Biogas upgrading and utilization from ICEs towards stationary molten carbonate fuel cell systems

Biogas production from anaerobic digestion has increased rapidly in the last years, in many parts of the world, mainly due to its local scale disposition and to its potential on greenhouse gases (GHG) emissions mitigation. Biogas can be used as fuel for combined heat and power systems (CHP), in particular for internal combustion engines (ICEs). In recent investigations, fuel cells have been considered as alternative CHP systems. In the present article, two different energy conversion systems are compared: a 1.4 MW class MCFC system, running on pipeline natural gas, and an in situ ICE, running on biogas. In the first case, biogas is considered as a source fuel to obtain upgraded gas to be injected in the natural gas grid. In such scenario, the location of the fuel cell power plant is no longer strictly connected to the anaerobic digester site. Several energy balances are evaluated, considering different upgrading techniques and different biogas methane/carbon dioxide ratios.     

Paper recycling and social policy

This paper examines the problems and operation of waste paper recycling in the UK. Long- and short-term forecasts for demand are developed, showing demand strongly correlated with Gross Domestic Product. These are used to simulate a buffer stock scheme and establish costs for operating such a scheme. The authors conclude, given that the only large source of waste paper not fully exploited is the householder, then grants for developing waste upgrading technologies are likely to be more effective than buffer stock schemes.     

Substituting energy crops with organic wastes and agro-industrial residues for biogas production

In this study, industrial and agro-industrial by-products and residues (BRs), animal manures (AMs), and various types of organic wastes (OWs) were analyzed to evaluate their suitability as substitutes for energy crops (ECs) in biogas production. A comparison between the costs of the volume of biogas that can be produced from each substrate was presented with respect to the prices of the substrates in the Italian market. Furthermore, four different feeding mixtures were compared with a mixture of EC and swine manure (Mixture A) used in a full-scale plant in Italy. Swine manure is always included as a basic substrate in the feeding mixtures, because many of the Italian biogas plants are connected to farms. When EC were partially substituted with BR (Mixture B), the cost (0.28 € Nm⁻³) of the volume of biogas of Mixture A dropped to 0.18 € Nm⁻³. Furthermore, when the organic fraction of municipal solid waste (OFMSW) and olive oil sludge (OS) were used as possible solutions (Mixtures C and D), the costs of the volume of biogas were −0.20 and 0.11 € Nm⁻³, respectively. The negative price signifies that operators earn money for treating the waste. For the fifth mix (Mixture E) of the OFMSW with a high solid substrate, such as glycerin from biodiesel production, the resulting cost of the volume of biogas produced was −0.09 € Nm⁻³. By comparing these figures, it is evident that the biogas plants at farm level are good candidates for treating organic residues of both municipalities and the agro-industrial sector in a cost-effective way, and in providing territorially diffused electric and thermal power. This may represent a potential development for agrarian economy.     

碳中和愿景的科技需求与技术路径

碳达峰与碳中和愿景的提出为我国低碳/脱碳发展明确了新方向,也对科技创新和技术发展提出了新要求。世界各国均将科技创新作为碳中和目标实现的重要保障。我国实现碳中和目标,归根结底也需要依靠科技进步。我国碳排放总量大、强度高,实现碳中和目标的时间周期短,现有技术尚存在不足,科技发展需要付出更多努力并提前部署。我国碳中和技术发展需要为保障我国碳排放高质量达峰和实现碳中和目标提供技术可行、经济可承受的科技支撑。各部门需要结合自身特点制定技术发展路径。"十四五"是碳达峰与碳中和目标实现的关键时期,应全面加强相关脱碳、零碳、负排放技术发展的全局性部署,加快开展研发示范。为了更好地推动面向碳中和愿景的科技发展,需要强化顶层设计、完善保障机制与加强国际合作。     

Application of modeling and simulation tools in costs and pollution monitoring

This paper presents the development and application of process modeling and simulation tools to aid in the monitoring and measuring of pollution from industry, and investigate a plant's overall performance. A case study of a generic reduction plant is investigated, taking into account the underlying principles that determine the amount of fluoride emissions released from the plant's processes. The simulation study includes the investigation of the gas cleaning system within the plant, such as the system's operating relationships between the scrubbing efficiency, wear of the scrubber filter bags, maintenance costs and its response to the change of scrubbing circulation. Two sets of simulation runs are performed to seek a balance for the plant's overall system performance, taking into account environmental issues (fluoride emissions) and cost. The final simulation result demonstrates that cost savings can be achieved when the plant operates in a cleaner manner.     

沼渣连续施用对土壤微生物量碳、氮剖面分布的影响

通过"棉花+小麦"轮作施用沼渣的定位试验,研究不同年限的沼渣施用对土壤剖面微生物量C、N(MBC、MBN)分布特征的影响。结果表明:在0~50cm剖面上,施用沼渣1年对0~30cm土壤的MBC、MBN影响较大,能显著提高30~40cm土层土壤MBC、MBN的含量,施用沼渣5年时对40~50cm土层MBC、MBN无明显影响。土壤MBC、MBN含量总体随施用沼渣年限的延长而增加,各土层MBC、MBN含量增幅随着施用年限的延长呈现不同趋势。施用沼渣1年,耕层土壤的MBC/MBN值较习惯耕作增加,施用沼渣3年后,其值呈降低趋势。各土层的MBC/TOC、MBN/TN和MBC的变化趋势基本一致,总体随着沼渣施用年限的延长而增加。针对"棉花+小麦"轮作模式,持续施用沼渣3年更有利于改善0~40cm土层土壤肥力。     

碳中和愿景的实现路径与政策体系

习近平主席在第七十五届联合国大会上郑重承诺中国将努力争取2060年实现碳中和目标，为中国未来低碳转型促进经济高质量发展、生态文明建设指明了方向、明确了目标，也提振了全球应对气候变化的信心。作为排放量全球最大的发展中国家，在2030年前达峰后用三十年左右的时间很快地实现碳中和愿景，任务异常艰巨，但总体上排放路径必然呈现尽早达峰、稳中有降、快速降低、趋稳中和的过程。支撑碳中和的技术几乎涉及所有的产业和经济活动，从控制碳排放途径的角度可以分为高能效循环利用技术、零碳能源技术、负排放技术。政府、企业、个人在迈向碳中和愿景进程中具有至关重要而又各有侧重的作用，需要科学的政策体系以形成系统有效的激励机制，促进资本和人才朝着碳中和技术创新和市场化推广应用方向快速汇集。     

Modeling and simulation of biogas-fueled power system

The main objective of this paper is to develop a complete model that fully simulate a biogas-fueled power plant which can be used to supply a rural farm with sufficient electricity. The reactor is fed with animal manure of the farm. The proposed model consists of three main parts; a biogas reactor, a microturbine (MT) coupled to a permanent magnet synchronous generator, and a storage system. The model describes the dynamics of an MT and it is suitable for both steady state and transient simulation and analysis. The volume of biogas output delivered from the Anaerobic Digester depends on the reactor volume, reactor temperature, and animal manure type. The storage system is used to store the excess value of biogas if any. It is composed of two parts: a comparator and a storage tank. The comparator compares the volume of biogas produced by the reactor with that needed to supply the load. An adaptive controller is developed to withstand the system against any transient condition such as suddenly load increase/decrease. The proposed model is implemented for chemical and physical behaviors of the biogas production process, as well as for different variables of MT-generator operations. The model is implemented in Matlab/Simulink environment and tested under different operating conditions in both steady state and transient status to study the impacts of different variables on the system output. The output results prove its applicability and effectiveness under different operating conditions.     

Fuelwood use by different tribal and non-tribal communities in north-east India

This paper analyses the fuelwood consumption pattern by different tribal and non-tribal communities ofMeghalaya in north-east India. The total fuelwood consumption including all activities such as cooking, rice beer preparation, room and water heating and festival celebration, ranged from 4.7 kg/capita/day for the Garos to 2.1 kg/capita/day for the Nepalese. The total energy expended for fuelwood collection was highest for the Nepalese (0.23 MJ/capital day) and least for the Garos (0.12 MJ/capital day). The present information on fuelwood consumption patterns by different tribal and non-tribal communities could form the basis for designing appropriate technologies for energy plantations in the region. Besides this, some other technologies such as the introduction of fuel efficient devices at the village level and recycling of resources through biogas could be appropriate.     

THE PRODUCTION OF WATER FROM GEOTHERMAL RESERVOIRS: SOME ECONOMIC CONSIDERATIONS1

ABSTRACT: Liquid dominated geothermal systems are expected to account for most of the growth in geothermal energy production in the coming decades. Production of water from such systems could significantly augment fresh water supplies. The feasibility of water exploitation is clouded by potential problems related to seismic impacts, land subsidence and the composition of geothermal brines. If these problems can be overcome at little cost, desalination of brines may be feasible. Estimates of water production costs are presented for a variety of desalination technologies, plant sizes and brine water compositions. These estimates show that production costs will range from $139.10/A.F. to $436.00/A.F. at the plant boundary. Economies of scale and brine composition are important determinants of cost. Production costs are substantially in excess of the value of water in alternative uses. However, in certain unique situations, it may be efficient to desalt brines for use in upgrading the quality of municipal water, industrial process water and irrigation water. Unique situations aside, geothermal brines are not likely to provide an economical source of fresh water in the absence of striking changes in the patterns of supply and demand for water.     

Techno-economic evaluation of biogas upgrading process using CO2 facilitated transport membrane

The biogas upgrading by membrane separation process using a highly efficient CO₂-selective polyvinylamine/polyvinylalcohol (PVAm/PVA) blend membrane was investigated by experimental study and simulation with respect to process design, operation optimization and economic evaluation. This blend membrane takes advantages of the unique CO₂ facilitated transport from PVAm and the robust mechanical properties from PVA, exhibits both high CO₂/CH₄ separation efficiency and very good stability. CO₂ transports through the water swollen membrane matrix in the form of bicarbonate. CO₂/CH₄ selectivity up to 40 and CO₂ permeance up to 0.55 m³(STP)/m² h bar at 2 bar were documented in lab with synthesized biogas (35% CO₂ and 65% CH₄). Membrane performances at varying feed pressures were recorded and used as the simulation basis in this work. The process simulation of an on-farm scale biogas upgrading plant (1000 Nm³/h) was conducted. Processes with four different membrane module configurations with or without recycle were evaluated technically and economically, and the 2-stage in cascade with recycle configuration was proven optimal among the four processes. The sensitivity of the process to various operation parameters was analyzed and the operation conditions were optimized.     

Assessment of biomass residue availability and bioenergy yields in Ghana

Biomass is an important renewable energy source that holds large potential as feedstock for the production of different energy carriers in a context of sustainable development, peak oil and climate change. In developing countries, biomass already supplies the bulk of energy services and future use is expected to increase with more efficient applications, such as the production of biogas and liquid biofuels for cooking, transportation and the generation of power. The aim of this study is to establish the amount of Ghana's energy demand that can be satisfied by using the country's crop residues, animal manure, logging residues and municipal waste. The study finds that the technical potential of bioenergy from these sources is 96 PJ in 2700 Mm³ of biogas or 52 PJ in 2300 ML of cellulosic ethanol. The biogas potential is sufficient to replace more than a quarter of Ghana's present woodfuel use. If instead converted to cellulosic ethanol, the estimated potential is seven times the estimated 336 ML of biofuels needed to achieve the projected 10% biofuels blends at the national level in 2020. Utilizing the calculated potentials involves a large challenge in terms of infrastructure requirements, quantified to hundreds of thousands of small-scale plants.     

Environmental and Ecological Aspects in the Overall Assessment of Bioeconomy

Bioeconomy solutions potentially reduce the utilization demand of natural resources, and therefore, represent steps towards circular economy, but are not per se equivalent to sustainability. Thus, production may remain to be achieved against losses in natural resources or at other environmental costs, and materials produced by bioeconomy are not necessarily biodegradable. As a consequence, the assumption that emerging bioeconomy by itself provides an environmentally sustainable economy is not justified, as technologies do not necessarily become sustainable merely through their conversion to using renewable resources for their production. A source of the above assumption is that the utility of bioeconomy is mostly assessed in interaction between technology developers and economists, resulting in biased assessment with private commercial technology benefits being included, but environmental costs, especially longer term ones, not being sufficiently considered in the economic models. A possible solution to this conceptual contradiction may come from bioethics, as a strong concept in environmental ethics is that no technological intervention can be imposed on nature beyond its receptive capacity. To achieve a better balanced analysis of bioeconomy, environmental and ecological, as well as non-economic social aspects, need to be included in the overall assessment.     

碳中和背景下欧盟碳边境调节机制对我国的影响及对策分析

在全球碳中和的新形势下,欧盟委员会于2021年7月正式提出"碳边境调节机制"(CBAM)立法提案,并计划于2023年起实施。本文在总结立法提案关键要素的基础上,着重分析欧盟CBAM的合法性与合理性,研判可能对我国产生的潜在影响,并从国际国内层面提出对策建议。分析发现,欧盟采取"名义"碳市场的形式,初期将覆盖水泥、电力、化肥、钢铁和铝等5个行业,只核算产品生产过程的直接排放,暂不考虑间接排放,2023—2025年是过渡期,2026年开始正式实施。欧盟CBAM的合法性与合理性面临诸多挑战:不符合世界贸易组织国民待遇原则和最惠国待遇原则,但存在满足关税与贸易总协定例外条款的可能性;违反国际气候治理的共同但有区别的责任原则、公平原则和各自能力原则,也不符合公约关于国际贸易歧视或变相限制的条款;对解决碳泄漏问题和保护本土竞争力的作用有限;产品隐含碳核算和碳价确定是技术难点问题。影响评估发现,欧盟CBAM将使我国受影响部门的对欧出口总额降低11%~13%,出口成本增加1亿~3.05亿美元,其中约四分之三的成本将由钢铁行业承担,对贸易隐含碳的下降作用有待进一步考量;此外,欧盟CBAM将会影响多边国际气候谈判进程,也会对我国经济社会发展、国际贸易、产业转型、技术提升等方面产生间接影响。我国应在国际层面坚定在气候治理多边框架下解决碳泄露问题,探索提出中国方案;积极推进贸易自由化,提升我国贸易优势;加强中欧对话协商,避免CBAM成为中欧"绿色贸易壁垒"。在国内层面稳步加快全国碳排放权交易体系建设,夯实碳排放核算基础能力,加强科学研究与交流合作。     

The impact of the carbon tax policy on green building strategy

As Green Corporate Social Responsibility spreads across the globe, the construction industry is under pressure to reduce the carbon emissions across their building projects. Between maximum profit and environment management, mathematical programming can be used as a decision support tool concerning the optimal green building projects portfolio. This environment strategic decision problem is addressed in this study where an activity-based costing decision model incorporating carbon tax costs and construction resources constraints is developed from the perspectives of capacity expansion and green technology outsourcing. The results illustrate the positive contribution of the mathematical programming approach to achieve viable green building projects portfolio solutions. Sensitivity analyses are carried out to analyse the impact of carbon footprint emission variation on maximum profit, and the corresponding results are discussed.     

广东省火电厂烟气脱硫装置的经济技术分析

简要介绍了广东省7个火电厂现有的5种烟气脱硫技术装置：海水脱硫、荷电干式烟气脱硫、湿式石灰石／石膏法烟气脱硫、DCL燃煤固硫剂脱硫及烟气循环流化床脱硫技术，对它们的经济、技术性进行了分析比较。     

Emerging technologies for removing nonpoint phosphorus from surface water and groundwater: introduction

Coastal and freshwater eutrophication continues to accelerate at sites around the world despite intense efforts to control agricultural P loss using traditional conservation and nutrient management strategies. To achieve required reductions in nonpoint P over the next decade, new tools will be needed to address P transfers from soils and applied P sources. Innovative remediation practices are being developed to remove nonpoint P sources from surface water and groundwater using P sorbing materials (PSMs) derived from natural, synthetic, and industrial sources. A wide array of technologies has been conceived, ranging from amendments that immobilize P in soils and manures to filters that remove P from agricultural drainage waters. This collection of papers summarizes theoretical modeling, laboratory, field, and economic assessments of P removal technologies. Modeling and laboratory studies demonstrate the importance of evaluating P removal technologies under controlled conditions before field deployment, and field studies highlight several challenges to P removal that may be unanticipated in the laboratory, including limited P retention by filters during storms, as well as clogging of filters due to sedimentation. Despite the potential of P removal technologies to improve water quality, gaps in our knowledge remain, and additional studies are needed to characterize the long-term performance of these technologies, as well as to more fully understand their costs and benefits in the context of whole-farm- and watershed-scale P management.     

Economic considerations for wastewater upgrading alternatives: an Israeli test case

Sewage effluent for land application is becoming an increasingly important source of irrigation water in many semi-arid regions of the world. Two main approaches to the use of sanitation to upgrade effluent for reuse in agriculture were analyzed: (i) sanitizing to the level required for each crop; or (ii) upgrading all effluent to the sanitary level mandated for unrestricted irrigation (<10 fecal coli/100mL). The first approach was authorized by the Israeli health authorities, who consider irrigation with secondary effluent to be complementary to the treatment process. The other approach was conceived mainly by the agricultural and environmental establishments, which debited the additional financial burden to the urban sector and/or the 'general public'. We show that upgrading all effluents in Israel to 'unrestricted irrigation quality' would cost $69 million each year for upgrading alone, in addition to the costs of treatment to the sanitary level required for each individual crop and of observing all the necessary additional precautions and boundaries. This difference in cost stems from the fact that most effluent is used for the irrigation of non-edible crops, for which partial pathogen removal is sufficient. Thus, upgrading to the sanitary level required by the most sensitive crops would be rather wasteful.     

Biofuels – tools for achieving environmental goals or green place branding? Present drivers and future visions in two Swedish municipalities

This paper presents a study of two Swedish municipalities’ engagement in biogas development. To analyse the drivers of such biogas development, the conceptual framing incorporates two perspectives on local biogas policy: first, policy drivers as connected to environmental goals and, second, policy as a matter of green place branding. The results indicate that biogas engagement serves as a self-governing activity with the fulfilment of environmental goals as a driver; furthermore, it is a way of expressing the mission of municipalities as “engines” of environmental policy. In one studied municipality, biogas engagement has an important symbolic value for green identity, meaning that green place branding is a driver. Still, interviewed actors from both municipalities lack clear long-term visions of biogas. Further studies of biofuel production should critically investigate visions of the future among central and local governments and evaluate the implications of municipalities as biofuel producers.     

Bioreactor applications in waste treatment

An overview of bioreactor applications in treatment of gaseous, liquid and solid wastes is presented with emphasis on newer technologies. Waste treatment is considered in a broad context including concentration by bioaccumulation, degradation to substances with reduced environmental impact and upgrading to such useful products as feeds, foods and fuels. Biofilters and bioscrubbers for gaseous pollutants, high-rate municipal and industrial wastewater treatment in airlift bioreactors, reactor-based soil bioremediation, artificial wetland filters for liquid effluents, and protein enrichment of agricultural solid residues are some of the technologies reviewed. The various treatment strategies are illustrated with examples. The developments discussed point to an increasing role for bioreactor based processes in waste treatment and reuse.