Estimation of annual CH4 and N2O emissions from fluidised bed combustion: An advanced measurement-based method and its application to Finland

The aim of this study was to develop and apply an advanced, measurement based method for the estimation of annual CH₄ and N₂O emissions and thus gain improved understanding on the actual greenhouse gas (GHG) balances of combustion of fossil fuels, peat, biofuels and REF. CH₄ and N₂O emissions depend strongly on combustion conditions, and therefore the emission factors used in the calculation of annual emissions contain significant uncertainties. Fluidised bed combustion (FBC) has many good properties for combustion of different types of fuels and fuels of varying quality, e.g., biofuels and wastes. Therefore, it is currently increasing its market share. In this study, long term measurements (up to 50 days) were carried out at seven FBC boilers representing different size classes, loadings and fuel mixes. Both decreasing load and increasing share of coal in fuel mix increased N₂O emissions. Measurement results from different loading levels were combined with the common loading curves of similar plants in Finland to estimate annual emissions. Based on the results, recommendations for emission factors for the Finnish GHG emission inventory are given. The role of FBC as a potential technology for the utilisation of biofuels and wastes with future GHG reduction requirements is discussed.     

Modeling the Production and Uses of Biological Resources from the Viewpoint of Energy Flow in a Rural Village in Sichuan,China

This study aimed at clarifying the impact of deforestation and afforestation on the quality of life in a village in Sichuan Province, China. We devised a conceptual model of bioresource production and use based on quantified energy flow. The basic structure of the model has three sectors: production, use, and externals. We developed comprehensive methodology to quantify the model. Bioresource use per person in 1997 was 3.7 GJ for food, 10.2 GJ for fodder, 0.2–0.4 GJ for building material, 12.8 GJ for fuel, and 1.8 GJ for fertilizer, totaling 28.6–28.8 GJ.We used four environmental indicators to evaluate bioresource production and use: a biological productivity indicator, a use-efficiency indicator, a supply–demand balance indicator, and a self-sufficiency indicator. Use of these indicators showed that supply-demand balance of fuel was dramatically improved from 30% to 85% by afforestation, but 99% of bioresource use still depends on domestic products. Thus, it is necessary to improve biological productivity and promote the efficient use of bioresources to achieve sustainable living in the area. Massive deforestation in the 1950s caused a direct shortage of building material and fuel wood. The shortage of wood led to a stagnation in the rebuilding of houses, and fuel wood was substituted with crop residues. Because crop residues had been used for fertilizer and fodder, their use as fuel caused a shortage of fertilizer and fodder. This was an indirect impact of deforestation on peoples quality of life.     

A cost-effective microbial slurry technology for rapid composting of municipal solid wastes in waste dump sites in India and its feasibility for use in Australia

This short article reports on commercial composting slurry now available in India. The slurry culture containing active decomposer bacteria and enzymes is spread on the surface of the garbage and inside the heaps in windrows constructed at waste dump sites. The microbes produce hydrolysing enzymes to break down the long chain complexes of the organic substrates. About 1 kg of slurry culture in the colloidal emulsion form mixed with 20 litres of water is sprayed on about 3 m of solid waste. For one tonne of waste 200 litres of slurry water are needed. The waste heaps are turned once in 7 to 10 days for proper aeration and the inoculant slurry is sprayed at each turning to enhance decomposition and to maintain the proper moisture level which is usually 45–55 percent. The process is exothermic and the windrows reach a temperature of 70°–75°C within 24–36 hours, killing many harmful pathogens and repelling all birds, stray animals, flies and mosquitos from the dump site. The entire process is completed within 4–6 weeks and as the decomposition is completed the temperature falls to normal. About 40–45 percent of the undecomposed matter is of recyclable materials, and of the rest about 25–30 percent requires safe disposal in adjacent land-fill sites. The problem of emission from tip gases and of leachate and discharge of effluents is greatly reduced. The foul odor of the tip also disappears within 2–3 days of sanitization. The compost produced is rich in sodium, potassium and phosphorous as well as certain trace elements, and contains active nitrogen fixing and phosphate solubulising bacteria.     

Particulates and carbon monoxide pollution on production floor of steel recycling plant

For this study, particulates or particulate matter (PM) and carbon monoxide (CO) levels were monitored at different sections on the production floor of a scrap metal recycling factory. A Met‐One GT331 dust monitor and A Toxi‐Rae gas monitor were used to measure PM and CO concentrations, respectively. The 24‐hr averaging period concentrations of particulate matter having diameters of 2.5 microns or less in diameter (PM_2.5), particulate matter having diameters of 10 microns or less in diameter (PM₁₀), and total suspended particulates (TSP) within the plant ranged between 8.3 and 50.4 μg/m³, 12.0 and 151.3 μg/m³, and 30.0 and 285.0 μg/m³, respectively, while the maximum 8‐hr concentration of CO within the plant was 20.5 parts per million (ppm). The United States’ Environmental Protection Agency (US EPA) limits for PM_2.5, PM₁₀, and CO were exceeded only in the area around the furnace. Nigeria's Federal Ministry of Environment (FMENV), the World Health Organization (WHO), and the World Bank statutory limit for TSP were also exceeded in the area around the furnace. Toxicity potentials (TP) of the investigated pollutants were greater than 1.0 around the furnace, indicating that work spaces in proximity to the furnace could expose workers to adverse health conditions.     

Biomass resources as energy in Nepal

Nepal's economic activity is dominated by agriculture. The volume of exports is small. About a quarter of the foreign exchange earned from export is required to cover costs of imported fossil fuels. Fossil fuels supply less than 7% of total energy consumption. More than 90% of primary energy consumption is supplied by biomass resources, and forests are the major source of biomass. The sustainable fuelwood yield of forest is far less than the total consumption, which has caused severe forest denudation. Consumption of crop residues and animal dung for fuel are increasing because of fuelwood shortage. The paper outlines the consequences of biomass consumption in Nepal and past efforts at biomass resources management and indicates their effectiveness. A few major practical policy measures have been suggested to correct the situation. The experiences and measures for biomass resources management explained in this paper are expected to be useful to other countries facing a similar situation.     

Fuel substitution and efficient woodstoves: Are they the answers to the fuelwood supply problem in Northern Nigeria?

Fuelwood consumption in Northern Nigeria exceeds the sustainable production, and the deficit is currently met through long-distance transport from the southern part of the country at an artificially low cost Current household fuel consumption patterns and factors affecting stove choice are discussed. Little has been done to promote more efficient woodstoves in the region, but prospects for stove programs are only good where fuelwood is marketed and the policy environment is conducive. At subsidized official prices for kerosene, liquefied petroleum gas (LPG), and electricity, wood is more expensive on a net usable heat basis, but the high capital cost of stoves for these fuels prevents many households from switching. Moreover, these fuels are often only available at much higher parallel market prices, which result in wood being the less expensive choice. There is little prospect for substitution of coal, solar cookers, or biogas digesters.     

Sludge-grown algae for culturing aquatic organisms: Part I. Algal growth in sludge extracts

This project is aimed at studying the feasibility of using sewage sludge to prepare culture media for microalgae (Chlorella-HKBU) and the use of the sludge-grown algae as a feed for some aquatic organisms. Part I of the project included results on preparing sludge extracts and their use on algal culture. By comparing two culturing techniques, aeration and shaking, it was noted that both lag and log phases were shortened in the aeration system. A subsequent experiment noted that algal growth subject to aeration rates of 1.0 and 1.5 liters/min had similar lag and log phases. In addition, both aeration rates had a significantly higher (P < 0.05) final cell density than that of 0.5 liters/min. A detailed study on the variation of growth conditions on the algal growth was done. The results indicated that pH values of all the cultures declined below 5 at day 12. The removal rates of ammonia N ranged from 62% to 70%. The sludge-grown algae contained a rather substantial amount of heavy metals (µg/g): Zn 289–581, Cu 443–682, Ni 310–963, Mn 96–126, Cr 25–118, and Fe 438–653. This implied that the rather high levels of heavy metals may impose adverse effects on higher trophic organisms.     

Fuel substitution in sub-Saharan Africa

Deforestation and decline in agricultural productivity are major concerns over large parts of sub-Saharan Africa. One of the principal causes for both these phenomena is the export of woodfuels from rural agroecosystems to urban markets. This process is noteworthy because of the size of the trade. Wood fuels (fuelwood, charcoal, and agricultural residues) constitute the most important source of energy in these countries, varying from 60% to 95% of total energy consumption. In terms of the environmental impact of the fuelwood trade, solutions typically considered are the introduction of improved cookstoves, fuelwood plantations, and fuel substitution by conventional fuels. This article examines the structure of the fuelwood problem, reviews the successes and failures of past experiences, and focuses on the potential for fuel substitution as an option to reduce the urban demand for fuelwood.     

Arsenic levels in the marine ecosystem off the Kuwait coast, Arabian Gulf

Arsenic levels in seawater, microplankton (diatoms and dinoflagellates), shrimp (Penaeus semisulcatus), mollusc (Cerithium scabridum) and five types of fish (Maid, Nakroor, Nuwaiby, Suboor and Sheim) in five sampling stations (I–V) off the Kuwait coast were determined during the years 1995 to 1999. The maximum mean concentration of arsenic was observed in the order; the five fish (0.50–0.78 g g^–1)> mollusc (0.26 g g^–1)> shrimp (0.23 g g^–1)> particulate matter (0.03 g g^–1)> water and phytoplankton (0.02 g g^–1) from all the sites of the Kuwait coast. Station II possessed the maximum arsenic levels. In comparison with the arsenic levels in other parts of the globe, low arsenic levels were observed in most of the marine organisms off the Kuwait Coast. However, an increasing trend in arsenic concentrations was anticipated due to rapid local industrialization and on account of recent spills of arsenic compounds.     

Impact of Vegetative Cover on Runoff and Soil Erosion at Hillslope Scale in Lanjaron, Spain

Soil loss and surface runoff patterns over a four-year period (1997–2000) were studied in erosion plots from three hillslopes under different vegetative covers (Rosmarinus officinalis, Triticum aestivum and natural-spontaneous vegetation) in Lanjaron (Alpujarras) on the south flank of the Sierra Nevada of southeast Spain. The erosion plots were located on the hillslopes at 35.5% incline, at 1,480 m in altitude and with 41.8 m² (21 m×1.9 m) in area. The vegetative covers were tested for effectiveness in controlling the surface runoff and soil loss production. The highest runoff and erosion values, ranging from 114.1 to 1.7 mmyr^–1 and from 14,564.3 to 6.6 kgha^–1yr^–1, respectively, over the entire study period, were measured under the Triticum aestivum. In the Rosmarinus officinalis, runoff ranged from 7.9 to 1.3 mmyr^–1 and erosion from 156.4 to 2.3 kgha^–1yr^–1, while on the hillslope under natural-spontaneous vegetation, runoff ranged from 4.4 to 0.9 mmyr^–1 and erosion from 322.3 to 2.2 kgha^–1yr^–1. According to the results the vegetative covers of Rosmarinus officinalis and natural-spontaneous vegetation reduced the soil losses by 99 and 98%, with respect to the Triticum aestivum, and the runoff losses by 94 and 96%, respectively. Also, the Rosmarinus officinalis and natural-spontaneous plants influenced infiltration by intercepting much of the rainfall water respect to the Triticum aestivum. Monitoring allowed more direct linkages to be made between management practices and their impacts on runoff and soil erosion, thereby enabling to identify problems and take appropriate preventive measures to improve the management practices.     

Nitrogen turnover on organic and conventional mixed farms

Separate focus on crop fertilization or feeding practices inadequately describes nitrogen (N) loss from mixed dairy farms because of (1) interaction between animal and crop production and between the production system and the manager, and (2) uncertainties of herd N production and crop N utilization. Therefore a systems approach was used to study N turnover and N efficiency on 16 conventional and 14 organic private Danish farms with mixed animal (dairy) and crop production. There were significant differences in N surplus at the farm level (242 kg. N/ha. vs. 124 kg. N/ha. on conventional and organic dairy farms respectively) with a correlation between stocking rate and N surplus. N efficiency was calculated as the output of N in animal products divided by the net N import in fodder, manure and fertilizer. N turnover in herd and individual crops calculated on selected farms showed differences in organic and conventional crop N utilization. This is explained via a discussion of the rationality behind the current way of planning the optimum fertilizer application in conventional agriculture. The concept of marginal N efficiency is insufficient for correcting problems of N loss from dairy farms. Substantial reductions in N loss from conventional mixed dairy farms is probably unlikely without lower production intensity. The concept of mean farm unit N efficiency might be a way to describe the relation between production and N loss to facilitate regulation. This concept is linked to differing goals of agricultural development—i.e. intensification and separation vs. extensification and integration. It is discussed how studies in private farms—using organic farms as selected critical cases—can demonstrate possibilities for balancing production and environmental concern.     

Economics and GHG emission reduction of a PLA bio-refinery system—Combining bottom-up analysis with price elasticity effects

This paper analyses energy savings, GHG emission reductions and costs of bio-refinery systems for polylactic acid (PLA) production. The systems comprise ‘multi-functional’ uses of biomass resources, i.e. use of agricultural residues for energy consumption, use of by-products, and recycling and waste-to-energy recovery of materials. We evaluate the performance of these systems per kg of bio-based polymer produced and per ha of biomass production. The evaluation is done using data of Poland assuming that biomass and PLA production is embedded in a European energy and material market. First, the performance of different bio-refinery systems is investigated by means of a bottom-up chain analysis. Second, an analysis is applied that derives market prices of products and land depending on the own-price elasticity of demand. Thus, the costs of bio-refinery systems depending on the demand of land and material are determined. It is found that all PLA bio-refinery systems considered lead to net savings of non-renewable energy consumption of 70–220 GJ/(ha yr) and net GHG emission reductions of 3–17 Mg CO_2eq/(ha yr). Most of these PLA bio-refinery systems lead to net costs for the overall system of up to 4600 €/(ha yr). PLA production from short rotation wood leads to net benefits of about 1100 €/(ha yr) if a high amount of a high value product, i.e. fibres, is produced. Multi-functionality is necessary to ensure the viability of PLA bio-refinery systems from biomass with regard to energy savings and GHG emission reduction. However, the multi-functional use of biomass does not contribute much to overall incomes. Multifunctional biomass use – especially the use of biomass residues for energy consumption – contributes significantly to savings of non-renewable energy sources. Own-price elasticity of the demand for materials influences the overall costs of the bio-refinery system strongly. The own-price elasticity of land demand markets could become important if bio-refineries are introduced on a large scale.     

Determination of urinary lead in school children in Manzini, Swaziland, Southern Africa

Two hundred and fifty-seven urine samples collected from school children living in the Manzini region, Swaziland, were analysed for lead (Pb), using a graphite furnace atomic absorption spectrometer. The mean urine lead concentration for the urban schools ranged from 0.038–0.040 gml^–1, while that for the rural schools ranged from 0.017–0.022 gml^–1. The observed range shown by the urban schools was above the normal (for healthy humans) urine lead concentration of 0.035 gml^–1. However, the mean urine lead concentration for the rural schools was found to be lower than this value. The mean urine lead concentration for the urban schools was significantly higher than that of the rural schools. The differences in the mean urine lead concentrations for boys and girls from both urban and rural schools were found not to be significant, despite the higher values shown by the girls. The difference in lead concentrations between urban and rural schools in Manzini was thought to be due to the traffic density within the urban area.     

Effects of herbage removal on productivity of selected high-sierra meadow community types

We investigated the effects of herbage removal on three subalpine meadow plant communities in the Rock Creek drainage of Sequoia National Park, California, USA. In the xericCarex exserta Mkze. (short-hair sedge) type, annual aboveground productivity averaged 19 g/m² in control plots (clipped once after plant senescence in late September) over a five-year period. Annual aboveground productivity was enhanced about 30%–35% when plots in this community type were clipped more frequently (i.e., additional herbage removal in the early, mid, and late seasons) during each of four treatment years but was reduced by 13%–19% during a fifth (recovery) year in which all but late September clipping was suspended. In a moderately mesicEleocharis pauciflora (Lightf.) Link. (few-flowered spike rush)-Calamagrostis breweri Thurb. (short-hair grass) type, control plot productivity averaged 115 g/m²/yr and was reduced by 20–30% by the additional herbage removal. A more mesicDeschampsia caespitosa (L.) Beauv. (tufted hairgrass)-Carex rostrata Stokes, (beaked sedge) type had the greatest mean above-ground productivity (169 g/m²/yr) but also showed damage (i.e., decrease in productivity by 15%–20%) caused by the additional herbage removal. These data suggest that longterm, intensive herbage removal may be more detrimental to moderately mesic and mesic subalpine meadow community types than to xeric types.     

Solid fuels in chemical-looping combustion

The feasibility of using a number of different solid fuels in chemical-looping combustion (CLC) has been investigated. A laboratory fluidized bed reactor system for solid fuel, simulating a chemical-looping combustion system by exposing the sample to alternating reducing and oxidizing conditions, was used. In each reducing phase 0.2 g of fuel in the size range 180–250 μm was added to the reactor containing 40 g oxygen carrier of size 125–180 μm. Two different oxygen carriers were tested, a synthetic particle of 60% active material of Fe₂O₃ and 40% MgAl₂O₄ and a particle consisting of the natural mineral ilmenite. Effect of steam content in the fluidizing gas of the reactor was investigated as well as effect of temperature. A number of experiments were also made to investigate the rate of conversion of the different fuels in a CLC system. A high dependency on steam content in the fluidizing gas as well as temperature was shown. The fraction of volatiles in the fuel was also found to be important. Furthermore the presence of an oxygen carrier was shown to enhance the conversion rate of the intermediate gasification reaction. At 950 °C and with 50% steam the time needed to achieve 95% conversion of fuel particles with a diameter of 0.125–0.18 mm ranged between 4 and 15 min depending on the fuel, while 80% conversion was reached within 2–10 min. In almost all cases the synthetic Fe₂O₃ particle with 40% MgAl₂O₄ and the mineral ilmenite showed similar results with the different fuels.     

A Baseline Study on Water Resources of the Tourist Island, Pulau Perhentian, Peninsular Malaysia, from an Ecological Perspective

Ambient water quality and bacterial populations in the water resources of Pulau Perhentian, a Marine Park of Malaysia, were studied during a peak tourist arrival, off-monsoon period. The overall water and bacteriological quality of swimming/boating sites in the island is at an acceptable condition, although the conductivity (0.88–60 mS m^–1) due to high dissolved solid concentrations is slightly high, when compared with the recommended standard and published guidelines for the protection/maintenance of recreation water and its aesthetic enjoyment (Universiti Malaya, Department of Environment, Malaysia, 1986). However, the bacteriological quality of the drinking/bathing water wells is poor, with faecal coliform counts (2 up to 1,600 MPN per 100 ml sample water) exceeding the permissible levels defined for raw water supplies (with or without treatment). This suggests that the groundwater, seepage and run-off into the wells is contaminated. Contrary to the belief of the water users being interviewed in a social survey, the untreated drinking/bathing water is not bacteria-free. The excessive counts are attributable to deoxygenated conditions (12–42 percent corresponding to 0.9–3.3 mg l^–1) prevailing in the wells, high total suspended solids (up to 202 mg l^–1) which promote bacterial growth, lack of adequate sewerage systems to receive effluents from lavatories of dwellings, chalets and resorts, as well as the lack of centralised water treatment plants and storage tanks to cope with water scarcity and waterway contamination.     

Toxicity and uptake of mercurials in a cyanobacterium

Nostoc calcicola cells exposed to mercuric chloride (0.05–0.25 M), methyl mercuric chloride (0.05–0.15 M) and the fungicide ceresan (phenyl mercuric acetate; 0.05–0.20 M) showed sensitivity in the sequence: methyl mercury3) over phenyl mercuric acetate (0.51×10³); inorganic mercury occupied the intermediate position with a bioconcentration factor of 1.32×10³. The data infer that larger molecules of organomercurials may not be taken up by cells at the rate and extent comparable to the smaller species.     

Environmental damage — environmental expenditure 2: Statistical evidence on the Federal Republic of Germany

Summary In part one of this paper (The Environmentalist,1990, pp.301–309) it was shown that conventional economic accounting does not reveal the actual damage to the natural environment, although an ever-increasing share of the Gross National Product is being spent for environmental protection activities. In this, part two of the paper, on the basis of acceptable conventions, the results of an empiric research on defensive expenditures in the GNP are presented, again taking the Federal Republic of Germany as an example. The authors would like to see more research of this type in order to understand better the environmental impacts and the structural deficiencies of modern industrial society. Dr Christian Leipert and Professor Udo E. Simonis have contributed frequently toThe Environmentalist (see 1989, pp.171–183; 1990, pp.25–38; 1990, pp.301–309). Dr Leipert is research fellow, Dr Simonis is research professor at the environmental policy unit of the Science Center Berlin.     

Causes and effects of siltation on the environment of Nepal

Summary The present investigation was carried out in 1986, and is based upon about 20 years of river discharge data (1960s to 1980s). There are three important river-systems in Nepal - Sapt Kosi River system in East Nepal, Sapt Gandaki River system in mid- Nepal, and Karnali River system in West Nepal. The average annual highest rainfall is 3,685 mm yr^–1, and the greatest mean annual suspended sediment load (1.434 g L^–1) was recorded in Sapt Gandaki, while the water discharge from Sapt Kosi (1,747 m³ s^–1) was the highest and so also was the silt discharge (0.4 million ton day^–1). The correlation between water discharge and silt discharge was found to be statistically highly significant as verified by correlation and regression analyses.An abatement of human interference in the catchment areas of these rivers, and fodder/fuelwood plantation through the active participation of local people in their marginal land to decrease the human pressure on natural forests, are considered the two major easy, effective and economic methods to control the siltation hazard that is causing extensive deterioration to the environment in Nepal.Dr Govind P.S. Ghimire is Reader and Associate Professor in the Central Department of Botany at Tribhuvan University. Mr B.K. Uprety is an ecologist working on the Environmental Impact Study Project of His Majesty's Government, Nepal.     

Destruction of Wetlands and Waterbird Populations by Dams and Irrigation on the Murrumbidgee River in Arid Australia

The Lowbidgee floodplain is the Murrumbidgee Rivers major wetland in southeastern Australia. From more than 300,000 ha in the early 1900s, at least 76.5% was destroyed (58%) or degraded (18%) by dams (26 major storages), subsequent diversions and floodplain development. Diversions of about 2,144,000 ML year^–1 from the Murrumbidgee River come from a natural median flow of about 3,380,000 ML year^–1 providing water for Australias capital, hydroelectricity, and 273,000 ha of irrigation. Diversions have reduced the amount of water reaching the Lowbidgee floodplain by at least 60%, from 1888 to 1998. About 97,000 ha of Lowbidgee wetland was destroyed by development of the floodplain for an irrigation area (1975–1998), including building of 394 km of channels and 2,145 km of levee banks. Over 19 years (1983–2001), waterbird numbers estimated during annual aerial surveys collapsed by 90%, from an average of 139,939 (1983–1986) to 14,170 (1998–2001). Similar declines occurred across all functional groups: piscivores (82%), herbivores (87%), ducks and small grebe species (90%), large wading birds (91%), and small wading birds (95%), indicating a similar decline in the aquatic biota that formed their food base. Numbers of species also declined significantly by 21%. The Lowbidgee floodplain is an example of the ecological consequences of water resource development. Yanga Nature Reserve, within the Lowbidgee floodplain, conserved for its floodplain vegetation communities, will lose these communities because of insufficient water. Until conservation policies adequately protect river flows to important wetland areas, examples such as the Lowbidgee will continue to occur around the world.