PI纤维在空间带电粒子辐照下的力学性能损伤

目的研究聚酰亚胺(PI)纤维在电子辐照、质子辐照、应力耦合质子辐照条件下力学性能的损伤行为。方法采用中国科学院长春应用化学研究所自主合成并纺丝制备的聚酰亚胺纤维,在空间环境模拟设备辐照的条件下,研究空间带电粒子对聚酰亚胺纤维辐照后的力学损伤行为,并通过XQ-1型纤维强度仪对辐照前后的样品进行拉伸试验。结果在低能电子辐照条件下,聚酰亚胺纤维的拉伸强度、模量和断裂伸长率均有所降低,但变化不太显著;高能电子辐照会提高材料的模量;质子辐照后,材料的拉伸强度和断裂伸长率随着辐照注量的增加明显降低;单一施加5%的应变会使聚酰亚胺纤维的拉伸力学性能有一定量下降。与单一应变样品相比,应力耦合质子辐照样品的拉伸强度和断裂伸长率进一步下降,但是与单一质子辐照样品相比,应力耦合辐照样品的拉伸强度和断裂伸长率都更高。结论无论是在低能电子辐照条件下,还是在高能电子辐照条件下,电子辐照对聚酰亚胺纤维力学性能影响均较微弱,而质子辐照会较大程度地降低材料的力学性能,增加应力耦合效应之后,质子辐照对材料的力学性能影响减弱。     

利用煤矸石熔制岩棉的机理与工艺研究

合理利用废弃物资源，防止环境污染是世界各国急待解决的问题．本文介绍了国内第一条煤矸石岩棉生产线的工艺设计及其年产万吨的生产性试验，表明该产品的主要技术性能已达到国家规定的优等品标准；并探讨了煤矸石熔制岩棉的机理，为煤矸石资源的高效益深度开发利用提供了新的途径．     

石棉废物的收集、管理与处置技术

石棉制品在生产和使用过程中都会产生大量的废物,废物通过纤维形态暴露在空气中会对人体产生严重危害.因此,要按照危险废物的有关管理法规,将用过的石棉废物尽可能地清除和收集起来,存放在密封容器或塑料袋中,妥善处理.要加强清除、包装、运输人员的技术培训和安全防护,减少健康风险,实行许可证管理.同时介绍了利用石棉废物生产氧化镁、制备吸附剂、采用焚烧法处理等研究发展方向,以及采用土地安全填埋处置的基本要求.     

脱硫设备用高效耐温防腐材料的研究

脱硫设备用有机高分子防腐材料，其性能主要取决于该材料的耐温抗老化性。本文通过机理分析及试验将研究一种有机硅改性的环氧树脂，并加入超细石墨粉和石棉绒，以硅烷偶联剂处理的玻璃布为增强骨架，做成耐温玻璃钢复合防腐材料。由实验发现，该防腐材料随温度的变化具有优良的稳定性和强度保留率，能够满足工业性应用要求。     

Symbiotic bacteria in hornet pupal silk

The silk weave spun by hornet larvae before undergoing pupal metamorphosis is composed of fibers and sheets, both containing symbiotic bacteria. The bacteria are secreted from the silk gland and are glued to the secreted silk, which is made up of amino-acid polymers. In the dark, it possesses at first an electric current amounting to several hundred nanoamperes (nA) (i.e., a thermoelectric property), and a high electric capacitance of up to several milliFarads (mF). This electrical charge is used gradually by the developing pupa. The symbiotic bacteria penetrate through slits in the coat of the silk fibers to the core or into pockets in the sheets, where they gradually digest parts of the silk weave, thereby nullifying its mechanical properties and facilitating in due time the egress of the imago from the puparium.     

From molecules to materials — a novel route for the synthesis of advanced ceramics

Dedicated to Prof. Dr. E. Fluck The present contribution reports on the synthesis of novel ceramic materials from molecular precursors like inorganic-organic hybrid polymers. This process, denoted as polymer pyrolysis, was developed in the mid-1970s for the fabrication of inorganic fibers made of silicon carbide (SiC). Current investigations and results in this field of research are highlighted. The main topics reviewed are related to the synthesis of appropriate polymeric ceramic precursors, especially for the preparation of multicomponent materials, the processing of the molecular compounds to ceramic components, and finally to the characterization of the material properties.     

石棉尾矿渣在土壤重金属及农药污染治理中的应用

石棉尾矿渣具有良好的孔道结构、较大的孔体积和较高的比表面积,是一种理想的吸附材料,在重金属和和有机污染等治理方面表现出巨大潜力。本文在对石棉尾矿渣的矿物组成、晶体结构、化学基团及理化性质进行分析的基础上,对其在重金属污染治理、农药污染治理、农药缓释助剂等方面的应用进行了汇总分析,并对应用中实际存在的问题进行了分析与探讨。指出天然石棉尾矿渣吸附能力不足、功能单一,对土壤结构、理化性质、微环境扰动较大的问题,应加强石棉尾矿渣酸浸改性及高温热解处理,以制备出吸附能力更强、功能更加丰富的石棉尾矿渣基功能材料;并指出了石棉尾矿渣在应用中的研究方向。     

Managing the cost of emissions for durable,carbon-containing products

We recognize that carbon-containing products do not decay and release CO₂ to the atmosphere instantaneously, but release that carbon over extended periods of time. For an initial production of a stock of carbon-containing product, we can treat the release as a probability distribution covering the time over which that release occurs. The probability distribution that models the carbon release predicts the amount of carbon that is released as a function of time. The use of a probability distribution in accounting for the release of carbon to the atmosphere realizes a fundamental shift from the idea that all carbon-containing products contribute to a single pool that decays in proportion to the size of the stock. Viewing the release of carbon as a continuous probabilistic process introduces some theoretical opportunities not available in the former paradigm by taking advantage of other fields where the use of probability distributions has been prevalent for many decades. In particular, theories developed in the life insurance industry can guide the development of pricing and payment structures for dealing with the costs associated with the oxidation and release of carbon. These costs can arise from a number of proposed policies (cap and trade, carbon tax, social cost of carbon, etc), but in the end they all result in there being a cost to releasing carbon to the atmosphere. If there is a cost to the emitter for CO₂ emissions, payment for that cost will depend on both when the emissions actually occur and how payment is made. Here we outline some of the pricing and payment structures that are possible which result from analogous theories in the life insurance industry. This development not only provides useful constructs for valuing sequestered carbon, but highlights additional motivations for employing a probability distribution approach to unify accounting methodologies for stocks of carbon containing products.     

Impact of ship-Breaking activities on the coastal environment of Bangladesh and a management system for its sustainability

Ship breaking or recycling in Bangladesh has been a catalyst for the economy by supporting the steel, shipbuilding, furniture, building construction, machinery and electrical industries since the 1980s. Although it has generated huge employment and provided 80–90% of the total steel consumption in the country, it has faced a host of challenges due to a number of negative environmental and social impacts that hinder the sustainable development of this blooming sector. The objective of this paper is to focus on how ship-breaking activities in Bangladesh affect the adjacent environment and the health and safety of workers, as well as management’s approach to the sustainability of the industry, by conducting a review of the available scientific literature. We found that grave environmental pollution, such as physiochemical properties, heavy metals, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyl compounds (PCBs), organotins, oil and grease pollution, asbestos and other atmospheric pollutants, and its impact on marine ecosystems, biodiversity, forestry, fisheries and human health are the main obstacles for the development of a sustainable ship-breaking industry. In addition, labour safety and occupational health problems, social unrest and conflicts have resulted from the development of the ship-breaking industry in Bangladesh. Inappropriate management practices and inadequate plans regarding ship-breaking activities and processes are the main reasons for these challenges. Effective management measures to mitigate the adverse environmental impact of the ship-breaking industry and to improve the health and safety of workers have now become an urgent requirement.     

锂电池正极材料Li2FeS2的充放电机理与热稳定性

随着移动电子设备的飞速发展,锂电池作为新型的能源载体也取得了巨大的进步。与嵌入式氧化物正极材料相比,Li2FeS2不仅具有理想的循环性能,而且其理论容量达到400mAh／g,约为嵌入式氧化物正极材料的2倍。因此,本文从晶体结构、电化学性能、充放电机制、充放电过程中的离子电导率变化以及热稳定性等方面对Li2FeS2正极材料进行了详细的阐述。     

石棉摩擦材料废弃物制吸附剂对染料的吸附研究

以石棉摩擦材料加工废弃物为材料制得的吸附剂,在色度５０００倍溶液中对阳离子黄Ｘ－５ＧＬ的静态吸附量为１５９．６８ｍｇ／ｇ,在色度５００倍的溶液中对阳离子艳蓝ＲＬ的静态吸附量为７９．６８ｍｇ／ｇ;对毛纺厂腈纶染缸废水的处理量可达２８０ｍｌ／ｇ,对活性染料亦有较好的吸附效果,吸附饱和吸附剂可通过后处理实现资源化。     

聚苯硫醚(PPS)掺炭纤维协同飞灰脱除气态汞的实验研究

利用汞蒸气发生器产生的单质汞和烟气中的一些主要气体成分模拟烟气条件,在固定床实验系统上分别进行了燃煤飞灰、聚苯硫醚(PPS)掺炭纤维及燃煤飞灰和PPS掺炭纤维联合对燃煤烟气中Hg0的脱除实验研究.结果表明:燃煤飞灰和PPS掺炭纤维对Hg0的吸附是物理吸附和化学吸附的共同结果,它们各自的脱汞效率分别可达27%和65%左右...     

活化粉煤灰填充聚氯乙烯板材的研究

用不同的活化粉煤灰代替活性碳酸钙作聚氯乙烯板材中的填料 ,制取试样并测试其性能。结果表明 ,选用好的改性剂 ,采用合适的活化方法时 ,得到的活化粉煤灰应用于聚氯乙烯板材中 ,其各项指标均符合标准规定 ,特别是在酸碱介质中表现出很好的耐腐蚀特性     

Polypropylene/poly (butylene terephthalate) melt spun alloy fibers dyeable with carrier-free exhaust dyeing as an environmentally friendlier process

Carrier agent as one of the synthetic persistent molecules present in textile effluents considered as one of the most highly toxic, carcinogenic and serious inhibitor of the microbial respirometric activity. This chemical is used as accelerants in the dyeing or printing the hydrophobic fibers by dispersed dyes. Hydrophobic polypropylene (PP) fibers cannot be dyed by conventional dyeing process due to the absence of dye sites in the molecular chain and their high crystallinity. This study presents a carrier-free exhaust dyeing as an environmentally friendlier and cleaner process. In order to produce dyeable PP fibers, the PP was blended and melt spun with poly(butylene terephthalate) (PBT) at various ratios. First PP and PBT granules at blend ratios of 5, 10, 20, 30, 40 percent of PBT dispersed phase were physically mixed then the melt spinning of blended samples was carried out by a Maddock mixing zone extruder. The results showed that suitable exhaust dyeing process without using any carrier agents was possible for all PP/PBT alloy fiber samples. The dye uptake of samples significantly increased by increasing the PBT dispersed phase content. By increasing the PBT dispersed phase content decrease in the crystallinity percent resulting in significant enhancement in dye uptake of the alloy fiber samples was observed. A degree of four polynomial equation for dye uptake against blend ratio was obtained by which the optimum blend ratio was 72/28 percent of PP/PBT alloy fiber composition. In all alloy fiber dyed samples uniform coloration was observed. No considerable changes in the mechanical properties for dyed samples against undyed samples were observed. Interestingly, the best mechanical property among alloy fiber samples was observed in the sample containing 30 percent PBT dispersed phase which approximately corresponds to optimum blend ratio gained from mathematical calculations. In all PP/PBT alloy fiber samples strong fastness to soaping and very good to excellent fastness to light were achieved.     

Optimization and evaluation of steel industry’s water-use system

In the steel industry, water is mainly used for cleaning and cooling. All these different tasks produce wastewaters that differ not only in quantity but also in quality. This study integrates all water-use processes into a system and applies substance flow analysis to build up an optimization model and an evaluation index system for the water-use network of a steel enterprise. Based on the index system, water-use status of large steel enterprises in China is evaluated and problems in the present water consumption are identified. A contrast analysis between present and optimized water-use is conducted, which then serves as the basis for the network optimization and countermeasure articulation. Finally, an analysis has been made on one of the most important and largest steel enterprise in China. The results indicate that after optimization fresh water consumption can be decreased by 11.1% and wastewater discharge can be decreased by 94.54%.     

A simple formula to calculate the ionization energies of two-, three-, and four-electron atomic ions

We have previously proposed a simple equation that is able to reproduce literature values (Moore 1970) for the ionization energies of one-electron (Lang and Smith 1981) and two-electron (Sabir Ali et al. 1984) atomic ions with very good agreement. However, our proposed equation has no firm theoretical basis, only that we consider our potential energy approach a logical alternative to the usual kinetic relativistic/quantum mechanical methodology. The results calculated from the equation give excellent agreement with literature values and differ by less than 1 eV and less than 0.02% in all cases from hydrogen up to atomic number 20. This paper provides an updated version of the two-electron equation adapted to calculate the ionization energies of three and four electron ions. Our equation also gives fairly good estimates of first electron affinities. Comparisons are made with another published equation, sources of data are described, and the calculated results are discussed.     

Krebs als Funktion von Disposition,Exposition und Alter

Essential parameters in carcinogenesis are the genetic and extragenetic disposition of an individual, its exposure to chemical, physical or viral influences in the environment as well as its age as the time that is needed to induce cancer. Cancer prevention seems only possible by reducing the exposure. It will be discussed whether the increase in life expectancy has become so important during the past decades that it compensates all efforts of reducing the exposure.     

中国森林资源的过去、现在与未来发展趋势

中国是少林国家。在20世纪70年代中期进行“四五”清查以前,中国只掌握一些局部性的调查数据。在1978—1981年间又进行了以省为总体的宏观抽样调查,即“五五”清查。两次清查结果很接近,但都表明中国森林太少,远低于世界平均水平和有代表性的国家。 古代中国的林区远比现在为大。森林面积则比现在大若干倍。中国缺林少材的现状是几千年来农业社会发展进程中火烧、滥伐、滥垦、滥牧的结果。其中,置森林于万劫不复的是滥垦和滥牧。这一过程至今尚未停止。 根据中国的自然条件和宜林地资源的状况,有条件大幅度扩大森林面积和增加森林蓄积量。经过努力,森林面积可达到2.53×10⁸ha,蓄积量可达到210×10⁸m³以上。都是现在的2倍多。但对保护生态环境和向国民经济提供木材和林产品来说,仍然不能完全满足需要。     

New energy vehicles in China: policies, demonstration, and progress

Since 2009, China has become the largest new vehicle market in the world. To address the energy security and urban air-pollution concerns that emerge from rapid vehicle population growth, China has initiated the Thousands of Vehicles, Tens of Cities (TVTC) Program to accelerate the new energy vehicle (NEV) commercialization. In this paper, we summarize the efforts made by the Chinese government since 1995 in the areas of research and development, demonstration, and communalization of NEVs; evaluate the progress of NEV demonstration; and provide some recommendations for future development. Our analysis has determined that the deployment of NEVs for the TVTC Program is lagging behind the original plan and, on average, only 26–36% of the goals have been attained by October 2011. Although China has approved many NEV models for sale, significantly more than 50% of them are not in production. On the other hand, stimulated by the policy shift, electric vehicle production has increased considerably, thereby contributing 23% and 44% of the total NEV production in 2010 and 2011, respectively. Additionally, because of the constraints imposed by price and technology maturity, lead-acid battery technology is a substantial factor in the high-volume sales of top NEV car models.     

黄土丘陵区生物结皮对土壤物理属性的影响

生物结皮在干旱、半干旱地区广泛发育。迄今,有关生物结皮发育过程中土壤物理属性的响应仍不明确。论文采用野外调查与室内分析相结合的方法,定量研究不同生物量生物结皮对土壤物理属性的影响。结果表明:①生物结皮的发育能够细化土壤,当生物结皮由初期藻结皮演替至60%~80%苔藓结皮时(5等级),生物结皮层粗砂粒含量降低了86%;②随着生物结皮生物量的增加,生物结皮层土壤容重和硬度较初期分别降低了15%和68%,田间持水量和孔隙度分别增加了36%和14%;生物结皮层粘结力是下层土壤的6~7倍;③生物结皮的发育对土壤物理属性的影响与生物量有关,当苔藓生物量达2.91±0.12 g/dm²时,其土壤物理属性基本稳定。研究结果为揭示生物结皮抗侵蚀机理提供了科学参考。