FOREST HARVESTING AND STREAMWATER INORGANIC CHEMISTRY IN WESTERN NORTH AMERICA: A REVIEW1

The solution chemistry of forested streams primarily in western North America is explained by considering the major factors that influence this chemistry — geological weathering; atmospheric precipitation and climate; precipitation acidity; terrestrial biological processes; physical/chemical reactions in the soil; and physical, chemical, and biological processes within streams. Due to the complexity of all these processes and their varying importance for different chemicals, stream water chemistry has exhibited considerable geographic and temporal variation and is difficult to model accurately. The impacts of forest harvesting on stream water chemistry were reviewed by considering the effects of harvesting on each of the important factors controlling this chemistry, as well as other factors influencing these impacts ‐ extent of the watershed harvested, presence of buffer strips between streams and harvested areas, nature of post‐harvesting site preparation, revegetation rate following harvesting, pre‐harvesting soil fertility, and soil buffering capacity. These effects have sometimes reinforced one another but have sometimes been counterbalancing or slight so that harvesting impacts on stream water chemistry have been highly variable. Eight major knowledge gaps were identified, two of which — a scarcity of detailed stream chemical budgets and knowledge of longitudinal variation in stream chemistry — relate to undisturbed streams, while the remainder relate to forest harvesting effects.     

Sources of salinity near a coal mine spoil pile, north-central Colorado

A small (1 km2) salt-affected stream drainage on the High Plains north of Denver, Colorado was sampled to determine the near-surface dispersion of soluble salts and metals from low-sulfur coal mining waste (spoil). Surface waters collected along the 0.8-km stream reach, and aqueous leachates of spoil and naturally saline local soil, were analyzed for chemical constituents and sulfur isotopes. In this semiarid setting with abundant carbonate-bearing surficial sediments, the limited, mildly acidic drainage from the spoil pile is quickly neutralized, restricting the mobility of many elements. However, some spoil-derived constituents were clearly traceable within the upper 0.4 km of the stream reach. Spoil leachates and surface water near the spoil pile have distinctive compositions of major anions and cations, and elevated levels of dissolved nitrate compared with downstream waters. Spoil-derived sulfate was traceable because it has generally positive values of delta34S that contrasted with generally negative values of delta34S in soil leachates and evaporite salts from the surrounding area. Spatial-chemical sampling of surface water showed an abrupt increase in dissolved U, Se, B, Li, and Mn in the lower 0.4 km of the stream reach where shallow ground water from surrounding irrigated fields contributed to surface flow. The downstream evolution of surface water chemistry and sulfur isotopic composition is consistent with mixing between spoil-affected upstream water and irrigation-return water. The methods described should be applicable at other sites in similar settings where the environmental effect of low-sulfur coal mining waste must be assessed and where access to samples of shallow ground water is limited.     

Watershed factors affecting stream acidification in the White Mountains of New Hampshire,USA

The streams tributary to acidic Cone Pond, pH 4.5–4.8, and circumneutral Black Pond, pH 5.3–6.4, in the White Mountains of New Hampshire, USA, were monitored for a year. The watersheds of these two ponds were characterized in terms of geology and stream hydrology. Chemical gradients and patterns in rock weathering and groundwater discharge explain many of the differences in mineral content and acidity of the streams. The rocks of Black watershed produced an average of ten times the equivalent of basic cations as rocks from Cone watershed. This is on the same order as the difference in acidity of the two streams. Down-stream changes in stream chemistry follow differing patterns, but reflect the same principle of residence time and water path length controlling chemical evolution of streamwater. Watershed and aquatic managers may use these parameters in an inexpensive and simple assessment of the susceptibility of individual streams and ponds to acidification. A method is recommended to determine quickly the potential influence of bedrock type to aquatic chemistry.     

CHARACTERIZATION OF SURFACE WATER QUALITY ALONG A WATERSHED DISTURBANCE GRADIENT1

ABSTRACT. Characterizing ecological indicators such as water quality is necessary to effectively manage human-dominated systems such as the New Jersey Pinelands. Pinelands surface waters are naturally acidic and low in nutrients and other dissolved substances. Water quality for 14 Pinelands stream sites monitored by the U.S. Geological Survey was characterized in relation to land use. A gradient of increasing pH, specific conductance, and concentration of dissolved calcium, dissolved magnesium, total nitrite + nitrate-nitrogen, total ammonia-nitrogen, and total phosphorus was associated with a watershed disturbance gradient of increasing land use intensity and waste water flow. These two parallel gradients emphasized the significant effect that watershed disturbance can have on natural water chemistry in the Pinelands. The results of this study can be applied to planning and regulatory programs in the Pinelands.     

Relative effects of land use and near-stream chemistry on phosphorus in an urban stream

Elevated levels of P in urban streams can pose significant water quality problems. Sources of P in urban streams, however, are difficult to identify. It is important to recognize both natural and anthropogenic sources of P. We investigated near-stream chemistry and land use factors on stream water P in the urbanizing Johnson Creek watershed in Portland, OR, USA. We sampled stream water and shallow groundwater soluble reactive P (SRP) and total P (TP) and estimated P flux at 13 sites along the main stem of Johnson Creek, with eight sites in urban land use areas and five sites in nonurban land use areas. At each site, we sampled the A and B horizons, measuring soil pH, water-soluble P, acid-soluble P, base-soluble P, total P, Fe, and Al. We found continuous input of P to the stream water via shallow groundwater throughout the Johnson Creek watershed. The shallow groundwater P concentrations were correlated with stream water P within the nonurban area; however, this correlation was not found in the urban area, suggesting that other factors in the urban area masked the relationship between groundwater P and stream water P. Aluminum and Fe concentrations were inversely correlated with shallow groundwater P, suggesting that greater P adsorption to Al and Fe oxides in the nonurban area reduced availability of shallow groundwater P. Using stepwise multiple regression analysis, however, we concluded that while riparian soil chemistry was related to stream water P, land use patterns had a more significant relationship with stream water P concentrations in this urbanizing system.     

Headwater Influences on Downstream Water Quality

We investigated the influence of riparian and whole watershed land use as a function of stream size on surface water chemistry and assessed regional variation in these relationships. Sixty-eight watersheds in four level III U.S. EPA ecoregions in eastern Kansas were selected as study sites. Riparian land cover and watershed land use were quantified for the entire watershed, and by Strahler order. Multiple regression analyses using riparian land cover classifications as independent variables explained among-site variation in water chemistry parameters, particularly total nitrogen (41%), nitrate (61%), and total phosphorus (63%) concentrations. Whole watershed land use explained slightly less variance, but riparian and whole watershed land use were so tightly correlated that it was difficult to separate their effects. Water chemistry parameters sampled in downstream reaches were most closely correlated with riparian land cover adjacent to the smallest (first-order) streams of watersheds or land use in the entire watershed, with riparian zones immediately upstream of sampling sites offering less explanatory power as stream size increased. Interestingly, headwater effects were evident even at times when these small streams were unlikely to be flowing. Relationships were similar among ecoregions, indicating that land use characteristics were most responsible for water quality variation among watersheds. These findings suggest that nonpoint pollution control strategies should consider the influence of small upland streams and protection of downstream riparian zones alone is not sufficient to protect water quality.     

Using heat to characterize streambed water flux variability in four stream reaches

Estimates of streambed water flux are needed for the interpretation of streambed chemistry and reactions. Continuous temperature and head monitoring in stream reaches within four agricultural watersheds (Leary Weber Ditch, IN; Maple Creek, NE; DR2 Drain, WA; and Merced River, CA) allowed heat to be used as a tracer to study the temporal and spatial variability of fluxes through the streambed. Synoptic methods (seepage meter and differential discharge measurements) were compared with estimates obtained by using heat as a tracer. Water flux was estimated by modeling one-dimensional vertical flow of water and heat using the model VS2DH. Flux was influenced by physical heterogeneity of the stream channel and temporal variability in stream and ground-water levels. During most of the study period (April-December 2004), flux was upward through the streambeds. At the IN, NE, and CA sites, high-stage events resulted in rapid reversal of flow direction inducing short-term surface-water flow into the streambed. During late summer at the IN site, regional ground-water levels dropped, leading to surface-water loss to ground water that resulted in drying of the ditch. Synoptic measurements of flux generally supported the model flux estimates. Water flow through the streambed was roughly an order of magnitude larger in the humid basins (IN and NE) than in the arid basins (WA and CA). Downward flux, in response to sudden high streamflows, and seasonal variability in flux was most pronounced in the humid basins and in high conductivity zones in the streambed.     

FOREST PRACTICES AS NONPOINT SOURCES OF POLLUTION IN NORTH AMERICA1

ABSTRACT: Forest management activities may substantially alter the quality of water draining forests, and are regulated as nonpoint sources of pollution. Important impacts have been documented, in some cases, for undesirable changes in stream temperature and concentrations of dissolved oxygen, nitrate-N, and suspended sediments. We present a comprehensive summary of North American studies that have examined the impacts of forest practices on each of these parameters of water quality. In most cases, retention of forested buffer strips along streams prevents unacceptable increases in stream temperatures. Current practices do not typically involve addition of large quantities of fine organic material to streams, and depletion of streamwater oxygen is not a problem; however, sedimentation of gravel streambeds may reduce oxygen diffusion into spawning beds in some cases. Concentrations of nitrate-N typically increase substantially after forest harvesting and fertilization, but only a few cases have resulted in concentrations approaching the drinking-water standard of 10 mg of nitrate-NIL. Road construction and harvesting increase suspended sediment concentrations in streamwater, with highly variable results among regions in North America. The use of best management practices usually prevents unacceptable increases in sediment concentrations, but exceptionally large responses (especially in relation to intense storms) are not unusual.     

The effect of Oja-titun market effluent on the chemical quality of receiving OPA reservoir in Ile-Ife, Nigeria

The effect of market effluent from the Oja-titun market in Ile-Ife, Nigeria on the chemical quality of the Opa Reservoir located 3.5 km downstream was investigated between February and November 2000. Water samples were collected in February, May, August and November from 16 sites, four along each of the market drainage channels (MDC), market stream, tributary stream and the Opa River and Reservoir. The peak level of each variable-biochemical oxygen demand, temperature, total alkalinity, Na(+), K(+), Ca(2+), Mg(2+), PO(4)(3+), SO(4)(2+), Cl(-), NO(3)(-), Pb and Zn-occurred at the MDC, and decreased significantly downstream, except pH, conductivity and dissolved oxygen, which increased. Seasonal fluctuation in most variables was pronounced. Generally, there were high values in the early dry and dry seasons and low values in the rainy and early rainy seasons. Comparison of the reservoir water with international limitation standards for drinking water supply showed that the quality of the reservoir water was very low and that treatment required to achieve minimum limitation standards for drinking water would be both intensive and expensive. The study concluded that the stream borne effluent from the market impacts significantly on the chemical quality of the reservoir water although other tributaries within the Reservoir's catchment are other possible sources of pollutants in the reservoir.     

SPATIAL VARIATION OF NUTRIENT BALANCE IN THE TRUCKEE RIVER,CALIFORNIA‐NEVADA1

ABSTRACT: Because the Truckee River connects two lakes along the Eastern Sierra Nevada Mountains with different limiting nutrients, this research addresses whether the nitrogen:phosphorus (N:P) balance of the river ecosystem changes longitudinally. Historical (1990 to 2000) total nitro‐gen:total phosphorus (TN:TP) ratios in river water exhibited the expected gradient from high N:P ratios upstream to low N:P ratios downstream, with the major gradient of the N:P balance occurring within the transition between montane and high desert terrain. During 2001, the river contained anomalously low total nitrogen concentrations in the far upper reaches and dissolved inorganic nitrogen concentrations in the lower reaches, resulting in a less apparent longitudinal gradient of N:P ratios. Measurements of periphyton growth and physiology (nutrient bioassays and ectoenzyme activities) and stoichiometry during the summer of 2001 also exhibited a complex picture of the spatial variation of N:P balance that was not entirely consistent with a strong N:P gradient. However, the compendium of the indicators did support the overall picture of an overarching longitudinal gradient from high to low N:P ratios. The results suggest that periphyton management efforts in the Truckee River should consider the overall spatial gradient as well as the small‐scale dynamics of the stream ecosystem structure.     

The Role of Headwater Wetlands in Altering Streamflow and Chemistry in a Maine,USA Catchment1

Morley, Terry R., Andrew S. Reeve, and Aram J.K. Calhoun, 2011. The Role of Headwater Wetlands in Altering Streamflow and Chemistry in a Maine, USA Catchment. Journal of the American Water Resources Association (JAWRA) 1‐13. DOI: 10.1111/j.1752‐1688.2011.00519.x Abstract: Headwater wetlands, including hillside seeps, may contribute to downstream systems disproportionately to their relatively small size. We quantified the hydrology and chemistry of headwater wetlands in a central Maine, USA, catchment from 2003 to 2005 to determine their role in maintaining headwater streamflow and in affecting stream chemistry. A few of these headwater wetlands, commonly referred to as “seeps,” were characterized by relatively high groundwater discharge. During summer base flow, seeps were the primary source of surface water to the stream, contributing between 40 and 80% of stream water. Comparisons of groundwater and surface water dominant ion chemistry revealed only slight differences at the bedrock interface; however, significant changes occurred at the shallow groundwater‐surface water interface where we found decreases in total and individual cation concentrations with decreasing depth. Seep outflows significantly increased total cation and calcium concentrations in streams. Outflows at two seeps produced relatively high nitrate concentrations (88 ± 15 and 93 ± 15 μg/l respectively), yet did not correspond to higher nitrate in stream water below seep outflows (2 ± 1 μg/l). We demonstrate that small wetlands (< 1,335 m²) can contribute to headwater stream processes by linking groundwater and surface‐water systems, increasing the duration and magnitude of stream discharge, and by affecting stream chemistry, particularly during periods of base flow.     

Linking river, floodplain, and vadose zone hydrology to improve restoration of a coastal river affected by saltwater intrusion

Floodplain forests provide unique ecological structure and function, which are often degraded or lost when watershed hydrology is modified. Restoration of damaged ecosystems requires an understanding of surface water, groundwater, and vadose (unsaturated) zone hydrology in the floodplain. Soil moisture and porewater salinity are of particular importance for seed germination and seedling survival in systems affected by saltwater intrusion but are difficult to monitor and often overlooked. This study contributes to the understanding of floodplain hydrology in one of the last bald cypress [Taxodium distichum (L.) Rich.] floodplain swamps in southeast Florida. We investigated soil moisture and porewater salinity dynamics in the floodplain of the Loxahatchee River, where reduced freshwater flow has led to saltwater intrusion and a transition to salt-tolerant, mangrove-dominated communities. Twenty-four dielectric probes measuring soil moisture and porewater salinity every 30 min were installed along two transects-one in an upstream, freshwater location and one in a downstream tidal area. Complemented by surface water, groundwater, and meteorological data, these unique 4-yr datasets quantified the spatial variability and temporal dynamics of vadose zone hydrology. Results showed that soil moisture can be closely predicted based on river stage and topographic elevation (overall Nash-Sutcliffe coefficient of efficiency = 0.83). Porewater salinity rarely exceeded tolerance thresholds (0.3125 S m(-1)) for bald cypress upstream but did so in some downstream areas. This provided an explanation for observed vegetation changes that both surface water and groundwater salinity failed to explain. The results offer a methodological and analytical framework for floodplain monitoring in locations where restoration success depends on vadose zone hydrology and provide relationships for evaluating proposed restoration and management scenarios for the Loxahatchee River.     

THROUGHFALL pH: EFFECT OF PRECIPITATION : TIMING AND AMOUNT1

ABSTRACT: Precipitation, throughfall, and stream pH were measured weekly over a 27-week period in 1982 on the Little Millseat watershed in eastern Kentucky. The average pH values over the study period were 4.3, 4.9, and 6.4, respectively, indicating significant buffering as water moved from the atmosphere, through the deciduous canopy, and through or over the soil to the stream. Regression analysis demonstrated that the timing and amount of precipitation were important factors influencing the pH of the throughfall. Weekly precipitation and the three-week average precipitation were statistically significant variables, explaining 53 percent of the variance in the observed through- fall pH. Precipitation pH was not a statistically significant variable for this watershed and sampling period.     

SENSITIVITY OF HIGH-ELEVATION STREAMS IN THE SOUTHERN BLUE RIDGE PROVINCE TO ACIDIC DEPOSITION1

ABSTRACT: The Southern Blue Ridge Province, which encompasses parts of northern Georgia, eastern Tennessee, and western North Carolina, has been predicted to be sensitive to impacts from acidic deposition, owing to the chemical composition of the bedrock geology and soils. This study confirms the predicted potential sensitivity, quantifies the level of total alkalinity and describes the chemical characteristics of 30 headwater streams of this area. Water chemistry was measured five times between April 1983 and June 1984 at first and third order reaches of each stream during baseflow conditions. Sensitivity based on total alkalinity and the Calcite Saturation Index indicates that the headwater streams of the Province are vulnerable to acidification. Total alkalinity and p11 were generally higher in third order reaches (mean, 72 μeq/θ and 6.7) than in first order reaches (64 μeq/θ and 6.4). Ionic concentrations were low, averaging 310 and 340 μeq/θ in first and third order reaches, respectively. A single sampling appears adequate for evaluating sensitivity based on total alkalinity, but large temporal variability requires multiple sampling for the detection of changes in pH and alkalinity over time. Monitoring of stream water should continue in order to detect any subtle effects of acidic deposition on these unique resource systems.     

Fish Assemblage Responses to Water Withdrawals and Water Supply Reservoirs in Piedmont Streams

Understanding effects of flow alteration on stream biota is essential to developing ecologically sustainable water supply strategies. We evaluated effects of altering flows via surface water withdrawals and instream reservoirs on stream fish assemblages, and compared effects with other hypothesized drivers of species richness and assemblage composition. We sampled fishes during three years in 28 streams used for municipal water supply in the Piedmont region of Georgia, U.S.A. Study sites had permitted average withdrawal rates that ranged from < 0.05 to > 13 times the stream’s seven-day, ten-year recurrence low flow (7Q10), and were located directly downstream either from a water supply reservoir or from a withdrawal taken from an unimpounded stream. Ordination analysis of catch data showed a shift in assemblage composition at reservoir sites corresponding to dominance by habitat generalist species. Richness of fluvial specialists averaged about 3 fewer species downstream from reservoirs, and also declined as permitted withdrawal rate increased above about 0.5 to one 7Q10-equivalent of water. Reservoir presence and withdrawal rate, along with drainage area, accounted for 70% of the among-site variance in fluvial specialist richness and were better predictor variables than percent of the catchment in urban land use or average streambed sediment size. Increasing withdrawal rate also increased the odds that a site’s Index of Biotic Integrity score fell below a regulatory threshold indicating biological impairment. Estimates of reservoir and withdrawal effects on stream biota could be used in predictive landscape models to support adaptive water supply planning intended to meet societal needs while conserving biological resources.     

Monitoring of Seasonal Variation in the Water Quality of Ubu River in Ekwusigo and Nnewi Local Government Areas of Anambra State,Nigeria

Investigation of the water quality of the Ubu river has been carried out. The upstream course of the river is slightly acidic (pH 5.45 ± 0.23), and the acidity decreases along the lower courses of the river. Turbidity, surfactant, and iron content parameters of the river increased during the wet season, and these changes have been attributed to inputs from flood, leachates of soil erosion, and storm water runoff discharged into the river in increased quantities during the season. Concentrations of some metals were found to increase during the dry season because of absence of dilution of the river by storm water runoff. Most water quality parameters are within World Health Organization acceptable limits set for potable water, and they include most of the cationic and anionic constituents. Although there is no hydrocarbon or metal ion pollution, potability is reduced along the mid to downstream courses of the river by unacceptable levels of turbidity, surfactant concentration, and iron content, particularly during the wet season.     

Physical and Temporal Isolation of Mountain Headwater Streams in the Western Mojave Desert,Southern California1

Abstract: Streams draining mountain headwater areas of the western Mojave Desert are commonly physically isolated from downstream hydrologic systems such as springs, playa lakes, wetlands, or larger streams and rivers by stream reaches that are dry much of the time. The physical isolation of surface flow in these streams may be broken for brief periods after rainfall or snowmelt when runoff is sufficient to allow flow along the entire stream reach. Despite the physical isolation of surface flow in these streams, they are an integral part of the hydrologic cycle. Water infiltrated from headwater streams moves through the unsaturated zone to recharge the underlying ground‐water system and eventually discharges to support springs, streamflow, isolated wetlands, or native vegetation. Water movement through thick unsaturated zones may require several hundred years and subsequent movement through the underlying ground‐water systems may require many thousands of years – contributing to the temporal isolation of mountain headwater streams.     

STREAM DEPTH SIGNIFICANCE DURING IN‐SITU SEDIMENT OXYGEN DEMAND MEASUREMENTS IN SHALLOW STREAMS1

ABSTRACT: Ninety‐one sediment oxygen demand (SOD) samples from six designated sites along the stretch of Lower Rapid Creek, South Dakota, were conducted using an in‐situ SOD chamber. Inside the chamber, readings of dissolved oxygen (DO), water temperature, pH, and specific conductance were recorded every minute for more than one hour using the Datasonde 3 Hydrolab. Initial readings of such parameters were recorded for the overlaying water before the deployment of the SOD chamber. Characteristics of the stream conditions, air temperature, barometric pressure, average flow velocity of the stream, depth of the stream, and the flow velocity by the chamber were recorded. Single and multiple linear regression analyses on all parameters indicated that the velocity of the stream is the least critical parameter for SOD in shallow streams.     

Baseflow nitrate in relation to stream order and agricultural land use

Management of agricultural nonpoint-source pollution continues to be a challenge because of spatial and temporal variability. Using stream order as an index, we explored the distribution of nitrate concentration and load along the stream network of a large agricultural watershed in Pennsylvania-the East Mahantango Creek Watershed and two of its sub-watersheds. To understand nitrate concentration variation in the stream water contributed from ground water, this study focused on baseflow. Impacts of agricultural land use area on baseflow nitrate in the stream network were investigated. Nitrate concentration showed a general decreasing trend with increasing stream order based on stream order averaged values; however, considerable spatial and temporal variability existed within each snapshot sampling. Nitrate loads increased with stream order in a power function because of the dominant effect of stream flow rate over the nitrate concentration. Within delineated sub-watersheds based on stream orders, positive linear functions were found between agricultural land use area percentage and the baseflow nitrate concentration and between agricultural drainage area and the nitrate load. The slope of the positive linear regression between the baseflow nitrate concentration and percent agricultural land area seems to be a valuable indicator of a watershed's water quality as influenced by agricultural practices, watershed size, and specific physiographic setting. Stream order seems to integrate, to a certain degree, the source and transport aspects of nonpoint-source pollution on a yearly averaged basis and thus might provide a quick estimate of the overall trend in baseflow nitrate concentration and load distribution along complex stream networks in agricultural watersheds.