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1.
One of the techniques used to dispose of 4,000 tons per day (TPD) of non‐recyclable waste from Tehran is to burn it as an alternative fuel in cement kilns. This practice reduces emissions from landfills, prevents the loss of waste energy, and conserves fossil fuel resources. The aim of our study was to conduct a life cycle assessment (LCA) of clinker production in cement kilns using a combination of natural gas, mazut, a form of heavy, low‐quality fuel oil, and refuse‐derived fuel (RDF) from Tehran. We used SimaPro 7.1 software to perform an LCA of 1 kilogram (kg) of clinker produced using the following fuel combinations: the first scenario involved natural gas consumption alone, the second scenario involved a combination of natural gas and mazut, with the mazut providing 5% to 30% of the heating value needed to produce cement clinker in the kiln, and the third scenario involved a combination of natural gas and RDF (providing 5% to 30% of the heating needed in the kiln). The impact categories in the LCA of global warming, eutrophication, and acidification were assessed by the Center of Environmental Science of Leiden University (Centrum voor Milieukunde Leiden—CML) CML 2000 method. The results indicated that the third scenario, involving natural gas and RDF, reduced acidification by 2.14–11.5% and global warming by 0–1.3% relative to the first scenario involving the use of only natural gas. In addition, we observed a 0.65–3.81% reduction in acidification and a 0.9–3.8% reduction in global warming under the third scenario compared with the second scenario (co‐firing of natural gas and mazut). The amount of nitrogen oxides (NOX) emitted from the combustion of the Tehran RDF was greater than that was emitted when burning mazut. Therefore, reduction of nitrogen from the RDF composition is necessary. This study indicates that the use of Tehran RDF (with reduced nitrogen) in Tehran cement kilns does not increase cement kiln NOX, sulfur dioxide (SO2), and carbon dioxide (CO2) emissions; however, we need to conduct additional investigation into the chemical composition of the Tehran waste before using solid waste in place of fossil fuels.  相似文献   

2.
Alternative scenarios to meet the demands of sustainable waste management   总被引:1,自引:0,他引:1  
This paper analyses different alternatives for solid waste management that can be implemented to enable the targets required by the European Landfill and Packaging and Packaging Waste Directives to be achieved in the Valencian Community, on the east coast of Spain. The methodology applied to evaluate the environmental performance of each alternative is Life Cycle Assessment (LCA). The analysis has been performed at two levels; first, the emissions accounted for in the inventory stage have been arranged into impact categories to obtain an indicator for each category; and secondly, the weighting of environmental data to a single unit has been applied. Despite quantitative differences between the results obtained with four alternative impact assessment methods, the same preference ranking has been established: scenarios with energy recovery (1v and 2v) achieve major improvements compared to baseline, with scenario 1v being better than 2v for all impact assessment methods except for the EPS'00 method, which obtains better results for scenario 2v. Sensitivity analysis has been used to test some of the assumptions used in the initial life cycle inventory model but none have a significant effect on the overall results. As a result, the best alternative to the existing waste management system can be identified.  相似文献   

3.
Municipal solid waste (MSW) disposal and management is one of the most significant challenges faced by urban communities around the world. Municipal solid waste management (MSWM) over the years has utilized many sophisticated technologies and smart strategies. Municipalities worldwide have pursued numerous initiatives to reduce the environmental burden of the MSW treatment strategies. One of the most beneficial MSWM strategies is the thermal treatment or energy recovery to obtain cleaner renewable energy from waste. Among many waste-to-energy strategies, refuse-derived fuel (RDF) is a solid recovered fuel that can be used as a substitute for conventional fossil fuel. The scope of this study is to investigate the feasibility of RDF production with MSW generated in Metro Vancouver, for co-processing in two cement kilns in the region. This study investigates environmental impacts and benefits and economic costs and profits of RDF production. In addition, RDF utilization as an alternative fuel in cement kilns has been assessed. Cement manufacturing has been selected as one of the most environmentally challenged industries and as a potential destination for RDF to replace a portion of conventional fossil fuels with less energy-intensive fuel. A comprehensive environmental assessment is conducted using a life cycle assessment (LCA) approach. In addition, cost–benefit analysis (CBA) has been carried out to study the economic factors. This research confirmed that RDF production and use in cement kilns can be environmentally and economically viable solution for Metro Vancouver.  相似文献   

4.
Life cycle assessment (LCA) offers a comprehensive approach to evaluate and improve the environmental impacts of pavements. First, a general pavement LCA methodology is created that describes the concepts necessary to conduct a comprehensive pavement LCA. Second, the methodology is applied to the life cycle of concrete pavements to quantify current emissions across the road network. System boundaries are drawn to include all phases of the pavement life cycle – materials production, construction, use, maintenance, and end of life. Greenhouse gas emissions are quantified for twelve functional units, which evaluate average conditions for each major roadway classification in the United States. The results present the relative contribution of each component in the life cycle, the annual emissions occurring during the 40-year analysis period, and the sensitivity of these results to model parameters. It is found for all roads that the majority of emissions occur in year one – from cradle-to-gate materials production, and pavement construction – primarily due to cement production. The results are most sensitive to traffic volume, and then to parameters affecting the cement production. Based on emissions and their sensitivity, the LCA results suggest three broad reduction approaches: reducing embodied emissions, reducing use phase emissions, and reducing end-of-life emissions.  相似文献   

5.
Volcanic soil can be used to remove metals from wastewaters. Once used, it is disposed in landfills. The utilization of this material in the cement industry as an alternative raw material was evaluated using life cycle assessment (LCA) methodology. This possibility has been studied from an environmental point of view in a Chilean cement facility, representative of the current operation state of art, including both technical and economic analysis. Two scenarios were compared: Scenario 1, which corresponds to the existing cement production process, and Scenario 2, which represents cement production using spent volcanic soil. With the exception of the categories of carcinogens (C) and minerals (M), the comparative results are favourable to Scenario 2, specially regarding to the category of ecotoxicity (E), mainly due to the avoided landfilling emissions of the volcanic soil. When considering the damage assessment, damage to human health (HH), ecosystem quality (EQ) and resources (R) are lower in Scenario 2. In addition, sensitivity analyses were performed to study the influence of particular parameters (i.e., transport of spent volcanic soil, CO2 emissions from the clinkerization process and heavy metals leaching from the spent volcanic soil) on the results of the assessment. The use of alternative raw materials (in this case, spent volcanic soil), which present the advantage to be wastes from other technical systems, appear to allow the development of cement production in a more sustainable way, slightly improving the economy of the process. The spent volcanic soil can be treated with zero cost for the wastewater treatment plant with savings of 0.23€ for each tonne of clinker production. Establishing a sound management way for the spent volcanic soil could foment its possible use as mineral adsorbent in industrial wastewater treatment facilities.  相似文献   

6.
In the present article, the thermal treatment of digested sewage sludge generated in the Swiss region of Zürich is modeled and optimized from an environmental perspective. The optimization problem is solved using a multi-objective mixed-integer linear program that combines material flow analysis, process models, life cycle assessment (LCA), and mathematical optimization techniques. The treatment options include co-incineration in municipal solid waste incineration, co-processing in cement production, and mono-incineration with the prospect of phosphorus recovery. The model is optimized according to six environmental objectives. Five of the six single-objective optimal solutions involve splits over the treatment options. The results reflect the available treatment capacities and other constraints, aspects rarely considered in conventional LCA studies. Co-processing in cement production is used to the maximum extent possible when minimizing impacts on climate change, human toxicity, fossil resource depletion, and fully aggregated impacts (ReCiPe H/A), whereas mono-incineration with phosphorus recovery receives the bulk of the sludge when optimizing for ecotoxicity and mineral resource depletion. Four of the single-objective optimal solutions (minimization of fossil energy resource depletion and contribution to climate change, human toxicity, and fully aggregated impacts) outperform the reference case over the six impact categories considered, showing that the current situation can be improved in some environmental categories without compromising others. The results of the sensitivity analysis indicate that assumptions regarding the product systems displaced by recovered by-products are critical for the outcome of the optimization. Our approach identifies in all of the cases solutions in which significant environmental improvements can be attained.  相似文献   

7.
Several alternatives exist for handling of individual waste fractions, including recycling, incineration and landfilling. From an environmental point of view, the latter is commonly considered as the least desirable option. Many studies based on life-cycle assessment (LCA) highlight the environmental benefits offered by incineration and especially by recycling. However, the landfilling option is often approached unjustly in these studies, maybe disregarding the remarkable technological improvements that landfills have undergone in the last decades in many parts of the world.This study, by means of LCA-modelling, aims at comparing the environmental performance of three major management options (landfilling, recycling and incineration or composting) for a number of individual waste fractions. The landfilling option is here approached comprehensively, accounting for all technical and environmental factors involved, including energy generation from landfill gas and storage of biogenic carbon. Leachate and gas emissions associated to each individual waste fraction have been estimated by means of a mathematical modelling. This approach towards landfilling emissions allows for a more precise quantification of the landfill impacts when comparing management options for selected waste fractions.Results from the life-cycle impact assessment (LCIA) show that the environmental performance estimated for landfilling with energy recovery of the fractions “organics” and “recyclable paper” is comparable with composting (for “organics”) and incineration (for “recyclable paper”). This however requires high degree of control over gas and leachate emissions, high gas collection efficiency and extensive gas utilization at the landfill. For the other waste fractions, recycling and incineration are favourable, although specific emissions of a variety of toxic compounds (VOCs, PAHs, NOx, heavy metals, etc.) may significantly worsen their environmental performance.  相似文献   

8.
The environmental impacts of food waste management strategies and the effects of energy mix were evaluated using a life cycle assessment model, EASEWASTE. Three different strategies involving landfill, composting and combined digestion and composting as core technologies were investigated. The results indicate that the landfilling of food waste has an obvious impact on global warming, although the power recovery from landfill gas counteracts some of this. Food waste composting causes serious acidification (68.0 PE) and nutrient enrichment (76.9 PE) because of NH3 and SO2 emissions during decomposition. Using compost on farmland, which can marginally reduce global warming (−1.7 PE), acidification (−0.8 PE), and ecotoxicity and human toxicity through fertilizer substitution, also leads to nutrient enrichment as neutralization of emissions from N loss (27.6 PE) and substitution (−12.8 PE). A combined digestion and composting technology lessens the effects of acidification (−12.2 PE), nutrient enrichment (−5.7 PE), and global warming (−7.9 PE) mainly because energy is recovered efficiently, which decreases emissions including SO2, Hg, NOx, and fossil CO2 during normal energy production. The change of energy mix by introducing more clean energy, which has marginal effects on the performance of composting strategy, results in apparently more loading to acidification and nutrient enrichment in the other two strategies. These are mainly because the recovered energy can avoid fewer emissions than before due to the lower background values in power generation. These results provide quantitative evidence for technical selection and pollution control in food waste management.  相似文献   

9.
Post-consumer carpet represents a high volume, high energy content waste stream. As a fuel for co-firing in cement kilns, waste carpet, like waste tires, has potential advantages. Technological challenges to be addressed include assessing potential emissions, in particular NO emissions (from nylon fiber carpets), and optimizing the carpet feed system. This paper addresses the former. Results of pilot-scale rotary kiln experiments demonstrate the potential for using post-consumer waste carpet as a fuel in cement kilns. Continuous feeding of shredded carpet fiber and ground carpet backing, at rates of up to 30% of total energy input, resulted in combustion without transient puffs and with almost no increase in CO and other products of incomplete combustion as compared to kiln firing natural gas only. NO emissions increased with carpet waste co-firing due to the nitrogen content of nylon fiber. In these experiments with shredded fiber and finely ground backing, carpet nitrogen conversion to NO ranged from 3 to 8%. Conversion increased with enhanced mixing of the carpet material and air during combustion. Carpet preparation and feeding method are controlling factors in fuel N conversion.  相似文献   

10.
Amorphous silicon (a-Si:H)-based solar cells have the lowest ecological impact of photovoltaic (PV) materials. In order to continue to improve the environmental performance of PV manufacturing using proposed industrial symbiosis techniques, this paper performs a life cycle analysis (LCA) on both conventional 1-GW scaled a-Si:H-based single junction and a-Si:H/microcrystalline-Si:H tandem cell solar PV manufacturing plants and such plants coupled to silane recycling plants. Both the energy consumed and greenhouse gas emissions are tracked in the LCA, then silane gas is reused in the manufacturing process rather than standard waste combustion. Using a recycling process that results in a silane loss of only 17% instead of conventional processing that loses 85% silane, results in an energy savings of 81,700 GJ and prevents 4400 tons of CO2 from being released into the atmosphere per year for the single junction plant. Due to the increased use of silane for the relatively thick microcrystalline-Si:H layers in the tandem junction plants, the savings are even more substantial – 290,000 GJ of energy savings and 15.6 million kg of CO2 eq. emission reductions per year. This recycling process reduces the cost of raw silane by 68%, or approximately $22.6 million per year for a 1-GW a-Si:H-based PV production facility and over $79 million per year for tandem manufacturing. The results are discussed and conclusions are drawn about the technical feasibility and environmental benefits of silane recycling in an eco-industrial park centered around a-Si:H-based PV manufacturing plants.  相似文献   

11.
In the UK, between 4 and 5% of the municipal solid waste stream is composed of clothes/textiles. Approximately 25% of this is recycled by companies such as the Salvation Army Trading Company Limited (SATCOL) who provide a collection and distribution infrastructure for ‘donated’ clothing and shoes. Textiles can be reused or undergo a processing stage and enter a recycling stream. Research was conducted in order to quantify the energy used by a reuse/recycling operation and whether this resulted in a net energy benefit. The energy footprint was quantified using a streamlined life cycle assessment (LCA), an LCA restricted in scope in order to target specific aspects of the footprint, in this case energy consumption. Taking into account extraction of resources, manufacture of materials, electricity generation, clothing collection, processing and distribution and final disposal of wastes it was demonstrated that for every kilogram of virgin cotton displaced by second hand clothing approximately 65 kWh is saved, and for every kilogram of polyester around 90 kWh is saved. Therefore, the reuse and recycling of the donated clothing results in a reduction in the environmental burden compared to purchasing new clothing made from virgin materials.  相似文献   

12.
This study presents the results of a comparative life cycle assessment (LCA) on the energy requirements and greenhouse gas (GHG) emission implications of recycling construction and demolition (C&D) rubble and container glass in Cape Town, South Africa. Cape Town is a medium sized city in a developing country with a growing population and a rising middle class, two factors that are resulting in increased generation of solid waste. The City is constrained in terms of landfill space and competing demands for municipal resources.The LCA assessment was based on locally gathered data, supplemented with ecoinvent life cycle inventory data modified to the local context. The results indicated that recycling container glass instead of landfilling can achieve an energy savings of 27% and a GHG emissions savings of 37%, with a net savings still being achieved even if collection practices are varied. The C&D waste results, however, showed net savings only for certain recycling strategies. Recycling C&D waste can avoid up to 90% of the energy and GHG emissions of landfilling when processed and reused onsite but, due to great dependence on haulage distances, a net reduction of energy use and GHG emissions could not be confidently discerned for offsite recycling. It was also found that recycling glass achieves significantly greater savings of energy and emissions than recycling an equivalent mass of C&D waste.The study demonstrated that LCA provides an important tool to inform decisions on supporting recycling activities where resources are limited. It also confirmed other researchers’ observations that strict adherence to the waste management hierarchy will not always result in the best environmental outcome, and that more nuanced analysis is required. The study found that the desirability of recycling from an energy and climate perspective cannot be predicted on the basis of whether such recycling conserves a non-renewable material. However, recycling that replaces a virgin product from an energy-intensive production process appears to be more robustly beneficial than recycling that replaces a product with little embodied energy. Particular caution is needed when applying the waste management hierarchy to the latter situations.  相似文献   

13.
Compost produced from biological treatment of organic waste has a potential for substituting peat in growth media preparation. The life-cycle-inventories (LCIs) of the two alternatives were compared using LCA-modelling (EASEWASTE) considering a 100-year period and a volumetric substitution ratio of 1:1. For the compost alternative, the composting process, growth media use, and offsetting of mineral fertilizers were considered. For the peat alternative, peatland preparation, excavation, transportation, and growth media use were considered. It was assumed that for compost 14% of the initial carbon was left in the soil after 100 years, while all carbon in peat was mineralized. With respect to greenhouse gas emissions, the former is considered a saving, while the later is considered an emission, because peat in a peatland is considered stored biogenic carbon. The leaching during the growth media use was assessed by means of batch leaching tests involving 4 compost samples and 7 peat samples. The compost leached 3–20 times more heavy metals and other compounds than the peat. The life-cycle-assessment showed that compost performs better regarding global warming (savings in the range of 70–150 kg CO2-eq. Mg−1) and nutrient enrichment (savings in the range of 1.7–6.8 kg NO3 Mg−1 compost), while peat performs better in some toxic categories, because of the lower content of heavy metals.  相似文献   

14.
Goal of the work is to present a simplified methodology to optimize an integrated solid waste management system. The methodology performs two optimizations, namely: (i) minimization of the total cost of the MSW system and (ii) minimization of the equivalent carbon dioxide emissions (CO2e) generated by the whole system. The methodology is modeled via non-linear mathematical equations, uses 32 decision variables and does not require complex LCA databases. The proposed model optimally allocates eight MSW components (paper, cardboard, plastics, metals, glass, food wastes, yard wastes and other wastes) to four MSW management technologies (incineration, composting, anaerobic digestion, and landfilling) after source separation of recyclables has taken place. The Region of East-Macedonia and Thrace in Greece was selected as a case study. Results showed that there is a trade off between cost and CO2e emissions. Incineration and composting were favored as the principal treatment technologies, while landfilling was always the least desirable management technology under both objective functions. The recycling participation rate significantly affected all optimum scenarios.  相似文献   

15.
Shredder residue is the residue from the shredding of end-of-life vehicles and white goods, after removal of the main metals. Approximately 850,000 tonnes of shredder waste is produced in the UK each year, and historically sent to landfill. Due to European legislation such as the End-of-Life Vehicle (ELV) Directive and the Landfill Directive there is pressure to minimise this waste through recycling and recovery.In this paper, primary data are presented showing that 40% of materials are potentially recoverable in the coarser fraction of UK automotive shredder residue (>30 mm). Barriers to such recycling are discussed in the context of several recent drivers, including this waste's possible reclassification as hazardous.The lack of full and timely implementation of the ELV Directive in the UK has made it an ineffective driver, and it is now unlikely that its 2006 recycling targets will be met as intended.  相似文献   

16.
This paper examines the 1-year anthropogenic stocks and flows of silver as it progresses from extraction to final disposal on the European continent. The primary flows of silver include production, fabrication and manufacturing, use, and waste management. A substance flow analysis (SFA) was used to trace the flows and inventory data, and mass balance equations were used to determine the quantity of flows. The results reveal that Europe has a low level of silver mine production (1580 Mg Ag/year) and instead relies on silver imports and the recycling of scrap in production and fabrication. In the year 1997, Europe imported 1160 Mg Ag of ore concentrate and 2010 Mg Ag of refined silver, and recycled 2750 Mg Ag of new and old scrap. There is a net addition of 3320 Mg Ag/year into silver reservoirs at the use stage. This is the result of a greater amount of silver entering the system from manufacturing than is leaving the system into waste management. The waste flow with the highest content of silver is municipal solid waste, which contains 1180 Mg Ag/year. In total, 62% of all discarded silver is recycled and 38% is sent to landfills. The results of this study and other element and material flow analyses can help guide resource managers, environmental policy makers, and environmental scientists in their efforts to increase material recovery and recycling, address resource sustainability, and ameliorate environmental problems.  相似文献   

17.
This study quantified carbon storage and sequestration by urban forests and carbon emissions from energy consumption by several industrial sources in Hangzhou, China. Carbon (C) storage and sequestration were quantified using urban forest inventory data and by applying volume-derived biomass equations and other models relating net primary productivity (NPP) and mean annual biomass increments. Industrial energy use C emissions were estimated by accounting for fossil fuel use and assigning C emission factors. Total C storage by Hangzhou's urban forests was estimated at 11.74 Tg C, and C storage per hectare was 30.25 t C. Carbon sequestration by urban forests was 1,328, 166.55 t C/year, and C sequestration per ha was 1.66 t C/ha/year. Carbon emissions from industrial energy use in Hangzhou were 7 Tg C/year. Urban forests, through sequestration, annually offset 18.57% of the amount of carbon emitted by industrial enterprises, and store an amount of C equivalent to 1.75 times the amount of annual C emitted by industrial energy uses within the city. Management practices for improving Hangzhou's urban forests function of offsetting C emissions from energy consumption are explored. These results can be used to evaluate the urban forests' role in reducing atmospheric carbon dioxide.  相似文献   

18.
In this article, for the treatment of two specific pharmaceutical waste solvents the resource consumption of an on-site distillation process is evaluated and compared with an off-site incineration process. Both techniques are evaluated based on a thermodynamic quantitative method. The exergy approach and the cumulative exergy extracted from the natural environment (CEENE) are envisaged in order to evaluate the overall resource intake at different levels. Scenarios are constructed to make a fair comparison of both techniques. Two waste solvents, toluene (TOL) and dichloromethane (DCM), from the pharmaceutical industry which are frequently sent to distillation were evaluated. The functional unit for the comparison of both treatment alternatives is the treatment of 1 kg waste solvent + the incineration of W kg low calorific hazardous waste + the delivery of X kg “recovered” solvent + the production of Y MJ heat and Z MJ electricity. W, X, Y and Z depend on the waste solvent properties. In terms of resource requirements, distillation requires 17% (TOL) and 66% (DCM) less resources than incineration. It can be concluded that the waste solvent properties, the efficiency of the distillation process and the efficiency of the fresh solvent production process are of major importance on the resource consumption and the final choice between incineration and distillation. For a full environmental impact analysis of both treatment options, also the emissions should be taken into account. It also has to be stressed that in practice, only solvents go to incineration which cannot be distilled due to the type and degree of pollution/composition of the solvent. If distillation is not feasible, then such solvents are sent to incineration with energy recovery, according to the EU directive 2006/12/EG.  相似文献   

19.
Environmental life cycle assessment (LCA) developed rapidly during the 1990s and has reached a certain level of harmonisation and standardisation. LCA has mainly been developed for analysing material products, but can also be applied to services, e.g. treatment of a particular amount of solid waste. This paper discusses some methodological issues which come into focus when LCAs are applied to solid waste management systems. The following five issues are discussed. (1) Upstream and downstream system boundaries: where is the ‘cradle’ and where is the ‘grave’ in the analysed system? (2) Open-loop recycling allocation: besides taking care of a certain amount of solid waste, many treatment processes also provide additional functions, e.g. energy or materials which are recycled into other products. Two important questions which arise are if an allocation between the different functions should be made (and if so how), or if system boundaries should be expanded to include several functions. (3) Multi-input allocation: in waste treatment processes, different materials and products are usually mixed. In many applications there is a need to allocate environmental interventions from the treatment processes to the different input materials. The question is how this should be done. (4) Time: emissions from landfills will continue for a long time. An important issue to resolve is the length of time emissions from the landfill should be considered. (5) Life cycle impact assessment: are there any aspects of solid waste systems (e.g. the time horizon) that may require specific attention for the impact assessment element of an LCA? Although the discussion centres around LCA it is expected that many of these issues are also relevant for other types of systems analyses.  相似文献   

20.
With the onset of social life, humans have considered waste disposal as essential, and they have been able to repel it through brick and clay channels. Checking sewage pipes for energy consumption and a longer lifetime than other sewage system components is important. Climate change and exploitation of industrial resources have made environmental impacts, which are important factors in decision making. The purpose of this study was to introduce the most suitable type of sewage pipe considering environmental protection. Therefore, we applied the environmental life cycle assessment (LCA) method, using Sima Pro 8.2.3 software for the one-kilometer length of concrete pipes (300 mm in diameter), Polyvinyl chloride (PVC), and polyethylene (PE) (315 mm in diameter). Also, the BEES method and sensitivity analysis were used to validate the results. The comparison between three types of municipal wastewater pipes indicated that PE pipes are a more environmentally friendly option than PVC, and concrete pipes in pipe recycling, reducing extraction from untapped resources, and inefficient extraction of resources. Electricity, diesel fuel, and sulfate resistance cement consumption for concrete production are the most pollution elements in the LCA of concrete pipes. Usage of PVC granular, sanitary landfill of PVC pipes, and using hydraulic drill in LCA of PVC pipes are the most elements of generating pollution. The usage of PE granules, PE pipes landfilling, hydraulic excavator, and electricity consumption in the LCA of the PE pipes are the greatest polluting parameters.  相似文献   

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