建德市国家生态示范区建设成效及其成功经验

建德市生态示范区创建工作是以"2066"工程推进、大力建设绿色食品基地和农村三大面源污染治理为主要特点,取得了生态环境明显好转、经济和环境协调发展的建设成效.其结合当地实际的农村面源治理模式等主要成功经验值得推广.     

四川省农村面源污染状况与治理对策研究

四川省农村面源主要分为农田面源、畜禽养殖粪便污染面源和农村生活污染面源,研究根据排放因子法计算了两种主要考核污染物化学需氧量和氨氮的排放量.根据四川省农村面源污染状况特征提出了面源治理对策措施,其中农田面源治理措施包括:推广测土配方施肥、农田面源生态拦截技术等;畜禽养殖污染治理措施包括:加强小型畜禽养殖污染治理,推广农牧结合、干清粪、发酵床处理工艺等;农村生活污染治理措施包括:推进农村生活污水收集及小型污水处理设施等.     

三台县农业面源污染的生态补偿机制与措施研究

三台县是一个农业大县,随着农业经济的迅速发展,农业面源污染日趋严重。种植业污染、畜禽养殖、农村生活污染成为三台县农业面源污染的主要因素。面源污染具有分散性、随机性和监测成本高的特点。对三台县农业面源污染产生进行了经济学分析,农业面源污染属于外部不经济性,通过建立生态补偿机制,控制农业面源污染。以三台县建立生态县和新农村建设为基础,通过转变农业生产方式,调整产业结构,发展生态农业,推进生态村的建设等生态补偿治理措施,改善三台县的农业生态环境。     

基于广义收益—成本分析的农村面源污染治理策略

应用污染排放系数法、技术经济评价方法,统筹考虑农村面源污染治理的环境效益与经济收益、技术成本与交易费用,构建面向一般区域的农村面源污染治理策略的分析框架与方法.研究表明,2011年宜兴市农村面源污染排放总氮2880.94t,总磷501.19t,水环境经济损失为3.38亿元.耕地测土配方施肥、规模化养殖沼气工程、分散养殖沼气工程和农村生活污水净化工程的净现值率分别为55.00、2.54、0.52、-0.15.综合考虑技术可行性、交易费用和政府管理支撑能力,近期应优先治理规模化养殖和种植业面源污染,分散养殖和农村生活污水污染可作为远期治理重点.     

玉溪市江川区九溪镇区域环境问题及对策探讨

介绍了九溪镇基本情况,分析了九溪镇点源、面源污染现状,从农业面源污染治理、人居环境整治、水土流失防治、畜禽养殖污染治理、河道综合治理、强化环境管理、健全工作机制等方面提出了治理措施,建议加快产业结构优化调整、强化领导工作、严格环境管理、加强农村环境管理体系建设,强化宣传教育、创建环境优美乡镇和生态镇。     

对开展农村环境联片整治的重要性的初步认识及建议

随着农村经济的不断发展,农村环境污染日趋严重。虽然吉林省在农村环境污染防治和生态保护方面取得了一些成效,但农村环保工作仍然十分薄弱。农村环境连片整治示范项目以饮用水水源保护和人居环境质量改善为主要目标,重点支持农村饮用水水源地保护、生活污水和生活垃圾污染治理、畜禽养殖污染治理与综合利用等项目。基于吉林省农村环境存在的共性问题和污染成因分析,有关人士提出了“切实保护农村饮用水源地,加强村庄生活污染治理力度,畜禽养殖污染治理,工矿企业污染治理,农业面源污染治理”等五方面治理措施,有利于促进全省农村环境的有效改善。     

农业面源污染及防治对策

农村面源污染源分布广泛,没有确切位置,其治理一直是个难题.由于化肥和农药的大量使用,农业面源污染已成为我国农村生态环境恶化的重要原因之一.本文对农业面源污染的特点、危害和现状进行了论述,并提出防治农业面源污染的具体防治对策和建议.     

基于加强农村面源污染综合治理的研究

随着农村土地制度的改革和社会经济发展,农村土地得到加速开发,随之而来的是极度追求经济利益的最大化而造成的土地过度开发,从而引发的面源污染问题。绿色发展的背景下,面源污染治理问题是农村发展工作的重中之重,本文探究面源污染的原因,结合当前农村发展现状,提出有效的防范和治理手段。     

倒水河武汉段水环境现状调查与保护对策

针对倒水河武汉段多次出现水质超标现象开展流域范围内水质状况及污染负荷数据收集和现状调研,分析得出流域范围内存在的主要问题为农业农村面源污染形势严峻、污水治理基础设施建设管理不足、水文水资源影响及上游水质恶化,结合倒水河实际提出系列水环境治理措施:农业农村污染控制、城镇生活污染物防治、实施连通湖泊保护工程、完善流域污染监控及联防联控工作机制。     

盈江县生态文明县建设中的农村环境污染现状与对策

盈江县党委、政府高度重视生态文明建设工作,提出在2018年前将盈江县建设为云南省生态文明县的目标。通过分析盈江县农村的面源污染和点源污染现状,结合盈江县实际,提出治理农村环境污染的对策和建议,以尽早实现云南省生态文明县的创建目标。     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.