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采用平板陶瓷膜中试装置处理石化废水,分析了处理效果与膜污染情况,获得了平板陶瓷膜稳定运行条件下的工艺参数。结果表明:在COD为50~100 mg/L、浊度为2~11 NTU的进水条件下,平板陶瓷膜出水COD与浊度分别为20~42 mg/L和0.05~0.2 NTU,与双层过滤器+中空纤维超滤工艺出水水质较为接近;在运行通量40 L/(m 2·h)、反洗周期45 min、反洗时间60 s的条件下,采用浓度为100~150 mg/L的次氯酸钠每7小时进行1次化学清洗,平板陶瓷膜系统运行较为稳定。 相似文献
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为解决煤矿工业广场生活污水再生利用的问题,采用超滤技术对二级生化出水进行深度处理试验研究.结果表明:超滤对浊度、CODcr及NH4+-N的平均去除率分别为94.1%、24.8%和32.7%,对粪大肠菌群数的去除率大于99.99%.在操作压力小于0.16MPa的情况下,膜通量随操作压力的提高而线性增大;当操作压力大于0.2 MPa后,膜通量受操作压力的影响较小,继续提高操作压力会加剧膜的污染,周期反冲洗能够有效抑制膜通量的下降.超滤在过滤15m in后反冲洗1min的条件下运行16h,膜通量仅下降7.3%. 相似文献
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以集成膜工艺处理回用钢铁废水现场试验为背景,介绍了超滤、活性炭于不同位置的预处理效果差异,分析了超滤、活性炭于工艺流程不同位置对CODCr去除效果、出水SDI15及超滤稳定运行工况的差异及原因,提出了两者组合工艺用于反渗透预处理的建议和进一步研究方向。 相似文献
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为提高超滤膜系统对污水处理厂二级出水中有机物和TN的去除效果,并降低超滤膜污染速率,改善超滤膜性能,分析了沸石粉、硅藻土2种预涂膜工艺在超滤膜系统中的应用效果. 结果表明:沸石粉/超滤工艺对超滤膜系统的膜通量恢复良好,反冲洗后能恢复到原来的膜通量;而硅藻土/超滤工艺中膜通量较初期下降0.01 L/(m2·h),对照组下降0.04 L/(m2·h). 沸石粉/超滤工艺对污水处理厂二级出水中CODCr、UV254和TN的去除率分别为17.5%、13.5%和11.7%,相比对照组均有较大程度提高. 通过电镜扫描分析发现,沸石粉能够在超滤膜表面有效形成一层保护膜,降低有机物在膜表面的沉积,保障膜系统的高效率及长期稳定运行. 通过比较各实际运行工况效果并进行筛选,确定沸石粉为预涂膜工艺的最佳材料. 相似文献
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聚合物驱采油污水中大量聚合物的存在影响了污水的性质,它对超滤膜的污染机理与一般采油污水不同。研究了超滤过滤模拟含聚合物污水过程中,聚合物浓度对膜通量的影响,通过对过滤实际原水污染膜纤维进行化学清洗以及污染膜表面和断面扫描电镜分析,优选化学清洗方案。在此基础上,采用优选的化学清洗方案对工程应用中的膜组件进行清洗。结果表明:随着聚合物浓度升高,膜通量衰减逐渐加剧;NaOH和十二烷基苯磺酸钠组合对聚合物污染清洗效果最佳,可恢复初始通量的75%;分析清洗后膜表面的扫描电镜图表明,原水中物质会在膜面累积形成稳定凝胶层并对膜造成不可逆污染。 相似文献
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用超滤法处理洗毛污水 总被引:6,自引:0,他引:6
本文就聚砜中空纤维超滤法处理洗毛污水进行了研究,首先考查了不同截留分子量的超滤膜对超滤性能的影响,发现截留分子量为3万的膜超滤性能较佳;然后考查了压力、温度、浓度及流速等操作参数对超滤性能的影响;污水经过超滤后,脂、总固体及COD去除率分别在98%、80%和95%以上. 相似文献
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Drinking water production by ultrafiltration of Songhuajiang River
with PAC adsorption 总被引:1,自引:0,他引:1
In recent years, membrane ultrafiltration (UF) of surface water for drinking water treatment has become a more attractive technology worldwide as a possible alternative treatment to conventional clarification. To evaluate the performance of ultrafiltration membranes for treatment of surface water in North China, a 48-m^2 low pressure hollow fiber membrane ultrafiltration pilot plant was constructed. Ultrafiltration was operated in cross-flow and with powdered activated carbon (PAC) adsorption. Turbidity was almost completely removed to less than 0.2 NTU (below Chinese standard 1 NTU). It was found that PAC addition enhanced organic matter removal. The combined process of PAC/UF allowed to 41% removal of CODMn, 46% removal of DOC and 57% decrease in UV254 absorbance. The elimination of particles, from average 12000/ml in the raw water to approximately 15/ml in the permeated, was observed. When PAC concentration was below 30 mg/L, backwashing could recovery the membrane flux with backwash interval/backwashing duration of 1/30. 相似文献
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XIA Sheng-ji LIU Ya-nan LI Xing YAO Juan-juan State Key Laboratory of Pollution Control Resources Reuse Tongji University Shanghai China. School of Environmental Science Engineering Dong Hua University Shanghai China School of Architecture Civil Engineering Beijing University of Technology Bejing China 《环境科学学报(英文版)》2007,(5)
In recent years, membrane ultrafiltration (UF) of surface water for drinking water treatment has become a more attractive technology worldwide as a possible alternative treatment to conventional clarification. To evaluate the performance of ultrafiltration membranes for treatment of surface water in North China, a 48-m2 low pressure hollow fiber membrane ultrafiltration pilot plant was constructed. Ultrafiltration was operated in cross-flow and with powdered activated carbon (PAC) adsorption. Turbidity was almost completely removed to less than 0.2 NTU (below Chinese standard 1 NTU). It was found that PAC addition enhanced organic matter removal. The combined process of PAC/UF allowed to 41% removal of CODMn 46% removal of DOC and 57% decrease in UV254 absorbance. The elimination of particles, from average 12000/ml in the raw water to approximately 15/ml in the permeated, was observed. When PAC concentration was below 30 mg/L, backwashing could recovery the membrane flux with backwash interval/backwashing duration of 1/30. 相似文献
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IntroductionThe application of ultrafiltration for producedwater treatment is still costly in terms of energyconsumption and equipment cost compared withconventional water treatment processes. Thehigh-energy consumption comes from the highcirculation velocity, and it is necessary for controllingconcentration polarization and membrane fouling,which still remain a topical problem for an industrialdevelopment of ultrafiltration processes. Membranefouling in ultrafiltration is complex, accumulatio… 相似文献
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大庆油田水务公司西水源水厂以地下水作为主要水源,采用臭氧/活性炭+超滤膜(UF)处理工艺;自2014年投产至2019年底已经运行5年,水厂出水浊度、有机物(CODMn)和菌落总数等水质指标均稳定达标,但超滤膜污染导致膜性能变化。为了探究5年运行过程中超滤膜处理性能演变情况,对膜出水水质、膜通量、跨膜压差和膜污染层等进行分析。结果表明:超滤膜对浊度和微生物的去除率保持在90%以上,对CODMn平均去除率维持在9%。运行5年过程中,超滤膜的比通量每年下降2.1%~4.6%,恢复性化学清洗(CIP)对超滤膜的通量与比通量恢复率分别维持在73%~91%和85%~92%。污染层分析结果表明,超滤膜的有机污染物主要是腐植酸和蛋白质等;无机污染物包括锰、铁、硅、钙和铝等。高价金属元素与有机物形成络合污染物,在污染层中起到支配作用;另外,钙和硅的无机盐垢也不可忽视。 相似文献
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应用多孔玻璃膜分离水中纳米有机胶体质的研究 总被引:2,自引:0,他引:2
应用新型的硼硅酸多孔玻璃膜(porous glass)于错流超滤(cross-flow ultrafiltration)系统中,分离出30-300nm有机质胶体。分别试验孔径为30nm、50nm和100nm等多孔玻璃膜对一些标准有机大分子的截留率。实验结果显示过滤溶液的酸度、温度、盐度对该分离膜的分离性能影响甚微。 相似文献