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Adebayo Tomiwa Sunday Akinsola Gbenga Daniel Kirikkaleli Dervis Bekun Festus Victor Umarbeyli Sukru Osemeahon Oseyenbhin Sunday 《Environmental science and pollution research international》2021,28(35):47942-47956
Environmental Science and Pollution Research - To minimize the awful situation confronting the entire globe, the global warming danger has raised the intensity of consciousness from all areas of... 相似文献
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Agunbiade FO Olu-Owolabi BI Adebowale KO 《Environmental monitoring and assessment》2012,184(1):89-102
The accumulation patterns of ten metals in tissues of plant, Eichornia crassipes, and fishes, Hydrocynus forskahlii and Oreochromis mossambicus, were modeled with simple fuzzy classification (SFC) to assess toxic effects of anthropogenic activities on the coastal biota.
The plant sample was separated into root, stem, and leaves and the fishes into bones, internal tissues, and muscles. They
were analyzed for As, Cd, Cr, Cu, Ni, Pb, V, Fe, Mn, and Zn after wet oxidation of their dried samples. The results were converted
into membership functions of five accumulation classes and aggregated with SFC. The classification results showed that there
was no metal accumulation in the plant parts while the fishes were classified into low accumulation category. The internal
tissues of the fishes had higher metal accumulation than the other parts. Generally, Fe and Mn had highest concentrations
in the biota but are natural to the area and may not constitute significant risk. Cr had the highest transfer and accumulation
from the coastal water into the aquatic lives and may be indicative of risk prone system being a toxic metal. Metal contaminations
in the zone had not significantly accumulated in the biota making them less prone to risk associated with metal accumulation. 相似文献
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Ganiyu O. Oyetibo Matthew O. Ilori Sunday Adekunle Adebusoye Oluwafemi S. Obayori Olukayode O. Amund 《Environmental monitoring and assessment》2010,168(1-4):305-314
Samples of soil, water, and sediments from industrial estates in Lagos were collected and analyzed for heavy metals and physicochemical composition. Bacteria that are resistant to elevated concentrations of metals (Cd2?+?, Co2?+?, Ni2?+?, Cr6?+?, and Hg2?+?) were isolated from the samples, and they were further screened for antibiotic sensitivity. The minimum tolerance concentrations (MTCs) of the isolates with dual resistance to the metals were determined. The physicochemistry of all the samples indicated were heavily polluted. Twenty-two of the 270 bacterial strains isolated showed dual resistances to antibiotics and heavy metals. The MTCs of isolates to the metals were 14 mM for Cd2?+?, 15 mM for Co2?+? and Ni2?+?, 17 mM for Cr6?+?, and 10 mM for Hg2?+?. Five strains (Pseudomonas aeruginosa, Actinomyces turicensis, Acinetobacter junni, Nocardia sp., and Micrococcus sp.) resisted all the 18 antibiotics tested. Whereas Rhodococcus sp. and Micrococcus sp. resisted 15 mM Ni2?+?, P. aeruginosa resisted 10 mM Co2?+?. To our knowledge, there has not been any report of bacterial strains resisting such high doses of metals coupled with wide range of antibiotics. Therefore, dual expressions of antibiotics and heavy-metal resistance make the isolates, potential seeds for decommissioning of sites polluted with industrial effluents rich in heavy metals, since the bacteria will be able to withstand in situ antibiosis that may prevail in such ecosystems. 相似文献
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Aerobic degradation of di- and trichlorobenzenes by two bacteria isolated from polluted tropical soils 总被引:7,自引:0,他引:7
Two polychlorinated biphenyl (PCBs)-degrading bacteria were isolated by traditional enrichment technique from electrical transformer fluid (Askarel)-contaminated soils in Lagos, Nigeria. They were classified and identified as Enterobacter sp. SA-2 and Pseudomonas sp. SA-6 on the basis of 16S rRNA gene analysis, in addition to standard cultural and biochemical techniques. The strains were able to grow extensively on dichloro- and trichlorobenzenes. Although they failed to grow on tetrachlorobenzenes, monochloro- and dichlorobenzoic acids, they were able to utilize all monochlorobiphenyls, and some dichlorobiphenyls as sole sources of carbon and energy. The effect of incubation with axenic cultures on the degradation of 0.9 mM 1,4-dichlorobenzene, 0.44 mM 1,2,3- and 0.43 mM 1,3,5-trichlorobenzene in mineral salts medium was studied. Approximately, 80-90% of these xenobiotics were degraded in 200 h, concomitant with cell increase of up to three orders of magnitude, while generation times ranged significantly (P<0.05) from 17-32 h. Catechol 1,2-dioxygenase and catechol 2,3-dioxygenase activities were detected in crude cell-free extracts of cultures pre-grown with benzoate, with the latter enzyme exhibiting a slightly higher activity (0.15-0.17 micromolmin(-1) mg of protein(-1)) with catechol, suggesting that the meta-cleavage pathway is the most readily available catabolic route in the SA strains. The wider substrate specificity of these tropical isolates may help in assessing natural detoxification processes and in designing bioremediation and bioaugmentation methods. 相似文献
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Adedibu C. Tell Samson O. Owalude Sunday J. Olatunji Vincent O. Adimul Sunday E. Elaigwu Lukman O. Alimi Peter A. Ajibade Oluwatobi S. Oluwafemi 《环境科学学报(英文版)》2018,30(2):264-275
We herein report the removal of amodiaquine, an emerging drug contaminant from aqueous solution using [Zn2(fum)2(bpy)] and [Zn4 O(bdc)3](fum = fumaric acid; bpy =4,4-bipyridine; bdc = benzene-1,4-dicarboxylate) metal–organic frameworks(MOFs) as adsorbents. The adsorbents were characterized by elemental analysis, Fourier transform infrared(FT-IR) spectroscopy, and powder X-ray diffraction(PXRD). Adsorption process for both adsorbents were found to follow the pseudo-first-order kinetics, and the adsorption equilibrium data fitted best into the Freundlich isotherm with the R~2 values of 0.973 and0.993 obtained for [Zn_2(fum)_2(bpy)] and [Zn_4 O(bdc)_3] respectively. The maximum adsorption capacities foramodiaquine in this study were found to be 0.478 and 47.62 mg/g on the[Zn_2(fum)_2(bpy)] and [Zn_4 O(bdc)_3] MOFs respectively, and were obtained at p H of 4.3 for both adsorbents. FT-IR spectroscopy analysis of the MOFs after the adsorption process showed the presence of the drug. The results of the study showed that the prepared MOFs could be used for the removal of amodiaquine from wastewater. 相似文献
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A bacterium classified as Achromobacter xylosoxidans strain IR08 by phenotypic typing coupled with 16S rRNA gene analysis was isolated from a soil contaminated with electrical transformer ?uid for over sixty years using Aroclor 1221 as an enrichment substrate. The substrate utilization profiles revealed that IR08 could grow on all three monochlorobiphenyls (CBs), 2,4'- and 4,4'-dichlorobiphenyl as well as 2-chlorobenzoate (2-CBA), 3-CBA, 4-CBA, and 2,3-dichlorobenzoate. Unusually, growth was poorly sustaine... 相似文献
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Ganiyu Oladunjoye Oyetibo Matthew Olusoji Ilori Oluwafemi Sunday Obayori Olukayode Oladipo Amund 《Environmental monitoring and assessment》2013,185(8):6809-6818
Chromium (VI) [Cr (VI)] biosorption by four resistant autochthonous bacterial strains was investigated to determine their potential for use in sustainable marine water-pollution control. Maximum exchange between Cr (VI) ions and protons on the cells surfaces were at 30–35 °C, pH?2.0 and 350–450 mg/L. The bacterial strains effectively removed 79.0–90.5 % Cr (VI) ions from solution. Furthermore, 85.3–93.0 % of Cr (VI) ions were regenerated from the biomasses, and 83.4–91.7 % of the metal was adsorbed when the biomasses was reused. Langmuir isotherm performed better than Freundlich isotherm, depicting that Cr (VI) affinity was in the sequence Rhodococcus sp. AL03Ni?>?Burkholderia cepacia AL96Co?>?Corynebacterium kutscheri FL108Hg?>?Pseudomonas aeruginosa CA207Ni. Biosorption isotherms confirmed that Rhodococcus sp. AL03Ni was a better biosorbent with a maximum uptake of 107.46 mg of Cr (VI) per g (dry weight) of biomass. The results highlight the high potential of the organisms for bacteria-based detoxification of Cr (VI) via biosorption. 相似文献
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Sunday A. Adebusoye Matthew O. Ilori Oluwafemi S. Obayori Ganiyu O. Oyetibo Kehinde A. Akindele Olukayode O. Amund 《The Environmentalist》2010,30(1):24-34
Soil artificially contaminated with diesel oil, treated with cassava steep liquor (CSL) and designated EXPS. Similar polluted
soil without CSL amendment (CSS1) and uncontaminated soil (CSS2) served as controls. There were dramatic changes in the physico-chemistry
of systems EXPS and CSS1 with utilization of the inorganic nutrients to near-depletion in the former than the latter. In contrast,
the properties of CSS2 remained relatively stable throughout the investigated period. Similarly, the population densities
of microflora in the polluted soils showed an initial decrease between days 0 and 5 before assuming an increasing trend with
percent hydrocarbon-utilizers ranging significantly (P < 0.05) from 0.56 to 6.6, 0.1 to 2.46 and 0.56 to 0.26, respectively for EXPS, CSS1, and CSS2. In EXPS, the residual oil
decreased from 98,045 to 1,102.3 mg/kg soil at day 35 representing about 98.88% degradation. The corresponding value for CSS1
was 98,106.1 to 52,110 mg/kg soil, amounting to 46.88% oil disappearance. The GC fingerprints of alkane fractions of the recovered
oil reduced significantly by day 15 for EXPS with near-similar results of CSS1. However, by day 35, there was complete disappearance
of all peaks including the pristane and phytane molecules in the former whereas in CSS1, there were no observable changes.
The germination and growth profiles of maize seed plants as evidence of recovery of oil-impacted soils were poor in CSS1 (10%)
with pronounced abnormal morphology when compared with the data obtained for EXPS (74%) and CSS2 (80%). These results suggest
that CSL could be an indispensable tool in bioremediation of environments contaminated with hydrocarbons. The technology of
application is simple, rapid and cost-effective and may be appropriate for use in developing countries to ameliorate the problems
of petroleum pollution. 相似文献
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Falusi Bamidele Ayodeji Olanipekun Edward Olorunsola Olanisebe Deborah Olukemi 《毒物与环境化学》2013,95(9):1665-1672
Transfer coefficients of the four metals As, Cd, Hg, and Pb were determined in the leaves and barks of Morinda lucida collected in Nigeria, with the view to quantify relative differences in the bioavailability of the metals to these parts of the plant. Samples were acid digested and the levels of the metals in the digestates were determined using an atomic absorption spectrophotometer. Certain properties of the soils, i.e., pH, clay fraction, electrical conductivity, cation exchange capacity, and organic matter, were also determined. The latter influence the bioavailability of the metals. All parameters correlated with the concentrations of the metals in soils. Transfer coefficient values recorded for Cd and Pb in various tissues of M. lucida Benth were within the expected ranges, while those of As and Hg showed elevated topsoil concentrations of metals. The order of bioavailability of the metals and their bioaccumulation in the tissues of M. lucida Benth was Hg > Cd > As > Pb. Stem barks of the plant showed the least bioaccumulation of all four metals and hence are most suitable for therapeutic purposes. Vegetative parts of M. lucida Benth used for therapeutic purposes should be sourced at sites that will give low transfer coefficient in order to reduce human exposure to toxicity associated with ingestion of heavy metals. 相似文献