Statistical evidence on the effectiveness of sewering to protect groundwater from VOC contamination

Volatile organic compounds (VOCs) are an important source of contamination of groundwater supplies in Massachusetts and many parts of the United States. One local response is to require sewering in wellhead protection areas as an easily enforceable policy designed to reduce the probability of VOC contamination of groundwater. Data were collected for 238 wellhead protection areas in Massachusetts on VOC contamination levels and the sewered and unsewered land uses in those aquifer recharge areas. Logistic regression procedures were used to see whether sewering had any statistical effect on likelihood of contamination of well water. The results provided limited, but not overpowering, support for the idea that requiring commercial and industrial land uses to use sewers would reduce the chance of VOC contamination.     

An approach for delineating drinking water wellhead protection areas at the Nile Delta, Egypt

In Egypt, production has a high priority. To this end protecting the quality of the groundwater, specifically when used for drinking water, and delineating protection areas around the drinking water wellheads for strict landuse restrictions is essential. The delineation methods are numerous; nonetheless, the uniqueness of the hydrogeological, institutional as well as social conditions in the Nile Delta region dictate a customized approach. The analysis of the hydrological conditions and land ownership at the Nile Delta indicates the need for an accurate methodology. On the other hand, attempting to calculate the wellhead protected areas around each of the drinking wells (more than 1500) requires data, human resources, and time that exceed the capabilities of the groundwater management agency. Accordingly, a combination of two methods (simplified variable shapes and numerical modeling) was adopted. Sensitivity analyses carried out using hypothetical modeling conditions have identified the pumping rate, clay thickness, hydraulic gradient, vertical conductivity of the clay, and the hydraulic conductivity as the most significant parameters in determining the dimensions of the wellhead protection areas (WHPAs). Tables of sets of WHPAs dimensions were calculated using synthetic modeling conditions representing the most common ranges of the significant parameters. Specific WHPA dimensions can be calculated by interpolation, utilizing the produced tables along with the operational and hydrogeological conditions for the well under consideration. In order to simplify the interpolation of the appropriate dimensions of the WHPAs from the calculated tables, an interactive computer program was written. The program accepts the real time data of the significant parameters as its input, and gives the appropriate WHPAs dimensions as its output.     

Development of a risk-based index for source water protection planning, which supports the reduction of pathogens from agricultural activity entering water resources

Source water protection planning (SWPP) is an approach to prevent contamination of ground and surface water in watersheds where these resources may be abstracted for drinking or used for recreation. For SWPP the hazards within a watershed that could contribute to water contamination are identified together with the pathways that link them to the water resource. In rural areas, farms are significant potential sources of pathogens. A risk-based index can be used to support the assessment of the potential for contamination following guidelines on safety and operational efficacy of processes and practices developed as beneficial approaches to agricultural land management. Evaluation of the health risk for a target population requires knowledge of the strength of the hazard with respect to the pathogen load (massxconcentration). Manure handling and on-site wastewater treatment systems form the most important hazards, and both can comprise confined and unconfined source elements. There is also a need to understand the modification of pathogen numbers (attenuation) together with characteristics of the established pathways (surface or subsurface), which allow the movement of the contaminant species from a source to a receptor (water source). Many practices for manure management have not been fully evaluated for their impact on pathogen survival and transport in the environment. A key component is the identification of potential pathways of contaminant transport. This requires the development of a suitable digital elevation model of the watershed for surface movement and information on local groundwater aquifer systems for subsurface flows. Both require detailed soils and geological information. The pathways to surface and groundwater resources can then be identified. Details of land management, farm management practices (including animal and manure management) and agronomic practices have to be obtained, possibly from questionnaires completed by each producer within the watershed. To confirm that potential pathways are active requires some microbial source tracking. One possibility is to identify the molecular types of Escherichia coli present in each hazard on a farm. An essential part of any such index is the identification of mitigation strategies and practices that can reduce the magnitude of the hazard or block open pathways.     

Assessment of potential groundwater contamination sources in a wellhead protection area

Determining the human health dangers from potential contamination sources, within a wellhead protection area (WHPA), requires that a risk analysis be undertaken. In this study, a desktop geographic information system and spreadsheet software are used to implement an EPA risk screening methodology for WHPAs called 'Managing Ground Water Contamination Sources in Wellhead Protection Areas--A Priority Setting Approach'. The methodology was applied to a WHPA in Gaston County, North Carolina. Results indicate that the risk of well contamination from an interstate highway and gas station with old steel underground storage tanks were comparatively high. Medium risks included a thoroughfare and highway, while low risks were assigned to machine shops, a body shop, septic systems and a gas station with new underground storage tanks and secondary containment. A sensitivity analyses of the Priority Setting Approach indicated that risk scores were extremely sensitive to hydrogeologic variables such as hydraulic conductivity. It is recommended that risk assessors utilize a range of hydrogeologic parameters to assess overall risk from each potential contamination source.     

Integrated Use of GLEAMS and GIS to Prevent Groundwater Pollution Caused by Agricultural Disposal of Animal Waste

/ In modern intensive animal farming the disposal of a large amount of waste is of great concern, as, if not properly performed, it can cause the pollution of water, mainly because of the high content of nitrate and phosphate. This paper presents the results of a study intended to assess the environmental sustainability of animal waste disposal on agricultural soils in the alluvial plain of the River Chiana (Tuscany, Italy), a particularly sensitive area because of the high vulnerability of the shallow aquifer and of the intensive agricultural and breeding activities. With this aim, a strategy has been employed, that consists of the integrated use of a management model and GISs. The consequences on groundwater of applying animal waste to different kind of soils and crop arrangements have been simulated by means of the management model GLEAMS (Groundwater Loading Effects of Agricultural Management Systems, ver 2.01). As the huge amount of data required by such a sophisticated model does not allow applications at a scale larger than the field size, IDRISI and GRASS GIS packages have been used to divide the study area into land units, with homogeneous environmental characteristics, and then to generalize on these units the outputs of the model. The main conclusions can be synthesized as follows: The amount of animal waste produced in some of the investigated areas (i.e., municipal territory) is greater than that disposable on their own agricultural soil with no risks to the groundwater; consequently a cooperative approach among municipalities is necessary in order to plan waste disposal in a comprehensive and centralized way.KEY WORDS: Land use; Animal waste disposal; Groundwater protection; GIS, Management models     

Identification of the source of nitrate contamination in ground water below an agricultural site, Jeungpyeong, Korea

This study applied hydrogeological characterization and isotope investigation to identify source locations and to trace a plume of ground water contaminated by nitrate. Most of the study site is agricultural fields with the remainder being residential. A poultry farm is also within the study area, so that potential point and nonpoint sources were present. Estimates of seasonal ground water recharge from irrigation and precipitation, leakage of sewage, and the regional ground water flow were linked to the seasonal changes in isotopic values. Ground water recharge largely occurred in spring and summer following precipitation or irrigation, depending on the locations. Natural and fertilized soils were identified as nonpoint sources of nitrate contamination in this area, while septic and animal wastes were identified as small point sources. The seasonal changes in the relative impact of these sources on ground water contamination were related to such factors as source distribution, the aquifer confining condition, precipitation rate, infiltration capacity, recharge rate, and the land use pattern.     

Nitrate Vulnerable Zones and Nitrate Sensitive Areas: A Policy and Technical Analysis of Groundwater Source Protection in England and Wales

The Nitrate Sensitive Area (NSA) scheme and the more recent Nitrate Vulnerable Zone (NVZ) scheme are responses by the British Government to the growing demands of European legislation on water quality. Both are designed to check nitrate contamination from agriculture at source, with 'polluting' activities being changed or prohibited in areas forming the catchment of waters where the 1980 European Commission (EC) limit of 50 mg/l nitrate (N) is exceeded, or is likely to be exceeded. The NVZ scheme provides protection to surface and ground water,whereas the NSA scheme relates directly to the latter. Furthermore, action programmes to reduce nitrate pollution within NVZs are mandatory and uncompensated, whilst the more strict but voluntary measures of the NSA scheme are compensated. This paper sets out to critically analyse the NVZ scheme, with reference to the NSA scheme and further makes recommendations for an improved nitrate pollution land use control policy in relation to ground water protection. The study area is Minster NVZ on the Isle of Thanet in north east Kent.     

MANAGING GROUND WATER QUALITY IN RELATION TO AGRICULTURAL ACTiVITIES1

ABSTRACT: Ground water quality is an environmental issue of national concern. Agricultural activities, because they involve large land areas, often are cited as a major contributor of ground water contaminants. It appears that some degree of ground water contamination from agricultural land use is inevitable, especially where precipitation exceeds evapotranspiration. For this reason, and because agriculture differs significantly from point sources of pollution, farmers, policymakers, and scientists need alternative management strategies by which to protect ground water. Mathematical models coupled to geographic information systems to form expert systems can be important management tools for both policymakers and agricultural producers. An expert system can provide farmers, researchers, and environmental managers with information by which to better manage agricultural production systems to minimize ground water contamination. Significant research is necessary to perfect such a system, necessitating interim ground water management strategies that include not only a strong research program, but educational and public policy components as well.     

IMPLICATIONS OF ON‐GROUND NITROGEN LOADING AND SOIL TRANSFORMATIONS ON GROUND WATER QUALITY MANAGEMENT1

ABSTRACT: This paper presents a modeling approach based on a geographic information system (GIS) to estimate the variability of on‐ground nitrogen loading and the corresponding nitrate leaching to ground water. The methodology integrates all point and nonpoint sources of nitrogen, the national land cover database, soil nitrogen transformations, and the uncertainty of key soil and land use‐related parameters to predict the nitrate mass leaching to ground water. The analysis considered 21 different land use classes with information derived from nitrogen sources such as fertilizer and dairy manure applications, dairy lagoons, septic systems, and dry and wet depositions. Simulations were performed at a temporal resolution of one month to capture seasonal trends. The model was applied to a large aquifer of 376 square miles in Washington State that serves more than 100,000 residents with drinking water. The results showed that dairy manure is the main source of nitrogen in the area followed by fertilizers. It was also seen that nitrate leaching is controlled by the recharge rate, and there can be a substantial buildup of soil nitrogen over long periods of time. Uncertainty analysis showed that denitrification rate is the most influential parameter on nitrate leaching. The results showed that combining management alternatives is a successful strategy, especially with the use of nitrification inhibitors. Also, change in the land use pattern has a noticeable impact on nitrate leaching.     

THE DEVELOPMENT AND IMPLEMENTATION OF A GIS-BASED CONTAMINANT SOURCE INVENTORY OVER THE SPOKANE AQUIFER,SPOKANE COUNTY WASHINGTON1

ABSTRACT: U.S. Environmental Protection Agency (EPA) statutes require identification of all potential sources of contamination within a wellhead protection area. All wells over Spokane County's aquifer are included in one wellhead protection zone called the Aquifer Sensitive Area (ASA). A GIS-based Contaminant Source Inventory (CSI) was developed for the ASA. Datasets listing businesses and agencies within the ASA were imported into the GIS from state, county, city, and local agencies. These datasets were selected, joined, and sorted using GIS relational database capabilities into one ASA “business master file.” Map files were projected and transformed into common coordinates. Next, business sites within the master file were spatially related by address to the digital map files. Likely Critical Materials Users (CMU) were identified by sorting on selected standard Industrial Codes (SIC). Additional files of CMUs were imported into the Contaminant Source Inventory. GIS queries were performed to locate specific materials, quantities, and storage facilities, and to analyze CMU activity within selected buffer zones. This project demonstrated the usefulness of GIS technology in the development, management, maintenance, and analysis of vast quantities of data associated with a local wellhead protection pro. gram.     

Water quality and restoration in a coastal subdivision stormwater pond

Stormwater ponds are commonly used in residential and commercial areas to control flooding. The accumulation of urban contaminants in stormwater ponds can lead to a number of water quality problems including high nutrient, chemical contaminant, and bacterial levels. This study examined the interaction between land use and coastal pond water quality in a South Carolina residential subdivision pond. Eutrophic levels of chlorophyll and phosphorus were present in all seasons. Harmful cyanobacterial blooms were prevalent during the summer months. Microcystin toxin and fecal coliform bacteria levels were measured that exceeded health and safety standards. Low concentrations of herbicides (atrazine and 2,4-D) were also detected during summer months. Drainage from the stormwater pond may transport contaminants into the adjacent tidal creek and estuary. A survey of residents within the pond's watershed indicated poor pet waste management and frequent use of fertilizers and pesticides as possible contamination sources. Educational and outreach activities were provided to community members to create an awareness of the water quality conditions in the pond. Pond management strategies were then recommended, and selected mitigation actions were implemented. Water quality problems identified in this study have been observed in other coastal stormwater ponds of varying size and salinity, leading this project to serve as a potential model for coastal stormwater pond management.     

MAXIMIZING THE VALUE OF INFORMATION FOR GROUND WATER PROTECTION: THREE TEST CASES1

ABSTRACT: Public awareness of the importance of protecting the nation's water supplies is growing. Recent studies have shown a substantial increase in the perceived value of protecting water supplies for future use. In the Northeast, much of the water supply comes from ground water. This paper examines three test cases, each with different approaches for using geographic information systems (GIS) for ground water protection planning. In Wellfleet, Massachusetts, build-out scenarios were used to support regulatory and land acquisition decisions for siting a public water supply well. In Hadley, Massachusetts, the focus was on a decision support model for septic suitability assessment in support of regulatory efforts and infrastructure expansion. For Cortland County, New York, an interactive graphic user interface was created to facilitate the manipulation and recombination of a large volume of data by county officials to target ground water pollution prevention efforts. As personal computers become more powerful and inexpensive, and GIS data become more readily available, community and county governments are turning to GIS as a tool for developing comprehensive resource protection plans. Once appropriate data are input, a GIS can effectively and efficiently be used to derive outcomes of various land use plans and regulations.     

A GEOGRAPHIC INFORMATION SYSTEMS APPROACH TO WELLHEAD PROTECTION1

ABSTRACT: The 1986 Amendments to the Safe Drinking Water Act mandate a multifaceted approach to wellhead protection. This approach includes: (1) delineating wellhead protection areas; (2) identifying and managing potential contaminants; (3) developing contingency plans in the event of weilfield contamination; (4) siting new wells; and (5) encouraging public participation. These elements encompass technical, administrative, and educational considerations. In functioning both as a research tool and as a decision support system, a geographic information system (GIS) is shown to have proven utility in addressing these issues. This article describes the application of common GIS functionality in facilitating a comprehensive wellhead protection scheme for an agricultural municipality in North Dakota.     

Land management impacts on dairy-derived dissolved organic carbon in ground water

Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L(-1) in wells downgradient from wastewater ponds, 8 to 30 mg L(-1) in corral wells, 5 to 12 mg L(-1) in tile drains, and 4 to 15 mg L(-1) in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 microg L(-1), well in excess of the maximum contaminant level of 80 microg L(-1) established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation ( approximately 4 to approximately 8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow ground water and hence should be considered when managing ground water resources and in any efforts to mitigate contamination of ground water with carbon-based contaminants, such as pesticides and pharmaceuticals.     

EVALUATING THE EFFECTIVENESS OF A FIXED WELLHEAD DELINEATION: REGIONAL CASE STUDY 1

The 1996 Safe Drinking Water Act amendments mandated that every state must determine the hydrogeologic origin of each public drinking water system and assess the degree to which each system may be adversely affected by potential sources of contamination. Wisconsin delineated and assessed one specific class of systems, transient noncommunity drinking water wells, with the least stringent standards of all governed system types. This study evaluates the effectiveness of Wisconsin's arbitrarily fixed radius approach used in determining susceptibility to potential contamination from 1,872 transient noncommunity ground water wells. Nearly 28 percent of the wells with contaminated water did not have any recorded potential sources of contamination within the delineation radii. Additionally, regression models derived from potential contaminant inventories within the delineation radii could not accurately predict actual incidences of water contamination. Differences between observed and expected frequencies of contamination further suggest that some transient noncommunity systems should probably be delineated with larger and more sophisticated methods that would account for varying geology and contaminant susceptibility. The majority of contamination cases without recorded potential sources of contamination within the delineation radii were in a karst area. Subsequently, the arbitrarily fixed radius delineation method should not be used in areas with karst aquifers.     

APPLICATION OF GEOGRAPHIC INFORMATION SYSTEMS TO GROUNDWATER MONITORING NETWORK DESIGN1

ABSTRACT: Effective monitoring configurations for contaminant detection in groundwater can be designed by analyzing the spatial relationships between candidate sampling sites and aquifer zones susceptible to contamination. Examples of such zones are the domain underlying the contaminant source, zones of probable contaminant migration, and areas occupied by water supply wells. Geographic information systems (GIS) are well-suited to performing key groundwater monitoring network design tasks, such as calculating values for distance variables which quantify the proximity of candidate sites to zones of high pollution susceptibility, and utilizing these variables to quantify relative monitoring value throughout a model domain. Through a case study application, this paper outlines the utility of GIS for detection-based groundwater quality monitoring network design. The results suggest that GIS capabilities for analyzing spatially referenced data can enhance the field-applicability of established methodologies for groundwater monitoring network design.     

Protection strategies for drinking groundwater sources in small Quebec municipalities

Awareness of groundwater protection has increased substantially in recent decades. In the Province of Quebec, Canada, the Groundwater Catchment Regulation (GWCR) was promulgated in 2002 to protect water quality in public wells. The goal of the present study was to document groundwater protection in the context of emerging regulations and identify factors explaining the propensity of municipalities applying protection strategies. Two types of information were used in this study: data from a questionnaire-based survey conducted among 665 municipalities in the Province of Quebec and complementary information gathered from various sources. Data from the survey revealed that fewer than half of the municipalities have been able to comply with the GWCR, mainly because of financial limitations. Also, close to half of the municipalities have either identified or are expecting land use conflicts to arise between protection areas required by the GWCR and other land usage, with agriculture being the main conflicting activity. Multivariate logistic regression models served to identify factors explaining the likelihood of municipalities to take groundwater protection measures. Those factors were municipality revenue, history of water contamination in distribution systems, land use near wellheads, location of municipalities within a provincial priority watershed and the importance of groundwater use in a region. Results of the study may prove helpful for government authorities in better understanding the groundwater protection issue and in implementing strategies that improve the ability of municipalities to protect groundwater.     

Conceptual Design of a System for Selecting Appropriate Groundwater Models in Groundwater Protection Programs

/ An effective groundwater protection program requires understanding of water flow and contaminant transport processes in the subsurface. Although many mathematical models have been developed to simulate the processes, few actually are used in groundwater protection programs due to the difficulties in data collection, model selection, and model implementation. This study presents a conceptual design of a GIS-supported model selection system that evaluates available data and mathematical models to facilitate groundwater protection programs. Steady-state groundwater and contaminant transport models applied in isotropic aquifers are placed into four classes to simulate conservative or nonconservative contaminant transports in simple or complex geohydrological conditions. After analyzing specific study objectives, available data, and model requirements, the proposed system selects a class of models that can be used in simulation and recommends any need for additional data collection. This study initiates an effort to integrate GIS, mathematical models, and expert knowledge in one system to promote the application of appropriate groundwater models. The new technology of GIS and digital data-base management makes it possible to develop such a system in practice.KEY WORDS: Groundwater models; Geographic information systems     

LAND USE FUNCTION IN WATER QUALITY MANAGEMENT1

ABSTRACT. The Nation has entered a new era of water quality management in which land use policy and regulation must assume an increasingly important role. The benefits of tertiary and advanced waste treatment may be offset by contradictory land use and pollution from land runoff. Unless land use planning and controls are included in water quality management, land-imposed constraints on water quality can be anticipated. Pollution from major types of land runoff are reviewed with respect to sources, effects, and control procedures. Emphasis is given to land use practices and controls. The crucial issue with regard to the latter is lack of land use policies at federal, state, and local levels. State legislation establishing guidelines and minimum standards for land use regulation by local government is required. The dependency of water quality on land use points to the fallacy of attempting to provide for comprehensive water pollution control outside the context of comprehensive land-water resource planning and management.     

Multi-criteria decision analysis for the optimal management of nitrate contamination of aquifers

We present an integrated methodology for the optimal management of nitrate contamination of ground water combining environmental assessment and economic cost evaluation through multi-criteria decision analysis. The proposed methodology incorporates an integrated physical modeling framework accounting for on-ground nitrogen loading and losses, soil nitrogen dynamics, and fate and transport of nitrate in ground water to compute the sustainable on-ground nitrogen loading such that the maximum contaminant level is not violated. A number of protection alternatives to stipulate the predicted sustainable on-ground nitrogen loading are evaluated using the decision analysis that employs the importance order of criteria approach for ranking and selection of the protection alternatives. The methodology was successfully demonstrated for the Sumas-Blaine aquifer in Washington State. The results showed the importance of using this integrated approach which predicts the sustainable on-ground nitrogen loadings and provides an insight into the economic consequences generated in satisfying the environmental constraints. The results also show that the proposed decision analysis framework, within certain limitations, is effective when selecting alternatives with competing demands.