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处理重金属废水的传统方法在投资和运行费用上都较高,加之沉淀去除效果不太理想,近年来国内外进行了大量的生化法去除重金属的研究。本文介绍了生物吸附法、生物絮凝法、微生物代谢法和植物吸收法。生化法处理重金属废水,成本低,效益高,易管理,可回收重金属,有利于生态环境的改善,具有十分广阔的应用前号。 相似文献
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有机溶剂回收技术的研究 总被引:3,自引:0,他引:3
本文对有机溶剂的回收方法,如吸附法、吸收法、冷凝法和膜分离法等的研究进展与应用进行了综述。其中,吸附法在工业上的应用最为广泛,本文着重介绍了吸附法的工艺以及吸附剂的研究。而膜分离法作为最有发展前景的一种回收方法,主要问题为提高膜的通量和选择性。 相似文献
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本文对所得税会计处理方法——应付税款法、递延法、损益表债务法和资产负债表债务法进行比较,借此总结分析了资产负债表债务法的优势;指出我国所得税会计采用资产负债表债务法的现实意义:第一,内容上更加规范;第二,真正确立了会计利润与应税所得的适当分离。最后对我国的处理方法提出一些建议。 相似文献
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以最大信息熵原理为理论基础的熵法估参方法,是一种具有严格物理和数学意义的新型参数估计方法,本文针对珠江广州河段主要污染物含量长年监测数据,对比熵法与传统方法矩法对四参数Г分布的估参结果,并以频率绝对离盖和最小为准则进行判定,结果表明,熵法估参结果与矩法总体上相当接近,且大部分样本的熵法估计参数优于矩法,在环境监测数据频率分析中具有实用性和推广价值。 相似文献
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J. William Carey Robert Svec Reid Grigg Jinsuo Zhang Walter Crow 《International Journal of Greenhouse Gas Control》2010,4(2):272-282
Wellbore integrity is one of the key performance criteria in the geological storage of CO2. It is significant in any proposed storage site but may be critical to the suitability of depleted oil and gas reservoirs that may have 10’s to 1000’s of abandoned wells. Much previous work has focused on Portland cement which is the primary material used to seal wellbore systems. This work has emphasized the potential dissolution of Portland cement. However, an increasing number of field studies (e.g., Carey et al., 2007), experimental studies (e.g., Kutchko et al., 2006) and theoretical considerations indicate that the most significant leakage mechanism is likely to be flow of CO2 along the casing–cement microannulus, cement–cement fractures, or the cement–caprock interface.In this study, we investigate the casing–cement microannulus through core-flood experiments. The experiments were conducted on a synthetic wellbore system consisting of a 5-cm diameter sample of cement that was cured with an embedded rectangular length of steel casing that had grooves to accommodate fluid flow. The experiments were conducted at 40 C and 14 MPa pore pressure for 394 h. During the experiment, 6.2 l of a 50:50 mixture of supercritical CO2 and 30,000 ppm NaCl-rich brine flowed through 10-cm of limestone before flowing through the 6-cm length cement–casing wellbore system. Approximately 59,000 pore volumes of fluid moved through the casing–cement grooves. Scanning electron microscopy revealed that the CO2–brine mixture impacted both the casing and the cement. The Portland cement was carbonated to depths of 50–250 m by a diffusion-dominated process. There was very little evidence for mass loss or erosion of the Portland cement. By contrast, the steel casing reacted to form abundant precipitates of mixed calcium and iron carbonate that lined the channels and in one case almost completely filled a channel. The depth of steel corroded was estimated at 25– m and was similar in value to results obtained with a simplified corrosion model.The experimental results were applied to field observations of carbonated wellbore cement by Carey et al. (2007) and Crow et al. (2009) to show that carbonation of the field samples was not accompanied by significant CO2–brine flow at the casing–cement interface. The sensitivity of standard-grade steel casing to corrosion suggests that relatively straight-forward wireline logging of external casing corrosion could be used as a useful indicator of flow behind casing. These experiments also reinforce other studies that indicate rates of Portland cement deterioration are slow, even in the high-flux CO2–brine experiments reported here. 相似文献
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Luke Flores Ryan T. Bailey Catherine Kraeger‐Rovey 《Journal of the American Water Resources Association》2020,56(2):310-322
When the cone of influence of a pumping well reaches a nearby river, the resulting hydraulic gradient can induce enhanced seepage of streamflow into the aquifer. The rate of seepage is often modeled using analytical solutions that are simple to apply but may not reproduce field data due to mathematical assumptions not being met in the field. Furthermore, the appropriateness of such models has not been investigated in detail due to difficulty in measuring streamflow loss in the field. In this study, a field experiment was conducted on a reach of the South Platte River near Denver, Colorado to estimate pumping‐induced streamflow loss. A network of stream gauges, monitoring wells, and in situ measurements was used to observe streamflow rates, groundwater levels, and temperature to assess if pumping wells have a significant impact on streamflow, and to compare observed streamflow depletion against analytical solutions. Data collected suggest that pumping wells have a noticeable impact on streamflow. The analytical solutions proved accurate if streamflow was low and constant but performed poorly if streamflow was high and variable. Therefore, for this reach, the use of analytical solutions to predict streamflow may only be appropriate under low‐flow, constant‐flow conditions. Methods and results can be used to guide other streamflow depletion studies and to inform cases of pumping‐induced streamflow depletion, particularly in regard to water rights. 相似文献
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Timothy B. Spruill 《Journal of the American Water Resources Association》1983,19(6):977-981
ABSTRACT: Data from 54 well in central and eastern Kansas developed in unconsolidated deposits of Quaternary age indicate that nitrate concentrations are inversely related to the depth of the well screen opening below the water level in the well casing because this relationship was found to exist in an area of Nebraska and in a large area of Kansas, the relationship is generally valid over a wide geo- graphical area. In addition, the data indicate that the incidence of nitrate concentrations exceeding 45 milligrams per liter and nitrate concentrations, in general, are significantly lower in water from wells with screens deeper than 25 feet below the water table in unconfined aquifers or where screens are placed in deep confined aquifers. No concentrations of nitrate greater than 45 milligrams per liter were in obseved wells where screens were deeper than 60 feet below the casing water level. These findings suggest that general placement of well screens as far below the water table as possible in unconfined unconsolidated aquifers in Kansas. and possibly other areas of the Midwest, may be an effective measure in preventing undesirable nitrate concentrations in ground water supplies. particularly in areas where nitrate is a problem. 相似文献
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V. Barlet-Gouédard G. Rimmelé O. Porcherie N. Quisel J. Desroches 《International Journal of Greenhouse Gas Control》2009,3(2):206-216
Capturing and storing carbon dioxide (CO2) underground for thousands of years is one way to reduce atmospheric greenhouse gases, often associated with global warming. Leakage through wells is one of the major issues when storing CO2 in depleted oil or gas reservoirs. CO2-injection candidates may be new wells, or old wells that are active, closed or abandoned. In all cases, it is critical to ensure that the long-term integrity of the storage wells is not compromised. The loss of well integrity may often be explained by the geochemical alteration of hydrated cement that is used to isolate the annulus across the producing/injection intervals in CO2-related wells. However, even before any chemical degradation, changes in downhole conditions due to supercritical CO2 injections can also be responsible for cement debonding from the casing and/or from the formation, leading to rapid CO2 leakage. A new cement with better CO2 resistance is compared with conventional cement using experimental procedure and methodology simulating the interaction of set cement with injected, supercritical CO2 under downhole conditions. Geochemical experimental data and a mechanical modeling approach are presented. The use of adding expanding property to this new cement to avoid microannulus development during the CO2 injection is discussed. 相似文献
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Anwar Battikhi Don Kirkham 《Journal of the American Water Resources Association》1979,15(4):1004-1015
ABSTRACT: A mathematical solution based on porous media flow is developed for solute travel time to a well as affected by a leak around the upper part of the casing. Consider a well of radius 0.2 meters (m) penetrating, fully, a semiconfined aquifer of thickness 6 m with impermeable casing length of 4.5 m, and screened casing length 1.5 m. Around the upper 1.5 m of the impermeable casing length, there is a highly permeable region (a leak). The radius of influence of the well is 10 m. The porous flow medium has a hydraulic conductivity of 10 m/day and a porosity of 0.25. Between the water table and the water level in the well, there is a steady state pumped down head difference of 0.3 m. Solute travel time from a point at the bottom of the leak to the well is 2.33 days. If the leak is sealed (grouted), the travel time is 6.24 days. Examples of six different geometries are given. Laboratory studies verify the theory. The computations should be useful in the design and protection of water wells from solutes, such as from agriculture, industry, strip mines, or sanitary landfills. 相似文献
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Garey A. Fox 《Journal of the American Water Resources Association》2004,40(3):755-763
ABSTRACT: Considerable advancements have been made in the development of analytical solutions for predicting the effects of pumping wells on adjacent streams and rivers. However, these solutions have not been sufficiently evaluated against field data. The objective of this research is to evaluate the predictive performance of recently proposed analytical solutions for unsteady stream depletion using field data collected during a stream/aquifer analysis test at the Tamarack State Wildlife Area in eastern Colorado. Two primary stream/aquifer interactions exist at the Tamarack site: (1) between the South Platte River and the alluvial aquifer and (2) between a backwater stream and the alluvial aquifer. A pumping test is performed next to the backwater stream channel. Drawdown measured in observation wells is matched to predictions by recently proposed analytical solutions to derive estimates of aquifer and streambed parameters. These estimates are compared to documented aquifer properties and field measured streambed conductivity. The analytical solutions are capable of estimating reasonable values of both aquifer and streambed parameters with one solution capable of simultaneously estimating delayed aquifer yield and stream flow recharge. However, for long term water management, it is reasonable to use simplified analytical solutions not concerned with early‐time delayed yield effects. For this site, changes in the water level in the stream during the test and a varying water level profile at the beginning of the pumping test influence the application of the analytical solutions. 相似文献
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Wayne W. Lapham Michael J. Moran John S. Zogorski 《Journal of the American Water Resources Association》2000,36(6):1321-1334
ABSTRACT: The U.S. Geological Survey (USGS) has compiled a national retrospective data set of analyses of volatile organic compounds (VOCs) in ground water of the United States. The data are from Federal, State, and local nonpoint‐source monitoring programs, collected between 1985–95. This data set is being used to augment data collected by the USGS National Water‐Quality Assessment (NAWQA) Program to ascertain the occurrence of VOCs in ground water nationwide. Eleven attributes of the retrospective data set were evaluated to determine the suitability of the data to augment NAWQA data in answering occurrence questions of varying complexity. These 11 attributes are the VOC analyte list and the associated reporting levels for each VOC, well type, well‐casing material, type of openings in the interval (screened interval or open hole), well depth, depth to the top and bottom of the open interval(s), depth to water level in the well, aquifer type (confined or unconfined), and aquifer lithology. VOCs frequently analyzed included solvents, industrial reagents, and refrigerants, but other VOCs of current interest were not frequently analyzed. About 70 percent of the sampled wells have the type of well documented in the data set, and about 74 percent have well depth documented. However, the data set generally lacks documentation of other characteristics, such as well‐casing material, information about the screened or open interval(s), depth to water level in the well, and aquifer type and lithology. For example, only about 20 percent of the wells include information on depth to water level in the well and only about 14 percent of the wells include information about aquifer type. The three most important enhancements to VOC data collected in nonpoint‐source monitoring programs for use in a national assessment of VOC occurrence in ground water would be an expanded VOC analyte list, recording the reporting level for each analyte for every analysis, and recording key ancillary information about each well. These enhancements would greatly increase the usefulness of VOC data in addressing complex occurrence questions, such as those that seek to explain the reasons for VOC occurrence and nonoccurrence in ground water of the United States. 相似文献
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ABSTRACT: Results of computer calculations are presented which predict the pressure response of a closed casing annulus of an injection well to temperature and pressure variations of the injected waste stream. For example, a 3000 ft. disposal well receiving fluid at 100d̀F might cause an increase in annular pressure of some 500 psi. Graphs summarizing these results are included. The results will be of interest to waste injection well operators, inasmuch as they are required to monitor annulus pressure to prove mechanical integrity of their injection wells. 相似文献