苏南运河镇江段水环境污染特征及治理对策

利用2010~2012年例行监测数据和2011年实地补充监测数据对苏南运河镇江段水环境状况进行分析,并采用等标污染负荷法对该区域污染源数据进行评价。结果表明:苏南运河镇江段在2010~2012年期间污染情况较为严重,其主要超标项目为总氮、氨氮、总磷、COD Cr,总氮项目超标2.706~2.998倍,显示污染类型以氮磷类和有机类为主。研究区域内污染负荷以生活污水的排放所造成的污染的贡献率最大(占56.8%),农业面源排放所造成的污染居第2位(占32.3%),表明苏南运河镇江段的治理重点在于生活污水和农业面源的控制上。在此结论基础上,提出一整套有针对性的水环境污染防治措施的完整体系。     

红枫湖流域主要入湖污染物调查与分析评价

为研究红枫湖流域主要入湖污染物情况,采用现场调查、资料收集等方法计算红枫湖流域主要入湖污染物,并分析各污染物的各类型污染源贡献率、各支流贡献率、内源和外源比值等情况。结果表明:在各种降水情景下,入湖的各污染物总量大小顺序均为COD总氮氨氮总磷;各污染物(COD、氨氮、总磷、总氮)入湖量贡献率均是羊昌河最大、麦包河最小,其贡献率范围分别为46.33%~76.6%和0.4%~0.6%;入湖主要污染物(COD、总氮、总磷)主要以外源为主,氨氮则以内源污染为主;研究为红枫湖水环境质量改善、治理方向提供技术支撑。     

岷江大桥控制单元水体氨氮和总磷源解析

采用单因素法对岷江流域国控断面的岷江大桥水体进行评价,从污染源分担率、污染物时空变化等方面解析污染物的主要来源与变化。结果表明,水体不达标的主要因子为氨氮和总磷;污染物的主要来自城镇生活污水和规模化畜禽养殖废水的不达标排放,按各个污染源占比统计,2个主要污染源对于氨氮和总磷的污染分担率分别是42.54%、35.31%;受上游来水、其他补给水源的影响,氨氮浓度集中在1~5月超标严重,在2013年4月份出现峰值,总磷在2011~2014年普遍超标严重,在2014年5月出现峰值,由于"十二五"期间治污力度的加强,2015年氨氮污染趋势得到控制,总磷浓度明显有所降低,MIKE 21二维水动力水质模型模拟显示只要汇入支流断面均达到要求、污染负荷得到有效控制,控制单元能满足达标要求;最后从源头减排、区域综合整治、全程监管3个方面构建了使控制单元水体达标的策略。     

岷江流域氨氮状况浅析

根据岷江断面水质氨氮监测数据,对岷江流域水质氨氮状况进行分析,阐述了岷江流域氨氮空间分布情况,支流和干流达标率情况、氨氮浓度的月季变化,并选择了5个代表性断面进行了氨氮浓度变化趋势分析,提出了氨氮污染防治建议。结果表明干流达标率好于支流达标率,2～4月份氨氮浓度高些,8～9月份氨氮浓度较低。岷江流域的氨氮状况的分析为更好地保护岷江流域的水资源提供一些理论依据。     

京杭大运河(无锡段)及其支流沉积物中重金属污染现状及分布特征

依据沉积学原理和水体沉积物重金属的环境地球化学特性，用地积累指数法和改进多变量Chernoff脸谱图，对京杭大运河（无锡段）和支流沉积物中重金属的污染状况以及不同重金属的地积累程度进行了综合性的评价。研究结果表明：（1）京杭大运河（无锡段）及支流沉积物中重金属的污染可划分为3个区域：锡北运河、古运河综合重污染区；京杭大运河无锡市段、京杭大运河无锡上游段、下游段及梁溪河综合中等污染区；锡澄运河相对较轻污染区。（2）京杭大运河（无锡段）及支流沉积物中重金属Cu、Zn的污染严重；Pb、As的污染中等；Cr的污染分布较均匀；Hg和Cd的污染程度较其它金属弱一些；Ni基本无污染。     

浅析涪江流域遂宁段氨氮和总氮的相关性

根据2015年涪江流域遂宁段桂花、老池两个断面氨氮和总氮的每月例行监测数据,研究了遂宁市城区、大气降水对氨氮和总氮浓度的影响,分析了在污染程度不同的水体中氨氮所占总氮的比例,并考察了氨氮和总氮两者的相关性。结果发现涪江流经遂宁市城区后,氨氮和总氮的浓度均有所升高,且总氮的升高幅度较小;这两个断面的氨氮和总氮浓度随时间均呈现出先升高、后下降,再升高的变化趋势;降水具有削减氨氮和总氮浓度的作用,且对氨氮的削减幅度较大;污染较重水体中,氨氮所占总氮的比例较大;两个断面的氨氮和总氮均具有较好的相关性,相关系数分别是0.984 3和0.925 5,并分别建立了线性回归方程。     

水环境多环芳烃污染溯源研究

基于正定矩阵因子分解（Positive Matrix Factorization,PMF）模型对石马河河口及滨岸带中多环芳烃（Polycyclic aromatic hydrocarbons,PAHs）污染来源及贡献率进行解析,分别于2021年4月（平水期）和7月（丰水期）采集地表水及表层沉积物水样进行研究分析。结果表明：该研究区内PAHs污染的来源主要包括原油泄漏、煤炭燃烧、交通运输及生物质燃烧等,其中,交通运输源对研究区沉积物中PAHs的贡献率超过60%;交通运输及煤炭燃烧源对地表水中PAHs的贡献率之和接近80%;原油泄漏与交通运输源对研究区悬浮颗粒中PAHs的贡献率之和接近70%。研究结果可为石马河地区水资源绿色开发与PAHs污染治理提供一定依据。     

中国煤炭消费对PM2.5污染的影响研究

国务院颁布的《大气污染防治行动计划》明确提出制定国家煤炭消费总量中长期控制目标,到2017年,煤炭占能源消费总量比重降低到65%以下,然而煤炭消费对PM_(2.5)污染的贡献到底多大,这是当前亟待研究的科学问题。为定量分析煤炭消费对我国PM_(2.5)污染的影响,本研究首先计算了2012年煤炭消费产生的大气污染物排量,然后利用CAMx空气质量模型,分别采用组分分析法和情景模拟法两种方法研究了煤炭消费对全国PM_(2.5)污染的影响。组分分析法研究表明,煤炭消费对全国PM_(2.5)年均浓度的贡献率约为61%,其中煤炭直接燃烧、煤炭相关行业的贡献率分别约为37%、24%;情景模拟法研究表明,煤炭消费对全国PM_(2.5)年均浓度的贡献率约为56%。因此,我国由于煤炭消费对全国PM_(2.5)年均浓度的贡献率为56%~61%。     

四川省出川断面主要污染物通量及来源研究

以2001～2007年实测水文、水质数据为基础,计算了四川省主要出川断面高锰酸盐指数(CODMn)和氨氮(NH3-N)污染负荷通量;利用断面水质目标约束,通过污染负荷历时曲线,分析了区域水环境承载力;在基流分割的基础上,利用水文分割法,识别了区域污染物的主要来源,为从源头上开展三峡水库水环境保护提供数据支撑。分析结果表明,各出川断面干流主要污染物(CODMn、NH3-N)大致在可接受的范围内,2001年以来,出川断面CODMn通量呈降低的趋势,有效的减缓了输入三峡库区的污染物总量,氨氮通量整体稳定。嘉陵江、涪江、渠江流域污染物来源主要为非点源,应重点加强面源的污染防控;长江干流为点面源混合型,简单的削减点源已不能保证高功能水体要求,应加强点源和面源污染的综合防控。     

辽宁省太子河水质现状及影响因素研究

对2015-2020年辽宁省太子河干流断面水质状况进行了统计分析,以氨氮、COD、总磷3项指标分析了太子河水质的沿程变化情况,结果表明,太子河中下游水质整体较差,且主要污染指标为氨氮.结合太子河流域的自然社会属性,支流河水质较差及农业农村污染较重导致这种水质状况,并在此基础上提出了太子河流域水质改善的措施建议.     

Mass Load-Based Pollution Management of the Han River and Its Tributaries, Korea

Spatio-temporal variations of biochemical oxygen demand (BOD) and total coliform (TC) in the Han River, Korea, were investigated in terms of concentration-based and mass loading-based approaches. Considering the river water quality criteria regulated by the Ministry of Environment in Korea, the tributaries linked to the mainstream of the Han River were found to be highly contaminated with respect to both BOD and TC and, in fact, most of the tributaries exceeded the maximum water quality criteria. To evaluate the pollution impact of tributaries on the mainstream, the monthly water quality monitoring data for six years (from 1995 to 2000) were collected from the Han River basin, and statistically analyzed using Pearson’s correlation coefficient. The results revealed that mass loading-based approach was superior to the concentration-based approach for effective Han River watershed management. Overall results supported that the mass loading-based approach associated with total maximum daily loads (TMDL) management would be a useful and suitable protocol in watershed management for improving the water quality of the Han River and protecting public health. Therefore, this study supporting TMDL management can be applicable to a wide array of contaminants and watershed settings in Korea.     

沱江上游支流石亭江水环境容量及模拟探讨

本文在对沱江上游支流石亭江水质现状监测和区域污染源调查的基础上,计算了石亭江水环境容量;探讨了石亭江化工开发试验区废水中难降解污染物排放对河流影响的水质模拟方法,导出了多点源同时排放对河流影响的水质模拟递推式。计算结果表明:控制开发试验区废水氟排放是防治石亭江和沱江水污染的主要途径。     

Assessing pollution prevention program by QUAL2E simulation analysis for the Kao-Ping River Basin, Taiwan

Wise and sustainable uses of water resources are essential for an effective river-basin-management planning. Recent management strategy further addresses the fact that quantity and quality of water are closely interrelated, and both must be considered simultaneously for all water resources and water quality management practices. The aim of this paper is to explore the impacts of water resources redistribution and pollution prevention actions between and within river basins simultaneously in South Taiwan. Much emphasis will be placed on assessing the impacts of water transfer over natural boundary to satisfy the needs of industrial development in the Tseng-Wen River system and its resultant influence on the water quality in the downstream area of the Kao-Ping River system where the pollution prevention program is to be implemented. The Kao-Ping River was further characterized hydraulically and environmentally, based on a full investigation of discharges and withdrawals in the river reaches. QUAL2E was successfully calibrated and validated using data collected between 1998 and 1999, and the model was capable of predicting the concentrations of biochemical oxygen demand, dissolved oxygen, total phosphate-phosphorus, and ammonia-nitrogen (NH3-N) for the entire river system. With the aid of QUAL2E simulation model, it shows eliminating the pig farming activities and constructing the sewer systems in the upstream area of Kao-Ping River cannot guarantee the full compliance with water quality standards in the downstream area and water transfer in the upstream area further increases negative impacts on the water quality in the wet season. The predicted situation of water quality in the dry season may even present worse condition. Additional water pollution control policy, such as the use of economic instruments, for controlling and reducing the waste-load of biochemical oxygen demand and ammonia-nitrogen is needed in the Kao-Ping River system in the long run.     

闽江支流梯级电站开发对生态环境的影响及防治措施

采用现场调查监测，并结合收集的水电、渔业等方面资料，对闽江上游渔塘溪支流上的布上、碧州、马坪三级电站开发对植被、水土保持、水生植物、浮游生物、底栖动物、鱼类、水质的影响作了分析。结果表明，电站开发造成库区污染严重、富营养化、河段断流并产生一定的不利影响等。提出其环境减缓补救措施及今后闽江支流梯级电站开发生态环境保护的防治措施。     

Nitrogen contamination in the Yellow River basin of China

Nitrogen contamination is one of the most serious problems in the Yellow River of China. This study was conducted to analyze monitoring data on nitrogen contamination for the Yellow River basin in the years 1980, 1990, 1997, and 1999. Several significant results have arisen from the study. First, in conjunction with an increase in economic indexes from the Yellow River's upper basin to its lower basin, the nitrogen concentration in the tributaries also showed an increasing trend from the upper to the lower basin, which, in turn, led to an increase in the nitrogen concentration of the mainstream from the upper to the lower reaches. Second, nitrogen in the river water in the mainstream and the tributaries of the Yellow River was attributed mainly to point sources. In spite of the fact that the ratio of point to nonpoint sources decreased from 2.7 in 1990 to 1.8 in 1997 for total inorganic nitrogen in river water at the Tongguan Station in the lower basin, point sources increased more than nonpoint sources. Third, the ammonium nitrogen and total inorganic nitrogen content of the river water increased significantly in the mainstream and the tributaries during the 1980-1999 period, a change caused by an increase in wastewater discharge and nitrogenous fertilizer application in the Yellow River catchment.     

RED RIVER OF THE NORTH BASIN,MINNESOTA, NORTH DAKOTA,AND SOUTH DAKOTA1

ABSTRACT: The environmental setting of the Red River of the North basin within the United States is diverse in ways that could significantly control the areal distribution and flow of water and, therefore, the distribution and concentration of constituents that affect water quality. Continental glaciers shaped a landscape of very flat lake plains near the center of the basin, and gently rolling uplands, lakes, and wetlands along the basin margins. The fertile, black, fine-grained soils and landscape are conducive to agriculture. Productive cropland covers 66 percent of the land area. The principal crops are wheat, barley, soybeans, sunflowers, corn, and hay. Pasture, forests, open water, and wetlands comprise most of the remaining land area. About one-third of the 1990 population (511,000) lives in the cities of Fargo and Grand Forks, North Dakota and Moorhead, Minnesota. The climate of the Red River of the North basin is continental and ranges from dry subhumid in the western part of the basin to subhumid in the eastern part. From its origin, the Red River of the North meanders northward for 394 miles to the Canadian border, a path that is nearly double the straight-line distance. The Red River of the North normally receives over 75 percent of its annual flow from the eastern tributaries as a result of regional patterns of precipitation, evapotranspiration, soils, and topography. Most runoff occurs in spring and early summer as a result of rains falling on melting snow or heavy rains falling on saturated soils. Lakes, prairie potholes, and wetlands are abundant in most physiographic areas outside of the Red River Valley Lake Plain. Dams, drainage ditches, and wetlands alter the residence time of water, thereby affecting the amount of sediment, biota, and dissolved constituents carried by the water. Ground water available to wells, streams, and springs primarily comes from sand and gravel aquifers near land surface or buried within 100 to 300 feet of glacial drift that mantles the entire Red River of the North basin. Water moves through the system of bedrock and glacial-drift aquifers in a regional flow system generally toward the Red River of the North and in complex local flow systems controlled by local topography. Many of the bedrock and glacial-drift aquifers are hydraulically connected to streams in the region. The total water use in 1990, about 196 million gallons per day, was mostly for public supply and irrigation. Slightly more than one half of the water used comes from ground-water sources compared to surface-water sources. Most municipalities obtain their water from ground-water sources. However, the largest cities (Fargo, Grand Forks and Moorhead) obtain most of their water from the Red River of the North. The types and relative amounts of various habitats change among the five primary ecological regions within the Red River of the North basin. Headwater tributaries are more diverse and tend to be similar to middle-reach tributaries in character rather than the lower reaches of these tributaries for the Red River of the North. Concentrations of dissolved chemical constituents in surface waters are normally low during spring runoff and after thunderstorms. The Red River of the North generally has a dissolved-solids concentration less than 600 milligrams per liter with mean values ranging from 347 milligrams per liter near the headwaters to 406 milligrams per liter at the Canadian border near Emerson, Manitoba. Calcium and magnesium are the principal cations and bicarbonate is the principal anion along most of the reach of the Red River of the North. Dissolved-solids concentrations generally are lower in the eastern tributaries than in the tributaries draining the western part of the basin. At times of low flow, when water in streams is largely from ground-water seepage, the water quality more reflects the chemistry of the glacial-drift aquifer system. Ground water in the surficial aquifers commonly is a calcium bicarbonate type with dissolved-solids concentration generally between 300 and 700 milligrams per liter. As the ground water moves down gradient, dissolved-solids concentration increases, and magnesium and sulfate are predominant ions. Water in sedimentary bedrock aquifers is predominantly sodium and chloride and is characterized by dissolved-solids concentrations in excess of 1,000 milligrams per liter. Sediment erosion by wind and water can be increased by cultivation practices and by livestock that trample streambanks. Nitrate-nitrogen concentrations also can increase locally in surficial aquifers beneath cropland that is fertilized, particularly where irrigated. Nitrogen and phosphorous in surface runoff from cropland fertilizers and nitrogen from manure can contribute nutrients to lakes, reservoirs, and streams. Some of the more persistent pesticides, such as atrazine, have been detected in the Red River of the North. Few data are available to conclusively define the presence or absence of pesticides and their break-down products in Red River of the North basin aquifers or streams. Urban runoff and treated effluent from municipalities are discharged into streams. These point discharges contain some quantity of organic compounds from storm runoff, turf-applied pesticides, and trace metals. The largest releases of treated-municipal wastes are from the population centers along the Red River of the North and its larger tributaries. Sugar-beet refining, potato processing, poultry and meat packing, and milk, cheese, and cream processing are among the major food processes from which treated wastes are released to streams, mostly in or near the Red River of the North.     

GIS-ASSISTED REGRESSION ANALYSIS TO IDENTIFY SOURCES OF SELENIUM IN STREAMS1

ABSTRACT: Using a geographic information system, a regression model has been developed to identify and to assess potential sources of selenium in the Kendrick Reclamation Project Area, Wyoming. A variety of spatially distributed factors was examined to determine which factors are most likely to affect selenium discharge in tributaries to the North Platte River. Areas of Upper Cretaceous Cody Shale and Quaternary alluvial deposits and irrigated land, length of irrigation canals, and boundaries of hydrologic subbasins of the major tributaries to the North Platte River were digitized and stored in a geographic information system. Selenium concentrations in samples of soil, plant material, ground water, and surface water were determined and evaluated. The location of all sampling sites was digitized and stored in the geographic information system, together with the selenium concentrations in samples. A regression model was developed using stepwise multiple regression of median selenium discharges on the physical and chemical characteristics of hydrologic subbasins. Results indicate that the intensity of irrigation in a hydrologic subbasin, as determined by area of irrigated land and length of irrigation delivery canals, accounts for the largest variation in median selenium discharges among subbasins. Tributaries draining hydrologic subbasins with greater intensity of irrigation result in greater selenium discharges to the North Platte River than do tributaries draining subbasins with lesser intensity of irrigation.     

A METHOD FOR DETERMINING SALT SOURCES IN SURFACE WATERS'

ABSTRACT: This paper presents a method for determining the causes of salinization of surface waters, in this case the upper Colorado River and its tributaries in Texas. The analysis, which includes a combination of statistical analysis and graphical methods, indicates that among the sources of salt (e.g., saline ground water discharge into surface waters and storm runoff, both surface and shallow subsurface, and washing minerals into surface waters) the major contributor is saline ground water, which discharges into the river and streams. Data also points to salt plume intrusion into the river and streams from sources of salt in the aquifers.     

浙江省上虞市水资源分析及饮用水水源地水质现状评价研究

本文通过大量的基础数据调研,获取了浙江省上虞市水资源现状及饮用水水源地水质现状的第一手资料,对当地的水资源空间分布现状及水资源平衡进行了科学分析,并结合当地的社会经济发展趋势及城市发展中的用水需求增长趋势,提出了科学合理的水源地建设与保护建议。自2009年6月起,对汤浦水库、四明湖水库、隐潭溪、下管溪、总干渠等5个水源地进行了长期连续监测,为进一步保护优质水源地,城乡统筹一体化供水系统的建设提供科学依据。监测结果表明,作为重要备用水源地的总干渠目前呈现有机微污染特征,需要加强水源保护区内的环境管理,尽快设立水源保护区,确定合理的入河污染物的源头削减任务,以确保2010年前达到水功能区的水质目标。     

TRANSPORT OF DIAZINON IN THE SAN JOAQUIN RIVER BASIN,CALIFORNIA1

ABSTRACT: Most of the application of the organophosphate insecticide diazinon in the San Joaquin River Basin occurs in winter to control wood-boring insects in dormant almond orchards. A federalstate collaborative study found that diazinon accounted for most of the observed toxicity of San Joaquin River water in February 1993. Previous studies focused mainly on west-side inputs to the San Joaquin River. In this 1994 study, the three major east-side tributaries to the San Joaquin River - the Merced, Tuolumne, and Stanislaus rivers - and a downstream site on the San Joaquin River were sampled throughout the hydrographs of a late January and an early February storm. In both storms, the Tuolumne River had the highest concentrations of diazinon and transported the largest load of the three tributaries. The Stanislaus River was a small source in both storms. On the basis of previous storm sampling and estimated travel times, ephemeral west-side creeks probably were the main diazinon source early in the storms, whereas the Tuolumne and Merced rivers and east-side drainages directly to the San Joaquin River were the main sources later. Although 74 percent of diazinon transport in the San Joaquin River during 1991–1993 occurred in January and February, transport during each of the two 1994 storms was only 0.05 percent of the amount applied during preceding dry periods. Nevertheless, some of the diazinon concentrations in the San Joaquin River during the January storm exceeded 0.35 μ/L, a concentration shown to be acutely toxic to water fleas. On the basis of this study and previous studies, diazinon concentrations and streamflow are highly variable during January and February storms, and frequent sampling is required to evaluate transport in the San Joaquin River Basin.