农业生态系统中的熵

本文以热力学定律为依据,根据农业生态系统的特性,给农业生态系统的熵下了定义。提出了评价农业生态系统的三个指标。并对二则实例进行了验算,取得了较为满意的结果。     

基于生态系统医学的城市生态系统健康诊治研究

城市生态系统健康诊治包括评价、诊断和治疗(调控),是融入生态系统医学和人体健康观点的新方法。建立类似于人体系统的健康评价指标体系,运用熵值赋权法和多专家打分赋权法确定指标权重,通过城市生态系统健康评价模型计算健康隶属度值并进行健康状态分级。连云港研究案例表明:连云港生态系统中的城市循环系统以及城市生殖系统仍然处于病态,应对其进行针对性的治疗;城市防御系统虽然有所好转,但仍然不容乐观;城市消化系统现在问题逐步凸现,应该给予足够的重视并做好防御准备。根据诊断结果并结合统计指标的原始数据与评价标准的对比分析,找到城市生态系统健康问题的症结,给出相应的健康诊治建议。     

生态系统健康研究综述与展望

生态系统健康是新兴的生态系统管理学概念,是环境管理和生态系统管理的目标.在调研文献的基础上阐述了生态系统健康概念的产生、发展及内涵,分析了不同尺度下的评价指标体系,着重回顾和讨论了生态系统健康的评价方法及其存在的问题,以期为生态系统管理提供理论基础.     

基于生态系统服务功能的穿越水源保护区公路设置开口的生态系统影响评估

生态系统服务功能在研究道路交通工程的生态影响方面有着重要的作用,尤其是对于存在交通穿越的饮用水水源保护区的生态系统影响评价。以深圳东部某高速公路设置开口为研究对象,计算公路开口带来的生态系统服务功能(包括调节气候、固碳释氧、土壤保持、涵养水源、净化环境、减弱噪声、农业生产直接经济价值、物种保育8个方面)损失。在此基础上,结合环境污染损失、经济社会效益和工程建设费用进行了损益综合分析,以全面评估饮用水水源保护区公路开口的生态系统影响。结果表明,该穿越水水源保护区的高速公路开口设置方案对于生态系统的影响很大,效益损失比为17.51%,方案的生态环境可行性不足,应予以修改完善。     

我国环境生态系统演变趋势

本文在对气候变化与环境生态系统现状进行了广泛调查的基础上，结合国内学者的研究，对近五年我国环境生态系统的演变趋势作了系统的回顾，并提出了保护我国生态系统的对策。     

水生生态系统在污水处理中的应用

利用水生生态系统治理水体污染是污水处理领域的研究热点之一.综述了水生生态系统在处理污水中的应用现状,分析了影响处理效果的主要因素,并探讨了水生生态系统处理废水的运行机理,展望了水生生态系统的发展前景.     

水生生态系统在污水处理中的应用

利用水生生态系统治理水体污染是污水处理领域的研究热点之一.综述了水生生态系统在处理污水中的应用现状,分析了影响处理效果的主要因素,并探讨了水生生态系统处理废水的运行机理,展望了水生生态系统的发展前景.     

阿尔卑斯山等高山生态系统面临威胁

生物学家最近研究表明 ,世界各地高山生态系统受气温升高的影响。高山生态系统那些原来适应寒冷气候和贫瘠土壤的物种正面临气温升高和大量入侵物种 (猎食者和竞争者 )。阿尔卑斯山生态系统更易受到气温升高的影响。体形微小的高原兔的数量将会直线下降 ;蝴蝶和鸟类等移动物种从 1 9世纪 6 0年代起 ,每隔 2 0年向两极地区平均移动 6 .1 km;苔原地带正在减少。过去 4 0年 ,澳大利亚境内高山上雪覆盖的面积已减少 30 % ,导致了野生猫和狐狸等物种的入侵。据新西兰一篇关于北极、南极和阿尔卑斯山的调查文章预测 ,下个世纪 ,气温将升高 3℃ ,按…     

水生生态系统中分子生物标记物的研究进展

生物标记物可用来评价水生生态系统中污染物 (金属、有机异生物质、有机金属化合物等 )的暴露和效应。金属硫蛋白、乙酰胆碱酯酶、细胞色素 P4 5 0、性别异常、应激蛋白等都是当前国内外的研究热点。文章对几种重要生物标记物的适用范围、测定方法及应用前景加以综述     

强化土壤生态系统净化机能的研究进展

本文综术了充分利用和强化土壤生态系统净化机能的研究进展，提出了以强化土壤生态系统的反硝化作用为根本措施，以及根据土壤的环境容量严格控制污水污泥和化肥的用量等对策措施，以防治对地表水和地下水的污染。     

Sources and fate of PCDD and PCDF

PCDD and PCDF were found in urban air particulates from St. Louis and Washington, D.C., and in sediments from the Great Lakes and Siskiwit Lake, Isle Royale. The similarity between the PCDD and PCDF found in air particulates and sediment samples and the presence of PCDD and PCDF in sediment from Siskiwit Lake (a location which can receive only atmospheric inputs) suggest that these compounds are emitted to the atmosphere from combustion sources. The historical input of PCDD and PCDF to dated sediment cores shows a strong increase since 1940, and this suggests that the incineration of chlorinated organic compounds is an important source of PCDD and PCDF to the environment.     

Meta-analysis of time-series studies of air pollution and mortality: effects of gases and particles and the influence of cause of death,age, and season

A comprehensive, systematic synthesis was conducted of daily time-series studies of air pollution and mortality from around the world. Estimates of effect sizes were extracted from 109 studies, from single- and multipollutant models, and by cause of death, age, and season. Random effects pooled estimates of excess all-cause mortality (single-pollutant models) associated with a change in pollutant concentration equal to the mean value among a representative group of cities were 2.0% (95% CI 1.5-2.4%) per 31.3 microg/m3 particulate matter (PM) of median diameter < or = 10 microm (PM10); 1.7% (1.2-2.2%) per 1.1 ppm CO; 2.8% (2.1-3.5%) per 24.0 ppb NO2; 1.6% (1.1-2.0%) per 31.2 ppb O3; and 0.9% (0.7-1.2%) per 9.4 ppb SO2 (daily maximum concentration for O3, daily average for others). Effect sizes were generally reduced in multipollutant models, but remained significantly different from zero for PM10 and SO2. Larger effect sizes were observed for respiratory mortality for all pollutants except O3. Heterogeneity among studies was partially accounted for by differences in variability of pollutant concentrations, and results were robust to alternative approaches to selecting estimates from the pool of available candidates. This synthesis leaves little doubt that acute air pollution exposure is a significant contributor to mortality.     

Meta-Analysis of Time-Series Studies of Air Pollution and Mortality: Effects of Gases and Particles and the Influence of Cause of Death,Age, and Season

Abstract

A comprehensive, systematic synthesis was conducted of daily time-series studies of air pollution and mortality from around the world. Estimates of effect sizes were extracted from 109 studies, from single- and multipollutant models, and by cause of death, age, and season. Random effects pooled estimates of excess all-cause mortality (single-pollutant models) associated with a change in pollutant concentration equal to the mean value among a representative group of cities were 2.0% (95% CI 1.5-2.4%) per 31.3 μg/m³ particulate matter (PM) of median diameter <10 μm (PM₁₀); 1.7% (1.2-2.2%) per 1.1 ppm CO; 2.8% (2.1-3.5%) per 24.0 ppb NO₂; 1.6% (1.1-2.0%) per 31.2 ppb O₃; and 0.9% (0.7-1.2%) per 9.4 ppb SO₂ (daily maximum concentration for O₃, daily average for others). Effect sizes were generally reduced in multipollutant models, but remained significantly different from zero for PM₁₀ and SO₂. Larger effect sizes were observed for respiratory mortality for all pollutants except O₃. Heterogeneity among studies was partially accounted for by differences in variability of pollutant concentrations, and results were robust to alternative approaches to selecting estimates from the pool of available candidates. This synthesis leaves little doubt that acute air pollution exposure is a significant contributor to mortality.     

Field and laboratory studies of the fate and enantiomeric enrichment of venlafaxine and O-desmethylvenlafaxine under aerobic and anaerobic conditions

The stereoselectivity of R,S-venlafaxine and its metabolites R,S-O-desmethylvenlafaxine, N-desmethylvenlafaxine, O,N-didesmethylvenlafaxine, N,N-didesmethylvenlafaxine and tridesmethylvenlafaxine was studied in three processes: (i) anaerobic and aerobic laboratory scale tests; (ii) six wastewater treatment plants (WWTPs) operating under different conditions; and (iii) a variety of wastewater treatments including conventional activated sludge, natural attenuation along a receiving river stream and storage in operational and seasonal reservoirs. In the laboratory and field studies, the degradation of the venlafaxine yielded O-desmethylvenalfaxine as the dominant metabolite under aerobic and anaerobic conditions. Venlafaxine was almost exclusively converted to O-desmethylvenlafaxine under anaerobic conditions, but only a fraction of the drug was transformed to O-desmethylvenlafaxine under aerobic conditions. Degradation of venlafaxine involved only small stereoisomeric selectivity. In contrast, the degradation of O-desmethylvenlafaxine yielded remarkable S to R enrichment under aerobic conditions but none under anaerobic conditions. Determination of venlafaxine and its metabolites in the WWTPs agreed well with the stereoselectivity observed in the laboratory studies. Our results suggest that the levels of the drug and its metabolites and the stereoisomeric enrichment of the metabolite and its parent drug can be used for source tracking and for discrimination between domestic and nondomestic wastewater pollution. This was indeed demonstrated in the investigations carried out at the Jerusalem WWTP.     

Sorption and desorption of Cu and Cd by macroalgae and microalgae

The sorption and desorption of Cu and Cd by two species of brown macroalgae and five species of microalgae were studied. The two brown macroalgae, Laminaria japonica and Sargassum kjellmanianum, were found to have high capacities at pHs between 4.0 and 5.0 while for microalgae, optimum pH lay at 6.7. The presence of other cations in solution was found to reduce the sorption of the target cation, suggesting a competition for sorption sites on organisms. Sorption isotherms obeyed the Freundlich equation, suggesting involvement of a multiplicity of mechanisms and sorption sites. For the microalgae tested, Spirulina platensis had the highest capacity for Cd, followed by Nannochloropsis oculata, Phaeodactylum tricornutum, Platymonas cordifolia and Chaetoceros minutissimus. The reversibility of metal sorption by macroalgae was examined and the results show that both HCl and EDTA solutions were very effective in desorbing sorbed metal ions from macroalgae, with up to 99.5% of metals being recovered. The regenerated biomass showed undiminished sorption performance for the two metals studied, suggesting the potential of such material for use in water and wastewater treatment.     

骆马湖富营养化和生态状况调查与评价

为了了解骆马湖水质状况，在2005年对骆马湖富营养化状态和生态特性进行了调查，并结合“十五”期间的监测资料进行了分析。2005年骆马湖水体中总氮和总磷的平均值超《地表水环境质量标准》（GB3838-2002）中Ⅲ类，超标情况分别为0．78倍和0．54倍，达到湖库特定项目Ⅳ类水标准，骆马湖处于轻度富营养化状态。对骆马湖生态特征分析表明，由于该湖泊的形态以及“藻型浊水状态”和“泥沙型浊水状态”交替出现，遏制了湖水从高营养盐含量向全面富营养化状态演变，保障了底栖动物的良好生长环境，从而形成了骆马湖独特的环境生态平衡。     

Sources and distribution of polychlorinated-dibenzo-p-dioxins and -dibenzofurans in soil and sediment from the Yellow Sea region of China and Korea

Polychlorinated-dibenzo-p-dioxins and -dibenzofurans (PCDD/Fs) were measured in soils and sediments from the Yellow Sea region. Korean soils and sediments mostly contained detectable PCDD/Fs and showed a widespread distribution among locations. Soil and sedimentary PCDD/Fs from China were comparable to or less than those in Korea. The patterns of relative concentrations of individual congeners in soils were different between the two countries, but similar in sediments. Sources of PCDD/Fs in China and Korea were found to be independent of each other and their distributions reflected matrix-dependent accumulation. Spatial distribution indicated some point sources in Korea while Chinese sources were more widespread and diffuse. PCDD/Fs measured in the coastal areas of the Yellow Sea were comparable to or less than those previously reported in for eastern Asia. However, ∑TEQs in soils and sediments were near to or, in some cases exceeded environmental quality guidelines.     

Aerobic and anaerobic degradation of profluralin and trifluralin

Abstract

The degradation of profluralin [N‐(cyclopropylmethyl)‐α,α,α‐trifluoro‐2,6‐dinitro‐N‐propyl‐]p‐toluidine] and trifluralin (α,α,α‐trifluoro‐2,6‐dinitro‐N,N‐dipropyl‐p‐toluidine) was studied under aerobic and anaerobic soil conditions. Three soils (Goldsboro loamy sand, Cecil loamy sand, Drummer clay loam) were each treated with 1 ppmw herbicide; anaerobic conditions were maintained by flooding. Soil samples were extracted monthly and subjected to TLC analysis. No degradation was detected in sterile controls. Aerobic degradation of both herbicides was greatest in the Cecil loamy sand soil over the entire incubation period. Degradation of profluralin in Cecil soil under aerobic conditions was 86 percent after 4 months with three products detected; 83 percent of the trifluralin was degraded with two products detected. Anaerobic degradation accounted for 72 percent of the profluralin and 78 percent of the trifluralin after 4 months. Degradation of both herbicides increased with incubation time for the first 3 months and decreased slightly thereafter. Generally there was more extensive degradation (percent and in number of products formed) of profluralin than trifluralin under the conditions tested. More degradation products were detected for both herbicides under aerobic conditions than under anaerobic conditions.     

Copper-catalyzed chlorination and condensation of acetylene and dichloroacetylene

The chlorination and condensation of acetylene at low temperatures is demonstrated using copper chlorides as chlorinated agents coated to model borosilicate surfaces. Experiments with and without both a chlorine source and borosilicate surfaces indicate the absence of gas-phase and gas-surface reactions. Chlorination and condensation occur only in the presence of the copper catalyst. C₂ through C₈ organic products were observed in the effluent; PCDD/F were only observed from extraction of the borosilicate surfaces. A global reaction model is proposed that is consistent with the observed product distributions. Similar experiments with dichloroacetylene indicate greater reactivity in the absence of the copper catalyst. Reaction is observed in the gas-phase and in the presence of borosilicate surfaces at low temperatures. The formation of hexachlorobenzene is only observed in the presence of a copper catalyst. PCDD/F were only observed from extraction of the borosilicate surfaces. A global reaction model is proposed for the formation of hexachlorobenzene from dichloroacetylene.