Determination of the level of contamination in Khuzestan coastal waters (Northern Persian Gulf) by using an ecological risk index

The aims of the present study were to investigate the metal contents of sediments of several creeks that discharged into coastal waters using the Risk index. This study was carried out in eight creeks in Mahshahr coastal waters in the Northwest of Persian Gulf from October 2005 to November 2006. Superficial sediments were collected seasonally by Peterson grab, and the concentrations of heavy metals were measured by using a voltammetric polarographic method. The range and the mean concentrations obtained in ppm were 15.03–35.16 (27.01) for Cu, 65.57–171.41 (102.67) for Ni, 4.63–20.06 (13.22) for Co, 0.093–0.78 (0.22) for Hg, 65.07–379 (113.70) for Zn, 0.27–1.00 (0.56) for Cd and 7.09–29.72 (14.66) for Pb. To evaluate the levels of sediment contamination, the background values of the different heavy metals were calculated, and the contamination factor for each metal and the degree of contamination for each creek were determined as well. The results show that some elements such as Hg, Zn, and Ni are at risk level, and all of the studied creeks are classified as undergoing a moderate degree of pollution except for Ghannam that showed a considerable degree of contamination. According to the Risk index values, based on sedimentological toxic factors (S_t) of each metal and the BIO Production Index (BPI) in the studied area, the creeks were classified as considerable and with a very high level of ecological risk.     

The importance of considering spatial attributes in evaluating estuarine habitat condition: the South Carolina experience

The South Carolina Estuarine and Coastal Assessment Program (SCECAP) was initiated in 1999 to assess the condition of the state's coastal habitats using multiple measures of water quality, sediment quality, and biological condition. Sampling was subsequently expanded to include components required for the National Coastal Assessment (Coastal 2000) Program. Habitats are classified as either tidal creeks (<#60; 100 meters in width) or larger open water bodies. Approximately 30 sites are sampled within each habitat during the summer months using a probability-based random sampling design. Results obtained from the first two years of sampling documented significant differences in several water quality parameters (DO, salinity, pH, turbidity, fecal coliform bacteria, total nitrogen, TKN, total phosphorus) and biological measures (chlorophyll-a, finfish and crustacean abundance and biomass and a number of benthic species) between the tidal creek and open water habitats. These differences highlight the value of partitioning shallow water habitats separately from the larger open water bodies traditionally sampled in estuarine monitoring programs, especially since tidal creeks serve as critical nursery areas for many species. Based on the differences observed, there is a clear need to identify different physical and biological thresholds for evaluating the condition of each habitat type.     

The polycyclic aromatic hydrocarbon and geochemical biomarker composition of sediments from sea lochs on the west coast of Scotland

Sediments from twelve sea lochs on the west coast of Scotland were analysed for parent and branched 2- to 6-ring polycyclic aromatic hydrocarbons (PAHs), n-alkanes and geochemical biomarkers (triterpanes). Where possible at least fourteen sediment samples were collected at random from each sea loch. All sea lochs were remote, most had limited industrial and urban inputs, although all had fish farms. Four lochs had moderate total PAH concentrations and eight lochs had high total PAH concentrations. Total PAH concentration was related to organic carbon content and particle size distribution, with sandier sediments having lower PAH concentrations. The highest total PAH concentrations, normalised for organic carbon, were in Loch Linnhe and Ballachulish Bay (Loch Leven), close to an aluminium smelter. PAH concentration ratios showed that pyrolysis was the main source of PAHs in most lochs. Only sediments from Loch Clash showed evidence of petrogenic input based on their geochemical biomarker (triterpane and sterane) and n-alkane profiles. PAH profiles were similar across lochs apart from Loch Linnhe and Ballachulish Bay, which had a greater proportion of heavy parent PAHs. West coast sediments had a smaller proportion of heavy PAHs than sediments collected from voes in Shetland and a smaller proportion of alkylated PAHs relative to sediments collected from coastal waters around Orkney.     

Microbiological profile of crude oil in storage tanks

Microbiological quality of crude oil storage tanks was determined. The samples were taken from crude oil storage tanks in three stations, at Ughelli, Escravos and Forcados tank farms in the Delta State of Nigeria. Two tanks were sampled at each station with samples collected from three levels of the tank, namely the oil layer, oil water interface, and effluent layer. Samples from the inner walls and bottom sediment of the only empty tank in Ughelli during the study were also taken. The total heterotrophic count of bacteria and total fungal count were obtained by plating samples on nutrient agar and sabouraud's glucose agar respectively and incubated for 14 days at 28 °C±2 °C. Oilutilizing bacteria and fungi were isolated on oil agar using fungizone and antibiotics to inhibit fungal and bacterial growth respectively. Pure cultures of bacteria and fungi were prepared on nutrient agar and sabouraud's glucose agar respectively at 28 °C±2 °C for 4 days. Isolates were identified using approved standard methods. Three bacterial genera, Pseudomonas, Proteus and Bacillus, and one actinomycete, Actinomyces and two fungal genera, Penicillium and Cunninghamella, were isolated. Pseudomonas was dominant among the bacteria (41.62%) and Penicillium dominant among the fungi (94%). It was also found that the total microbial load of the effluent layer was higher than that of the oil layer.     

Relationship between land use classification and grass shrimp Palaemonetes spp. population metrics in coastal watersheds

Estuaries in the southeastern USA have experienced increased loading of contaminants from nonpoint source runoff as well as changes in habitat (e.g., loss of wetlands) due to urbanization. These changes may pose significant risks to estuarine fauna, including crustaceans. Several studies have shown relationships between land use classification and levels of stress in estuarine populations. The grass shrimp of the genus Palaemonetes is one of the dominant species found in estuarine tidal creeks, accounting for more than 50 % of all macropelagic fauna. Grass shrimp populations were sampled monthly for 3 years at six estuarine creeks on Kiawah Island, SC. Creek watersheds were estimated using National Aerial Photograph Program color infrared and low-altitude true color aerial photography combined with in situ differentially corrected global positioning system mapping of engineered features. Land classifications delineated included water, marsh, buildings, roads, and lawns. Pairwise comparisons for grass shrimp densities among sites showed significant differences on an annual and seasonal basis. Significant relationships (p?<?0.05) between land class variables and grass shrimp density were identified both annually and seasonally. These findings suggest an influence of land use on Palaemonetes spp. populations.     

Biogeochemistry of mercury and methylmercury in sediment cores from Sundarban mangrove wetland, India—a UNESCO World Heritage Site

This study was performed to elucidate the distribution, concentration trend and possible sources of total mercury (Hg(T)) and methylmercury (MeHg) in sediment cores (<63 μm particle size; n?=?75) of Sundarban mangrove wetland, northeastern part of the Bay of Bengal, India. Total mercury was determined by atomic absorption spectrometry (AAS) in a Leco AMA 254 instrument and MeHg by gas chromatography-atomic fluorescence spectrometry (GC-AFS). A wide range of variation in Hg(T) (0.032-0.196 μg g(-1) dry wt.) as well as MeHg (0.04-0.13 ng g(-1) dry wt.) concentrations revealed a slight local contamination. The prevalent low Hg(T) levels in sediments could be explained by sediment transport by the tidal Hugli (Ganges) River that would dilute the Hg(T) values via sediment mixing processes. A broader variation of MeHg proportions (%) were also observed in samples suggesting that other environmental variables such as organic carbon and microbial activity may play a major role in the methylation process. An overall elevated concentration of Hg(T) in surface layers (0-4 cm) of the core is due to remobilization of mercury from deeper sediments. Based on the index of geoaccumulation (I (geo)) and low effects-range (ER-L) values, it is considered that the sediment is less polluted by Hg(T) and there is less ecotoxicological risk. The paper provides the first information of MeHg in sediments from this wetland environment and the authors strongly recommend further examination of Hg(T) fluxes for the development of a detailed coastal MeHg model. This could provide more refine estimates of a total flux into the water column.     

Response of lake water quality to wastewater inputs from land-based fish farm located on Yuvarlakçay Creek in Köyceğiz–Dalyan Specially Protected Area, Turkey

Köyce?iz Lake is located in the south-western part of Turkey. The area between the Köyce?iz Lake and the Mediterranean Sea is covered with four small lakes and several canals. The surroundings of the lake, canals and forests have a great potential as a reproduction areas for Mediterranean Sea turtles (Caretta caretta) and sheltering place for various animals. In the vicinity of this system there are agricultural areas and small settlements. In this region the most important economic activities are tourism and fisheries. However, the lake is currently threatened by pollution because of (1) non-point source pollution (agriculture); (2) point sources (land-based fish farms); (3) inefficient sewerage systems; (4) uncontrolled soil erosion in its drainage basin; (5) inappropriate flood control measures; and (6) channel traffic. This study evaluates the influence of its influent creeks namely Namnam and Yuvarlakçay Creek on the water quality of Köyce?iz Lake, mainly because the creeks are believed to be responsible for the major pollutant load reaching the lake. Accordingly, this study demonstrates (1) change in the water quality of Köyce?iz Lake from 2006 to 2007; (2) the water quality classification of the major influent creeks feeding Köyce?iz Lake; and (3) how land-based fish farm influences Yuvarlakçay Creek water quality in a Köyce?iz–Dalyan Specially Protected Area.     

Land use effects on macrobenthic communities in southeastern United States tidal creeks

Runoff from impervious land cover has a major impact on headwater tidal creek ecosystems resulting from ever increasing development along the coastline. Tidal creek habitats can serve as "early warning systems" for anthropogenic stressors due to their proximity to the uplands. In this study, the macrobenthic community was sampled along the longitudinal gradient of tidal creeks (i.e., first order, second order, and third order) in North Carolina, South Carolina, and Georgia which varied in their levels of watershed development (salt marsh, forested, suburban, and urban). This study was designed to assess the condition of macrobenthic communities in tidal creek ecosystems under varying levels of anthropogenic stressors and test whether the conclusions of a previous study in South Carolina (Holland et al., J Exp Mar Biol Ecol 298:151-178, 2004) could be generalized to the southeastern USA. Metrics of community-level and species-specific response within tidal creeks draining watersheds of varying degrees of impervious cover suggest the macrobenthic community may be a useful indicator of development in tidal creeks ecosystems. The differences observed when data from all three states were pooled was consistent with previous findings in South Carolina tidal creeks which illustrates that macrobenthic communities in tidal creeks may react to watershed development in similar patterns along the southeastern coast of the USA.     

Assessment Of A Natural Wetland For Use In Wastewater Remediation

An environmental study was conducted to assess various aspects of the water and sediment quality of a natural wetland to determine its feasibility for advanced wastewater treatment in Louisiana. Nitrate (NO₃), nitrite (NO₂), ammonia (NH₄), total Kjeldahl nitrogen (TKN), total phosphorus, chloride, total organic carbon, pH, trace metals, fecal coliform, dissolved oxygen (DO), and biochemical oxygen demand (BOD) were monitored. Productivity of a dominant shrub, Iva frutescens, in the wetland was also assessed. Research results indicated that gradients of chloride and salinity concentrations showed a broad mixing of the discharged fresh water into the more saline natural brackish waters. This provided an ideal pattern for nutrient assimilation by the receiving marsh. NH₄ was reduced in the range of 50–100% when all combinations of sources and outflows were considered. For total phosphorus and TKN, reduction ranged from 0–95.1% and 11.2–89.7%, respectively. Some nutrient concentrations in the effluent outlet, NO₃ in particular, were lower than background concentrations found in the reference wetland. Sediment and water showed no significant deficiency or toxicity problems for the major nutrients and metals analyzed. The secondary effluent discharges had little demonstrable negative impact on the wetland during the study period from 1995 to 1996.     

Dispersion and retrievability of water quality indicators during tidal cycles in coastal Salaya, Gulf of Kachchh (West coast of India)

Bacterial indicators in relation to tidal variations were studied at five locations for over 2 days covering three tidal cycles in the southwestern region of Gulf of Kachchh, India. Tidal flow here is predominantly in the east west direction and can transport particles up to 32 km. Tidal amplitude appears to play a prominent role in abundance, distribution, and dispersal of coliform bacteria examined during this study. Shallow depths, clayey sediments, strong currents, and higher tidal amplitudes appear to rise by an order of magnitude in total bacterial abundance up to 2.4×10⁴ ml^???1 due to their resuspension from the churned up sediments. Dispersal of allochthonous microflora far into coastal marine regions appears to be governed by the strong tidal amplitude in this region.     

Spatial scales and probability based sampling in determining levels of benthic community degradation in the Chesapeake Bay

The extent of degradation of benthic communities of the Chesapeake Bay was determined by applying a previously developed benthic index of biotic integrity at three spatial scales. Allocation of sampling was probability-based allowing areal estimates of degradation with known confidence intervals. The three spatial scales were: (1) the tidal Chesapeake Bay; (2) the Elizabeth River watershed; and (3) two small tidal creeks within the Southern Branch of the Elizabeth River that are part of a sediment contaminant remediation effort. The areas covered varied from 10^–1 to 10⁴ km² and all were sampled in 1999. The Chesapeake Bay was divided into ten strata, the Elizabeth River into five strata and each of the two tidal creeks was a single stratum. The determination of the number and size of strata was based upon consideration of both managerially useful units for restoration and limitations of funding. Within each stratum 25 random locations were sampled for benthic community condition. In 1999 the percent of the benthos with poor benthic community condition for the entire Chesapeake Bay was 47% and varied from 20% at the mouth of the Bay to 72% in the Potomac River. The estimated area of benthos with poor benthic community condition for the Elizabeth River was 64% and varied from 52–92%. Both small tidal creeks had estimates of 76% of poor benthic community condition. These kinds of estimates allow environmental managers to better direct restoration efforts and evaluate progress towards restoration. Patterns of benthic community condition at smaller spatial scales may not be correctly inferred from larger spatial scales. Comparisons of patterns in benthic community condition across spatial scales, and between combinations of strata, must be cautiously interpreted.     

Benthic foraminifera from polluted marine environment of Sulaibikhat Bay (Kuwait)

Quantitative analyses of recent benthic foraminiferal assemblages (living and dead) were carried out on the surface sediments of Sulaibikhat Bay. Marked contrast in foraminiferal assemblages between the shallow tidal mudflats and the deep tidal channel and their relation to the extent of pollution were observed. Cluster analysis of quantitative data on the distribution of foraminiferal tests revealed three assemblages that depend mainly on the intensity of pollution; (1) a highly polluted tidal flat assemblage, (2) normal (or less polluted) mud flat assemblage and, (3) tidal channel and subtidal assemblage. The highly polluted assemblage characterized by a drop in species densities (< 100 tests/20 cm(3) sediment) but with high average diversity (5.8 Yule-Simpson Index). The microfauna of the less polluted flat displays relatively lower diversity (4.6) but high density of tests (47.2% of the total picked tests). The most abundant species of this assemblage is Ammonia tepida, displays its maximum density in this assemblage. Ammonia tepida drops in density from 17.12% to 3.07% in the polluted assemblage. Tidal channel foraminiferal assemblages should normally display lower diversities than those of tidal flats, because tidal current in the channels tend to wash away most nutrient materials. However, this is not the case of the present study area which could be due to environmental setting of the Sulaibikhat Bay in which tidal currents bring in exceptionally high amounts of nutrients from Shatt Al-Arab Estuary and in which the tidal flats are strongly and adversely polluted.     

Assessment of Cu, Pb, and Zn contamination in sediment of north western Peninsular Malaysia by using sediment quality values and different geochemical indices

Surface sediments were collected from the north western aquatic area (13 intertidal sites and 5 river drainages) of Peninsular Malaysia, which were suspected to have received different anthropogenic sources. These sites included town areas, ports, fishing village, industrial areas, highway sides, jetties and some relatively unpolluted sites. The present study revealed that 4.79-32.91 μg/g dry weight for Cu, 15.85-61.56 μg/g dry weight for Pb, and 33.6-317.4 μg/g dry weight for Zn based on 13 intertidal surface sediments while those based on 5 river drainage surface sediments were 10.24-119.6 μg/g dry weight for Cu, 26.7-125.7 μg/g dry weight for Pb and 88.7-484.1 μg/g dry weight for Zn. In general, the metal levels in the drainage sediments are higher than in the intertidal sediments, suggesting dilution factor in the intertidal sediment and direct effluent from point sources in the drainage sediment. In particular, the total concentrations of Cu, Pb, and Zn for the sampling site at Kuala Kurau Town exceeded the Effect Range Median values for Cu, Pb, and Zn for assessments of sediment quality values for freshwater sediment as proposed by MacDonald et al. (Arch Environ Contam Toxicol 39:20-31, 2000), thus adverse biological effects would be observed above this level. Assessment using enrichment factor (using Fe as a normalizer) and geoaccumulation index showed that the three metals at Kuala Kurau Town and Juru Industry drainage were evidenced as having more enrichment and mostly due to non-natural sources. However, caution should be exercised that the interpretation can only become valid when the ratios, indices, and sediment quality values are combined. This is due to the fact that not all the established indices are applicable and, to a certain extent, some of them should be further revised and improved to suit a different metal for Malaysian sediment. Undoubtedly, sites near drainages at Kuala Kurau Town and Juru River Basin need greater attention to mitigate the heavy metal pollution in the future.     

Hydrocarbon Pollution in the Sediment of Some Malaysian Coastal Areas

A study was carried out at some selected coastal areas of Malaysia to determine the present status of hydrocarbon pollution. Five sites were chosen and these include Pulau Langkawi and Pulau Ketam in the west coast, Tanjung Piai in the south, and Pulau Tioman and Kemaman in the east coast of Peninsular Malaysia. The levels of total hydrocarbon in the sediments are found to vary from 18.2 to 847.4 mg kg-1 with sediments from Pulau Langkawi and Tanjung Piai recorded the highest values (691.2 to 847.4 mg kg-1) while Kemaman and Pulau Ketam recorded the lowest values (18.2 to 59.8 mg kg-1). It was noted that these values are related not only to possible sources of hydrocarbon but also to the physical characteristics of the sediments analysed. Sandy sediment generally contains less hydrocarbon than clayey sediment. Further analyses of the sediment extracts indicate that the sources of the hydrocarbon pollution are predominantly petrogenic with significant contribution from biogenic hydrocarbon.     

Phosphorus geochemistry in a Brazilian semiarid mangrove soil affected by shrimp farm effluents

Wastewater discharge from shrimp farming is one of the main causes of eutrophication in mangrove ecosystems. We investigated the phosphorus (P) geochemistry in mangrove soils affected by shrimp farming effluents by carrying out a seasonal study of two mangrove forests (a control site (CS); a site affected by shrimp farm effluents (SF)). We determined the soil pH, redox potential (Eh), total organic carbon (TOC), total phosphorus (TP), and dissolved P. We also carried out sequential extraction of the P-solid phases. In SF, the effluents affected the soil physicochemical conditions, resulting in lower Eh and higher pH, as well as lower TOC and higher TP than in CS. Organic P forms were dominant in both sites and seasons, although to a lesser extent in SF. The lower TOC in SF was related to the increased microbial activity and organic matter decomposition caused by fertilization. The higher amounts of P oxides in SF suggest that the effluents alter the dominance of iron and sulfate reduction in mangrove soils, generating more reactive Fe that is available for bonding to phosphates. Strong TP losses were recorded in both sites during the dry season, in association with increased amounts of exchangeable and dissolved P. The higher bioavailability of P during the dry season may be attributed to increased mineralization of organic matter and dissolution of Ca-P in response to more oxidizing and acidic conditions. The P loss has significant environmental implications regarding eutrophication and marine productivity.     

Seasonal monitoring of heavy metals and physicochemical characteristics in a lentic ecosystem of subtropical industrial region, India

Assessment of seasonal changes in surface water quality is an important aspect for evaluating temporal variations of lentic ecosystem (lakes and reservoirs) pollution due to industrial effluent discharge. In this study, nine metals and 15 physicochemical parameters, collected from four sampling sites in a tropical lake receiving the discharge from thermal power plant, coal mine, and chloralkali industry, during the years from 2004 to 2005, were analyzed. For greater efficacy in monitoring of heavy metals, particle-induced X-ray emission has been used during present investigation. Different statistical techniques like analysis of variance, Pearson correlation, principal component analysis, and factor analysis were employed to evaluate the seasonal correlations of physicochemical parameters. Most of the metals and physicochemical parameters monitored in the present study exhibited high spatial and temporal variability. Pertaining to metal pollution, the most polluted site was Belwadah, i.e., waters and sediments had the highest concentration of all the relevant metals. The reference site was characterized by the presence of low concentrations of metals in waters and in sediments. Based on the high metal concentration recorded in lake ambient, drinking, bathing, and irrigation water should not be used by the local people at the effluent discharge points.     

Heavy Metal Levels in Marine Sediments of Singapore

Marine environmental levels of the metals copper (Cu), zinc (Zn), lead (Pb) and cadmium (Cd) were measured from sediments collected around 20 coastal locations around Singapore, over a 2-year period. Sediment-size analysis was conducted on sediment samples, and Atomic Absorption Spectrophotometry was used in the analyses of sediment heavy metal concentrations. The levels of heavy metals in marine sediment was largely dependant on sediment particle size, as illustrated by the correlation of sediment size with Multidimensional Scaling (MDS) configurations of sediment metal concentrations. In addition, the proximity to shipping activity, and the release of anti-fouling paint from boats also influence heavy metal concentrations in marine sediments of Singapore.     

Anthropogenic plutonium in the North Jiangsu tidal flats of the Yellow Sea in China

The ^239+240Pu activities and ²⁴⁰Pu/²³⁹Pu atom ratios were analyzed using a double-focusing SF-ICP-MS for sediment core samples obtained in 2007–2008 from the North Jiangsu tidal flats in the Yellow Sea in China. Particular attention was focused on the ²⁴⁰Pu/²³⁹Pu atom ratios in the sediment to identify the origins of Pu isotopes. The profiles of ^239+240Pu activities in the sediment cores are similar to those of the ¹³⁷Cs activities. The ²⁴⁰Pu/²³⁹Pu atom ratios in the tidal flats showed typical global fallout values, indicating that this area did not receive the possible early direct close-in fallout or oceanic current transported Pu from the Pacific Proving Grounds (PPG). If any, the contribution of the PPG source Pu to the total Pu inventory is negligible. This is different from the sediments in the Yangtze River estuary in the East China Sea, where the PPG source Pu contributed ca. 45 % to the total inventory. In addition, the observation of the global fallout origin Pu in the North Jiangsu tidal flats indicated that the nuclear power plant in the region was not causing any alteration/contamination to the ²⁴⁰Pu/²³⁹Pu atom ratios. The ^239+240Pu and ¹³⁷Cs activities/inventories in the sediment cores showed correlation to the mean clay sediment compositions (fine particles) in the tidal flats. Therefore, mud deposits are served as sinks for the anthropogenic radionuclides in the tidal flats and the Yellow Sea. Integrated with the previously reported spatial distributions of ^239+240Pu and ¹³⁷Cs activities in the surface sediments of the Yellow Sea, the mechanism of Pu transport with the ocean currents and the scavenging characteristics in the Yellow Sea were discussed.     

Advanced energy consumption system for smart farm based on reactive energy utilization technologies

Over the decades, both agriculture and energy grids have encountered significant challenges, such as the lack of power supply to agricultural farms and the difficulties of renewable energy use in the electricity sector. To overcome and address these issues, this paper presents an idea of merging smart farm and renewable energy, using surplus renewable energy for the agriculture sector using the smart farm for renewable energy supplies. First, demonstrate the framework to connect a smart farm energy system and analyze its feasibility and advantages. In this paper, Reactive Energy Utilization Technology (REUT) has been used as an efficient energy consumption system for the smart farm. It is used to predict the optimum wind power scenario in the smart farm by monitoring continuous control variables, with the lowest voltage reached in each scenario, and minimized actual total power losses. A combined system consisting of smart farming production, as well as renewable energy consumption, has been evaluated in experimental results. Experimental results and discussion shows that the proposed method has better renewable energy consumption, accuracy(96.7%), and efficiency(95.6%) for smart farming.