不同土地利用情景下四平市生态系统碳储量时空演变

基于1990～2020年四平市土地利用类型数据,运用GeoSOS-FLUS模型,设定自然发展、耕地保护和生态优先三种情景,模拟不同情景下2030年四平市土地利用空间格局,同时结合InVEST模型定量分析研究区1990～2020年碳储量的时空分异特征,并探讨不同情境下土地利用变化对碳储量的影响,评估未来碳储量的潜力.结果表明:1990～2020年四平市耕地和林地分别减少了951.5 5km²和357.54km²,且以1990～2000年间的降幅最大.草地和建设用地呈增加趋势,分别增加了702.97km²和587.64km².2030年在生态优先情景下,林地呈扩张态势,耕地有少量增加,在耕地保护情景下,耕地数量得到有效保障,而林地和草地有不同程度缩减.建设用地在三种情景下都呈现扩张的趋势,在自然发展情景下增长幅度最大.1990～2020年,四平市陆地生态系统的总碳储量及平均碳密度呈连续减少的势态,以1990～2000年的降幅最大,主要原因是该时段内土地利用变化以耕地的减少和建设用地的增加为主.四平市碳储...     

基于FLUS模型的湖北省生态空间多情景模拟预测

改革开放以来,中国经济在飞速发展的同时,生态环境问题日益严峻。为保障国家和地区的生态安全,对未来生态空间进行模拟预测十分必要。在长江大保护和长江经济带绿色发展背景下,以湖北省为研究区,利用FLUS模型基于湖北省2010年、2015年土地利用数据及包含自然和人文因素的15种驱动因子数据,对2035年的湖北省生态空间进行模拟预测。结果表明：利用2010年土地利用现状模拟出的2015年湖北省土地利用变化情况,总体精度达到0.976,Kappa系数达到0.961,模拟精度较高。设置的生产空间优先、生活空间优先、生态空间优先以及综合空间优化4种不同情景,基本满足未来湖北省不同发展导向的需求。从地貌单元角度来看,在不同情景下,湖北省生态空间主要分布于湖北省边陲四大山区,中部江汉平原生态空间零星分布。从数量规模上来看,不同情景下各个用地类型数量规模差异较为明显,生产空间优先情景下耕地面积增加1216 km²,生活空间优先情景下城镇用地规模增加5959 km²,生态空间优先情景下生态空间用地增长722 km²,综合空间优化情景下生态空间用地规模变化更趋于平缓。从生态空间变化分布来看,四大山区的生态空间变化不大,但中部江汉平原生态空间变化较为明显,其中从行政区划上来看,变化范围主要分布于武汉城市圈、襄阳市、宜昌市中西部地区及随州市中部地区。总而言之,FLUS模型对于湖北省生态空间模拟的适用性较好,多情景模拟结果可为湖北省未来国土空间规划及未来生态空间管控提供多角度、多方向的政策决策参考。     

生态退耕前后张家口市耕地变化及影响因素识别

耕地变化与相关土地政策密切相关,为揭示生态退耕政策实施前后,耕地变化特征及其影响因素的差异性,该研究以北方农牧交错区——张家口市为例,分析了生态退耕前后（1989—2000年和2000—2015年）耕地变化特征。在此基础上,应用多项Logistic回归模型研究了耕地变化的影响因素。研究结果表明：1）耕地面积由1989年的1 090 031.02 hm²减少到2015年的924 647.32 hm²,持续减少了15.17%,特别是生态退耕后,耕地减少速度加快;但耕地仍然集中分布在张北县、康保县、沽源县。2）生态退耕前后,耕地转出与转入并存。与生态退耕前相比,生态退耕后耕地转换变化总面积增加121 695.72 hm²,其中转出面积增加占88.72%;耕地主要转换去向由草地（17 063.59 hm²）、建设用地（9 007.00 hm²）、林地（8 932.72 hm²）和园地（5 981.19 hm²）,变为林地（51 902.41 hm²）、园地（40 311.23 hm²）、草地（32 292.66 hm²）和建设用地（23 152.11 hm²）。3）生态退耕前后,耕地转换变化的影响因素不同。退耕前,海拔和坡度分别是耕地转为园地、林地和转为草地、建设用地的主导因素;退耕后,耕地转化的影响因素多样化,海拔仍是耕地向园地转换的主导影响因素,人均GDP变化和到最近道路距离分别成为耕地转为林地、草地和转为建设用地的首要因素。基本农田保护区和自然保护区对耕地转为园地、林地和草地也起着重要作用。研究结果能为张家口市耕地保护、生态环境保护及经济社会协调发展提供科学依据。     

以环境质量改善为目标的贵安新区生态安全格局构建虚拟

以贵安新区为例,将水环境安全格局与大气环境安全格局纳入城市综合生态安全格局的评价框架;将GIS空间分析技术、ArcSWAT模型、WRF-Chem空气质量模型等进行耦合,对水环境、大气环境、石漠化、生物多样性、自然人文环境以及基本农田等在内的6项生态安全格局因子进行分析;将贵安新区生态安全格局划分为底线、满意和理想3个不同等级,并在此基础上对贵安新区城市扩展方案进行模拟.结果表明,贵安新区底线级生态安全格局面积为215.6km²,满意级生态安全格局面积为473.9km²,理想级生态安全格局面积为828.4km²,分别占贵安新区总面积的11.3%,24.9%和43.6%.生态宜居的城市建设用地面积为179.8km²,生态经济均衡发展模式下城市建设用地面积为708.9km²,经济优先发展模式下城市建设用地面积为1288.9km²,分别占贵安新区总面积的9.5%,37.3%和67.8%.综合生态安全格局的划定可作为一种有力的空间管控手段,以实现城市生态环境保护与宜居城镇的和谐发展.     

江苏沿海地区耕地利用转型及其生态系统服务价值变化响应

论文以江苏沿海地区1990、2000和2010年3期土地利用空间数据为基础,在GIS、地学信息图谱理论和Costanza等生态系统服务价值测算方法的支持下合成时间序列表征下的耕地利用转型图谱、耕地利用转型模式图谱和生态系统服务价值图谱,据此揭示江苏沿海地区耕地转型时空变化特征及其生态系统服务价值变化响应规律。结果表明：1）1990-2000年阶段耕地以建设用地、水域和林地占用为主,补充耕地来源除建设用地、水域和林地外,还包括了草地,耕地占用大于补充。空间差异以“耕地→建设用地”、“草地→耕地”最为明显,空间分离度低。2）2000-2010年阶段耕地占用的去向增加了未利用地,草地仍是主要的耕地补充来源。空间上以“耕地→建设用地”和“耕地→水域”图谱变化最为显著,空间分离度变大。3）1990-2010年耕地利用转型模式以后期变化最为显著。4）近20 a间,江苏沿海生态系统服务总价值由170.85×10⁸元提升为182.23×10⁸元,水域是提高生态系统服务价值最主要的贡献类型。耕地利用转型导致耕地的生态系统服务价值降低,“耕地→建设用地”是最主要的生态减值图谱 类型。     

东北典型黑土区讷谟尔河流域土地利用变化对沟蚀影响研究

论文以东北典型黑土区中的黑龙江省讷谟尔河流域作为研究区,以1965年的Corona 和2005年的SPOT5影像做为数据源,获取研究区1965和2005年的侵蚀沟分布数据;以地形图、Landsat/MSS影像和TM影像作为数据源,获取1954、1975、1995和2005年的土地利用数据,据此就研究区沟蚀动态和土地利用变化对沟蚀发展的影响进行分析。结果表明：40 a间侵蚀沟密度>250 m/km²的区域由1965年的0 km²增加到4 077.17 km²,占总侵蚀区面积的37.57%;侵蚀沟密度以北东—南西向为轴线从剧烈增加区逐渐过渡到微度增加区;耕地上沟蚀状况最严重,草地和沼泽地次之,林地侵蚀沟密度较小;耕地和草地之间的互相转换,侵蚀沟密度增加最大,分别为600.60和456.08 m/km²;其次是林地转变为耕地,侵蚀沟密度增加346.91 m/km²;各沟蚀变化区耕地的增加比例在29.21%~46.54%之间,草地减少的比例在27.10%~41.50%之间,沼泽地减少的比例在5.86%~12.50%之间。     

中国南北过渡带生态系统碳储量时空变化及动态模拟

山地是全球变化的敏感地带,对生态安全与发展具有重要作用,山地生态系统服务变化和生态环境承载力是地理学与生态学的研究热点。以中国南北过渡带的主体秦巴山地为研究对象,采用CA-Markov模型与InVEST模型模拟和预测（2000—2040年）不同土地利用情景下秦巴山地生态系统碳储量变化,运用热点分析（Getis-Ord G_i^*）探讨秦巴山地生态系统碳储量的空间分布差异。结果表明：（1）2000—2040年,研究区土地利用/土地覆被变化主要是耕地、林地、草地和建设用地。（2）2000—2020年,碳储量增加1.12×10⁷ t;2020—2040年自然增长情景下,碳储量损失剧烈,减少50.24×10⁷ t;生态保护情景下,碳损失幅度明显变弱,减少29.52×10⁷ t,说明采取生态环境保护政策,能够有效控制碳储量减少。（3）土地利用/土地覆被与生态系统碳储量的变化呈现显著的一致性,土地利用数量变化决定了生态系统碳储量的质量和空间分布格局。（4）随着海拔抬升,碳储量呈现出“先增后减”的趋势;随着坡度升高,碳储量呈现出“W”型变化趋势。（5）热点分析结果显示,2000—2020年间,碳储量热点区和冷点区零散分布在研究区内;2040年自然增长情景下,碳储量冷热点分布范围有逐渐变大的趋势;2040年生态保护情景较2020年,秦巴山地生态系统碳储量的冷热点分布范围整体变化不大。     

基于LUCC的陕西渭北旱塬区景观生态风险评价

基于土地利用/土地覆被变化构建景观生态风险评价模型,评价了渭北旱塬区1980~2018年的生态风险状况.结果表明,随着城镇快速扩张,土地开发利用强度加大,各土地利用类型发生了不同程度的变化,其中,耕地减少量最多,共减少了636.36km²,建设用地增加量最大,共增加了496.17km²;受人口增长和退耕还林、还草政策实施等因素的影响,渭北旱塬区共有3492.40km²土地发生了转化,变化比例为8.80%,耕地、林地、草地和建设用地之间的转化最明显,转化面积为3177.22km²,占转化总面积的90.98%;研究期间,低、中低风险区面积占比由20.23%降至19.01%,中风险区面积占比由41.62%升至43.23%,中高、高风险区面积占比由38.15%降为37.77%,生态风险等级整体表现偏高,呈现出"四周低,中间高"的分布特征,高风险区主要分布在景观较破碎的地区,这些地区容易受到人类活动的干扰.此外,研究区生态风险均值呈现先上升后下降的波动降低趋势,整体生态安全有所改善,但局部地区的生态环境质量减低;研究区5期生态风险值的全局Moran’s I 指数均高于0.55,说明生态风险值在空间上呈显著的正相关性,高-高聚集区主要分布在中高、高风险区,外界活动对该区域自然生态的干扰较大,生态环境受到较为严重的破坏.     

环杭州湾地区城市扩张的遥感动态监测

以环杭州湾地区为研究对象,应用决策树和形状指数相结合的方法从TM影像中分别提取了2003年和2006年的城镇用地信息,并对杭州市、绍兴市和宁波市的城市扩张特点进行了分析和研究。通过精度检验,城镇用地总体Kappa系数都在0.87以上,说明该方法提取城镇信息是行之有效的。2003年环杭州湾地区的城镇用地面积为914.04km²,2006年为1 286.1km²,4年间城镇用地净增了372.06km²,主要城市用地净增了192.6km²;杭州市、绍兴市、宁波市市区面积增加了43.7 km²;而其它县城与开发区增加了145.6 km²;说明小城市在环杭州湾地区城市化进程中处于主导地位;而大城市的作用则相对较小。杭州市、绍兴市城市扩张明显,其中尤以杭州市下沙区和绍兴市袍江工业园区的扩张最显著;宁波市城市扩张最小,特别是余姚城区。扩张方向上,杭州市主要向西北和北面扩张;宁波市在各个方向上的扩张比较平均。     

三峡库区消落带地表覆被时空变化特征研究

地表覆被变化对区域的经济、自然和生态的发展具有重要的影响,地表覆被变化时空变化特征是地表覆被变化的核心研究之一。为探讨三峡库区消落带的地表覆被时空变化特征,该研究基于2010年、2014年、2018年及2020年4期夏季高分遥感影像数据,获取地表覆被数据;利用地表覆被动态度、Flow矩阵、地形位指数及构建地表覆被结构指数等方法多角度分析研究区2010-2020年地表覆被转化情况,科学揭示库区消落带地表覆被时空变化特征。结果表明：(1)数量结构上,研究区地表覆被类型主要为水域、草地和裸地,面积共264.10 km²,占研究区总面积的75.79%;(2)时间变化上,近10年研究区耕地变化速度最小,建设用地的变化速度最大,草地主要呈流入状态;(3)空间变化上,研究区地表覆被结构呈现破碎度下降,聚集度上升趋势,同类型地表覆被分布逐渐集中;(4)地形位梯度上,2010-2020年研究区Ⅱ类地形位梯度为变化拐点,耕地减少面积最大,为9.66 km²,建设用地增加面积最多,为4.52 km²。研究结果可为三峡库区消落带的土地资源合理规...     

Evaluation of phytoextracting cadmium and lead by sunflower, ricinus, alfalfa and mustard in hydroponic culture

Soil contaminated with heavy metals cadmium(Cd)and lead(Pb)is hard to be remediated.Phytoremediation may be a feasible method to remove toxic metals from soil,but there are few suitable plants which can hyperaccumulate metals.In this study,Cd and Pb accumulation by four plants including sunflower(Helianthus annuus L.),mustard(Brassica juncea L.),alfalfa(Medicago sativa L.), ricinus(Ricinus communis L.)in hydroponic cultures was compared.Results showed that these plants could phytocxtract heavy metals, the ability of accumulation differed with species,concentrations and categories of heavy metals.Values of BCF(bioconcentration factor)and TF(translocation factor)indicated that four species had dissimilar abilities of phytoextraction and transportation of heavy metals.Changes on the biomass of plants,pH and Eh at different treatments revealed that these four plants had distinct responses to Cd and Pb in cultures.Measurements should be taken to improve the phytoremediation of sites contaminated with heavy metals,such as pH and Eh regulations,and so forth.     

Oxidation of As(Ⅲ) by potassium permanganate

The oxidation of As(Ⅲ) with potassium permanganate was studied under conditions including pH, initial As(Ⅲ) concentration and dosage of Mn(Ⅶ). The results have shown that potassium permanganate was an effective agent for oxidizing of As(Ⅲ) in a wide pH range. The pH value of tested water was not a significant factor affecting the oxidation of As(Ⅲ) by Mn(Ⅶ). Although theoretical redox analyses suggest that Mn(Ⅶ) should have better performance in oxidization of As(Ⅲ) within lower pH ranges, the experimental results show that the oxidation efficiencies of As(Ⅲ) under basic and acidic conditions were similar, which may be due to the adsorption of As(Ⅲ) on the Mn(OH)2 and MnO2 resulting from the oxidation of As(Ⅲ).     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Chlorobenzenes in waterweeds from the Xijiang River （Guangdong section） of the Pearl River

The Xijiang River is the major source of water for about 4.5 millions of urban population and 28.7 millions of rural population. The water quality is very important for the health of the rural population. The concentration and distribution of chlorobenzenes (CBs) in both water and waterweeds collected from 4 stations in the Xijiang River (Gangdong section) of the Pearl River in April and November were determined. The result showed that nearly every congener of CBs was detected. The total contents of CBs (∑CBs) in the river water ranged from 111.1 to 360.0 ng/L in April and from 151.9 to 481.7 ng/L in November, respectively. The pollution level of CBs in the water in April was higher than that in November. The contents of ∑ CBs in waterweeds ranged from 13.53×102 μg/g to 38.27×102μg/g dry weight (dw). There was no significant difference between April and November in waterweeds. The distribution of CBs in roots, caulis, and leaves of Vallisneria spiralis L. showed different patterns. The leaves mainly contained low-molecular-weight CBs(DCBs), whereas the roots accumulated more PCBs and HCBs. The average lgBCFlip (bioconcentration factor) of CBs ranged from 0.64 to 3.57 in the waterweeds. The spatial distribution character of CBs in the Xijiang River was: Fengkai County ＜ Yunan County ＜Yun'an County ＜ Gaoyao County according to the ∑CBs, and the pollution deteriorated from the upstream to the downstream of the Xijiang River. Further analysis demonstrated that the discharge of waste containing CBs may be the main source of CBs pollution in the Xijiang River.     

Degradation of 2,4-dichlorophenol with a novel TiO2/Ti-Fe-graphite felt photoelectrocatalytic oxidation process

Degradation of 2,4-dichlorophenol(2,4-DCP)was studied in a novel three-electrode photoelectrocatalytic(PEC)integrative oxidation process,and the factors influencing the degradation rate,such as applied current,flow speed of O_2,pH,adscititious voltage and initial 2,4-DCP concentration were investigated and optimized.H_2O_2 was produced nearby cathode and Fe~(2 )continuously generated from Fe anode in solution when current and O_2 were applied,so,main reactions,H_2O_2-assisted TiO_2 PEC oxidation and E-Fenton reaction,occurred during degradation of 2,4-DCP in this integrative system.The degradation ratio of 2,4-DCP was 93% in this integrative oxidation process,while it was only 31% in E-Fenton process and 46% in H_2O_2-assisted TiO_2 PEC process.So,it revealed that the degradation of 2,4-DCP was improved greatly by photoelectrical cooperation effect.By the investigation of pH,it showed that this integrative process could work well in a wide pH range from pH 3 to pH 9.     

Effect of copper on the degradation of pesticides cypermethrin and cyhalothrin

The influence of coexisting copper (Cu) ion on the degradation of pesticides pyrethroid cypermethrin and cyhalothrin in soil and photodegradation in water system were studied.Serial concentrations of the pesticides with the addition of copper ion were spiked in the soil and incubated for a regular period of time,the analysis of the extracts from the soil was carried out using gas chromatography (GC).The photodegradation of pyrethroids in water system was conducted under UV irradiation.The effect of Cu~(2 ) on the pesticides degradation was measured with half life (t_(0.5)) of degradation.It was found that a negative correlation between the degradation of the pyrethroid pesticides in soil and Cu addition was observed.But Cu~(2 ) could accelerate photodegradation of the pyrethroids in water.The t_(0.5) for cyhalothrin extended from 6.7 to 6.8 d while for cypermethrin extended from 8.1 to 10.9 d with the presence of copper ion in soil.As for photodegradation,t_(0.5) for cyhalothrin reduced from 173.3 to 115.5 rain and for cypermethrin from 115.5 to 99.0 min.The results suggested that copper influenced the degradation of the pesticides in soil by affecting the activity of microorganisms.However, it had catalyst tendency for photodegradation in water system.The difference for the degradation efficiency of pyrethroid isomers in soil was also observed.Copper could obviously accelerate the degradation of some special isomers.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.