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硫化氢废气治理研究进展 总被引:9,自引:0,他引:9
综合评述了硫化氢废气的各类净化方法及最新的研究进展。硫化氢废气的净化有吸收法、吸附法、氧化法、分解法和生物法。本文对超级克劳斯法和分解法研究进展进行了重点阐述。 相似文献
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硫化氢废气治理研究进展 总被引:22,自引:0,他引:22
综合评述了硫化氢废气的各类净化方法及最新的研究进展。硫化氢废气的净化有吸收法、吸附法、氧化法、分解法和生物法。本文对超级克劳斯法和分解法研究进行了重点阐述。 相似文献
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近年来,在一大批工厂中均选用生物过滤器减少大气污染物的排放,尤其用在净化含气味大的有机成份的废气上。一般来说,这种方法适宜在农业生产(养殖业)、净化装置以及植物和动物原料的加工业范围内使用。使用生物过滤器无论是净化工业废气还是其它类型废气均可以得到既有效又经济的结果。本文建立在对净化废气的体积流量达200,000立方米/小时的60个生物过滤装置从规划、安装到运转的大量实际经验的基础上。 1.引言 继以有效吸附原理为基础的土壤和肥料 相似文献
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生物法净化再生胶生产废气工业试验研究 总被引:5,自引:0,他引:5
在再生橡胶厂进行橡胶再生低浓度有机废气的生物法净化工业试验研究,对于甲苯浓度为300~1400mg/m^3的再生胶脱硫废气,在常温常压下以气体流量10~20m^3/h、循环液体喷淋量300~500L/h运行生物法废气净化装置获得了良好物净化效果。该装置连续运行100d的结果显示,其对再生胶废气中甲苯的净化效率可较长时间的保持在90%左右,废气经处理后可以实现达标排放,废气处理成本约为工厂再生胶产值的0.12%~0.14%,具有明显的技术先进性和经济合理性。 相似文献
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生物滴滤器净化低浓度甲苯废气的非稳态工况研究 总被引:2,自引:0,他引:2
生物法处理大气污染物时,经常会遇到条件波动或污染物间歇排放等非稳态工况。在不同非稳态条件下,考察了甲苯废气间歇排放对生物滴滤器净化性能的影响。实验方案分3种情况:无甲苯废气排放、无循环液供应或同时没有甲苯废气和循环液的供应。间歇排放时间从2~47 d不等。结果表明,不管何种形式的停运或故障,甲苯净化能力4 d以内基本不下降;停运时间超过5 d,则甲苯去除能力严重下降,仅为原来的1/3~1/2;停运时间在10 d以内,24 h内即可恢复,47 d的长期停运,3 d内也可恢复净化能力。 相似文献
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Jaana Koistinen Sirpa Herve Raija Paukku Mirja Lahtiperä Jaakko Paasivirta 《Chemosphere》1997,34(12):2553-2569
Concentrations of different chlorinated compounds were measured in mussels incubated in two polluted watercourses, a river (the River Kymijoki) and a lake (Lake Vanaja) for four weeks in summer 1995. The sum concentrations of polychlorinated phenols (PCP) and biphenyls (PCB) were both about 1 μg/g lipid weight (lw) in Lake Vanaja mussels, while in the River Kymijoki mussels PCPs were non-detectable and PCBs were measured 120 ng/g lIw. The concentrations of toxic polychlorinated dibenzo-p-dioxin (PCDD) and dibenzofuran (PCDF) congeners ranged between <17 and 370 pg/g Iw in Lake Vanaja mussels and between <38 and 11,000 pg/g lw in the River Kymijoki mussels. Polychlorinated diphenyl ethers (PCDE) were detected in the mussels incubated in the River Kymijoki (0.4–1.1 ng/g Iw), but not in those incubated in Lake Vanaja. Polychlorinated phenoxyanisoles (PCPA) were measured 33 ng/g lw and polychlorinated phenoxyphenols (PCPP) 300 ng/g lw in the mussels incubated in the River Kymijoki. PCPAs were also detected in reference samples, which were sediment and pike from the River Kymijoki and Baltic salmon, seal and white-tailed sea eagle. 相似文献
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G T Brooks 《Journal of environmental science and health. Part. B》2013,48(5):619-621
The Pesticide Manual ‐ A World Compendium, 8th Edition, C.R. Worthing, Editor and S.B. Walker, Assistant Editor, British Crop Protection Council, BCPC Publications Sales, Bear Farm, Binfield, Bracknell, Berkshire RG12 5QE, England. 1987, 1100 pp., UK £50; Overseas £56. ISBN 0–948404–01–9. 相似文献
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Wilkins K Nielsen KF Din SU 《Environmental science and pollution research international》2003,10(3):162-166
We reported previously that trichodiene, a volatile trichothecene derivative, was produced by a Stachybotrys isolate, also known to produce highly cytotoxic, non-volatile, macrocyclic trichothecenes (satrotoxins). We investigated the relationship between the production of trichodiene and various non-volatile trichothecenes for several molds. Volatile metabolites were concentrated by adsorption on Tenax TA and analyzed by GC/MS, while non-volatile metabolites were separated by HPLC, derivatized and analyzed by GC/MS. Stachybotrys chartarum isolates producing macrocyclic trichothecenes secreted significantly larger amounts of trichodiene and other sesquiterpenes than isolates which only produced simple trichothecenes. The amounts of secreted trichodiene were relatively small in all cases. With the exception of Memnoniella, which excreted small amounts of sesquiterpenes, the other isolates produced varying amounts of sesquiterpenes, including trichodiene, as well as simple tricothecenes, no detectable trichodiene, but large amounts of griseofulvin derivatives. In Stachybotrys there is apparently a correlation between trichodiene and macrocyclic trichothecene production. In the remaining isolates, there was no simple relationship between trichodiene and non-volatile trichothecene synthesis. Trichodiene is produced in larger amounts by Stachybotrys isolates, which also produce satratoxins, but it will be difficult to utilize this metabolite to detect toxic isolates in buildings due to the relatively small amounts excreted. 相似文献
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Ralph A. Chapman Carol Harris 《Journal of environmental science and health. Part. B》2013,48(4-5):397-407
Abstract The active ingredients in commercial formulations of malathion, oxamyl, carbaryl, diazinon, and chlorpyrifos diluted to “spray tank”; concentrations with buffered distilled or natural water of pH 4–9 were stable for at least 24 hr. Formulations of trichlorfon were not stable at pH 7 or above but disappearance rates were slower than for the pure chemical in homogeneous solution. Cupric ion was observed to be an effective catalyst for the hydrolysis of a variety of pure organophosphorus insecticides but did not catalyze hydrolysis of the active ingredients of the formulations examined. Increasing the dilution of the formulation increased the susceptibility of malathion, oxamyl, and carbaryl to hydrolysis. 相似文献
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Organochlorine compounds in a three-step terrestrial food chain 总被引:1,自引:0,他引:1
The concentrations of 15 organochlorine chemicals (PCBs and pesticides) were studied in a Central European oak wood food chain system: Great tit (Parus major), caterpillars (Tortrix viridana, Operophtera brumata, Erannis defoliaria), and oak-leaves (Quercus robur). Juvenile tits receive organochlorines from the mother via egg transfer and, eventually to a greater extent, from the caterpillar food source during nestling period. The concentrations of PCB 153 (2,2′,4,4′,5,5′-hexachlorobiphenyl, the most abundant in this study) was found in leaf material at ca. 1 ng/g, in caterpillars 10 ng/g, and in bird eggs 170 ng/g on an average and on a dry mass basis. 相似文献
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P.R. Fresquez D.H. Kraig M.A. Mullen L. Naranjo Jr. 《Journal of environmental science and health. Part. B》2013,48(5):885-899
Abstract The purpose of this study was to determine radionuclide and trace element concentrations in bottom‐feeding fish (catfish, carp, and suckers) collected from the confluences of some of the major canyons that cross Los Alamos National Laboratory (LANL) lands with the Rio Grande (RG) and the potential radiological doses from the ingestion of these fish. Samples of muscle and bone (and viscera in some cases) were analyzed for 3H, 90Sr, 137Cs, totU, 238Pu, 239,240Pu, and 241Am and Ag, As, Ba, Be, Cr, Cd, Cu, Hg, Ni, Pb, Sb, Se, and Tl. Most radionuclides, with the exception of 90Sr, in the muscle plus bone portions of fish collected from LANL canyons/RG were not significantly (p<0.05) higher from fish collected upstream (San Ildefonso/background) of LANL. Strontium‐90 in fish muscle plus bone tissue significantly (p<0.05) increases in concentration starting from Los Alamos Canyon, the most upstream confluence (fish contained 3.4E‐02 pCi g‐1 [126E‐02 Bq kg‐1]), to Frijoles Canyon, the most downstream confluence (fish contained 14E‐02 pCi g‐1 [518E‐02 Bq kg‐1]). The differences in 90Sr concentrations in fish collected downstream and upstream (background) of LANL, however, were very small. Based on the average concentrations (±2SD) of radionuclides in fish tissue from the four LANL confluences, the committed effective dose equivalent from the ingestion of 46 lb (21 kg) (maximum ingestion rate per person per year) of fish muscle plus bone, after the subtraction of background, was 0.1 ± 0.1 mrem y‐1 (1.0 ± 1.0 μSv y‐1), and was far below the International Commission on Radiological Protection (all pathway) permissible dose limit of 100 mrem y‐1 (1000 μSv y‐1). Of the trace elements that were found above the limits of detection (Ba, Cu, and Hg) in fish muscle collected from the confluences of canyons that cross LANL and the RG, none were in significantly higher (p<0.05) concentrations than in muscle of fish collected from background locations. 相似文献
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P.R. Fresquez J.D. Huchton M.A. Mullen L. Naranjo Jr. 《Journal of environmental science and health. Part. B》2013,48(5):611-622
Abstract One of the dominant tree species growing within and around the eastern portion of Los Alamos National Laboratory (LANL), Los Alamos, NM, lands is the pinon pine (Pinus edulis). Pinon pine is used for firewood, fence posts, and building materials and is a source of nuts for food—the seeds are consumed by a wide variety of animals and are also gathered by people in the area and eaten raw or roasted. This study investigated the (1) concentration of 3H, 137Cs, 90Sr, totU, 238Pu, 239, 240Pu, and241 Am in soils (0‐ to 12‐in. [31 cm] depth underneath the tree), pinon pine shoots (PPS), and pinon pine nuts (PPN) collected from LANL lands and regional background (BG) locations, (2) committed effective dose equivalent (CEDE) from the ingestion of nuts, and (3) soil to PPS to PPN concentration ratios (CRs). Most radionuclides, with the exception of 3H in soils, were not significantly higher (p < 0.10) in soils, PPS, and PPN collected from LANL as compared to BG locations, and concentrations of most radionuclides in PPN from LANL have decreased over time. The maximum net CEDE (the CEDE plus two sigma minus BG) at the most conservative ingestion rate (10 lb [4.5 kg]) was 0.0018 mrem (0.018 μSv); this is far below the International Commission on Radiological Protection (all pathway) permissible dose limit of 100 mrem (1000 μSv). Soil‐to‐nut CRs for most radionuclides were within the range of default values in the literature for common fruits and vegetables. 相似文献
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Jennifer C. Anhalt Thomas B. Moorman William C. Koskinen 《Journal of environmental science and health. Part. B》2013,48(3):207-213
Degradation and sorption/desorption are important processes affecting the leaching of pesticides through soil. This research characterized the degradation and sorption of imidacloprid (1-[(6-chloro-3-pyridinyl)-methyl]-N-nitro-2-imidazolidinimine) in Drummer (silty clay loam) and Exeter (sandy loam) surface soils and their corresponding subsurface soils using sequential extraction methods over 400 days. By the end of the incubation, approximately 55% of imidacloprid applied at a rate of 1.0 mg kg?1 degraded in the Exeter sandy loam surface and subsurface soils, compared to 40% of applied imidacloprid within 300 days in Drummer surface and subsurface soils. At the 0.1 mg kg?1 application rate, dissipation was slower for all four soils. Water-extractable imidacloprid in Exeter surface soil decreased from 98% of applied at day 1 to > 70% of the imidacloprid remaining after 400 d, as compared to 55% in the Drummer surface soil at day 1 and 12% at day 400. These data suggest that imidacloprid was bioavailable to degrading soil microorganisms and sorption/desorption was not the limiting factor for biodegradation. In subsurface soils > 40% of 14C-benzoic acid was mineralized over 21 days, demonstrating an active microbial community. In contrast, cumulative 14CO2 was less than 1.5% of applied 14C-imidacloprid in all soils over 400 d. Qualitative differences in the microbial communities appear to limit the degradation of imidacloprid in the subsurface soils. 相似文献
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A.H. El‐Sebae S.A. Soliman N.S. Ahmed A. Curley 《Journal of environmental science and health. Part. B》2013,48(4):465-474
Abstract Five organophosphorous insecticides: Leptophos, EPN, Cyano‐fenphos, trichloronate and salithion proved to cause irreversible ataxia not only to chicken but also to mice and sheep. TOCP was included as a reference. Cyanofenphos blocked the catecholamine B‐receptor binding activity with 3H‐norepinephrine at a level similar to that of the specific inhibitor propranolol in the mouse heart preparation. In the lamb heart preparation, the B‐receptor was more sensitive to Leptophos, salithion and TOCP than to propranolol. The six compounds and their oxons were screened for their in‐vitro inhibition to monamine oxidase (MAO), acetyl cholinesterase (AChE) and neurotoxic esterase (NTE) in the brain of either mouse, lamb or chicken. It is believed that their AChE inhibition stands for their acute toxicity, while NTE inhibition is responsible for their paralytic ataxia. 相似文献
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