共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
为促进我国锌锰废电池集中资源化处理,开发了一种高温回收废电池中锰的新工艺.废电池分选后,破碎和筛分,其中二氧化锰与还原剂碳制成球团,烧结后在感应炉中还原锰,制成锰钢.实验表明,球团中不加表面活性剂的二氧化锰还原率为34%,球团中加入硫化物表面活性剂促进二氧化锰在钢中的还原率,达到80%,钢液中锰含量可达3.97%,本实验条件下,还原最佳时间为20 min.在铸钢生产中可以直接应用该工艺处理废电池. 相似文献
3.
4.
5.
6.
7.
固定化微生物技术及其在重金属废水处理中的应用 总被引:15,自引:0,他引:15
固定化微生物技术是一种有效的废水生物处理技术。较为全面地介绍了其定义、分类及载体选择。全面系统地介绍了固定化微生物(主要是菌类和藻类)技术近年来在重金属废水处理中的应用现状,分析认为,固定化微生物技术对于处理含各种重金属离子的废水均有很广阔的应用前景,并对今后的研究方向做了探讨。 相似文献
8.
T Khafif C M Coste J Bastide 《Journal of environmental science and health. Part. B》1982,17(2):153-170
Kinetics of degradation of chlorbufam is determined in aqueous solution, in aqueous solution with humic acids, argilo-humic complexes, soil and sterile soil. The adsorption is also evaluated in this different fractions. The adsorption process has a protecting effect and the chlorbufam is not chemically degraded when it is adsorbed on organic matter. The biodisponibility is also decreased by adsorption. 相似文献
9.
多相催化-臭氧氧化法处理模拟有机磷农药废水 总被引:12,自引:0,他引:12
实验通过臭氧氧化法来降解模拟废水中的有机磷农药,将其转化为无害物质,并试验研究了在废水中加入2种自制的催化剂对降解结果的影响。采用气相色谱法测定水中有机磷农药的量。结果表明,只用臭氧处理的情况下1周后有机磷的去除率为78.03%;在催化剂A存在下,去除率可达93.85%;在催化剂B存在下,去除率可达为88.35%。结果表明,臭氧氧化法对此类污水:具有较好的降解作用,尤其在有催化剂存在的情况下处理效果更好,在室温和中性介质中均属于一级反应。 相似文献
10.
Charles H. Worsham Robert B. Long John P. Longwell 《Journal of the Air & Waste Management Association (1995)》2013,63(3):135-140
Present methods for the determination of carbon monoxide are discussed including indicator tubes, the iodine pentoxide reaction and measurement by gas chromatography. In the gas chromatographic method an air sample is separated on a gas-solid chromatogra-phic column and the separated CO is converted to methane by hydrogenation at elevated temperature. The separated CO, in the form of methane, is passed into a hydrogen flame detector and measured. The conversion from CO to methane allows the use of a sensitive ionization detector in place of the thermal conductivity cell which is insufficiently sensitive for the measurement of trace amounts of CO. The optimum operating conditions are discussed. It is possible to determine one ppm CO in air. The iodine pentoxide reaction with CO has been combined with electrometric measurement. The iodine liberated is passed into a Ditte cell and the current generated is measured by an electrometerrecorder combination. This method is continuously direct reading with a permanent record. It is suitable for the continuous routine analysis of one ppm CO. 相似文献
11.
Pattern and sources of naturally produced organohalogens in the marine environment: biogenic formation of organohalogens 总被引:4,自引:0,他引:4
Ballschmiter K 《Chemosphere》2003,52(2):313-324
The pattern of organohalogens found in the marine environment is complex and includes compounds, only assignable to natural (chloromethane) or anthropogenic (hexachlorobenzene, PCBs) sources as well as compounds of a mixed origin (trichloromethane, halogenated methyl phenyl ether).The chemistry of the formation of natural organohalogens is summarized. The focus is put on volatile compounds carrying the halogens Cl, Br, and I, respectively. Though marine natural organohalogens are quite numerous as defined components, they are mostly not produced as major compounds. The most relevant in terms of global annual production is chloromethane (methyl chloride). The global atmospheric mixing ratio requires an annual production of 3.5-5 million tons per year. The chemistry of the group of haloperoxidases is discussed. Incubation experiments reveal that a wide spectrum of unknown compounds is formed in side reactions by haloperoxidases in pathways not yet understood. 相似文献
12.
The physical state of the Baltic Sea in possible future climates is approached by numerical model experiments with a regional coupled ocean-atmosphere model driven by different global simulations. Scenarios and recent climate simulations are compared to estimate changes. The sea surface is clearly warmer by 2.9 degrees C in the ensemble mean. The horizontal pattern of average annual mean warming can largely be explained in terms of ice-cover reduction. The transfer of heat from the atmosphere to the Baltic Sea shows a changed seasonal cycle: a reduced heat loss in fall, increased heat uptake in spring, and reduced heat uptake in summer. The interannual variability of surface temperature is generally increased. This is associated with a smoothed frequency distribution in northern basins. The overall heat budget shows increased solar radiation to the sea surface, which is balanced by changes of the other heat flux components. 相似文献
13.
总量控制规划中允许排放量的平权分配 总被引:4,自引:0,他引:4
对总量控制规划中公平合理分配各污染源允许排放量的意义以及现有平权分配方法中存在的问题进行分析。阐明了允许排放量平权分配的原则,提出了平权分配污染源允许排放量的B值法。剖析了分析平权后剩余环境容量的必要性,并提出了相应的解决方法。 相似文献
14.
以渗滤液回灌为核心的填埋场生化反应器是当今国际固体废物研究的新方向 ,其具有减少渗滤液处理难度和加速填埋场稳定化的作用 ,其中控制填埋场水分是关键。本文通过对填埋场水分运移特征的分析 ,建立了渗滤液回灌条件下 ,生化反应器填埋场水分迁移的饱和 -非饱和三维非稳定数学模型 ,并求其有限单元数值解 ,定量模拟和预报不同回灌条件下填埋场水分的时空分布规律并进行实用研究。针对重庆市长生桥卫生填埋场设计情况和实际条件 ,运移模拟模型分析了水平沟和竖式井回灌条件下填埋场内水分的分布规律 ,证明了协同回灌方式的有效性 相似文献
15.
以一种特种陶瓷--炻器为载体,分别用负载TiO2光催化薄膜和添加抗菌剂的方法进行炻器餐饮具的抗菌研究.结果表明,在紫外光和日光下,表面负载了TiO2膜的炻器灭菌率分别为90%和88%,均高于未负载TiO2膜的炻器,且灭菌率随光强的增加而提高.复合银盐显示了很好的杀菌效果,当釉表层银含量为0.2%时,24 h内对所有细菌的灭菌率为94.6%、总大肠菌群为96.9%.复合锌盐也有一定的灭菌效果,当釉表层锌含量为1.1%时,24 h内对所有细菌的灭菌率为56.8%,总大肠菌群为59.3%.但将TiO2粉末加入炻器表层的釉中,却未显示灭菌作用.对掺杂的炻器表面层成分和掺杂后Ag 、Zn2 的溶出量进行了测定,对灭菌结果和机理也进行了讨论. 相似文献
16.
多相催化-臭氧氧化法处理模拟有机磷农药废水 总被引:1,自引:0,他引:1
实验通过臭氧氧化法来降解模拟废水中的有机磷农药,将其转化为无害物质,并试验研究了在废水中加入2种自制的催化剂对降解结果的影响。采用气相色谱法测定水中有机磷农药的量。结果表明,只用臭氧处理的情况下1周后有机磷的去除率为78.03%;在催化剂A存在下,去除率可达93.85%;在催化剂B存在下,去除率可达为88.35%。结果表明,臭氧氧化法对此类污水具有较好的降解作用,尤其在有催化剂存在的情况下处理效果更好,在室温和中性介质中均属于一级反应。 相似文献
17.
18.
《Atmospheric environment (Oxford, England : 1994)》1999,33(21):3473-3486
The acid deposition model is developed and applied to assess the sulfur deposition pathways in Asia. Simulations for four seasons are conducted: February, April, August, and October. The predicted results of summer and winter are compared to measured concentration of SO2, sulfate, and sulfate wet deposition in Japan. Further comparison of sulfate wet deposition to observations in China is made to assess the general performance of the model. The study shows that wet deposition is more important than dry deposition. It is the predominant factor in each of these four months. It is also found that rainout process, compared to washout process, make a larger contribution to sulfate wet deposition in summer and spring than in the dry months, such as October. The total sulfur wet to dry deposition ratio is 1.6 in February, 1.2 in April, 2.9 in August, and 1.9 in October. 相似文献
19.
M. T. H. Ragab 《Journal of environmental science and health. Part. B》2013,48(2):155-161
Abstract The developed thin‐layer chromatogram of DCPA (Dacthal) is sprayed with 4‐(p‐nitrobenzyl)pyridine chromogenic reagent followed by ammonium carbonate solution. The chromatogram is then heated in an oven at 130°C for 20 minutes. When cool, the chromatogram is sprayed with tetraethylenepentamine reagent. DCPA spots appear blue against a white background. The sensitivity of this test is about 1 μg. The procedure is useful to detect DCPA in water and in soil. 相似文献
20.
新型管式微孔曝气器性能研究 总被引:1,自引:0,他引:1
以废旧橡胶为主要原料研制的微孔曝气器,传质效率高,曝气充氧性能优良,搅拌能力强;沿管长方向具有很好的均匀布气性,输气曝气合二为一;制造工艺简单,价格低廉,安装方便;拓展了废旧橡胶的综合利用途径,以废治废,减少了废旧橡胶对环境的污染。 相似文献