Biosorption of colours is an important technology for treatment of different types of industrial wastewaters containing dyes. The objective of this study was to convert green alga Ulva lactuca to dye adsorbents for wastewater treatment. The importance of commonly available green alga Ulva lactuca was investigated as viable biomaterials for the biological treatment of synthetic basic blue 9 (5-ch1oro-N,N,N',N'-tetramethyl-5λ4-phenothiazine-3,7-diamine) effluents. The results obtained from the batch experiments revealed the ability of the green algae to remove the basic blue 9, and this was dependent on the dye concentration, pH, and algal biomass. We investigated the equilibrium and kinetics of adsorption, and the Langmuir and Freundlich equations were used to fit the equilibrium isotherm. The adsorption isotherm of basic blue 9 followed both the Langmuir and Freundlich models with a correlation coefficient of ∼0.96-0.99, and the adsorption kinetics followed the pseudo-second-order model (R2=1.0). The maximum adsorption capacity was about 40.2 mg of dye per gram of dry green algae at pH 10, 25 g l-1 dye and 2.5 g l-1 alga concentrations. This study demonstrated that the green algae could be used as an effective biosorbent for the treatment of dye-containing wastewater streams. 相似文献
One of the criteria used by the International Union for Conservation of Nature (IUCN) to assess threat status is the rate of decline in abundance over 3 generations or 10 years, whichever is longer. The traditional method for calculating generation length (T) uses age‐specific survival and fecundity, but these data are rarely available. Consequently, proxies that require less information are often used, which introduces potential biases. The IUCN recommends 2 proxies based on adult mortality rate, = α + 1/d, and reproductive life span, = α + z*RL, where α is age at first reproduction, d is adult mortality rate, RL is reproductive life span, and z is a coefficient derived from data for comparable species. We used published life tables for 78 animal and plant populations to evaluate precision and bias of these proxies by comparing and with true generation length. Mean error rates in estimating T were 31% for and 20% for , but error rates for were 16% when we subtracted 1 year ( ), as suggested by theory; also provided largely unbiased estimates regardless of the true generation length. Performance of depends on compilation of detailed data for comparable species, but our results suggest taxonomy is not a reliable indicator of comparability. All 3 proxies depend heavily on a reliable estimate of age at first reproduction, as we illustrated with 2 test species. The relatively large mean errors for all proxies emphasized the importance of collecting the detailed life‐history information necessary to calculate true generation length. Unfortunately, publication of such data is less common than it was decades ago. We identified generic patterns of age‐specific change in vital rates that can be used to predict expected patterns of bias from applying . 相似文献
In this study, FeVO4 was prepared and used as Fenton-like catalyst to degrade orange G (OG) dye. The removal of OG in an aqueous solution containing 0.5 g·L–1 FeVO4 and 15 mmol·L–1 hydrogen peroxide at pH 7.0 reached 93.2%. Similar rates were achieved at pH 5.7 (k = 0.0471 min–1), pH 7.0 (k = 0.0438 min–1), and pH 7.7 (k = 0.0434 min–1). The FeVO4 catalyst successfully overcomes the problem faced in the heterogeneous Fenton process, i.e., the narrow working pH range. The data for the removal of OG in FeVO4 systems containing H2O2 conform to the Langmuir–Hinshelwood model (R2 = 0.9988), indicating that adsorption and surface reaction are the two basic mechanisms for OG removal in the FeVO4–H2O2 system. Furthermore, the irradiation of FeVO4 by visible light significantly increases the degradation rate of OG, which is attributed to the enhanced rates of the iron cycles and vanadium cycles.
The quantification and effects of system pH value on the interactions between Pb(II) and the biopolymer in activated sludge were investigated. The biopolymer had two protein-like fluorescence peaks (Ex/Em = 280 nm/326–338 nm for peak A; Ex/Em = 220–230 nm/324–338 nm for peak B). The fluorescence intensities of peak B were higher than those of peak A. The fluorophores of both peaks could be largely quenched by Pb(II), and the quencher dose for peak B was about half of that for peak A. The modified Stern-Volmer equation well depicted the fluorescence quenching titration. The quenching constant (Ka) values for both peaks decreased with rising system pH value, and then sharply decreased under alkaline conditions. It could be attributed to that the alkaline conditions caused the reduction of available Pb(II) due to the occurrence of Pb(OH)2 sediments. The Ka values of peak B were bigger than those for peak A at the same system pH values. Accordingly, the aromatic proteins (peak B) played a key role in the interactions between metal ions and the biopolymer.
Two strains of Bacillus sp. resistant to arsenate and lead designated as AsSP9 and PbSP6, respectively were isolated from the slag disposal site. They were identified to be related to Bacillus cereus cluster on the basis of 16S rDNA based sequence analysis and phenotypic characteristics. Both were rod-shaped (AsSP9, 2-5 microm and PbSP6, 2-4 microm), aerobic, salt tolerant (2-8% NaCI), endospore forming bacteria with minor differences like the AsSP9 showed sporangial bulging and PbSP6 had positive lipase activity. The temperature range for their growth was 20-40 degrees C and pH range 6.0-9.0 with an optimum temperature of 37 degrees C and pH of 7 for both strains. The principal nitrogen sources forAsSP9 and PbSP6 were DL-Tryptophan and L-Phenylalanine, respectively. The suitable carbon source forAsSP9 was lactose and for PbSP6 sucrose. The heavy metal accumulation efficiency was found to be 0.0047 mg g(-1) of dry mass forAsSP9 and 0.686 mg g(-1) of dry mass for PbSP6. 相似文献
The isolation procedure of the seed proteins of Amaranthus blitum have been analyzed at different pH conditions. Qualitative studies were carried out by using electrophoretic technique sodium dodecyl sulphate polyacrylamide gel electrophoresis (SDS-PAGE). Mainly four protein fractions i.e. albumin, globulin, prolamin and glutelin were obtained. Protein isolates were prepared by (a) extraction at different alkaline pH (9, 10, 11 and 12) and precipitation atpH 5 and (b) extraction at pH 9 and precipitation atdifferentpH (4, 5, 6 and 7). The composition of isolates, prepared by method (a), depended on extraction pH. The isolate extracted at pH 8 was mainly composed of albumin and globulin, whereas at pH 9, 10 and 11 showed the presence of prolamin and glutelin. Electrophoretic pattern of different isolates had five major bands with molecular weight of 30, 45, 72, 84 and 90 kDt respectively. The increase of the extraction pH led to the increase in protein yield. With method (b) isolates obtained were variable in composition. At pH 7 albumin and prolamine were present, whereas at pH 4, 5 and 6 all 4 protein fractions were precipitated. According to the quantitative estimation of the albumin, globulin, prolamin and glutelin in the seed flour the contents were 26.4, 25, 5.81 and 42.7%, respectively. The results suggest that composition of protein isolates could be controlled by different extraction and precipitation pH. 相似文献
