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1.
为全面研究广州市土壤多环芳烃(PAHs)污染特征,采集广州市222个表层土壤样品进行分析,利用效应区间低/中值法(ERL/ERM)和(BaP)毒性当量法评价土壤PAHs污染生态风险状况,终生癌症风险增量模型评价土壤PAHs污染健康风险状况,特征化合物比值法和PMF模型对PAHs来源进行解析.结果表明,广州市表层土壤ω(∑16PAHs)为38~11 115 μg·kg-1,平均值为526 μg·kg-1,16种多环芳烃单体均为强变异;广州存在潜在生态风险,个别采样点的PAHs污染已存在较大的生态风险,整体处于轻度污染的状态;基于健康风险评价结果表明,成年和儿童的总致癌风险的贡献率都呈现为:皮肤接触 > 误食土壤 > 呼吸摄入,儿童的健康风险大于成年,健康风险总体处于可接受范围;源解析表明广州市土壤PAHs的主要来源为:煤炭源(37.1%) > 柴油源(32%) > 炼焦源 (17.3%) > 交通排放、生物质燃烧和石化产品挥发的混合源(13.6%),整体土壤PAHs来源属于混合源.研究结果丰富了对广州市表层土壤PAHs污染特征的认识,有助于推动土壤污染防治行动的开展.  相似文献   

2.
基于GIS及APCS-MLR模型的兰州市主城区土壤PAHs来源解析   总被引:3,自引:2,他引:1  
为了解兰州市主城区表层土壤多环芳烃(PAHs)的污染现状,采集兰州市主城区表层土样62份,利用GC-MS (气相色谱-质谱联用仪)分析土样中16种优控PAHs的含量,采用描述性统计方法表征PAHs污染特征,运用APCS-MLR (绝对主成分分析-多元线性回归)模型判断土壤PAHs的来源,并验证模型结果的准确性,最后结合地统计方法确定各PAHs来源的主要影响区域.结果表明,兰州市主城区表层土壤Σ16 PAHs的含量为1069~7377 μg·kg-1,平均为2423 μg·kg-1;其中,以4~6环的高分子量PAHs为主,占Σ16 PAHs的质量分数为72.81%.APCS-MLR模型验证结果表明,实测值与预测值吻合性较高,该模型对于研究区土壤PAHs源解析有很好的适用性.兰州市主城区表层土壤PAHs的来源主要为交通排放源(35.42%)、石油排放源(29.88%)和煤炭与生物质燃烧混合源(33.91%),高值区主要分布在交通密集范围和工业区.结果表明研究区土壤PAHs来源复杂,且受人为活动的影响较大,应根据各污染源的贡献率和影响区域加强控制,以减少污染源排放量,从而降低土壤PAHs的污染程度.  相似文献   

3.
张小红  陶红  王亚娟  马志义  周泽英 《环境科学》2021,42(10):4933-4941
采集银川市农田表层土壤样品共43个,采用高效液相色谱法检测了土霉素(OTC)、四环素(TC)、金霉素(CTC)和强力霉素(DOC)的含量,结合空间克里金插值方法,分析了银川市农田土壤中这4种四环素类抗生素(TCs)的污染特征及空间分布状况,采用风险商值法评价了农田土壤中OTC、TC、CTC和DOC的生态风险.结果表明,四环素类抗生素在所有土壤样品中均有检出,土壤中ΣTCs含量在40.68~1074.42 μg·kg-1之间,平均值为462.24 μg·kg-1,在ΣTCs中平均占比为:CTC(69.26%) > OTC(16.34%) > TC(12.86%) > DOC(1.54%),CTC为主要污染物;在空间分布上OTC、CTC和DOC这3种抗生素的浓度呈现中部高四周低的趋势,而TC则在西北部浓度最高;在不同种植类型土壤中ΣTCs的平均含量为:设施菜地(596.01 μg·kg-1) > 牧草地(487.04 μg·kg-1) > 耕地(437.52 μg·kg-1) > 园地(404.99 μg·kg-1);生态风险评价结果显示,农田土壤中OTC、TC、CTC和DOC的风险平均值分别为0.14、0.69、0.14和1.02,其中23.26%样品的TC与6.98%样品的DOC处于高风险水平,应当引起重视.  相似文献   

4.
城郊农田土壤多环芳烃污染特征及风险评价   总被引:2,自引:2,他引:0  
为明确城郊农田土壤多环芳烃(PAHs)的污染特征,按照网格布点法在南京城郊采集29个样点,测定了15种PAHs的含量.结果表明,二氢苊(Ace)均未检出,农田土壤PAHs含量为24.49~750.04 μg ·kg-1,均值为226.64 μg ·kg-1;高环PAHs与总PAHs空间分布类似,农田土壤PAHs主要以高环PAHs为主.相关性分析结果表明,农田土壤PAHs与有机质(SOM)、pH、阳离子交换量(CEC)和全氮(TN)无显著相关性,容重(ρb)与低环PAHs极显著相关.源解析结果表明,农田土壤PAHs主要来源为燃烧源和石油源的混合源.CSI指数结果表明,农田土壤PAHs不存在生态风险.健康风险评价结果表明,农田土壤PAHs对儿童和成人不存在潜在致癌风险,主要暴露途径是:皮肤接触>摄食>呼吸吸入.  相似文献   

5.
姚成  倪进治  刘瑞  杨柳明  陈卫锋  魏然 《环境科学》2020,41(4):1847-1854
对扬州市6个不同功能区(公园、菜地、文教区、居民区、加油站和工业区)共59个表层土壤样品(0~10 cm)中15种美国环境保护署优控的多环芳烃(PAHs)的含量和来源进行了分析,并利用苯并[a]芘(BaP)毒性当量浓度(TEQBaP)评价了土壤中PAHs的生态风险.结果表明,扬州市土壤中Σ15PAHs总量范围为21~36118 μg·kg-1,中值为295 μg·kg-1,PAHs组成中以4~6环为主.不同功能区Σ15PAHs总量平均值高低顺序为工业区 > 加油站 > 文教区 > 菜地 > 居民区 > 公园.相关性分析表明,整个扬州市土壤中Σ15PAHs总量与土壤总有机碳(TOC)(P<0.05)和黑碳(BC)(P<0.01)含量都呈显著性正相关,但除了加油站土壤中Σ15PAHs总量与BC含量呈显著性正相关(P<0.01)外,不同功能区土壤中Σ15PAHs总量与TOC、BC含量都无显著相关性.特征比值法结果表明,不同功能区土壤中PAHs来源虽有些差异,但都主要来源于石油泄漏以及石油、煤和生物质等的燃烧.扬州市土壤中15种PAHs总TEQBaP值的范围是2~4448 μg·kg-1.以荷兰土壤环境标准中的10种PAHs总TEQBaP值33 μg·kg-1为标准,扬州市有45.8%的土样超标,各功能区点位超标率高低顺序为工业区(70%) > 加油站(60%) > 文教区(55.6%) > 菜地(50.0%) > 居民区(30%) > 公园(10%).因此,扬州市不同功能区中都有部分表层土壤存在潜在的生态风险,工业区和加油站风险相对较高,而居民区和公园风险相对较低.  相似文献   

6.
为了解宁东能源化工基地核心区表层土壤多环芳烃的污染现状,按网格布点法在宁东能源化工基地核心区采集了146个代表性表层土壤样品,分析了16种优控多环芳烃(PAHs)的含量.结果表明,16种优控PAHs均检出,表层土壤中ΣPAHs含量介于ND~123.12mg·kg-1之间,平均值为10.19mg·kg-1;空间上存在3个PAHs高含量区,为研究区的西北部、西南部以及东部,且不同PAHs区域分异性显著;源解析表明宁东基地PAHs污染为混合源,石油污染、燃煤、交通污染及汽油源对ΣPAHs的贡献分别为39.4%、33.3%、19.2%和8.1%;质量基准与质量标准法生态风险评价表明,该区域PAHs产生的生态影响较小,出现负面生态效应的可能性较低;健康风险评价结果表明,该区域土壤PAHs对于不同年龄段的人群不存在潜在的致癌风险,主要的暴露途径是皮肤接触 > 误食 > 呼吸吸入.  相似文献   

7.
随着城市化和工业化进程加速,城市土壤多环芳烃(PAHs)含量及污染状况受到广泛关注.以石嘴山市为例,分析8个城市功能区156个表层土壤(0~20 cm)样品PAHs含量的空间分布特征,运用单因子指数、内梅罗综合指数和终生癌症风险增量模型评价土壤PAHs污染状况,利用正定矩阵因子分解模型(PMF)对PAHs来源进行解析.结果表明,石嘴山市表层土壤PAHs总含量均值为489.82 ng·g-1,除芘(Pyr)外的15种PAH单体变异系数均大于100%,属强变异;不同功能区土壤PAHs含量呈现出:交通区(1217.61 ng·g-1) > 工业区(809.58 ng·g-1) > 公园(273.66 ng·g-1) > 文教区(268.18 ng·g-1) > 商业区(240.05 ng·g-1) > 农业区(226.81 ng·g-1) > 医疗区(211.90 ng·g-1) > 居民区(183.49 ng·g-1);内梅罗综合指数显示82.58%的样点不存在污染,轻微、轻度和中度污染占比分别为6.45%、4.52%和0.65%,5.8%的样点存在重度污染;健康风险评价结果表明,皮肤接触和误食是最主要的土壤PAHs暴露途径,其健康风险处于可接受水平;源解析表明石嘴山市土壤PAHs的主要来源为交通排放源、煤炭燃烧源、生物质/重油燃烧的混合源以及石油源,其贡献率分别为10.5%、36.6%、50.3%和2.6%,且高值大多分布在工业或煤炭生产区域.研究结果可为工业城市土壤污染研究提供参考,并对预防土壤污染、保障土壤环境质量及人体健康安全有积极作用.  相似文献   

8.
微生物群落作为土壤生态系统重要组分,长期低含量抗生素干扰会影响土壤中微生物群落结构及其功能.选取石家庄市为研究区,在2020年9月采集12个样点的表层土壤(0~25 cm),并根据空间方位将其划分为4个区(S1、S2、S3和S4);运用超高效液相色谱-质谱联用(HPLC-MS/MS)方法测定土壤中典型抗生素——喹诺酮类(quinolones,QNs)含量,明晰QNs在土壤中的空间分布特征,同时利用16S rRNA高通量测序技术对土壤中微生物群落结构及功能进行研究,识别其主要环境影响因子.结果表明:①4个区域的QNs总含量平均值由大到小依次为:S3(313.5 μg·kg-1)>S4(65.54 μg·kg-1)>S1(46.19 μg·kg-1)>S2(12.63 μg·kg-1).其中诺氟沙星(NOR)含量最高(平均值为91.99 μg·kg-1),而喹草酸(OXO)含量最低(平均值为0.4486 μg·kg-1);②土壤颗粒以粉粒(2~50 μm)占比最高(66.7%~93.2%),而黏粒(小于2 μm)占比最低(2.50%~9.10%);土壤中总磷(TP)和氨氮(NH4+-N)无显著空间差异,而硝氮(NO3--N)、亚硝氮(NO2--N)和土壤粒径呈现显著空间差异;③6种,优势菌属有5种,其中放线菌门(18.3%~34.6%)和变形菌门(13.6%~34.1%)为主要优势菌门,Arthrobacter(3.24%~8.61%)和Nitrososphaeraceae(2.93%~9.46%)为主要优势菌属;α多样性分析结果表明,Shannon值在S2区最高(6.48),而在S3区最低(5.89);④相关性结果表明,QNs和土壤理化参数均会显著改变微生物群落的结构组成,OXO、NO3--N和土壤粒径会影响微生物群落多样性,而FLU、NH4+-N和NO2--N和土壤粒径会对微生物群落的功能产生影响.因此,需进一步加强石家庄市土壤环境中抗生素的风险管控.  相似文献   

9.
不同植物覆盖下黄河三角洲湿地土壤中微塑料的分布   总被引:5,自引:2,他引:3  
为揭示黄河三角洲湿地地区土壤中微塑料分布与植物覆盖的相关性,选择低盐优势物种芦苇(Phragmites communis)和高盐优势物种盐地碱蓬(Suaeda salsa)为研究对象,探讨其生长土壤共计16个样点中微塑料的分布特征.结果表明,该地区植物覆盖土壤中微塑料丰度范围为80~4640 n·kg-1,粒径范围为13 μm~5 mm,大粒径微塑料成分主要有聚乙烯(PE)、聚对苯二甲酸乙二醇酯(PET)和聚苯乙烯(PS),其中PET含量为0.22~1.16 μg·kg-1.芦苇相对盐地碱蓬对土壤中微塑料有更大的阻隔.芦苇生长点位上土壤微塑料丰度和PET含量均值分别为1423 n·kg-1和0.62 μg·kg-1,以50 μm以下粒径的小颗粒为主;盐地碱蓬生长点位上土壤微塑料丰度均值和PET含量分别为584 n·kg-1和0.33 μg·kg-1,以100~1000 μm粒径的碎片和纤维为主.微塑料丰度与植物生长状况具有显著相关性(P=0.001).因此,同一区域不同植物覆盖下土壤中微塑料的分布可能会存在空间差异.  相似文献   

10.
探究典型岩溶湿地沉积物营养物质的污染状况及其富营养化风险,以期为岩溶湿地水-沉积物污染的控制与治理提供参考和依据.以典型岩溶流域普者黑为研究区,运用抓斗式底泥采样器对流域内河流湿地、湖泊湿地、沼泽湿地和库塘湿地的表层沉积物进行采样,并采用国家标准方法对沉积物中总氮(TN)、总磷(TP)及有机质(OM)的含量进行测定,并运用单因子指数法、有机指数法及有机氮指数法对普者黑岩溶流域不同类型湿地沉积物的污染程度进行评价.结果表明:①在干季,河流湿地TP含量最高,为1.18 g·kg-1,沼泽湿地TN和OM含量最高,分别为2.93、2.71 g·kg-1;库塘湿地TN、TP和OM含量最低,分别为1.44、0.63、1.43 g·kg-1.在湿季,河流湿地TP和OM含量最高,分别为0.95、2.16 g·kg-1,湖泊湿地TN含量最高,为2.22 g·kg-1;沼泽湿地TP和OM含量最低,分别为0.42、1.28 g·kg-1,库塘湿地TN含量最低,为1.22 g·kg-1.②普者黑不同类型湿地沉积物TN、TP、OM在干、湿季下的污染程度不同.在干季,河流湿地和沼泽湿地沉积物磷污染均为重度污染,4种湿地沉积物氮污染均为重度污染,有机污染除库塘湿地属于轻度污染外,其他3种湿地均为中度污染.在湿季,河流湿地沉积物磷污染为重度污染,河流湿地和湖泊湿地沉积物氮污染均为重度污染,湖泊湿地沉积物有机污染属于重度污染.总体上看,各类湿地沉积物氮磷污染干季的污染程度比湿季严重,干季以外源为主,湿季以内源为主;故干季湿地沉积物营养盐潜在释放风险较湿季大.  相似文献   

11.
Soil contaminated with heavy metals cadmium(Cd)and lead(Pb)is hard to be remediated.Phytoremediation may be a feasible method to remove toxic metals from soil,but there are few suitable plants which can hyperaccumulate metals.In this study,Cd and Pb accumulation by four plants including sunflower(Helianthus annuus L.),mustard(Brassica juncea L.),alfalfa(Medicago sativa L.), ricinus(Ricinus communis L.)in hydroponic cultures was compared.Results showed that these plants could phytocxtract heavy metals, the ability of accumulation differed with species,concentrations and categories of heavy metals.Values of BCF(bioconcentration factor)and TF(translocation factor)indicated that four species had dissimilar abilities of phytoextraction and transportation of heavy metals.Changes on the biomass of plants,pH and Eh at different treatments revealed that these four plants had distinct responses to Cd and Pb in cultures.Measurements should be taken to improve the phytoremediation of sites contaminated with heavy metals,such as pH and Eh regulations,and so forth.  相似文献   

12.
The oxidation of As(Ⅲ) with potassium permanganate was studied under conditions including pH, initial As(Ⅲ) concentration and dosage of Mn(Ⅶ). The results have shown that potassium permanganate was an effective agent for oxidizing of As(Ⅲ) in a wide pH range. The pH value of tested water was not a significant factor affecting the oxidation of As(Ⅲ) by Mn(Ⅶ). Although theoretical redox analyses suggest that Mn(Ⅶ) should have better performance in oxidization of As(Ⅲ) within lower pH ranges, the experimental results show that the oxidation efficiencies of As(Ⅲ) under basic and acidic conditions were similar, which may be due to the adsorption of As(Ⅲ) on the Mn(OH)2 and MnO2 resulting from the oxidation of As(Ⅲ).  相似文献   

13.
Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury (HgT), combinative mercury (Hgc) and gaseous mercury (HgG), and content of total organic carbon (TOC), but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of (HgG,/HgT)1992〉(HgG/HgT)1996〉〉(HgG/HgT)2000. A simple outline of Hg release in landfill could be drawn: with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants (e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum) are capable of enriching more Hg than herbaceous plants.  相似文献   

14.
Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.  相似文献   

15.
Decomposition of alachlor by ozonation and its mechanism   总被引:1,自引:0,他引:1  
Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.  相似文献   

16.
The influence of the nonionic surfactant Tween 80 on pentachlorophenol (PCP) oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration (CMC). Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.  相似文献   

17.
The Xijiang River is the major source of water for about 4.5 millions of urban population and 28.7 millions of rural population. The water quality is very important for the health of the rural population. The concentration and distribution of chlorobenzenes (CBs) in both water and waterweeds collected from 4 stations in the Xijiang River (Gangdong section) of the Pearl River in April and November were determined. The result showed that nearly every congener of CBs was detected. The total contents of CBs (∑CBs) in the river water ranged from 111.1 to 360.0 ng/L in April and from 151.9 to 481.7 ng/L in November, respectively. The pollution level of CBs in the water in April was higher than that in November. The contents of ∑ CBs in waterweeds ranged from 13.53×102 μg/g to 38.27×102μg/g dry weight (dw). There was no significant difference between April and November in waterweeds. The distribution of CBs in roots, caulis, and leaves of Vallisneria spiralis L. showed different patterns. The leaves mainly contained low-molecular-weight CBs(DCBs), whereas the roots accumulated more PCBs and HCBs. The average lgBCFlip (bioconcentration factor) of CBs ranged from 0.64 to 3.57 in the waterweeds. The spatial distribution character of CBs in the Xijiang River was: Fengkai County < Yunan County <Yun'an County < Gaoyao County according to the ∑CBs, and the pollution deteriorated from the upstream to the downstream of the Xijiang River. Further analysis demonstrated that the discharge of waste containing CBs may be the main source of CBs pollution in the Xijiang River.  相似文献   

18.
Degradation of 2,4-dichlorophenol(2,4-DCP)was studied in a novel three-electrode photoelectrocatalytic(PEC)integrative oxidation process,and the factors influencing the degradation rate,such as applied current,flow speed of O_2,pH,adscititious voltage and initial 2,4-DCP concentration were investigated and optimized.H_2O_2 was produced nearby cathode and Fe~(2 )continuously generated from Fe anode in solution when current and O_2 were applied,so,main reactions,H_2O_2-assisted TiO_2 PEC oxidation and E-Fenton reaction,occurred during degradation of 2,4-DCP in this integrative system.The degradation ratio of 2,4-DCP was 93% in this integrative oxidation process,while it was only 31% in E-Fenton process and 46% in H_2O_2-assisted TiO_2 PEC process.So,it revealed that the degradation of 2,4-DCP was improved greatly by photoelectrical cooperation effect.By the investigation of pH,it showed that this integrative process could work well in a wide pH range from pH 3 to pH 9.  相似文献   

19.
The influence of coexisting copper (Cu) ion on the degradation of pesticides pyrethroid cypermethrin and cyhalothrin in soil and photodegradation in water system were studied.Serial concentrations of the pesticides with the addition of copper ion were spiked in the soil and incubated for a regular period of time,the analysis of the extracts from the soil was carried out using gas chromatography (GC).The photodegradation of pyrethroids in water system was conducted under UV irradiation.The effect of Cu~(2 ) on the pesticides degradation was measured with half life (t_(0.5)) of degradation.It was found that a negative correlation between the degradation of the pyrethroid pesticides in soil and Cu addition was observed.But Cu~(2 ) could accelerate photodegradation of the pyrethroids in water.The t_(0.5) for cyhalothrin extended from 6.7 to 6.8 d while for cypermethrin extended from 8.1 to 10.9 d with the presence of copper ion in soil.As for photodegradation,t_(0.5) for cyhalothrin reduced from 173.3 to 115.5 rain and for cypermethrin from 115.5 to 99.0 min.The results suggested that copper influenced the degradation of the pesticides in soil by affecting the activity of microorganisms.However, it had catalyst tendency for photodegradation in water system.The difference for the degradation efficiency of pyrethroid isomers in soil was also observed.Copper could obviously accelerate the degradation of some special isomers.  相似文献   

20.
以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.  相似文献   

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