共查询到19条相似文献,搜索用时 111 毫秒
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本文在环境水文地质地球化学调查的基础上,以相似论为依据,采用模拟实验方法,获取NH4在水-岩土体系中的运移规律,进而建立实验拟合模型,经检验修正,可初步用于污染预测,这种把NH4的力学迁移与地球化学的融为一体的建模方法,具有合理,直观,简便等优点。 相似文献
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一、引言致突变实验约有200多种,大多处于探索阶段。目前,较为可靠的已得到国际公认的致突变实验有Ames法和微核实验法等。而微核实验法以小白鼠骨髓多染红细胞微核计数法,已公认为环境毒理检验的手段之一。 相似文献
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用示波极谱法对酚类化合物进行分析,方法的线性范围在3.0×10 ̄(-5)~8.0×10 ̄(-3)mg/L之间,最低检出限为6.0×10 ̄(-6)mg/L,浓度为0.26×10 ̄(-2)~0.52mg/L时的相对标准偏差为1.8%~4.0%,浓度为0.3×10 ̄(-2)~0.51mg/L时的回收率为95.0%~102.1%,其结果与4-氨基胺替比林分光光度法相一致。 相似文献
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利用微型滴定法测定白醋中的总酸度,并对常量实验和微型实验的测定结果进行了比较分析。结果两种方法无显著性差异,F检验、t检验均在允许范围内,微型实验的准确度和精密度均达到常量实验的测定水平,完全满足化学分析要求,并且有效地节省了实验试剂,大大降低了实验成本。 相似文献
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本文以SO4^2-与过量Ba^2+形成BaSO4沉淀反应为基础,较详细地讨论了反应条件,从而拟定了用AAS和ICP-AES间接测定天然水中SO4^2-的方法、确定了方法的精密度,AAS法的RSD%为1.5,ICP-AES法为3.2, 两种方法对比分析的结果接近,误差为1.0%(相对)。用于天然水中SO4^2-的测定,获得满意的结果。 相似文献
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采用吸附法对酸水汽提净化水中的酚进行了处理。这种方法不仅可以满足对实验浓度酚的处理,同时可以回收酚。通过吸收过程及不同流速对比实验得出:树脂的吸附效果显著,吸附能力较强,吸附时间较长;净化水的流速与吸附效果具有一定的线性关系;不同流速吸附效果不同,对应树脂需要再生的时间也不同。应用结果表明:吸附法中较可行的方法为树脂吸附法。 相似文献
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超声-双氧水和亚铁离子体系处理含酚废水研究 总被引:3,自引:2,他引:3
在实验装置上对超声-双氧水和亚铁离子体系联合处理含酚废水进行了实验研究。主要考察了废水初始pH值、初始双氧水浓度、超声功率、反应时间等因素对酚去除率的影响。实验结果表明:超声辐射可以在双氧水和亚铁离子体系氧化过程中起加速反应的作用,而且随着超声功率的增大,加速反应的能力增强;实验条件下废水初始pH值为4~6.8,初始双氧水浓度为140mg/L时酚去除效果最佳;超声-双氧水和亚铁离子体系处理含酚废水过程中苯酚的降解规律符合表现一级反应。 相似文献
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As a large and diverse group of secondary metabolites, phenolic compounds are one of the most common chemical pollutants present in water resources. these compounds can have toxic effects on ecosystems and humans. Therefore, their removal from water sources appears to be of great importance. In this study, a magnetic graphene oxide (MGO) photocatalyst was synthesized and used to remove phenol from water. The fabricated GO magnetic nanocomposites were determined by SEM and FTIR techniques. Afterward, these nanoparticles were used to remove phenol from aquatic media considering different operational parameters, including pH of the solution, initial concentration of phenol, contact time, and adsorbent dosage. The results showed that the magnetized GO nanoparticles could remove 90.83% of phenol molecules under the optimal conditions of solution pH = 3.0, initial phenol concentration of 20 mg/L, adsorbent concentration of 300 mg/L, and contact time of 120 min. additionally have compared the results of UV, Fe3O4/GO, and Fe3O4/GO/UV on the removal of phenol under optimum conditions. Accordingly, the phenol removal efficiencies for UV alone, Fe3O4/GO, and Fe3O4/GO/UV were obtained at 4.5, 65.73, and 90.83%, respectively. Based on the findings, the prepared magnetic GO nanoparticles have extended capabilities such as easy and rapid separation from sample and high potential in removing phenolic compounds, so, it can be introduced as an appropriate adsorbent for removal of this pollutant from water and wastewater. 相似文献
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Adsorption of phenol and its derivatives from water using synthetic resins and low-cost natural adsorbents: a review 总被引:1,自引:0,他引:1
In this article, the technical feasibility of the use of activated carbon, synthetic resins, and various low-cost natural adsorbents for the removal of phenol and its derivatives from contaminated water has been reviewed. Instead of using commercial activated carbon and synthetic resins, researchers have worked on inexpensive materials such as coal fly ash, sludge, biomass, zeolites, and other adsorbents, which have high adsorption capacity and are locally available. The comparison of their removal performance with that of activated carbon and synthetic resins is presented in this study. From our survey of about 100 papers, low-cost adsorbents have demonstrated outstanding removal capabilities for phenol and its derivatives compared to activated carbons. Adsorbents that stand out for high adsorption capacities are coal-reject, residual coal treated with H3PO4, dried activated sludge, red mud, and cetyltrimethylammonium bromide-modified montmorillonite. Of these synthetic resins, HiSiv 1000 and IRA-420 display high adsorption capacity of phenol and XAD-4 has good adsorption capability for 2-nitrophenol. These polymeric adsorbents are suitable for industrial effluents containing phenol and its derivatives as mentioned previously. It should be noted that the adsorption capacities of the adsorbents presented here vary significantly depending on the characteristics of the individual adsorbent, the extent of chemical modifications, and the concentrations of solutes. 相似文献
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Photocatalytic degradation of phenol on different phases of TiO2 particles was examined under 400-W UV irradiation. The effects of various operating parameters including TiO2 dosage, solution pH (4–10), and initial phenol concentration (0.13–1.05 mM) on phenol degradation were investigated. Three forms of TiO2 photocatalysts such as pure anatase phase, pure rutile phase, and the mixed phase were prepared by sol-gel method and followed annealing at different temperatures. The annealing temperature used were 500 °C, 700 °C and 900 °C for pure anatase phase, the mixed phase, and pure rutile phase, respectively. It was shown that pure anatase TiO2 exhibited higher photocatalytic activity than the physical mixture of pure anatase and rutile TiO2. Moreover, the TiO2 particle with a specific fraction of mixed anatase and rutile phases exhibited better performance than pure anatase TiO2. Finally, the degradation rate could be satisfactorily fitted by a pseudo-first-order kinetic model. 相似文献