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1.
The purpose of this study was to observe the economic sustainability of three different biogas full scale plants, fed with different organic matrices: energy crops (EC), manure, agro-industrial (Plants B and C) and organic fraction of municipal solid waste (OFMSW) (Plant A). The plants were observed for one year and total annual biomass feeding, biomass composition and biomass cost (€ Mg?1), initial investment cost and plant electric power production were registered. The unit costs of biogas and electric energy (€ Sm?3biogas, € kW h?1EE) were differently distributed, depending on the type of feed and plant. Plant A showed high management/maintenance cost for OFMSW treatment (0.155  Sm?3biogas, 45% of total cost), Plant B suffered high cost for EC supply (0.130 € Sm?3biogas, 49% of total cost) and Plant C showed higher impact on the total costs because of the depreciation charge (0.146  Sm?3biogas, 41% of total costs). The breakeven point for the tariff of electric energy, calculated for the different cases, resulted in the range 120–170  MW h?1EE, depending on fed materials and plant scale. EC had great impact on biomass supply costs and should be reduced, in favor of organic waste and residues; plant scale still heavily influences the production costs. The EU States should drive incentives in dependence of these factors, to further develop this still promising sector.  相似文献   

2.
Methane oxidation was studied at a closed boreal landfill (area 3.9 ha, amount of deposited waste 200,000 tonnes) equipped with a passive gas collection and distribution system and a methane oxidative top soil cover integrated in a European Union landfill directive-compliant, multilayer final cover. Gas wells and distribution pipes with valves were installed to direct landfill gas through the water impermeable layer into the top soil cover. Mean methane emissions at the 25 measuring points at four measurement times (October 2005–June 2006) were 0.86–6.2 m3 ha?1 h?1. Conservative estimates indicated that at least 25% of the methane flux entering the soil cover at the measuring points was oxidized in October and February, and at least 46% in June. At each measurement time, 1–3 points showed significantly higher methane fluxes into the soil cover (20–135 m3 ha?1 h?1) and methane emissions (6–135 m3 ha?1 h?1) compared to the other points (<20 m3 ha?1 h?1 and <10 m3 ha?1 h?1, respectively). These points of methane overload had a high impact on the mean methane oxidation at the measuring points, resulting in zero mean oxidation at one measurement time (November). However, it was found that by adjusting the valves in the gas distribution pipes the occurrence of methane overload can be to some extent moderated which may increase methane oxidation. Overall, the investigated landfill gas treatment concept may be a feasible option for reducing methane emissions at landfills where a water impermeable cover system is used.  相似文献   

3.
Mechanical biological treatment (MBT) is an effective technique, which removes organic carbon from municipal solid waste (MSW) prior to deposition. Thereby, methane (CH4) production in the landfill is strongly mitigated. However, direct measurements of greenhouse gas emissions from full-scale MBT landfills have not been conducted so far. Thus, CH4 and nitrous oxide (N2O) emissions from a German MBT landfill in operation as well as their concentrations in the landfill gas (LFG) were measured. High N2O emissions of 20–200 g CO2 eq. m?2 h?1 magnitude (up to 428 mg N m?2 h?1) were observed within 20 m of the working face. CH4 emissions were highest at the landfill zone located at a distance of 30–40 m from the working face, where they reached about 10 g CO2 eq. m?2 h?1. The MBT material in this area has been deposited several weeks earlier. Maximum LFG concentration for N2O was 24.000 ppmv in material below the emission hotspot. At a depth of 50 cm from the landfill surface a strong negative correlation between N2O and CH4 concentrations was observed. From this and from the distribution pattern of extractable ammonium, nitrite, and nitrate it has been concluded that strong N2O production is associated with nitrification activity and the occurrence of nitrite and nitrate, which is initiated by oxygen input during waste deposition. Therefore, CH4 mitigation measures, which often employ aeration, could result in a net increase of GHG emissions due to increased N2O emissions, especially at MBT landfills.  相似文献   

4.
This work presents the use of two composts as filter media for the treatment by biofiltration of odors emitted during the aerobic composting of a mixture containing sewage sludge and yard waste. The chemical analysis of the waste gas showed that the malodorous compounds at trace level were the reduced sulfur compounds (RSCs) which were dimethyl sulfide (Me2S), methanethiol (MeSH) and hydrogen sulfide (H2S). Laboratory tests for biofiltration treatment of RSCs were performed in order to compare the properties of two filter media, consisted of a mature compost with yard waste (YW) and a mixture of mature compost with sewage sludge and yard waste (SS/YW). The maximum elimination capacity (EC) values obtained with the YW mature compost as packing material were 12.5 mg m?3 h?1 for H2S, 7.9 mg m?3 h?1 for MeSH and 34 mg m?3 h?1 for Me2S, and the removal efficiency decreased in the order of: H2S > MeSH > Me2S. Moreover, the YW compost filter medium had a better behavior than the filter medium based on SS/YW in terms of acclimation of the microbial communities and moisture content. According to these results, a YW mature compost as packing material for an industrial biofilter were designed and this industrial biofilter was found effective under specified conditions (without inoculation and addition of water). The results showed that the maximum EC value of RSCs was 935 mg m?3 h?1 (100% removal efficiency, RE) for an inlet loads (IL) between 0 and 1000 mg m?3 h?1. Thus, YW compost medium was proven efficient for biofiltration of RSCs both at laboratory and industrial scale.  相似文献   

5.
Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25–207 kg CO2-eq t?1 rw. Within all process stages, the emission of fossil CO2 from the combustion of MSW was the main contributor (111–254 kg CO2-eq t?1 rw), while the substitution of electricity reduced the GHG emissions by 150–247 kg CO2-eq t?1 rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.  相似文献   

6.
The effects of organic loading rate on the performance and stability of anaerobic co-digestion of municipal biomass waste (MBW) and waste activated sludge (WAS) were investigated on a pilot-scale reactor. The results showed that stable operation was achieved with organic loading rates (OLR) of 1.2–8.0 kg volatile solid (VS) (m3 d)?1, with VS reduction rates of 61.7–69.9%, and volumetric biogas production of 0.89–5.28 m3 (m3 d)?1. A maximum methane production rate of 2.94 m3 (m3 d)?1 was achieved at OLR of 8.0 kg VS (m3 d)?1 and hydraulic retention time of 15 days. With increasing OLRs, the anaerobic reactor showed a decrease in VS removal rate, average pH value and methane concentration, and a increase of volatile fatty acid concentration. By monitoring the biogas production rate (BPR), the anaerobic digestion system has a higher acidification risk under an OLR of 8.0 kg VS (m3 d)?1. This result remarks the possibility of relating bioreactor performance with BPR in order to better understand and monitor anaerobic digestion process.  相似文献   

7.
Kolkata is one of four metropolitan cities in India. With an area of 187.33 sq km and a population of about 8 million, it generates around 3,000 t d?1 of municipal solid waste (MSW) at a rate of 450–500 g per capita per day. With rapid urbanization as a result of planned and unplanned growth and industrialization, the problems associated with handling MSW have increased at an alarming rate over the past few years. No source segregation arrangement exists; there is only limited (60%) house-to-house collection; and 50–55% open vats are used in the present collection system. The operational efficiency of the Kolkata Municipal Corporation (KMC) transport system is about 50%, with a fleet composed of about 30–35% old vehicles. The majority (80%) of these, particularly the hired vehicles, are more than 20 years old. The newly added areas covered by KMC have even lower collection efficiencies, and only an informal recycling system exists. The waste collected has a low energy value (3,350–4,200 kJ kg?1) with high moisture and inert content. A 700 t d?1 compost plant set up in 2000 has not been functioning effectively since 2003. Open dumping (without liners and without a leachate management facility) and the threat of groundwater pollution, as well as saturation of an existing landfill site (Dhapa) are the most pressing problems for the city today. KMC spends 70–75% of its total expenditures on collection of solid waste, 25–30% on transportation, and less than 5% on final disposal arrangements. The Kolkata Environmental Improvement Project, funded by the Asian Development Bank, is seen as only a partial solution to the problem. A detailed plan should emphasize segregation at the source, investment in disposal arrangements (including the use of liners and leachate collection), and an optimized transport arrangement, among improvements.  相似文献   

8.
The global gaseous emissions produced by landfilling the Mechanically Sorted Organic Fraction (MSOF) with different weeks of Mechanical Biological Treatment (MBT) was evaluated for an existing waste management system. One MBT facility and a landfill with internal combustion engines fuelled by the landfill gas for electrical energy production operate in the waste management system considered. An experimental apparatus was used to simulate 0, 4, 8 and 16 weeks of aerobic stabilization and the consequent biogas potential (Nl/kg) of a large sample of MSOF withdrawn from the full-scale MBT. Stabilization achieved by the waste was evaluated by dynamic oxygen uptake and fermentation tests. Good correlation coefficients (R2), ranging from 0.7668 to 0.9772, were found between oxygen uptake, fermentation and anaerobic test values. On the basis of the results of several anaerobic tests, the methane production rate k (year?1) was evaluated. k ranged from 0.436 to 0.308 year?1 and the bio-methane potential from 37 to 12 N m3/tonne, respectively, for the MSOF with 0 and 16 weeks of treatment. Energy recovery from landfill gas ranged from about 11 to 90 kW h per tonne of disposed MSOF depending on the different scenario investigated. Life cycle analysis showed that the scenario with 0 weeks of pre-treatment has the highest weighted global impact even if opposite results were obtained with respect to the single impact criteria. MSOF pre-treatment periods longer than 4 weeks showed rather negligible variation in the global impact of system emissions.  相似文献   

9.
The Outer Loop landfill bioreactor (OLLB) in Louisville, KY, USA has been the site of a study to evaluate long-term bioreactor performance at a full-scale operational landfill. Three types of landfill units were studied including a conventional landfill (Control cell), a new landfill area that had an air addition and recirculation piping network installed as waste was being placed (As-Built cell), and a conventional landfill that was modified to allow for liquids recirculation (Retrofit cell). During the monitoring period, the Retrofit, Control, and As-Built cells received 48, 14, and 213 L Mg?1 (liters of liquids per metric ton of waste), respectively. The leachate collection system yielded 60, 57 and 198 L Mg?1 from the Retrofit, Control, and As-Built cells, respectively. The head on liner in all cells was below regulatory limits. In the Control and As-Built cells, leachate head on liner decreased once waste placement stopped. The measured moisture content of the waste samples was consistent with that calculated from the estimate of accumulated liquid by the liquid balance. Additionally, measurements on excavated solid waste samples revealed large spatial variability in waste moisture content. The degree of saturation in the Control cells decreased from 85% to 75%. The degree of saturation increased from 82% to 83% due to liquids addition in the Retrofit cells and decreased back to 80% once liquid addition stopped. In the As-Built cells, the degree of saturation increased from 87% to 97% during filling activities and then started to decrease soon after filling activities stopped to reach 92% at the end of the monitoring period. The measured leachate generation rates were used to estimate an in-place saturated hydraulic conductivity of the MSW in the range of 10?8 to 10?7 m s?1 which is lower than previous reports. In the Control and Retrofit cells, the net loss in liquids, 43 and 12 L Mg?1, respectively, was similar to the measured settlement of 15% and 5–8% strain, respectively (Abichou et al., 2013). The increase in net liquid volume in the As-Built cells indicates that the 37% (average) measured settlement strain in these cells cannot be due to consolidation as the waste mass did not lose any moisture but rather suggests that settlement was attributable to lubrication of waste particle contacts, softening of flexible porous materials, and additional biological degradation.  相似文献   

10.
With limited assessment, leachate treatment of a specified landfill is considered to be a significant source of greenhouse gas (GHG) emissions. In our study, the cumulative GHG emitted from the storage ponds and process configurations that manage fresh or aged landfill leachate were investigated. Our results showed that strong CH4 emissions were observed from the fresh leachate storage pond, with the fluxes values (2219–26,489 mg C m?2 h?1) extremely higher than those of N2O (0.028–0.41 mg N m?2 h?1). In contrast, the emission values for both CH4 and N2O were low for the aged leachate tank. N2O emissions became dominant once the leachate entered the treatment plants of both systems, accounting for 8–12% of the removal of N-species gases. Per capita, the N2O emission based on both leachate treatment systems was estimated to be 7.99 g N2O–N capita?1 yr?1. An increase of 80% in N2O emissions was observed when the bioreactor pH decreased by approximately 1 pH unit. The vast majority of carbon was removed in the form of CO2, with a small portion as CH4 (<0.3%) during both treatment processes. The cumulative GHG emissions for fresh leachate storage ponds, fresh leachate treatment system and aged leachate treatment system were 19.10, 10.62 and 3.63 Gg CO2 eq yr?1, respectively, for a total that could be transformed to 9.09 kg CO2 eq capita?1 yr?1.  相似文献   

11.
Ex situ nitrification and sequential in situ denitrification represents a novel approach to nitrogen management at landfills. Simultaneous ammonia and organics removal was achieved in a continuous stirred tank reactor (CSTR). The results showed that the maximum nitrogen loading rate (NLR) and the maximum organic loading rate (OLR) was 0.65 g N l?1 d?1 and 3.84 g COD l?1 d?1, respectively. The ammonia and chemical oxygen demand (COD) removal was over 99% and 57%, respectively. In the run of the CSTR, free ammonia (FA) inhibition and low dissolved oxygen (DO) were found to be key factors affecting nitrite accumulation. In situ denitrification was studied in a municipal solid waste (MSW) column by recalculating nitrified leachate from CSTR. The decomposition of MSW was accelerated by the recirculation of nitrified leachate. Complete reduction of total oxidized nitrogen (TON) was obtained with maximum TON loading of 28.6 g N t?1 TS d?1 and denitrification was the main reaction responsible. Additionally, methanogenesis inhibition was observed while TON loading was over 11.4 g N t?1 TS d?1 and the inhibition was enhanced with the increase of TON loading.  相似文献   

12.
Biogas or landfill gas can be converted to a high-grade gas rich in methane with the use of municipal solid waste incineration bottom ash as a reactant for fixation of CO2 and H2S. In order to verify results previously obtained at a laboratory scale with 65–90 kg of bottom ash (BA), several test runs were performed at a pilot scale, using 500–1000 kg of bottom ash and up to 9.2 N m3/h real landfill gas from a landfill in the Tuscany region (Italy). The input flow rate was altered. The best process performance was observed at a input flow rate of 3.7 N m3/(h tBA). At this flow rate, the removal efficiencies for H2S were approximately 99.5–99%.  相似文献   

13.
A case study of landfill liquids addition using small diameter (5 cm) vertical wells is reported. More than 25,000 m3 of leachate was added via 134 vertical wells installed 3 m, 12 m, and 18 m deep over five years in a landfill in Florida, US. Liquids addition performance (flow rate per unit screen length per unit liquid head) ranged from 5.6 × 10?8 to 3.6 × 10?6 m3 s?1 per m screen length per m liquid head. The estimated radial hydraulic conductivity ranged from 3.5 × 10?6 to 4.2 × 10?4 m s?1. The extent of lateral moisture movement ranged from 8 to 10 m based on the responses of moisture sensors installed around vertical well clusters, and surface seeps were found to limit the achievable liquids addition rates, despite the use of concrete collars under a pressurized liquids addition scenario. The average moisture content before (51 samples) and after (272 samples) the recirculation experiments were 23% (wet weight basis) and 45% (wet weight basis), respectively, and biochemical methane potential measurements of excavated waste indicated significant (p < 0.025) decomposition.  相似文献   

14.
Pyrolysis of large printed circuit board (PCB) waste particle was conducted on a specially designed laboratory-scale thermobalance (Macro-TG) with sample loading of 30 g under dynamic nitrogen atmosphere. The effects of heating rate (10, 15, 20 and 25 °C min?1) and particle size (1 mm × 1 mm, 5 mm × 5 mm, 10 mm × 10 mm and 10 mm × 20 mm) were examined. To compare the different decomposition behavior of fine and large one, the thermal decomposition of PCB waste powder (approximately 5 mg) was also performed on a thermogravimetric analyzer (common TG) under various heating rates (10, 15, 20 and 40 °C min?1) and particle size ranges (0.198–0.165 mm, 0.165–0.074 mm, 0.074–0.055 mm and 0.055–0.047 mm). Experimental results show that large particle has a pyrolysis reaction retardancy compared to fine one. The distributed activation energy model was used to study the pyrolysis kinetics. It was found that during pyrolysis process, values of frequency factor (k0) changed with different activation energy (E) values. On common TG, the E values range from 156.95 to 319.37 kJ mol?1 and k0 values range from 2.67 × 1013 to 2.24 × 1027 s?1. While, on Macro-TG, the range of E was 31.48–41.26 kJ mol?1 and of the frequency factor was 19.80–202.67 s?1.  相似文献   

15.
The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6–3.5 kg week?1 and the temperature inside the composting units was in all cases only a few degrees (2–10 °C) higher than the ambient temperature. The emissions of methane (CH4) and nitrous oxide (N2O) were quantified as 0.4–4.2 kg CH4 Mg?1 input wet waste (ww) and 0.30–0.55 kg N2O Mg?1 ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH4 and N2O emissions) of 100–239 kg CO2-eq. Mg?1 ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH4 during mixing which was estimated to 8–12% of the total CH4 emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg?1 ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO2-eq. Mg?1 ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.  相似文献   

16.
Garden waste generation and composition were studied in Aarhus, Denmark. The amount of garden waste generated varied seasonally, from 2.5 kg person?1 month?1 in winter to 19.4 kg person?1 month?1 in summer. Seasonal fractional composition and chemical characterization of garden waste were determined by sorting and sampling garden waste eight times during 1 year. On a yearly basis, the major fraction of garden waste was “small stuff” (flowers, grass clippings, hedge cuttings and soil) making up more than 90% (wet waste distribution) during the summer. The woody fractions (branches, wood) are more significant during the winter. Seasonal trends in waste chemical composition were recorded and an average annual composition of garden waste was calculated, considering the varying monthly generation and material fraction composition: the wet garden waste contained 40% water, 30% organic matter (VS) and 30% ash. The ash content suggests that the garden waste contains a significant amount of soil. This is in particular the case during summer. Of nutrients, the garden waste contained in average on a dry matter basis 0.6% N, 0.1% P, and 1.0% K. However, the contents varied significantly among the fractions and during the year. The content of trace elements (Cd, Cr, Cu, Hg, Ni, Pb, and Zn) was low.  相似文献   

17.
Mineralization potentials are often used to classify organic wastes. These methods involve measuring CO2 production during batch experiments, so variations in chemical compounds are not addressed. Moreover, the physicochemical conditions are not monitored during the reactions. The present study was designed to address these deficiencies. Incubations of a mixture of soil and waste (vinasse at 20% dry matter from a fermentation industry) were conducted in aerobic and anaerobic conditions, and liquid samples obtained by centrifugation were collected at 2 h, 1 d and 28 d. Dissolved organic carbon (DOC) patterns highlighted that: there was a “soil effect” which increased organic matter (OM) degradation in all conditions compared to vinasse incubated alone; and OM degradation was faster under aerobic conditions since 500 mg kg?1 of C remained after aerobic incubation, as compared to 4000 mg kg?1 at the end of the anaerobic incubation period. No changes were detected by Fourier transform infrared spectroscopy (FTIR) between 2 h and 1 d incubation. At 28 days incubation, the FTIR signal of the aerobic samples was deeply modified, thus confirming the high OM degradation. Under anaerobic conditions, the main polysaccharide contributions (ν(C–O)) disappeared at 1000 and 1200 cm?1, as also confirmed by the 13C NMR findings. Under aerobic incubation, a 50% decrease in the polysaccharide proportion was observed. Under anaerobic conditions, significant chemical modifications of the organic fraction were detected, namely formation of low molecular weight organic acids.  相似文献   

18.
In this paper rejected streams coming from a waste packaging material recovery facility have been characterized and separated into families of products of similar nature in order to determine the influence of different types of ingredients in the products obtained in the pyrolysis process. The pyrolysis experiments have been carried out in a non-stirred batch 3.5 dm3 reactor, swept with 1 L min?1 N2, at 500 °C for 30 min. Pyrolysis liquids are composed of an organic phase and an aqueous phase. The aqueous phase is greater as higher is the cellulosic material content in the sample. The organic phase contains valuable chemicals as styrene, ethylbenzene and toluene, and has high heating value (HHV) (33–40 MJ kg?1). Therefore they could be used as alternative fuels for heat and power generation and as a source of valuable chemicals. Pyrolysis gases are mainly composed of hydrocarbons but contain high amounts of CO and CO2; their HHV is in the range of 18–46 MJ kg?1. The amount of COCO2 increases, and consequently HHV decreases as higher is the cellulosic content of the waste. Pyrolysis solids are mainly composed of inorganics and char formed in the process. The cellulosic materials lower the quality of the pyrolysis liquids and gases, and increase the production of char.  相似文献   

19.
Vermitechnology is gaining recognition as an environmental friendly waste management strategy. Its successful implementation requires that the key operational parameters like earthworm stocking density be established for each target waste/waste mixture. One target waste mixture in South Africa is waste paper mixed with cow dung and rock phosphate (RP) for P enrichment. This study sought to establish optimal Eisenia fetida stocking density for maximum P release and rapid bioconversion of RP enriched cow dung–paper waste mixtures. E. fetida stocking densities of 0, 7.5, 12.5, 17.5 and 22.5 g-worms kg?1 dry weight of cow dung–waste paper mixtures were evaluated. The stocking density of 12.5 g-worms kg?1 resulted in the highest earthworm growth rate and humification of the RP enriched waste mixture as reflected by a C:N ratio of <12 and a humic acid/fulvic acid ratio of >1.9 in final vermicomposts. A germination test revealed that the resultant vermicompost had no inhibitory effect on the germination of tomato, carrot, and radish. Extractable P increased with stocking density up to 22.5 g-worm kg?1 feedstock suggesting that for maximum P release from RP enriched wastes a high stocking density should be considered.  相似文献   

20.
The anaerobic digestion performances of kitchen waste (KW) and fruit/vegetable waste (FVW) were investigated for establishing engineering digestion system. The study was conducted from lab-scale to pilot-scale, including batch, single-phase and two-phase experiments. The lab-scale experimental results showed that the ratio of FVW to KW at 5:8 presented higher methane productivity (0.725 L CH4/g VS), and thereby was recommended. Two-phase digestion appeared to have higher treatment capacity and better buffer ability for high organic loading rate (OLR) (up to 5.0 g (VS) L?1 d?1), compared with the low OLR of 3.5 g (VS) L?1 d?1 for single-phase system. For two-phase digestion, the pilot-scale system showed similar performances to those of lab-scale one, except slightly lower maximum OLR of 4.5 g (VS) L?1 d?1 was allowed. The pilot-scale system proved to be profitable with a net profit of 10.173 $/ton as higher OLR (?3.0 g (VS) L?1 d?1) was used.  相似文献   

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