 1% and 5% significance level of thermal comfort among points. Mann–Kendall statistical test was used for identifying possibly significant trends in a time series for air temperature, relative humidity, and class A pan evaporation for the city of Campina Grande. The present study found UHI intensities of 1.48°C and ??0.7°C for the months taken as representative of the dry and rainy seasons, respectively. Summer in the city has partially comfortable conditions while the winter is fully comfortable. There are significant changes in DI hourly values between seasons. Only during the rainy season did all points of the city have a comfortable condition until 8:19 h, at which time they become partially comfortable for the rest of the day. Results indicated that there was a 1.5°C increase in air temperature and a 7.2% reduction in relative humidity throughout the analyzed time series. The DI also showed a statistically significant increasing trend (Mann–Kendall test, p?<?0.01) for the dry and rainy seasons and annual period of approximately 1°C in the last 41 years in the city of Campina Grande.     

Spatiotemporal distribution and the characteristics of the air temperature of a river source region of the Qinghai-Tibet Plateau

As the backland of the Qinghai-Tibet Plateau, the river source region is highly sensitive to changes in global climate. Air temperature estimation using remote sensing satellite provides a new way of conducting studies in the field of climate change study. A geographically weighted regression model was applied to estimate synchronic air temperature from 2001 to 2015 using Moderate-Resolution Imaging Spectroradiometry (MODIS) data. The results were R²?=?0.913 and RMSE?=?2.47 °C, which confirmed the feasibility of the estimation. The spatial distribution and variation characteristics of the average annual and seasonal air temperature were analyzed. The findings are as follows: (1) the distribution of average annual air temperature has significant terrain characteristics. The reduction in average annual air temperature along the elevation of the region is 0.19 °C/km, whereas the reduction in the average annual air temperature along the latitude is 0.04 °C/degree. (2) The average annual air temperature increase in the region is 0.37 °C/decade. The average air temperature increase could be arranged in the following decreasing order: Yangtze River Basin > Mekong River Basin > Nujiang River Basin > Yarlung Zangbo River Basin > Yellow River Basin. The fastest, namely, Yangtze River Basin, is 0.47 °C/decade. (3) The average air temperature rise in spring, summer, and winter generally increases with higher altitude. The average annual air temperature in different types of lands following a decreasing order is as follows: wetland > construction land > bare land glacier > shrub grassland > arable land > forest land > water body and that of the fastest one, wetland, is 0.13 °C/year.     

Effect of Building Orientations on Gaseous Dispersion in Street Canyon: a Numerical Study

This paper studies the effects of building orientations on the gaseous pollutant dispersion released from vehicles exhaust in street canyons through computational fluid dynamics (CFD) numerical simulations using three k–ε turbulence models. Four building orientations of the street canyon were examined in the atmospheric boundary layer. The numerical results were validated against wind-tunnel results to optimize the turbulence models. The numerical results agreed well with the wind-tunnel results. The simulation demonstrated that the minimum concentration at the human respiration height in the street canyon was on the windward side for the building orientations θ?=?112.5°, 135°, and 157.5°. The pollutant concentration level decreases as the building orientation increases from θ?=?90°. The concentration in the cavity region for the building orientation θ?=?90° was higher than for the wind directions θ?=?112.5°, 135°, and 157.5°. The wind velocity and turbulence energy increase as the building orientation increases. The finding from this work can be used to help urban designers and policy-makers in several aspects.     

Prediction of the solubility of zinc, copper, nickel, cadmium, and lead in metal-contaminated soils

Risk assessment of metal-contaminated soil depends on how precisely one can predict the solubility of metals in soils. Responses of plants and soil organisms to metal toxicity are explained by the variation in free metal ion activity in soil pore water. This study was undertaken to predict the free ion activity of Zn, Cu, Ni, Cd, and Pb in metal-contaminated soil as a function of pH, soil organic carbon, and extractable metal content. For this purpose, 21 surface soil samples (0–15 cm) were collected from agricultural lands of various locations receiving sewage sludge and industrial effluents for a long period. One soil sample was also collected from agricultural land which has been under intensive cropping and receiving irrigation through tube well water. Soil samples were varied widely in respect of physicochemical properties including metal content. Total Zn, Cu, Ni, Cd, and Pb in experimental soils were 2,015?±?3,373, 236?±?286, 103?±?192, 29.8?±?6.04, and 141?±?270 mg kg^?1, respectively. Free metal ion activity, viz., pZn²⁺, pCu²⁺, pNi²⁺, pCd²⁺, and pPb²⁺, as estimated by the Baker soil test was 9.37?±?1.89, 13.1?±?1.96, 12.8?±?1.89, 11.9?±?2.00, and 11.6?±?1.52, respectively. Free metal ion activity was predicted by pH-dependent Freundlich equation (solubility model) as a function of pH, organic carbon, and extractable metal. Results indicate that solubility model as a function of pH, Walkley–Black carbon (WBC), and ethylenediaminetetraacetic acid (EDTA)-extractable metals could explain the variation in pZn²⁺, pCu²⁺, pNi²⁺, pCd²⁺, and pPb²⁺ to the extent of 59, 56, 46, 52, and 51 %, respectively. Predictability of the solubility model based on pH, KMnO₄-oxidizable carbon, and diethylenetriaminepentaacetic acid-extractable or CaCl₂-extractable metal was inferior compared to that based on EDTA-extractable metals and WBC.     

Bacterial response to dynamic metal concentrations in the surface sediments of a solar saltern (Goa, India)

The Ribandar solar saltern, situated adjacent to the Mandovi estuary is influenced by the barge transport of ferromanganese ore to the Mormugao harbour (Arabian Sea). The current study focuses on the distribution of metals and related heterotrophic bacterial populations in the surface sediments (0–10 cm) of the Ribandar salterns (Goa, India) during the salt-making (January to May) and non salt-making seasons (August and November). The concentrations of heavy metals in the sediments ranged from 17.2?±?2.8 to 26.3?±?6.7 % Fe; 0.6?±?0.2 to 0.9?±?0.2 % Mn; 27.6?±?7.3 to 51?±?8.3 ppm Ni; 28.4?±?8.9 to 35.2?±?10.6 ppm Co; 44?±?21.6 to 62.8?±?23.6 ppm Zn; 0.1?±?0.01 ppm Cd and 1.7?±?0.1 to 2.6?±?0.7 ppm Pb and were much higher than those reported at the same site in a previous study by Kerkar (2004). Hg concentrations were below detection limits. In general, computation of “geoaccumulation index” revealed the sediments as ‘uncontaminated to moderately contaminated’ with Fe, Mn, Ni, Co, Pb and Zn during the salt-making season. The abundance of metal-tolerant bacteria was comparatively restricted to the salt-making season and was higher than the non salt-making season. Fe-, Mn-, Ni-, Co- and Pb- (200 ppm) tolerant bacteria were retrieved and restricted to the surface sediments (0–5 cm), Cd and Fe being the two most regulatory elements governing bacterial populations in the non salt-making season. However, during the salt-making season, the concentration of Zn was found to be pivotal in regulating the counts of Fe-, Mn- and Ni-tolerant bacteria. In general, the strength of correlation of metals and microbes was higher in the non salt-making season as compared to the salt-making season. This would probably indicate metal-induced limitations in microbial populations in the non salt-making season and the absence of this effect during the salt-making season. In this study, we test the hypothesis that solar salterns behave as ecological sinks with a potential to transform native bacterial populations to metal-resistant strains, in relation to the dynamic changes in the surrounding metal concentrations.     

Biogas from poultry waste—production and energy potential

The objective of this study was to evaluate the effect of heat treatment on poultry litter with different levels of reutilisation for potential generation of biogas in experimental biodigesters. Chicken litter used was obtained from two small-scale poultry houses where 14 birds m^?2 were housed for a period of 42 days per cycle. Litter from aviary 1 received no heat treatment while each batch of litter produced from aviary 2 underwent a fermentation process. For each batch taken, two biodigesters were set for each aviary, with hydraulic retention time of 35 days. The efficiency of the biodigestion process was evaluated by biogas production in relation to total solids (TS) added, as well as the potential for power generation. Quantified volumes ranged from 8.9 to 41.1 L of biogas for aviary 1, and 6.7 to 33.9 L of biogas for aviary 2, with the sixth bed reused from both aviaries registering the largest biogas potential. Average potential biogas in m³ kg^?1 of TS added were 0.022 to 0.034 for aviary 1 and 0.015 to 0.022 for aviary 2. Energy values ??of biogas produced were calculated based on calorific value and ranged from 0.06 to 0.33 kWh for chicken litter without fermentation and from 0.05 to 0.27 kWh for chicken litter with fermentation. It was concluded that the re-use of poultry litter resulted in an increase in biogas production, and the use of fermentation in the microbiological treatment of poultry litter seems to have negatively influenced production of biogas.     

A dynamic analysis of the global warming potential associated with air conditioning at a city scale: an empirical study in Shenzhen,China

Heating, ventilation and air conditioning (HVAC) systems are a major source of energy consumption in buildings, directly and indirectly contributing to greenhouse gas (GHG) emissions. In the urban environment, and depending on local climatic conditions, air conditioning units attribute to these high energy demands. This study analyzes the use of residential air conditioning units and their associated global warming potential (GWP) between 2005 and 2030 for the city of Shenzhen, a fast-growing megacity located in Southern China. A life cycle assessment approach was adopted to quantify the GWP impacts which arise from both direct (refrigerant release) and indirect (energy consumption) sources, in combination with a materials flow analysis approach. The results show that the total GWP (expressed as carbon dioxide equivalents, CO₂ eq.) from residential air conditioning systems increased from 2.2 ± 0.2 to 5.1 ± 0.4 million tonnes (Mt) CO₂ eq. between 2005 and 2017, with energy consumption and refrigerant release contributing to 72.5% and 27.5% of the total demands, respectively. Immediate measures are required to restrict refrigerant release and reduce the energy consumption of air conditioning units, to help mitigate the predicted additional total emissions of 36.4 Mt. CO₂ eq. potentially released between 2018 and 2030. This amount equals to approximately New Zealand's national CO₂ emissions in 2017. The findings proposed in this study targets air conditioning units to reduce the GWP emissions in cities, and provide useful data references and insights for local authorities to incentivise measures for improving building energy efficiency management and performance.     

Evaluation of applicability of the Sartorius Airport MD8 sampler for detection of Bacillus endospores in indoor air

This study was designed to evaluate the measuring range and lowest limit of detection of Bacillus endospores in the ambient room air when the Sartorius MD8 sampler, and two different culture methods for bacterial enumeration were used. Different concentrations of bioaerosol were generated inside the test chamber filled with either the high-efficiency particulate air (HEPA)-filtered air or with the ambient room air. The detection of endospores in the HEPA-filtered air was achievable: (1) when they were aerosolized at a concentration above 7.56?×?10³ CFU/m³ and analyzed with spread plate method, and (2) when they were aerosolized at a concentration above 4.00?×?10² CFU/m³ and analyzed with pour plate method. The detection of endospores in the ambient room air was possible: (1) when they were aerosolized at a concentration above 9.1?×?10³ CFU/m³ and analyzed with spread plate method, and (2) when they were aerosolized at a concentration above 5.6?×?10² CFU/m³ and analyzed with pour plate method. The microorganisms present in the ambient room air interfere with precise quantification of Bacillus endospores when their concentration is relatively low. The results of this study may be helpful in critical assessment of the results obtained from monitoring the air for bacterial endospores.     

Variations in global temperature and precipitation for the period of 1948 to 2010

Climate change has impacts on both natural and human systems. Accurate information regarding variations in precipitation and temperature is essential for identifying and understanding these potential impacts. This research applied Mann–Kendall, rescaled range analysis and wave transform methods to analyze the trends and periodic properties of global and regional surface air temperature (SAT) and precipitation (PR) over the period of 1948 to 2010. The results show that 65.34 % of the area studied exhibits significant warming trends (p?<?0.05) while only 3.18 % of the area exhibits significant cooling trends. The greatest warming trends are observed in Antarctica (0.32 °C per decade) and Middle Africa (0.21 °C per decade). Notably, 62.26 % of the area became wetter, while 22.01 % of the area shows drying trends. Northern Europe shows the largest precipitation increase, 12.49 mm per decade. Western Africa shows the fastest drying, ?21.05 mm per decade. The rescaled range analysis reveals large areas that show persistent warming trends; this behavior in SAT is more obvious than that in PR. Wave transform results show that a 1-year period of SAT variation dominates in all regions, while inconsistent 0.5-year bands are observed in East Asia, Middle Africa, and Southeast Asia. In PR, significant power in the wavelet power spectrum at a 1-year period was observed in 17 regions, i.e., in all regions studied except Western Europe, where precipitation is instead characterized by 0.5-year and 0.25-year periods. Overall, the variations in SAT and PR can be consistent with the combined impacts of natural and anthropogenic factors, such as atmospheric concentrations of greenhouse gases, the internal variability of climate system, and volcanic eruptions.     

Carbon sequestration in the soils of aquaculture ponds,crop land,and forest land in southern Ohio,USA

Soil samples were collected from four aquaculture ponds (yellow perch culture), a control pond (without aquaculture activities, fallow pond), crop land (under corn), and forest land to estimate the carbon (C) sequestration potential in the Piketon county, Ohio, USA. The averaged total of C was 6.5?±?2, 8.8?±?2, 8.53?±?0.2 and 10.49?±?1.1 Mg/ha (Mg=10⁶g) in <?0.25 mm fraction; 15.2?±?2, 16.0?±?3, 11.49?±?0.8 and 17.23?±?3.4 Mg/ha in micro aggregates (0.25–2.5 mm); and 22.1?±?3, 26.4?±?3, 12.16?±?1.6 and 18.51?±?4.3 Mg/ha in macro aggregates (?>?2.5mm), for aquaculture ponds, control ponds, cropland and forest land, respectively. The soil/sediment C pool followed the order of forest?>?crop land soils?>?aquaculture pond soils.     

The effects of low frequency noise on mental performance and annoyance

Low frequency noise (LFN) as background noise in urban and work environments is emitted from many artificial sources such as road vehicles, aircraft, and air movement machinery including wind turbines, compressors, and ventilation or air conditioning units. In addition to objective effects, LFN could also cause noise annoyance and influence mental performance; however, there are no homogenous findings regarding this issue. The purpose of this research was to study the effects of LFN on mental performance and annoyance, as well as to consider the role of extraversion and neuroticism on the issue. This study was conducted on 90 students of Iran University of Medical Sciences (54 males and 36 females). The mean age of the students was 23.46 years (SD?=?1.97). Personality traits and noise annoyance were measured by using Eysenck Personality Inventory and a 12-scale self-reported questionnaire, respectively. Stroop and Cognitrone computerized tests measured mental performance of participants each exposed to 50 and 70 dBA of LFN and silence. LFNs were produced by Cool Edit Pro 2.1 software. There was no significant difference between mental performance parameters under 50 and 70 dBA of LFN, whereas there were significant differences between most mental performance parameters in quiet and under LFN (50 and 70 dBA). This research showed that LFN, compared to silence, increased the accuracy and the test performance speed (p?<?0.01). There was no association between LFN and noise annoyance (p?>?0.01). Introverts conducted the tests faster than extraverts (p?<?0.05). This research showed that neuroticism does not influence mental performance. It seems that LFN has increased arousal level of participants, and extraversion has a considerable impact on mental performance.     

Distributions, sources, and ecological risks of DDT-related contaminants in water, suspended particulate matter, and sediments from Haihe Plain, Northern China

The residual levels of dichlorodiphenyltrichloroethane (DDT) and its metabolites (DDXs, including p,p′-DDT, DDD, and DDE) in water, suspended particulate matter (SPM), and sediments from major rivers, lakes, and reservoirs in Haihe Plain were measured with a gas chromatograph equipped with a ⁶³Ni microelectron capture detector. In the fall of 2004, the contents of the total DDXs in the water and SPM were 0.29?±?0.69 ng L^?1 and 423.13?±?577.85 ng g^?1 dry wt., respectively. In the spring of 2005, the total DDXs were 0.36?±?0.91 ng L^?1 for water and 35.93?±?62.65 ng g^?1 dry wt. for SPM. The average concentration of DDXs for sediments was 7.10?±?7.57 ng g^?1 dry wt. during the two seasons. The Eastern-Hebei-Province Coastland River System was the most polluted, which was mainly attributable to the extensive use of DDT pesticide and dicofol in that system. Recent DDT inputs still occur in some regions, as indicated by DDT/(DDD + DDE) > 1 at 29–36 % of the sites for water and 55–61 % of the sites for SPM. The potential ecological risks of DDT in the water were assessed using a species sensitivity distribution model. Only shrimp and crabs were found to have potentially affected fraction values of 1.63?×?10^?3 to 2.27?×?10^?4, with probabilities beyond the hazardous concentration for 5 % of species (HC5) values of 1.90–2.56 %, suggesting only slight risks. DDXs in the sediments of some sites were also of potential risk to benthic organism based on consensus-based sediment quality guidelines.     

Evaluation of airborne lead levels in storage battery workshops and some welding environments in Kumasi metropolis in Ghana

Airborne lead levels were assessed in nine workshops, three each from battery, electronic repair, and welding sources within the Kumasi Metropolis in Ghana. Samples were collected at 0, 2.5, and 5.0 m away from the emission source at the workshops during working hours and another at 5.0 m during break hours. Airborne lead particulates were collected and analyzed using the filter membrane technique and flame atomic absorption spectrophotometry, respectively. There were significant differences (p ≤ 0.05) among the air lead levels from the workshops. Workshop 3b produced the highest significant values of air lead concentrations of 2,820.31 ± 53.89, 2,406.74 ± 71.87, 754.55 ± 72.52, and 549.01 ± 67.30 μg/m³ at distances of 0, 2.5, 5.0, and 5.0 m (break-time measurement), respectively, while workshop 1w significantly produced the lowest air lead concentration values of 261.06 ± 21.60, 190.92 ± 36.90, 86.43 ± 16.26, and 61.05 ± 3.88 μg/m³ at distances of 0, 2.5, 5.0, and 5.0 m (break-time measurement), respectively. The air lead levels reduced with distance from emission source at the workshops. At all the distances of measurement at working hours, the airborne lead levels were higher than the World Health Organization standard of 50 μg/m³ and exceeded the threshold limit values of 100 to 150 μg/m³ recommended in most jurisdictions. Workers and people in the immediate environs were exposed to air lead levels that were too high by most international standards, thus posing a serious threat to their health.     

Dual character of Sundarban estuary as a source and sink of CO2 during summer: an investigation of spatial dynamics

A comprehensive attempt has been made to evaluate the diurnal and spatial pattern of CO₂ exchange between the atmosphere and water along the estuarine track of Indian Sundarbans during the two summer months, April and May, 2011. Rigorous field observations were carried out which included the hourly measurements of total alkalinity, pH, fugacity of CO₂ in ambient air and water surface, dissolved oxygen, and chlorophyll a. The estuarine water was found rich in total alkalinity and was oversaturated with CO₂ throughout the diurnal cycle in the two stations situated at the inner and middle estuary, respectively, whereas an entirely reverse situation was observed in the outer fringes. The fugacity of CO₂ in water ranged from 152 to 657 μatm during the study period. The percentage of over-saturation in inner and middle estuary varied from 103 to 168 and 103 to 176 %, respectively, whereas the degree of under-saturation in the outer estuary lied between 40 and 99 %. Chlorophyll a concentrations were found higher in the outer estuary (12.3?±?2.2 mg?m^?3) compared to the middle (6.4?±?0.6 mg?m^?3) and inner parts (1.6?±?0.2 mg?m^?3), followed by a similar decreasing pattern in nutrient availability from the outer to inner estuary. The sampling stations situated at the inner and middle estuary acted as a net source of 29.69 and 23.62 mg?CO₂?m^?2 day^?1, respectively, whereas the outer station behaved as a net sink of ?33.37 mg?CO₂ m^?2 day^?1. The study of primary production and community respiration further supports the heterotrophic nature of the estuary in the inner region while the outer periphery was marked by dominant autotrophic character. These contrasting results are in parity with the source characters of many inner estuaries and sinking characters of the outer estuaries situated at the distal continental shelf areas.     

Uptake of heavy metals by some edible vegetables irrigated using wastewater: a preliminary study in Accra, Ghana

The heavy metals (Fe, Zn, Pb, Ni, Cr, Co, and Cd) burden in wastewater, soil, and vegetable samples from a wastewater irrigated farm located at KorleBu, Accra has been investigated. Flame atomic absorption spectrometry after microwave digestion using a combination of HNO₃, HCl, and H₂O₂ (for water), and HNO₃ and HCl (for soil and vegetables). The mean concentrations (in milligrams per kilogram) of heavy metals in the soil samples were in the order of Fe (171?±?5.22)?>?Zn (36.06?±?4.54)?>?Pb (33.35?±?35.62)?>?Ni (6.31?±?8.15)?>?Cr (3.40?±?3.63)?>?Co (1.36?±?0.31)?>?Cd (0.43?±?0.24), while the vegetables were in the order of Fe (183.11?±?161.2)?>?Zn (5.38?±?3.50)?>?Ni (3.52?±?1.27)?>?Pb (2.49?±?1.81)?>?Cr (1.46?±?0.51)?>?Co (0.66?±?0.25)?>?Cd (0.36?±?0.15). The bioconcentration factors suggest environmental monitoring for the heavy metals as follows: Cd (0.828), Cr (0.431), Ni (0.558), Co (0.485), and Fe (1.067). Estimated daily intakes were very low for both children and adults except Fe (0.767 mg/kg/day) in children. The population that consume vegetables from the study area were, however, estimated to be safe based on the results obtained from the health risk index, which were all?<?<1. The sodium absorption ratio according to FAO (1985) classifications indicate that the wastewater in the study area is unsuitable for irrigation purposes.