玉米燃料乙醇生命周期碳平衡分析

玉米燃料乙醇作为化石燃料的替代品,其温室气体排放的多少(净碳排放量)是评价其可持续性的一个重要标准.基于生命周期分析原理,建立了玉米燃料乙醇的碳平衡分析方法.以我国夏玉米燃料乙醇的生产为例,计算了玉米燃料乙醇生命周期的净碳排放量并对其影响因素进行了分析.研究表明:与汽油相比,目前我国夏玉米燃料乙醇的生产并不能明显减少温室气体的排放,为此玉米生产过程中氮肥施用和灌溉以及乙醇转化过程的能耗等方面有待于重点改善.     

Forest carbon accounting methods and the consequences of forest bioenergy for national greenhouse gas emissions inventories

While bioenergy plays a key role in strategies for increasing renewable energy deployment, studies assessing greenhouse gas (GHG) emissions from forest bioenergy systems have identified a potential trade-off of the system with forest carbon stocks. Of particular importance to national GHG inventories is how trade-offs between forest carbon stocks and bioenergy production are accounted for within the Agriculture, Forestry and Other Land Use (AFOLU) sector under current and future international climate change mitigation agreements. Through a case study of electricity produced using wood pellets from harvested forest stands in Ontario, Canada, this study assesses the implications of forest carbon accounting approaches on net emissions attributable to pellets produced for domestic use or export. Particular emphasis is placed on the forest management reference level (FMRL) method, as it will be employed by most Annex I nations in the next Kyoto Protocol Commitment Period. While bioenergy production is found to reduce forest carbon sequestration, under the FMRL approach this trade-off may not be accounted for and thus not incur an accountable AFOLU-related emission, provided that total forest harvest remains at or below that defined under the FMRL baseline. In contrast, accounting for forest carbon trade-offs associated with harvest for bioenergy results in an increase in net GHG emissions (AFOLU and life cycle emissions) lasting 37 or 90 years (if displacing coal or natural gas combined cycle generation, respectively). AFOLU emissions calculated using the Gross-Net approach are dominated by legacy effects of past management and natural disturbance, indicating near-term net forest carbon increase but longer-term reduction in forest carbon stocks. Export of wood pellets to EU markets does not greatly affect the total life cycle GHG emissions of wood pellets. However, pellet exporting countries risk creating a considerable GHG emissions burden, as they are responsible for AFOLU and bioenergy production emissions but do not receive credit for pellets displacing fossil fuel-related GHG emissions. Countries producing bioenergy from forest biomass, whether for domestic use or for export, should carefully consider potential implications of alternate forest carbon accounting methods to ensure that potential bioenergy pathways can contribute to GHG emissions reduction targets.     

Wood-based building materials and atmospheric carbon emissions

This study investigates the global impact of wood as a building material by considering emissions of carbon dioxide to the atmosphere. Wood is compared with other materials in terms of stored carbon and emissions of carbon dioxide from fossil fuel energy used in manufacturing. An analysis of typical forms of building construction shows that wood buildings require much lower process energy and result in lower carbon emissions than buildings of other materials such as brick, aluminium, steel and concrete. If a shift is made towards greater use of wood in buildings, the low fossil fuel requirement for manufacturing wood compared with other materials is much more significant in the long term than the carbon stored in the wood building products.As a corollary, a shift from wood to non-wood materials would result in an increase in energy requirements and carbon emissions.The results presented in this paper show that a 17% increase in wood usage in the New Zealand building industry could result in a 20% reduction in carbon emissions from the manufacture of all building materials, being a reduction of about 1.5% of New Zealand’s total emissions. The reduction in emissions is mainly a result of using wood in place of brick and aluminium, and to a lesser extent steel and concrete, all of which require much more process energy than wood. There would be a corresponding decrease of about 1.5% in total national fossil fuel consumption. These figures have implications for the global forestry and building industries. Any increases in wood use must be accompanied by corresponding increases in areas of forest being managed for long term sustained yield production.     

Forest Management for Mitigation of CO2 Emissions: How Much Mitigation and Who Gets the Credits?

Forestry projects can mitigate the net flux of carbon (C) to the atmosphere in four ways: (1) C is stored in forest biomass—trees, litter and soil, (2) C is stored in durable wood products, (3) biomass fuels displace consumption of fossil fuels, and (4) wood products often require less fossil-fuel energy for their production and use than do alternate products that provide the same service. We use a mathematical model of C stocks and flows (GORCAM) to illustrate the inter-relationships among these impacts on the C cycle and the changing C balance over time. The model suggests that sustainable management for the harvest of forest products will yield more net C offset than will forest protection when forest productivity is high, forest products are produced and used efficiently, and longer time periods are considered. Yet it is very difficult to attribute all of the C offsets to the forestry projects. It is, at least in concept, straightforward to measure, verify, and attribute the C stored in the forests and in wood products. It is more challenging to measure the amount of fossil fuel saved directly because of the use of biomass fuels and to give proper attribution to a mitigation project. The amount of fossil fuel saved indirectly because biomass provides materials and services that are used in place of other materials and services may be very difficult to estimate and impossible to allocate to any project. Nonetheless, over the long run, these two aspects of fossil fuel saved may be the largest impacts of forestry projects on the global C cycle.     

Greenhouse gas emissions,life-cycle inventory and cost-efficiency of using laminated wood instead of steel construction.: Case: beams at Gardermoen airport

This article compares the use of glulam beams at the new airport outside Oslo with an alternative solution in steel in order to (1) make an inventory of greenhouse gas (GHG) emissions and energy use over the life cycle of glulam and of steel, (2) calculate the avoided GHG emissions and the cost of the substitution, and (3) analyse which factors have the strongest influence on the results. Compared to previous analyses of substitution between steel and glulam related to greenhouse gas emissions, this article brings in three new methodological elements: combining traditional life-cycle analysis with economic costs, considering explicitly the emissions’ points in time, and using discounted global warming potential (DGWP).The total energy consumption in manufacturing of steel beams is two to three times higher and the use of fossil fuel 6–12 times higher than in the manufacturing of glulam beams. Manufacturing of steel in the most likely scenario gives five times higher GHG emissions compared to manufacturing of glulam beams. Waste handling of glulam can either be very favourable or unfavourable compared to steel depending on the glulam being landfilled or used for energy production. Other assumptions that substantially affect the results over the life cycle are carbon fixation on the forest land that is regenerated after harvesting, whether the steel production is scrap-based or ore-based, and which energy sources are used for producing the electricity used by the steel industry. The uncertainty in the inventory data for glulam do not influence the results much compared to changes in these main assumptions. The glulam construction cannot be more than 1–6% more expensive than steel before the price per ton avoided greenhouse gas emissions becomes high compared to the present Norwegian CO₂-tax on gasoline. In the most likely scenario, and not including carbon fixation on forest land, 0.24–0.31 tons of CO₂-equivalents per cubic metre input of sawn wood in glulam production is avoided by using glulam instead of steel, whereas this figure increases to 0.40–0.97 t/m³ if carbon fixation on forest land is included. Using DGWP does not influence the results of the analysis significantly.     

Bioenergy and the forest industry in Finland after the adoption of the Kyoto protocol

In Finland the percentage of biomass fuels of total primary energy supply is relatively high, close to 17%. The share of biomass in the total electricity generation is as much as 10%. This high share in Finland is mainly due to the cogeneration of electricity and heat within forest industry using biomass-based by-products and wastes as fuels. Forest industry is also a large user of fossil-based energy. About 28% of total primary energy consumption in Finland takes place in forest industry, causing about 16% of the total fossil carbon dioxide emissions.The Kyoto protocol limits the fossil CO₂ and other greenhouse gas emissions and provides some incentives to the Finnish forest sector. There are trade-offs among the raw-material, energy and carbon sink uses of the forests. Fossil emissions can be reduced e.g. by using more wood and producing chemical pulp instead of mechanical one. According to the calculation rules of the Kyoto protocol Finnish forests in 2008–2012 are estimated to form a carbon source of 0.36 Tg C a⁻¹ due to land use changes. Factually the forest biomass will still be a net carbon sink between 3.5 and 8.8 Tg C a⁻¹. Because the carbon sinks of existing forests are not counted in the protocol, there is an incentive to increase wood use in those and to decrease the real net carbon sink. Also the criteria for sustainable forestry could still simultaneously be met.     

Global warming potential factors and warming payback time as climate indicators of forest biomass use

A method is presented for estimating the global warming impact of forest biomass life cycles with respect to their functionally equivalent alternatives based on fossil fuels and non-renewable material sources. In the method, absolute global warming potentials (AGWP) of both the temporary carbon (C) debt of forest biomass stock and the C credit of the biomass use cycle displacing the fossil and non-renewable alternative are estimated as a function of the time frame of climate change mitigation. Dimensionless global warming potential (GWP) factors, GWP_bio and GWP_biouse, are derived. As numerical examples, 1) bioenergy from boreal forest harvest residues to displace fossil fuels and 2) the use of wood for material substitution are considered. The GWP-based indicator leads to longer payback times, i.e. the time frame needed for the biomass option to be superior to its fossil-based alternative, than when just the cumulative balance of biogenic and fossil C stocks is considered. The warming payback time increases substantially with the residue diameter and low displacement factor (DF) of fossil C emissions. For the 35-cm stumps, the payback time appears to be more than 100 years in the climate conditions of Southern Finland when DF is lower than 0.5 in instant use and lower than 0.6 in continuous stump use. Wood use for construction appears to be more beneficial because, in addition to displaced emissions due to by-product bioenergy and material substitution, a significant part of round wood is sequestered into wood products for a long period, and even a zero payback time would be attainable with reasonable DFs.     

钢铁行业生命周期碳排放核算及减排潜力评估

钢铁行业是中国碳密集度最高的工业行业之一,为分析钢铁行业生命周期碳排放及碳减排潜力,从生命周期角度构建碳排放核算模型,以2020年为例开展实证分析,通过优化废钢使用量、化石燃料燃烧量、电力碳足迹因子以及清洁运输比例4项变量,对钢铁行业生命周期碳减排潜力作预测评估,同时使用敏感性分析确定影响钢铁生命周期碳减排因素的关键程度.结果表明,2020年中国钢铁行业全生命周期二氧化碳(CO₂)排放总量约24.04亿t,其中原料获取和加工生产阶段是钢铁行业碳排放的关键环节,占钢铁行业生命周期CO₂排放总量的98%以上.从CO₂排放源类别分析,化石燃料节约和外购电力清洁化是钢铁行业降碳的重中之重.到2025年,通过推广低碳技术、优化电力结构、增加废钢炼钢量、提高清洁方式运输比例,分别可使钢铁行业实现20%、 6%、 5%和1%的碳减排潜力.化石燃料燃烧量对钢铁行业生命周期CO₂排放的影响最显著,电力碳足迹因子和废钢炼钢使用量次之.关于钢铁行业节能低碳技术,短期内以推广轧钢工序与高炉炼铁工序低碳技术为主,未来随着电炉...     

Life cycle greenhouse gas emissions, fossil fuel demand and solar energy conversion efficiency in European bioethanol production for automotive purposes

Crop derived biofuels such as (bio)ethanol are increasingly applied for automotive purposes. They have, however, a relatively low efficiency in converting solar energy into automotive power. The outcome of life cycle studies concerning ethanol as to fossil fuel inputs and greenhouse gas emissions associated with such inputs depend strongly on the assumptions made regarding e.g. allocation, inclusion of upstream processes and estimates of environmentally relevant in- and outputs. Peer reviewed studies suggest that CO₂ emissions linked to life cycle fossil fuel input are typically about 2.1–3.0 kg CO₂ kg⁻¹ starch-derived ethanol. When biofuel production involves agricultural practices that are common in Europe there are net losses of carbon from soil and emissions of the greenhouse gas N₂O. Dependent on choices regarding allocation, they may, for wheat (starch) be in the order of 0.6–2.5 kg CO₂ equivalent kg⁻¹ of ethanol. This makes ethanol derived from starch, or sugar crops, in Europe still less attractive for mitigating climate change. In case of wheat, changes in agricultural practice may reduce or reverse carbon loss from soils. When biofuel production from crops leads to expansion of cropland while reducing forested areas or grassland, added impetus will be given to climate change.     

Carbon Dioxide Balance of Wood Substitution: Comparing Concrete- and Wood-Framed Buildings

In this study a method is suggested to compare the net carbon dioxide (CO₂) emission from the construction of concrete- and wood-framed buildings. The method is then applied to two buildings in Sweden and Finland constructed with wood frames, compared with functionally equivalent buildings constructed with concrete frames. Carbon accounting includes: emissions due to fossil fuel use in the production of building materials; the replacement of fossil fuels by biomass residues from logging, wood processing, construction and demolition; carbon stock changes in forests and buildings; and cement process reactions. The results show that wood-framed construction requires less energy, and emits less CO₂ to the atmosphere, than concrete-framed construction. The lifecycle emission difference between the wood- and concrete-framed buildings ranges from 30 to 130 kg C per m² of floor area. Hence, a net reduction of CO₂ emission can be obtained by increasing the proportion of wood-based building materials, relative to concrete materials. The benefits would be greatest if the biomass residues resulting from the production of the wood building materials were fully used in energy supply systems. The carbon mitigation efficiency, expressed in terms of biomass used per unit of reduced carbon emission, is considerably better if the wood is used to replace concrete building material than if the wood is used directly as biofuel.     

面向2035的节能与新能源汽车全生命周期碳排放预测评价

发展节能与新能源汽车是降低交通运输行业碳排放的重要技术路径.为量化预测节能与新能源汽车的全生命周期碳排放,利用全生命周期评价方法,以汽车相关技术路线和政策为参考,选取燃油经济性、整车轻量化水平、电力结构碳排放因子和氢能碳排放因子为关键参数,构建传统燃油汽车(ICEV)、轻度混合动力汽车(MHEV)、重度混合动力汽车(HEV)、纯电动汽车(BEV)和燃料电池汽车(FCV)的数据清单并对其全生命周期碳排放进行量化预测评价,对电力结构碳排放因子和不同制氢方式碳排放因子进行了敏感性分析和讨论.结果发现,2022年ICEV、 MHEV、 HEV、 BEV和FCV的全生命周期碳排放量(以CO₂-eq计)分别为208.0、 195.5、 150.0、 113.5和205.0 g·km^-1.到2035年,BEV和FCV相比于ICEV具有较为显著的减碳效益,分别降低69.1%和49.3%.电力结构的碳排放因子对BEV的全生命周期碳排放的影响最显著.关于燃料电池汽车的不同制氢方式,短期应以工业副产氢提纯为主供应FCV氢能需求,长期以可再生能源电解水制氢和化石能源...     

Full accounting of the greenhouse gas budget in the forestry of China

Forest management to increase carbon (C) sinks and reduce C emissions and forest resource utilization to store C and substitute for fossil fuel have been identified as attractive mitigation strategies. However, the greenhouse gas (GHG) budget of carbon pools and sinks in China are not fully understood, and the forestry net C sink must be determined. The objective of this study was to analyze potential forest management mitigation strategies by evaluating the GHG emissions from forest management and resource utilization and clarify the forestry net C sink, and its driving factors in China via constructing C accounting and net mitigation of forestry methodology. The results indicated that the GHG emissions under forest management and resource utilization were 17.7 Tg Ce/year and offset 8.5% of biomass and products C sink and GHG mitigation from substitution effects from 2000 to 2014, resulting in a net C sink of 189.8 Tg Ce/year. Forest resource utilization contributed the most to the national forestry GHG emissions, whereas the main driving factor underlying regional GHG emissions varied. Afforestation dominated the GHG emissions in the southwest and northwest, whereas resource utilization contributed the most to GHG emissions in the north, northeast, east, and south. Furthermore, decreased wood production, improved product use efficiency, and forests developed for bioenergy represented important mitigation strategies and should be targeted implementation in different regions. Our study provided a forestry C accounting in China and indicated that simulations of these activities could provide novel insights for mitigation strategies and have implications for forest management in other countries.     

Climate change mitigation strategies in the forest sector: biophysical impacts and economic implications in British Columbia,Canada

Managing forests to increase carbon sequestration or reduce carbon emissions and using wood products and bioenergy to store carbon and substitute for other emission-intensive products and fossil fuel energy have been considered effective ways to tackle climate change in many countries and regions. The objective of this study is to examine the climate change mitigation potential of the forest sector by developing and assessing potential mitigation strategies and portfolios with various goals in British Columbia (BC), Canada. From a systems perspective, mitigation potentials of five individual strategies and their combinations were examined with regionally differentiated implementations of changes. We also calculated cost curves for the strategies and explored socio-economic impacts using an input-output model. Our results showed a wide range of mitigation potentials and that both the magnitude and the timing of mitigation varied across strategies. The greatest mitigation potential was achieved by improving the harvest utilization, shifting the commodity mix to longer-lived wood products, and using harvest residues for bioenergy. The highest cumulative mitigation of 421 MtCO₂e for BC was estimated when employing the strategy portfolio that maximized domestic mitigation during 2017–2050, and this would contribute 35% of BC’s greenhouse gas emission reduction target by 2050 at less than $100/tCO₂e and provide additional socio-economic benefits. This case study demonstrated the application of an integrated systems approach that tracks carbon stock changes and emissions in forest ecosystems, harvested wood products (HWPs), and the avoidance of emissions through the use of HWPs and is therefore applicable to other countries and regions.     

氢燃料电池汽车动力系统生命周期评价及关键参数对比

发展氢燃料电池汽车被认为是解决能源安全和环境污染问题的理想解决方案之一,为量化探究氢燃料电池汽车动力系统的化石能源消耗和排放情况,运用GaBi软件建模,以新能源汽车相关技术路线为参考,构建我国氢燃料电池汽车动力系统的数据清单并对其全生命周期化石能源消耗和全球变暖潜值情况进行定量评价计算和预测分析,对不同类型的双极板、不同能量控制策略和不同制氢方式对环境的影响分别进行了对比研究,并对关键数据进行了不确定分析.结果表明,预计到2030年我国每台氢燃料电池汽车动力系统生命周期的化石能源消耗量（ADP_f）、全球变暖潜值（GWP,以CO₂ eq计）和酸化潜值（AP,以SO₂ eq计）分别为1.35×10⁵ MJ、9108 kg和15.79 kg.动力系统生产制造阶段的化石能源消耗和全球变暖潜值均高于使用阶段,主要原因是燃料电池堆栈和储氢罐的制造过程.金属双极板、石墨复合双极板和石墨双极板的制造工艺中石墨复合双极板的综合环境效益最好.能量控制策略的优化会使得氢能消耗降低,当氢能消耗降低22.8%时,动力系统的生命周期化石能源消耗和全球变暖潜值分别降低10.4%和8.3%.相比于甲烷蒸气重整制氢,基于混合电网电解水制氢的动力系统生命周期全球变暖潜值高出53.7%[KG-*6],而基于水电电解水制氢降低39.6%.降低动力系统生命周期化石能源消耗和全球变暖潜值的措施包括优化能量控制策略降低氢能消耗、规模化发展可再生能源发电电解水制氢产业和聚焦突破燃料电池堆栈关键技术实现性能提升.     

The contribution of the paper cycle to global warming

Worldwide, paper production is a major industry that contributes about 3 percent of Gross World Product. The paper cycle involves a broad range of natural resource and environmental impacts because fiber supply relies on trees, paper manufacturing requires fuel inputs, and paper waste disposal can contribute to emissions of the potent greenhouse gas (GHG), methane (CH₄). In some countries, the paper cycle may be seen as a net sink for GHG because of reliance on renewable wood by-products and the maintenance of forest plantations. On a worldwide basis, however, this study demonstrates that the paper cycle is a significant contributor to GHG emissions, adding emissions at least comparable in magnitude to that of Australia each year. The estimated global warming contribution of paper in landfills is estimated to be similar to that of paper manufacturing processes, on a heating-equivalent basis. In some temperate regions, original old-growth forests are still harvested to supply pulpwood, resulting in a significant loss of carbon (C) storage. In theory, the paper cycle holds the promise of achieving zero net emissions if pulpwood production, consumption and disposal are carefully managed. In practice, even stabilization of emissions at current levels would be challenging and entail changes comparable to a 20 percent reduction in CH₄ generation from landfilled paper, and a 2.5 percent annual increase in plantation establishment would be needed to offset the projected increase in emissions from paper manufacturing.     

中国氢燃料电池车燃料生命周期的化石能源消耗和CO2排放

氢燃料电池车(FCV)具有运行阶段高能效和零排放的优点,近年来得到快速的商业化发展.氢能生产具有多种技术路径,不同路径的能源和环境效益存在显著差异.本研究采用生命周期评价方法,运用GREET模型对不同氢燃料路径下的FCV燃料周期(WTW)的化石能源消耗和CO_2排放进行了全面评价.选取了多种制氢路径作为评价对象,建立了中国本地化的FCV燃料生命周期数据库,在此基础上分析了FCV相对传统汽油车的WTW节能减排效益,并和混合动力车和纯电动车进行比较.结果表明,使用可再生电力和生物质等绿色能源制氢供应FCV能取得显著的WTW节能减排效益,可削减约90%的化石能耗和CO_2排放.在发展相对成熟的传统能源制氢路径中,以焦炉煤气制得氢气为原料的FCV,能产生显著的节能减排效益,其化石能耗低于混合动力车,CO_2排放低于混合动力车和纯电动车.结合对资源储备和技术成熟度的考虑,我国在发展氢能及FCV过程中,近期可考虑利用焦炉煤气等工业副产物制氢,并且规划中远期的绿色制氢技术发展.     

Impacts of international trade on carbon flows of forest industry in Finland

Finland is a forested country with a large export oriented forest industry. In addition to domestic forest extraction, roundwood is imported, thus displacing the environmental impacts of harvests. In this paper, we analyse the international carbon flows of forest industries in Finland from a consumption-based perspective. Quantitative analyses are available on trade embedded emissions of CO₂ from fossil fuel combustion, and here we address in a similar way the impact of trade on the carbon budget of the forest products sector in Finland. Carbon flows through the forest industry system increased substantially between 1991 and 2005. We show that the annual carbon balance related to forests and forest industry system in Finland functioned as a sink in 1991, whereas in 2005 the system was a sink on a national level, but not on a global level. Through calculating the carbon content in traded forest industry products and emissions embodied in forest industry activities, we further show that the direct impacts of the forest industry in Finland are only a minor fraction of the total CO₂ emissions related to Finnish production. Nearly all of the emissions were caused due to production of exports. Yet, direct carbon dioxide emissions of the industrial production are reported to Finland in the production based inventories.     

Life cycle emissions of greenhouse gases associated with burning animal wastes in countries of the European Union

Burning animal wastes for the production of electricity is stimulated in the European Union because of the ‘climate neutrality’ of its life cycle. In doing so fossil fuel inputs in animal husbandry and the N₂O and CH₄ emissions associated with animal husbandry are neglected. Here types of relatively fossil fuel efficient animal husbandry in the European Union are analysed without neglecting such inputs and emissions. The burning of pig derived animal meal, a single-output process, was found to be associated with an emission of greenhouse gases equivalent to 33 × 10²–44 × 10² g CO₂/kilowatt-hour (kWh). In most cases, however, animal wastes can be viewed as outputs from a multi-output production process. If system expansion is not possible, one may allocate multi-output process emissions on the basis of financial value or on a physical basis. Allocating on the basis of energy content of outputs of animal husbandry the burning of manure from poultry, dairy cows and pigs was estimated to generate between 6.3 × 10² and 19.5 × 10² g CO₂ equivalent per kWh. When allocating on the basis of financial value, burning manure in the Netherlands corresponds with net-sequestration, as the monetary value of manure is negative. For chicken manure a net sequestration was found of 2.5 × 10²–3.9 × 10² g CO₂ equivalent/kWh. Thus life cycle emissions of burning animal waste are extremely sensitive to the allocation principle favoured. One may extend the life cycle for instance by including indirect effects such as the substitution of carbon that is lost to agriculture due to burning animal wastes. Such an extension may well lead to a changed emission in terms of CO₂ equivalent emitted per kWh.     

Greenhouse gas balances of molasses based ethanol in Nepal

This paper evaluates life cycle greenhouse gas (GHG) balances in production and use of molasses-based ethanol (EtOH) in Nepal. The total life cycle emissions of EtOH is estimated at 432.5 kgCO_2eq m⁻³ ethanol (i.e. 20.4 gCO_2eq MJ⁻¹). Avoided emissions are 76.6% when conventional gasoline is replaced by molasses derived ethanol. A sensitivity analysis was performed to verify the impact of variations in material and energy flows, and allocation ratios in the GHG balances. Market prices of sugar and molasses, amount of nitrogen-fertilizers used in sugarcane production, and sugarcane yield per hectare turn out to be important parameters for the GHG balances estimation. Sales of the surplus electricity derived from bagasse could reduce emissions by replacing electricity produced in diesel power plants. Scenario analysis on two wastewater processes for treatment of effluents obtained from ethanol conversion has also been carried out. If wastewater generated from ethanol conversion unit is treated in pond stabilization (PS) treatment process, GHG emissions alarmingly increase to a level of 4032 kgCO_2eq m⁻³ ethanol. Results also show that the anaerobic digestion process (ADP) and biogas recovery without leakages can significantly avoid GHG emissions, and improve the overall emissions balance of EtOH in Nepal. At a 10% biogas leakage, life cycle emissions is 1038 kgCO_2eq m⁻³ ethanol which corresponds to 44% avoided emissions compared to gasoline. On the other hand, total emissions surpass the level of its counterpart (i.e. gasoline) when the leakage of biogas exceeds 23.4%.     

Atmospheric impacts of the life cycle emissions of fuel ethanol in Brazil: based on chemical exergy

An assessment is made of the atmospheric emissions from the life cycle of fuel ethanol coupled with the cogeneration of electricity from sugarcane in Brazil. The total exergy loss from the most quantitative relevant atmospheric emission substances produced by the life cycle of fuel ethanol is 3.26E+05 kJ/t of C₂H₅OH. Compared with the chemical exergy of 1 t of ethanol (calculated as 34.56E+06 kJ), the exergy loss from the life cycle's atmospheric emission represents 1.11% of the product's exergy. The activity that most contributes to atmospheric emission chemical exergy losses is the harvesting of sugarcane through the methane emitted in burning. Suggestions for improved environmental quality and greater efficiency of the life cycle of fuel ethanol with cogenerated energy are: harvesting the sugarcane without burning, renewable fuels should be used in tractors, trucks and buses instead of fossil fuel and the transportation of products and input should be logistically optimized.