THE EFFECT OF EL NIÑO-RELATED DROUGHT ON THE RECOVERY OF ACIDIFIED LAKES

Although SO₂ emissions and deposition rates havedeclined substantially since the implementation of sulphuremission control programmes in North America [1], recovery(measured as decreases in concentrations) of affected lakes in central Ontario has been much less substantial thananticipated based on the decrease in deposition. The slowrecovery is attributed to the reoxidation and release of storedsulphur in catchments. Reduced sulphur retained in previousyears when sulphur deposition was higher is exposed to air andoxidized during severe droughts, then exported duringsubsequent wet periods. Elevated stream concentrations and export rates occur in the autumns of yearswith prolonged severe droughts, particularly in catchments withextensive wetlands. Drought in our study catchments occurred inyears following strong El Niño events. When the SouthernOscillation Index (SOI) was strongly negative (1976–77, 1982–83,1986–87, 1991–92, 1993–94) the frequency of occurrence ofdrought the following summer in small catchments with shallowoverburden was extremely high. A lakes rate of recovery fromacidification depends upon the amount of excess reduced Sthat has been stored in anoxic zones in the catchment (largely afunction of the extent of wetlands) during years of elevated Sdeposition rates, and the frequency and severity of droughts. Iflong-term changes in global or regional climate alter thefrequency or magnitude of El Niño-related droughts, therecovery of acidified lakes will be affected.     

Temporal and Spatial Variation of Nutrient Levels in the Nemunas River (Lithuania and Belarus)

There are discordant results on trends in nutrient river water quality from the economical transition countries in Europe. The present study assessed the impact of these economical changes on the load and concentration at 17 monitoring stations along the Nemunas River and its major tributaries (Lithuania and Belarus). Three time periods were evaluated: the Soviet rule command system period 1986–1991, the transfer to market economy period 1992–1996 and the post reform period 1997–2002. The most surprising result in this study, was the increased area-specific load of NO₃-N from the first to the third period at almost all the sampling sites. The increase was particularly large (43–78%) at the sites in the Lithuanian part of the river. The corresponding load increase in the Belarussian part of the river was only 1–15%. The statistical analyses of concentration data confirm the strong upward NO₃-N trend at the Nemunas mouth and at 5 of the 6 tributaries in the lower part of Nemunas. Temporal and spatial analysis of nitrates transport in the Nemunas River and its main tributaries revealed that nitrates mainly originate from agricultural areas. The upward trends were most likely an effect of ploughing of pastures and unbalanced crop fertilisation in combination with large storage and accumulation of soil-nitrogen during the Soviet period.On contrary to nitrate-N, the area-specific load of PO₄-P decreased significantly from the first to the third period at all sites along the Nemunas River (31–86%). Seasonal (SMK) and Partial (PMK) Mann-Kendall tests on PO₄-P concentrations also showed significant downward trend at 14 of 16 investigated sites. The decrease of PO₄-P levels was attributed to the reduction of municipal and industrial point source emissions and to the decreased livestock numbers.The NH₄-N load showed the same pattern as PO₄-P. At the river mouth the load was 90 kg km⁻² yr⁻¹ during the first period compared to only 20–30 kg km⁻² yr⁻¹ in the third period. The trend test on NH₄-N concentrations detected significant downward trends at 5 out of 16 sites. The declines were explained by decreased emissions from cities and large animal breeding farms.This study showed that trend analysis at multiple sites in a river basin is crucial for the understanding of the variability in time and space. Such analysis is also important for our interpretation of underlying sources and fluxes in a drainage basin over time. This is particularly important for compounds that have different source origin.     

Monitoring the results of Canada/U.S.A acid rain control programs: some lake responses

Aquatic acidification by deposition of airborne pollutants emerged as an environmental issue in southeastern Canada during the 1970s. Drawing information from the extensive research and monitoring programs, a sequence of issue assessments demonstrated the necessity of reducing the anthropogenic emissions of acidifying pollutants, particularly sulphur dioxide (SO₂). The 1991 Canada-U.S. Air Quality Agreement (AQA) was negotiated to reduce North American SO₂ emissions by 40% relative to 1980 levels by 2010, and at present, both countries have reduced emissions beyond their AQA commitment. In response to reduced SO₂ emissions, atmospheric deposition of sulphate (SO₄ ^2–) and SO₄ ^2– concentrations in many lakes have declined, particularly in south-central Ontario and southern Québec. Sulphate deposition still exceeds aquatic critical loads throughout southeastern Canada however. Increasing pH or alkalinity (commonly deemed recovery) has been observed in only some lakes. Several biogeochemical factors have intervened to modify the lake chemistry response to reduced SO₄ ^2– input, notably release of stored SO₄ ^2– from wetlands following periods of drought and reduction in the export of base cations from terrestrial soils. Three examples from Ontario are presented to illustrate these responses. Significant increases in pH and alkalinity have been observed in many lakes in the Sudbury area of Ontario due to the large reductions in local SO₂ emissions; early-stage biological recovery is evident in these lakes. An integrated assessment model predicts that AQA emission reductions will not be sufficient to promote widespread chemical or biological recovery of Canadian lakes. Monitoring and modeling are mutually supporting assessment activities and both must continue.     

Losses of nitrogen and phosphorus from agricultural and forest areas in Finland during the 1980s and 1990s

The temporal changes and spatial variability of phosphorus andnitrogen losses and concentrations in Finland during the period1981–1997 were studied in 15 small agricultural and forestedcatchments. In addition, four coastal river basins with highagricultural land use located in southern Finland were includedin the study in order to assess the representativeness ofagricultural loss estimates from small agricultural catchments.The mean annual loss specific for agricultural land was estimatedto be on average 110 kg km^-2 a^-1 for total phosphorusand 1500 kg km^-2 a^-1 for total nitrogen. The resultsfrom small agricultural catchments were in agreement with thecorresponding loss estimates from rivers, with an average of137 kg km^-2 a^-1 for total phosphorus and 1800 kg km^-2a^-1 for total nitrogen. The results from the studiedagricultural catchments and rivers during the period 1981–1997suggest that weather-driven fluctuation in discharge was usuallythe main reason for changes in nutrient losses, and little or noimpact of changes in agricultural production or managementpractises can be observed. In forested areas the total phosphorusloss (average 9 kg km^-2 a^-1) and total nitrogen loss(average 250 kg km^-2 a^-1) were lower than inagricultural areas. In forested catchments the impact of forestryoperations, such as clear-cutting and fertilization, and theimpact of atmospheric nitrogen deposition can be seen in changesin nutrient losses.     

Estimation of the Human Impact on Nutrient Loads Carried by the Elbe River

The reunification of Germany led to dramatically reduced emissions of nitrogen (N) and phosphorus (P) to the environment. The aim of the present study was to examine how these exceptional decreases influenced the amounts of nutrients carried by the Elbe River to the North Sea. In particular, we attempted to extract anthropogenic signals from time series of riverine loads of nitrogen and phosphorus by developing a normalization technique that enabled removal of natural fluctuations caused by several weather-dependent variables. This analysis revealed several notable downward trends. The normalized loads of total-N and NO3-N exhibited an almost linear trend, even though the nitrogen surplus in agriculture dropped dramatically in 1990 and then slowly increased. Furthermore, the decrease in total-P loads was found to be considerably smaller close to the mouth of the river than further upstream. Studying the predictive ability of different normalization models showed the following: (i) nutrient loads were influenced primarily by water discharge; (ii) models taking into account water temperature, load of suspended particulate matter, and salinity were superior for some combinations of sampling sites and nutrient species; semiparametric normalization models were almost invariably better than ordinary regression models.     

Synchronous variation in water chemistry for 80 lakes in Southern Sweden

Variation in water chemistry was studied in 80 lakes in southern Sweden. The lakes had forest dominated catchments. The length of the time series was 14 years. Synchrony was calculated as Pearsons product moment correlation coefficients for all combinations of lakes, i.e. 3160 lake-pairs. The chemical variables studied were non-marine sulphate (SO₄ ^*), non-marine calcium (Ca^*), absorbance and acid neutralising capacity (ANC). Statistically significant synchrony occurred in 93% of all lake-pairs for SO₄ ^*, and between 58 and 67% for absorbance, Ca^* and ANC. In 70% of all lake-pairs, the synchrony was \s>0.71 for SO₄ ^*, which means that more than half of the variation in one lake could be explained by the variation in the other lake. For absorbance, Ca^* and ANC, about 25% of the lake-pairs had a synchrony \s>0.71. The relatively high synchrony for SO₄ ^* occurred during an overall downward trend in SO₄ ^* concentration.The degree of synchrony in our study was at a level comparable to other studies in northern America and England. However, our study included lakes in a much larger area, with distances of up to 500 km between the lakes, while earlier studies were made on small lake districts with lakes located within approximately 50 km. In contrast to these earlier studies, there was no correlation between synchrony and distance, lake characteristics or catchment characteristics. However, when a small subset of 15 lakes in the southeast of Sweden was selected, such relations were found.     

Mercury trends in fish from rivers and lakes in the United States, 1969�C2005

A national dataset on concentrations of mercury in fish, compiled mainly from state and federal monitoring programs, was used to evaluate trends in mercury (Hg) in fish from US rivers and lakes. Trends were analyzed on data aggregated by site and by state, using samples of the same fish species and tissue type, and using fish of similar lengths. Site-based trends were evaluated from 1969 to 2005, but focused on a subset of the data from 1969 to 1987. Data aggregated by state were used to evaluate trends in fish Hg concentrations from 1988 to 2005. In addition, the most recent Hg fish data (1996?C2005) were compared to wet Hg deposition data from the Mercury Deposition Network (MDN) over the same period. Downward trends in Hg concentrations in fish from data collected during 1969?C1987 exceeded upward trends by a ratio of 6 to 1. Declining Hg accumulation rates in sediment and peat cores reported by many studies during the 1970s and 1980s correspond with the period when the most downward trends in fish Hg concentrations occurred. Downward Hg trends in both sediment cores and fish were also consistent with the implementation of stricter regulatory controls of direct releases of Hg to the atmosphere and surface waters during the same period. The southeastern USA had more upward Hg trends in fish than other regions for both site and state aggregated data. Upward Hg trends in fish from the southeastern USA were associated with increases in wet deposition in the region and may be attributed to a greater influence of global atmospheric Hg emissions in the southeastern USA. No significant trends were found in 62% of the fish species from six states from 1996 to 2005. A lack of Hg trends in fish in the more recent data was consistent with the lack of trends in wet Hg deposition at MDN sites and with relatively constant global emissions during the same time period. Although few significant trends were observed in the more recent Hg concentrations in fish, it is anticipated that Hg concentrations in fish will respond to changes in atmospheric Hg deposition, however, the magnitude and timing of the response is uncertain.     

Monitoring programme revision highlights long-term salinity changes in selected South African rivers and the value of comprehensive long-term data sets

Determination of data adequacy for detection of long-term salinity changes was an important task in the revision of the South African National Chemical Monitoring Programme (NCMP). The NCMP has been running for more than 30 years with several hundred active monitoring sites. Twenty-five sites on major rivers had sufficient continuous data for the estimation of salinity changes over a 25-year period and statistically significant upward or downward trends occurred at 17 of the 25 sites. Most sites were too far apart for detailed analysis of whole river systems, though an upward trend is apparent in the Lower Orange River and a downward trend in the Great Fish River. Salinity in the Tugela River remained stable, well below the 70 mS m( - 1) guideline for drinking water. The results underline the importance of long-term data sets for assessing and managing aquatic systems and provide the impetus to continue building and maintaining long-term sampling programmes.     

Factors affecting N and P losses from small catchments (Lithuania)

Most of the important factors causing differences in nutrient losses and their interaction were analysed in three small catchments that are located in partially different geographic and climatic conditions in Lithuania. The investigation revealed that climatic factors change the amount and pattern of water discharge over year (larger water discharge during winter in the catchment located closer to the sea), but nutrient leaching is more dependent on land use. Agricultural factors, such as larger cultivated area and excessive fertilisation in one catchment cause larger nitrogen losses (15 kg N ha^–1 year^–1). Large area of non-intensively used grassland leads to very small nitrogen losses (5.7 kg N ha^–1 year^–1) in another catchment. However, larger water discharge combined with loamy sandy soils leads to comparatively high nitrogen losses (12 kg N ha^–1 year^–1). The highest P losses (0.318 kg P ha^–1 year^–1) occurred in the catchment with hilly relief and clay soil texture. In summary, extensive agriculture in the post-Soviet countries has reduced the importance of agricultural activity for the extent of nutrient losses and agricultural factors (cultivation, fertilisation and livestock density) are responsible for the losses only in the region of sufficient agricultural activity (N input – 71.5 kg N ha^–1, livestock density – 0.87 LU ha^–1).     

Trace elements in the livers of cod (Gadus morhua L.) from the Baltic Sea: levels and temporal trends

This paper presents and discusses the levels and temporal trends of concentrations of Cd, Pb, Hg, Cu, Zn, and As in livers and Hg in the muscle tissues of cod (Gadus morhua L) from the Baltic Sea during the period 1994–2010. Concentrations of Pb, Hg, and Cd exhibited significant downward trends. Cu and Zn concentrations exhibited upward trends in the period 1994 to 2010. No trends were detected for concentrations of As. The temporal trends identified in heavy metal concentrations in cod livers corresponded to the directions of changes in concentrations of these elements introduced into the Baltic Sea via river runoff and atmospheric emission, and those in surface and deep waters of the Baltic. Downward trends in the concentrations of toxic metals in cod livers suggest that advantageous changes are occurring in concentrations of heavy metals in the environment of the southern Baltic Sea.     

Recent Trends and Patterns of Nutrient Concentrations in Small Agricultural Streams in Sweden

Long-term median total phosphorus (TotP) and total nitrogen (TotN) concentrations were 0.08 and 5.5 P/N (mg L^-1), respectively, in 10 agricultural streams monitored since 1988 in Sweden. The areas ofthe respective catchments are 2–20 km². The period 1992/2002 was characterised by stable hydrological conditions without any flow trends in nearly all of the streams. The highest average TotP concentration, 0.17 mg P L^-1, was found in a small agriculturalstream in the largest Swedish agricultural plain. The soil texture is here characterised by a large specific surface area of the soil particles, and the agriculture by cereal production. The second highestaverage TotP concentration, 0.14 mg P L ^-1, was measured in the surface water from a catchment characterised partly by clay soils andby production of potato, spring cereals and grass. This catchment had twice as many fields with a calculated high risk for P losses comparedwith another monitored catchment in the same watershed (River Rönneå). There was a significant downward TotP trend during 1992/2002 of 0.0012 mg P L^-1 yr^-1 (Sen's slope estimator) in the catchment where many fields risk P losses and which had a reduced P manure application rate of –20% during 1995/2000. In recent years practically no manure has been spread during autumn. Bypass flow of nitrate through one soil has been suggested to influence the LOWESS (LOcally WEighted Scatterplot Smothing) fitting curve of TotN. Total nitrogen concentration decreased in most of the catchment. The average downward slope was similar to a general TotN reduction of 0.069 mg N L^-1 yr^-1. During the period 1992/2002 this was equal to slightly more than 10 per cent. Cultivation of catch crops wasrelatively uncommon until 2002, but this practice is expected to expandto larger areas during 2003 and in the future.     

Estimation of Emissions of γ-Hexachlorcyclohexane from the Great Lakes–St. Lawrence Ecosystem Using a Coupled Efficient Kalman Filter–Atmospheric Transport–Soil Model

An efficient linear Kalman filter has been combined with a coupled atmospheric transport and soil–air exchange model to determine organochlorine pesticides emissions on the regional scale. In this study, results of -HCH emissions from the Great Lakes–St. Lawrence ecosystem, estimated from the coupled model, are presented and discussed. A source receptor technique is used to identify a priori the locations of emission sources of -HCH, the emissions are then updated through a Kalman filtering procedure which minimizes the weighted difference between the predicted mixing ratios from the coupled model and the measured concentrations over the Great Lakes–St. Lawrence river region. Two experiments using the inverse algorithm are carried out. In the first experiment, the coupled atmospheric transport and soil–air exchange model is implemented to predict -HCH air and soil concentrations. Emissions are then updated every 12 days using the updated soil concentrations and emission factors. However, the updated emissions are not input into the coupled atmospheric transport and soil–air exchange model. On the other hand, in the second experiment the updated emissions are fed back to the coupled model, so that the model is reinitialized in each 12 days. The results from the inverse technique for the year 1995 have been compared with grided -HCH emission inventory in Canada, generated by emission factors. It is shown that the estimated emissions of -HCH are consistent with the measured emissions. It is found that the St. Lawrence valley has larger emissions of -HCH than the Great Lakes region, indicating an opposite distribution to the emission usage inventory, but in agreement with the measured -HCH concentration.     

Water quality trends in New Zealand rivers: 1989–2009

Recent assessments of water quality in New Zealand have indicated declining trends, particularly in the 40 % of the country’s area under pasture. The most comprehensive long-term and consistent water quality dataset is the National Rivers Water Quality Network (NRWQN). Since 1989, monthly samples have been collected at 77 NRWQN sites on 35 major river systems that, together, drain about 50 % of New Zealand’s land area. Trend analysis of the NRWQN data shows increasing nutrient concentrations, particularly nitrogen (total nitrogen and nitrate), over 21 years (1989–2009). Total nitrogen and nitrate concentrations were increasing significantly over the first 11 years (1989–2000), but for the more recent 10-year period, only nitrate concentrations continued to increase sharply. Also, the increasing phosphorus trends over the first 11 years (1989–2000) levelled off over the later 10-year period (2000–2009). Conductivity has also increased over the 21 years (1989–2009). Visual clarity has increased over the full time period which may be the positive result of soil conservation measures and riparian fencing. NRWQN data shows that concentrations of nutrients increase, and visual clarity decreases (i.e. water quality declines), with increasing proportions of pastoral land in catchments. As such, the increasing nutrient trends may reflect increasing intensification of pastoral agriculture.     

Transport of NO<Subscript>X</Subscript> Emissions from Sugarcane Fertilisation into the Great Barrier Reef Lagoon

The Great Barrier Reef World Heritage Area contains highly sensitive ecosystems that are threatened by the effects of anthropogenic activity including eutrophication. The nearby sugarcane plantations of tropical north Queensland are fertilised annually and there has been ongoing concern about the magnitude of the loss of applied nitrogen to the environment. Previous studies have considered the potential of rainwater run-off to deposit reactive nitrogen species into rivers and ultimately into the Great Barrier Reef Lagoon, but have neglected the possibility of transport via the atmosphere. This paper reports the results of a modelling study commissioned by Australia’s National Heritage Trust aimed at assessing whether or not atmospheric deposition of reactive nitrogen from Queensland’s sugarcane plantations posed a potential threat to the Great Barrier Reef Lagoon. Atmospheric dispersion modelling was undertaken using The Air Pollution Model, developed by Australia’s Commonwealth Scientific and Industrial Research Organisation. Despite the predominance of onshore southeasterly winds, the dispersion model results indicate that 9% of the time during the sugarcane fertilization season (in the modeled years 2001–2006) the meteorological conditions resulted in emissions from the coastal regions of north Queensland being transported out over the ocean around the Great Barrier Reef. The results suggest that there may be a greater efficiency for transport out over the reef during October than for November and December. For the 2 months that exhibited the greatest potential for transport of coastal pollution to the Great Barrier Reef, the modeled deposition of nitrogen oxides (NO_X) into the Great Barrier Reef lagoon was less than 1% of the total emissions from the sugarcane plantations, but was not zero. Our model has a simple chemical scheme that does not cover the full chemistry of all reactive nitrogen compounds and so the results are only indicative of the potential levels of deposition. Nevertheless, our study shows that small amounts of NO_X that originate from sugarcane fertilization may be transported and dry deposited into the Great Barrier Reef lagoon. Other pathways not included in the modeling scheme may provide a more efficient transport mechanism. Whilst modern practices for the application of fertilizer to sugarcane plantations have drastically reduced emissions, the potential efficiency of transport of pollutants via the atmosphere may be of concern for other more highly polluting agricultural industries.     

Losses of biota from American aquatic communities due to acid rain

Models based on chemical survey data and geochemical assumptions were calibrated for areas where rates of acidification are known, then used to predict the declines in alkalinity and pH of lakes in the eastern and midwestern U.S.A. These results were combined with known acid tolerances of different taxonomic groups to estimate the extent of damage caused by acid rain to biological assemblages.An average of over 50% of the species in some taxonomic groups have probably been eliminated from lakes in the Adirondacks, Poconos-Catskills and southern New England. Moderate damage to biotic communities was predicted for lakes in central New England, and north-central Wisconsin. Damage predicted in Maine, upper Michigan, northeastern Minnesota and the remainder of the upper Great Lakes region was slight. Crustaceans, molluscs, leeches and insects were among the most severely affected groups. Among fishes, species of minnows (Cyprindae) were depleted in the most heavily acidified regions, with some declines in salmonid and centrarchid species.Predicted damage to individual lakes in all areas was highly variable. In areas receiving highly acidic deposition, 100% of the species in acid-sensitive taxonomic groups were eliminated in some lakes, while damage to other lakes was predicted to be slight.Estimated damage varied from lake to lake within each subregion, based on chemical characteristics. The most heavily damaged lakes in the Adirondacks and Pocono-Catskills have probably lost all species of molluscs, leeches and crustaceans. On the other hand, lakes of the Midwest showed either slight increases or decreases in the richness of predicted biotic communities.The possible ranges of original sulfate concentrations in lakes and the proportion of sulfuric acid in precipitation that liberated base cations from catchments were confined to relatively narrow limits by the model.Contribution from Fourth World Wilderness Congress-Acid Rain Symposium, Denver (Estes Park), Colorado, September 11–18, 1987.     

Sulphate, Nitrogen and Base Cation Budgets at 21 Forested Catchments in Canada, the United States and Europe

To assess the concern over declining base cation levels in forest soils caused by acid deposition, input-output budgets (1990s average) for sulphate (SO₄), inorganic nitrogen (NO₃-N; NH₄-N), calcium (Ca), magnesium (Mg) and potassium (K) were synthesised for 21 forested catchments from 17 regions in Canada, the United States and Europe. Trend analysis was conducted on monthly ion concentrations in deposition and runoff when more than 9 years of data were available (14 regions, 17 sites). Annual average SO₄ deposition during the 1990s ranged between 7.3 and 28.4 kg ha⁻¹ per year, and inorganic nitrogen (N) deposition was between 2.8 and 13.8 kg ha⁻¹ per year, of which 41–67% was nitrate (NO₃-N). Over the period of record, SO₄ concentration in deposition decreased in 13/14 (13 out of 14 total) regions and SO₄ in runoff decreased at 14/17 catchments. In contrast, NO₃-N concentrations in deposition decreased in only 1/14 regions, while NH₄-N concentration patterns varied; increasing at 3/14 regions and decreasing at 2/14 regions. Nitrate concentrations in runoff decreased at 4/17 catchments and increased at only 1 site, whereas runoff levels of NH₄-N increased at 5/17 catchments. Decreasing trends in deposition were also recorded for Ca, Mg, and K at many of the catchments and on an equivalent basis, accounted for up to 131% (median 22%) of the decrease in acid anion deposition. Base cation concentrations in streams generally declined over time, with significant decreases in Ca, Mg and K occurring at 8, 9 and 7 of 17 sites respectively, which accounted for up to 133% (median 48%) of the decrease in acid anion concentration. Sulphate export exceeded input at 18/21 catchments, likely due to dry deposition and/or internal sources. The majority of N in deposition (31–100%; median 94%) was retained in the catchments, although there was a tendency for greater NO₃-N leaching at sites receiving higher (<7 kg ha^-1 per year) bulk inorganic N deposition. Mass balance calculations show that export of Ca and Mg in runoff exceeds input at all 21 catchments, but K export only exceeds input at 16/21 sites. Estimates of base cation weathering were available for 18 sites. When included in the mass balance calculation, Ca, Mg and K exports exceeded inputs at 14, 10 and 2 sites respectively. Annual Ca and Mg losses represent appreciable proportions of the current exchangeable soil Ca and Mg pools, although losses at some of the sites likely occur from weathering reactions beneath the rooting zone and there is considerable uncertainty associated with mineral weathering estimates. Critical loads for sulphur (S) and N, using a critical base cation to aluminium ratio of 10 in soil solution, are currently exceeded at 7 of the 18 sites with base cation weathering estimates. Despite reductions in SO₄ and H⁺ deposition, mass balance estimates indicate that acid deposition continues to acidify soils in many regions with losses of Ca and Mg of primary concern. The U.S. Government's right to retain a non-exclusive, royalty free licence in and to any copyright is acknowledged. The Canadian Crown reserves the right to retain a non-exclusive, royalty free licence in and to any copyright.     

A Regional Analysis of Lake Acidification Trends for the Northeastern U.S., 1982-1994

Acidic deposition is a regional phenomenon, but its effects have traditionally been studied using site-specific, intensive monitoring. We present trends information for 36 lakes of high-to-moderate acid sensitivity (defined as acid neutralizing capacity [ANC] < 100 eq L-1), and 15 deposition monitoring stations, in the northeastern U.S. for the period 1982-1994. Trends at each site were assessed through use of the Seasonal Kendall tau test; the resulting statistics were combined, through a technique analogous to analysis of variance, to produce quasi-regional estimates of change for key chemical variables. Rates of sulfate deposition declined significantly across all of the northeastern region during this time period, while rates of nitrate and ammonium deposition were unchanged. All lakes exhibited strong decreases in sulfate concentrations in response to declining sulfate deposition, but there was a strong contrast in the response of acid/base status between lakes in New England and lakes in the Adirondacks. As a group, the New England lakes exhibited recovery (ANC = +0.8 eq L-1yr-1, p<0.001), while the Adirondack lakes exhibited either no trend or further acidification (as a group, ANC = -0.5 eq L-1yr-1, p<0.01). This contrast can be attributed to changes in base cation concentrations: New England lakes exhibited base cations declines that were smaller in magnitude than declines in sulfate, producing the observed recovery in ANC; Adirondack lakes showed base cation declines that were very similar to those of sulfate, and no recovery was evident.     

Seasonal baseline of nutrients and stable isotopes in a saline lake of Argentina: biogeochemical processes and river runoff effects

The seasonal variability of inorganic and organic nutrients and stable isotopes and their relations with plankton and environmental conditions were monitored in Lake Chasicó. Principal component analysis evidenced the strong influence of the river runoff on several biogeochemical variables. Silicate concentrations were controlled by diatom biomass and river discharge. Higher values of nitrate and soluble reactive phosphorus (SRP) indicated agricultural uses in the river basin. Elevated pH values (～9) inhibiting nitrification in the lake explained partially the dominance of ammonium: ～83 % of dissolved inorganic nitrogen (DIN). The low DIN/SRP ratio inferred nitrogen limitation, although the hypotheses of iron and CO₂ limitation are relevant in alkaline lakes. Particulate organic matter (POM) and dissolved organic matter (DOM) were mainly of autochthonous origin. The main allochthonous input was imported by the river as POM owning to the arid conditions. Dissolved organic carbon was likely top-down regulated by the bacterioplankton grazer Brachionus plicatilis. The δ¹³C signature was a good indicator of primary production and its values were influenced probably by CO₂ limitation. The δ¹⁵N did not evidence nitrogen fixation and suggested the effects of anthropogenic activities. The preservation of a good water quality in the lake is crucial for resource management.     

Water quality status and trends in agriculture-dominated headwaters; a national monitoring network for assessing the effectiveness of national and European manure legislation in The Netherlands

Large nutrient losses to groundwater and surface waters are a major drawback of the highly productive agricultural sector in The Netherlands. The resulting high nutrient concentrations in water resources threaten their ecological, industrial, and recreational functions. To mitigate eutrophication problems, legislation on nutrient application in agriculture was enforced in 1986 in The Netherlands. The objective of this study was to evaluate this manure policy by assessing the water quality status and trends in agriculture-dominated headwaters. We used datasets from 5 agricultural test catchments and from 167 existing monitoring locations in agricultural headwaters. Trend analysis for these locations showed a fast reduction of nutrient concentrations after the enforcement of the manure legislation (median slopes of ?0.55 mg/l per decade for total nitrogen (N-tot) and ?0.020 mg/l per decade for total phosphorus (P-tot)). Still, up to 76 % of the selected locations currently do not comply with either the environmental quality standards (EQSs) for nitrogen (N-tot) or phosphorus (P-tot). This indicates that further improvement of agricultural water quality is needed. We observed that weather-related variations in nutrient concentrations strongly influence the compliance testing results, both for individual locations and for the aggregated results at the national scale. Another important finding is that testing compliance for nutrients based on summer average concentrations may underestimate the agricultural impact on ecosystem health. The focus on summer concentrations does not account for the environmental impact of high winter loads from agricultural headwaters towards downstream water bodies.