Use of reactive materials to bind phosphorus

Phosphorus (P) losses from agricultural soils have caused surface water quality impairment in many regions of the world, including The Netherlands. Due to the large amounts of P accumulated in Dutch soils, the generic fertilizer and manure policy will not be sufficient to reach in time the surface water quality standards of the European Water Framework Directive. Additional measures must be considered to further reduce P enrichment of surface waters. One option is to immobilize P in soils or manure or to trap P when it moves through the landscape by using reactive materials with a large capacity to retain P. We characterized and tested two byproducts of the process of purification of deep groundwater for drinking water that could be used as reactive materials: iron sludge and iron-coated sand. Both materials contain low amounts of inorganic contaminants, which also have a low (bio)availability, and bound a large amount of P. We could describe sorption of P to the iron sludge in batch experiments well with the kinetic Freundlich equation (Q = × t (m) × C(n)). Kinetics had a large influence on P sorption in batch and column experiments and should be taken into account when iron-containing materials are tested for their capability to immobilize or trap P. A negative aspect of the iron sludge is its low hydraulic conductivity; even when mixed with pure sand to a mixture containing 20% sludge, the conductivity was very low, and only 10% sludge may be needed before application is possible in filters or barriers for removing P from groundwater. Due to its much higher hydraulic conductivity, iron-coated sand has greater potential for use under field conditions. Immobilizing P could be an option for using iron sludge as a reactive material.     

Floodplain Trapping and Cycling Compared to Streambank Erosion of Sediment and Nutrients in an Agricultural Watershed

Floodplains and streambanks can positively and negatively influence downstream water quality through interacting geomorphic and biogeochemical processes. Few studies have measured those processes in agricultural watersheds. We measured inputs (floodplain sedimentation and dissolved inorganic loading), cycling (floodplain soil nitrogen [N] and phosphorus [P] mineralization), and losses (bank erosion) of sediment, N, and P longitudinally in stream reaches of Smith Creek, an agricultural watershed in the Valley and Ridge physiographic province. All study reaches were net depositional (floodplain deposition > bank erosion), had high N and P sedimentation and loading rates to the floodplain, high soil concentrations of N and P, and high rates of floodplain soil N and P mineralization. High sediment, N, and P inputs to floodplains are attributed to agricultural activity in the region. Rates of P mineralization were much greater than those measured in other studies of nontidal floodplains that used the same method. Floodplain connectivity and sediment deposition decreased longitudinally, contrary to patterns in most watersheds. The net trapping function of Smith Creek floodplains indicates a benefit to water quality. Further research is needed to determine if future decreases in floodplain deposition, continued bank erosion, and the potential for nitrate leaching from nutrient‐enriched floodplain soils could pose a long‐term source of sediment and nutrients to downstream rivers.     

INTERSTATE AND INTERNATIONAL AQUIFERS1

Many important groundwater aquifers cross state and national boundaries. The flow of water in these aquifers is not influenced by the boundaries but may be materially influenced by mans activities on one or both sides of a boundary. Interstate and international problems may develop because of excessive groundwater lowering on one side of a boundary affecting water users on the opposite side of the line. Similarly, intensive groundwater development along a surface stream may influence the amount of surface water that flows across a boundary. A third type of problem may develop when pumping on one side of the boundary induces poor quality water into an aquifer on the other side of the boundary. Several specific interstate and international aquifer problems are briefly described.     

Physiological and morphological response patterns of Populus deltoides to alluvial groundwater pumping

We examined the physiological and morphological response patterns of plains cottonwood [ Populus deltoides subsp. monilifera (Aiton) Eck.] to acute water stress imposed by groundwater pumping. Between 3 and 27 July 1996, four large pumps were used to withdraw alluvial groundwater from a cottonwood forest along the South Platte River, near Denver, Colorado, USA. The study was designed as a stand-level, split-plot experiment with factorial treatments including two soil types (a gravel soil and a loam topsoil over gravel), two water table drawdown depths ( approximately 0.5 m and >1.0 m), and one water table control (no drawdown) per soil type. Measurements of water table depth, soil water potential (Psi(s)), predawn and midday shoot water potential (Psi(pd) and Psi(md)), and D/H (deuterium/hydrogen) ratios of different water sources were made in each of six 600-m(2) plots prior to, during, and immediately following pumping. Two additional plots were established and measured to examine the extent to which surface irrigation could be used to mitigate the effects of deep drawdown on P. deltoides for each soil type. Recovery of tree water status following pumping was evaluated by measuring stomatal conductance ( g(s)) and xylem water potential (Psi(xp)) on approximately hourly time steps from before dawn to mid-afternoon on 11 August 1996 in watered and unwatered, deep-drawdown plots on gravel soils. P. deltoides responded to abrupt alluvial water table decline with decreased shoot water potential followed by leaf mortality. Psi(pd) and percent leaf loss were significantly related to the magnitude of water table declines. The onset and course of these responses were influenced by short-term variability in surface and ground water levels, acting in concert with physiological and morphological adjustments. Decreases in Psi(pd) corresponded with increases in Psi(md), suggesting shoot water status improved in response to stomatal closure and crown dieback. Crown dieback caused by xylem cavitation likely occurred when Psi(pd) reached -0.4 to -0.8 MPa. The application of surface irrigation allowed trees to maintain favorable water status with little or no apparent cavitation, even in deep-drawdown plots. Two weeks after the partial canopy dieback and cessation of pumping, g(s) and Psi(xp) measurements indicated that water stress persisted in unwatered P. deltoides in deep-drawdown plots.     

The “Short Cut” Approach for the Reality of Enhanced Groundwater Contamination

Based on the reality of (a) soil heterogeneity in the vadose zone, (b) enhanced desorption from soil and solubility in water of water insoluble contaminants in the presence of surfactants, and (c) wetting/drying cycles of groundwater recharge (a major cause of fractures formation), a coherent “short-cut” conceptual approach is advanced to account for enhanced groundwater contamination. This is an attempt to close the gap between theory, lab simulations and conventional modelling-based predictions, and observed higher concentrations and more rapid arrival times of contaminants reaching groundwater. Recent data concerning chloride ion and non-ionic surfactants concentrations in aquifers and groundwater wells, combined with previous results concerning the concentrations of tritium, chlorides, metals, organic hydrocarbons and surfactants in the unsaturated and saturated zones of Israel's aquifers, are accounted for in terms of the “short-cut” approach. The contradiction between predictions of groundwater contamination made with conventional, deterministic, homogeneous models and the actual observed behavior of contaminants in soils and aquifers is thus explaind. The “short cut” approach should not be perceived as a better type of model to guide modelling. Rather, it is a proposal for a conceptual change from the realistically invalid, but commonly accepted, conventional “buffer-protective soil/long-term groundwater contamination” to the “short cut” conceptual model to explain the enhanced groundwater contamination actually observed. Although the validity of the proposed approach is strongly supported by the data here presented for the case of Israel (serving as an illustrative case study), selected results and conclusions drawn from studies conducted worldwide suggest its general applicability and usefulness. A major conclusion evolved from the “short-cut” conceptual model is that contemporary groundwater management policies, based on the current perception of groundwater contamination processes and their modelling, may result in an irreversible detrimental effect on the environmental situation in the long run. In any case, prevention, rather than correction/remediation, is strongly recommended as the strategy of choice for rational long-term management of groundwater resources.     

Movement of coliform bacteria and nutrients in ground water flowing through basalt and sand aquifers

Large-scale deposition of animal manure can result in contamination of surface and ground water and in potential transfer of disease-causing enteric bacteria to animals or humans. We measured total coliform bacteria (TC), fecal coliform bacteria (FC), NO3, NH4, total P, and PO4 in ground water flowing from basalt and sand aquifers, in wells into basalt and sand aquifers, in irrigation water, and in river water. Samples were collected monthly for 1 yr. Total coliform and FC numbers were always higher in irrigation water than in ground water, indicating that soil and sediment filtered most of these bacteria before they entered the aquifers. Total coliform and FC numbers in ground water were generally higher in the faster flowing basalt aquifer than in the sand aquifer, indicating that the slower flow and finer grain size may filter more TC and FC bacteria from water. At least one coliform bacterium/100 mL of water was found in ground water from both basalt and sand aquifers, indicating that ground water pumped from these aquifers is not necessarily safe for human consumption according to the American Public Health Association and the USEPA. The NO3 concentrations were usually higher in water flowing from the sand aquifer than in water flowing from the basalt aquifer or in perched water tables in the basalt aquifer. The PO4 concentrations were usually higher in water flowing from the basalt aquifer than in water flowing from the sand aquifer. The main concern is fecal contamination of these aquifers and health consequences that may arise from human consumption.     

Seasonal and Flood‐Induced Variations in Groundwater–Surface Water Exchange in a Northern Coldwater Fishery

Groundwater upwelling is important to coldwater fisheries survival. This study used stable isotopes to identify upwelling zones within a watershed, then combined isotope analyses with reach‐scale monitoring to measure surface water–groundwater exchange over time. Research focused on Amity Creek, Minnesota, a basin that exemplifies conditions limiting coldwater species survival along Lake Superior's North Shore where shallow bedrock limits groundwater capacity, lowering baseflows and increasing temperatures. Groundwater‐fed reaches were identified through synoptic isotope sampling, with results highlighting the importance of isolated shallow surficial aquifers (glacially derived sands and gravels) for providing cold baseflow waters. In an alluvial reach, monitoring well results show groundwater was stored in two reservoirs: one that reacts quickly to changes in stream levels, and one that remained isotopically isolated under most flow conditions, but which helps sustain summer baseflows for weeks to months. A 500‐year flood demonstrated the capacity of high‐flow events to alter surface water–groundwater connectivity. The previously isolated reservoir was exchanged or mixed during the flood pulse, while incision lowered the water table for years. The results here provide insight for streams that lack substantial groundwater inputs yet maintain coldwater species at risk in a warming climate and an approach for managers seeking to protect cold baseflow sources.     

Potential Impacts of Stormwater Runoff on Water Quality in Urban Sand Pits and Adjacent Groundwater1

Whittemore, Donald O., 2012. Potential Impacts of Stormwater Runoff on Water Quality in Urban Sand Pits and Adjacent Groundwater. Journal of the American Water Resources Association (JAWRA) 48(3): 584-602. DOI: 10.1111/j.1752-1688.2011.00637.x Abstract: Entrance of stormwater runoff into water-filled pits and adjacent aquifers is a contamination concern. The water and sediment quality in several sand pits and surrounding groundwater in Wichita, Kansas, were studied to comprehensively address stormwater runoff impact. The pits are used for residential development after sand and gravel mining. Water samples were analyzed for inorganic constituents, bacteria, and 252 organic compounds, and pit sediments for inorganic components and 32 organic chemicals. Although many pesticide and degradate compounds were found in the pit and well waters, none of these chemicals exceeded existing health levels. Other organic contaminants were detected in the waters, with those exceeding health levels at one site attributed to an undiscovered groundwater contamination plume and not to stormwater runoff. Persistent insecticides and polychlorinated biphenyls detected in sediment of two pits are related to the age of residential development. The concentration distributions of pesticides and other organics at most of the sites, as well as iron, manganese, and ammonia patterns in downgradient well waters relative to upgradient well and pit waters, indicate that groundwater quality at the sites is affected by contaminants entering the pit surface waters. Thus, although current stormwater runoff does not appear to have contaminated sand-pit water and adjacent groundwater above health levels, the data show that the potential exists if stormwater became polluted.     

Denitrification potential in relation to lithology in five headwater riparian zones

The influence of riparian zone lithology on nitrate dynamics is poorly understood. We investigated vertical variations in potential denitrification activity in relation to the lithology and stratigraphy of five headwater riparian zones on glacial till and outwash landscapes in southern Ontario, Canada. Conductive coarse sand and gravel layers occurred in four of the five riparian areas. These layers were thin and did not extend to the field-riparian perimeter in some riparian zones, which limited their role as conduits for ground water flow. We found widespread organic-rich layers at depths ranging from 40 to 300 cm that resulted from natural floodplain processes and the burial of surface soils by rapid valley-bottom sedimentation after European settlement. The organic matter content of these layers varied considerably from 2 to 5% (relic channel deposit) to 5 to 21% (buried soils) and 30 to 62% (buried peat). Denitrification potential (DNP) was measured by the acetylene block method in sediment slurries amended with nitrate. The highest DNP rates were usually found in the top 0- to 15-cm surface soil layer in all riparian zones. However, a steep decline in DNP with depth was often absent and high DNP activity occurred in the deep organic-rich layers. Water table variations in 2000-2002 indicated that ground water only interacted frequently with riparian surface soils between late March and May, whereas subsurface organic layers that sustain considerable DNP were below the water table for most of the year. These results suggest that riparian zones with organic deposits at depth may effectively remove nitrate from ground water even when the water table does not interact with organic-rich surface soil horizons.     

OCCURRENCE OF TOTAL DISSOLVED PHOSPHORUS IN UNCONSOLIDATED AQUIFERS AND AQUITARDS IN IOWA1

ABSTRACT: Seven sets of ground water samples from 103 observation wells were analyzed for total dissolved phosphorus (TDP) in four areas and five materials including loess and loess derived alluvium in the Deep Loess Hills of western Iowa, outwash and fractured till adjacent to Clear Lake in north central Iowa, fractured till in central Iowa, and a sand and gravel aquifer in northwest Iowa. Land use in ground water recharge zones in all four areas is dominated by crop or animal production or both. Concentrations of TDP exceeding the minimum laboratory detection limit of 20 μg/l as P were found in all areas and in all materials sampled. Samples from the outwash deposits associated with Clear Lake contained significantly larger concentrations than all other areas and materials with a median of 160 μg/l. Water from fractured till in three areas produced the smallest range of concentrations with a median of 40 μg/l. The mean value of TDP in all sample sets exceeded 50 μg/l, an important ecological threshold that causes increased productivity in lakes and perennial streams and one being considered as a surface water nutrient standard by regulatory agencies. These results clearly show that ground water in essentially all near‐surface aquifers and aquitards discharging to Iowa's streams and lakes is capable of sustaining P concentrations of 50 to 100 μg/l in streams, lakes, and reservoirs. Consequently, even if point discharges and sediment sources of P are substantially reduced, ground‐water discharge to surface water may exceed critical thresholds under most conditions.     

Landscape Hydrogeology and its Influence on Patterns of Groundwater Flux and Nitrate Removal Efficiency in Riparian Buffers

This study uses data from 46 riparian sites to examine the influence of landscape hydrogeology on patterns of groundwater flux and the buffer width required for effective nitrate removal in humid temperate agricultural regions. There is a considerable imbalance in the research focus on different hydrogeologic settings. More than 40% of the buffers are located in landscapes with surficial sand aquifers, whereas few buffers have been studied in glacial till and weathered bedrock landscapes which cover large areas. Annual groundwater fluxes for 29 of these sites ranged from <20 L/m/day for buffers on flat sand plains and uplands with fine‐textured deposits to 50‐1,200 L/m/day for many sites with upland sand aquifers. Despite a similar range of water fluxes, buffers in gently to moderately sloping landscapes with <4 m depths of sand sediments reached a 90% removal efficiency within 30‐60 m while sites with >4 m depths required a 150‐200 m width. The width for 90% efficiency in buffers with loamy sand and sandy loam sediments also increased from 10‐20 m with <4 m sediment depths to 50‐100 m for >4 m depths. Limited data for buffers with fine‐textured sediments suggest that 90% of the nitrate flux was often depleted in a 10‐20 m width. Groundwater flux did not have a significant relationship with nitrate removal percent per meter buffer width because of the variation in efficiency that occurred in buffers with similar fluxes in different hydrogeologic settings.     

Assessment of Groundwater Depletion and Implications for Management in the Denver Basin Aquifer System

The Denver Basin Aquifer System (DBAS) is a critical groundwater resource along the Colorado Front Range. Groundwater depletion has been documented over the past few decades due to the increased water use among users, presenting long‐term sustainability challenges. A spatiotemporal geostatistical analysis is used to estimate potentiometric surfaces and evaluate groundwater storage changes between 1990 and 2016 in each of the four DBAS aquifers. Several key depletion patterns and spatial water‐level changes emerge in this work. Hydraulic head changes are the largest in the west‐central side of the DBAS and have decreased in some areas by up to 180 m since 1990, while areas to the northwest show increases in hydraulic head by over 30.5 m. The Denver and Arapahoe aquifers show the largest groundwater storage losses, with the highest rates occurring in the 2000s. The results highlight uncertainty in the volumetric predictions under various storage coefficient calculations and emphasize the importance of representative aquifer characterization. The observed groundwater storage depletions are due to a combination of factors, which include population growth increasing the demand for water, variable precipitation, and drought influencing recharge, and increased groundwater pumping. The methods applied in this study are transferable to other groundwater systems and provide a framework that can help assess groundwater depletion and inform management decisions at other locations.     

Interactions between soil texture and placement of dairy slurry application: II. Leaching of phosphorus forms

Managing phosphorus (P) losses in soil leachate folllowing land application of manure is key to curbing eutrophication in many regions. We compared P leaching from columns of variably textured, intact soils (20 cm diam., 20 cm high) subjected to surface application or injection of dairy cattle (Bos taurus L.) manure slurry. Surface application of slurry increased P leaching losses relative to baseline losses, but losses declined with increasing active flow volume. After elution of one pore volume, leaching averaged 0.54 kg P ha(-1) from the loam, 0.38 kg P ha(-1) from the sandy loam, and 0.22 kg P ha(-1) from the loamy sand following surface application. Injection decreased leaching of all P forms compared with surface application by an average of 0.26 kg P ha(-1) in loam and 0.23 kg P ha(-1) in sandy loam, but only by 0.03 kg P ha(-1) in loamy sand. Lower leaching losses were attributed to physical retention of particulate P and dissolved organic P, caused by placing slurry away from active flow paths in the fine-textured soil columns, as well as to chemical retention of dissolved inorganic P, caused by better contact between slurry P and soil adsorption sites. Dissolved organic P was less retained in soil after slurry application than other P forms. On these soils with low to intermediate P status, slurry injection lowered P leaching losses from clay-rich soil, but not from the sandy soils, highlighting the importance of soil texture in manageing P losses following slurry application.     

Phosphorus in surface runoff from calcareous arable soils of the semiarid Western United States

Management strategies that minimize P transfer from agricultural land to water bodies are based on relationships between P concentrations in soil and runoff. This study evaluated such relationships for surface runoff generated by simulated sprinkler irrigation onto calcareous arable soils of the semiarid western United States. Irrigation was applied at 70 mm h(-1) to plots on four soils containing a wide range of extractable P concentrations. Two irrigation events were conducted on each plot, first onto dry soil and then after 24 h onto wet soil. Particulate P (>0.45 microm) was the dominant fraction in surface runoff from all soils and was strongly correlated with suspended sediment concentration. For individual soil types, filterable reactive P (<0.45 microm) concentrations were strongly correlated with all soil-test P methods, including environmental tests involving extraction with water (1:10 and 1:200 soil to solution ratio), 0.01 M CaCl(2), and iron strips. However, only the Olsen-P agronomic soil-test procedure gave models that were not significantly different among soils. Soil chemical differences, including lower CaCO(3) and water-extractable Ca, higher water-extractable Fe, and higher pH, appeared to account for differences in filterable reactive P concentrations in runoff from soils with similar extractable P concentrations. It may therefore be possible to use a single agronomic test to predict filterable reactive P concentrations in surface runoff from calcareous soils, but inherent dangers exist in assuming a consistent response, even for one soil within a single field.     

Physiological and Morphological Response Patterns of <Emphasis Type="Italic">Populus deltoides</Emphasis> to Alluvial Groundwater Pumping

We examined the physiological and morphological response patterns of plains cottonwood [Populus deltoides subsp. monilifera (Aiton) Eck.] to acute water stress imposed by groundwater pumping. Between 3 and 27 July 1996, four large pumps were used to withdraw alluvial groundwater from a cottonwood forest along the South Platte River, near Denver, Colorado, USA. The study was designed as a stand-level, split-plot experiment with factorial treatments including two soil types (a gravel soil and a loam topsoil over gravel), two water table drawdown depths (∼0.5 m and >1.0 m), and one water table control (no drawdown) per soil type. Measurements of water table depth, soil water potential (Ψ_s), predawn and midday shoot water potential (Ψ_pd and Ψ_md), and D/H (deuterium/hydrogen) ratios of different water sources were made in each of six 600-m² plots prior to, during, and immediately following pumping. Two additional plots were established and measured to examine the extent to which surface irrigation could be used to mitigate the effects of deep drawdown on P. deltoides for each soil type. Recovery of tree water status following pumping was evaluated by measuring stomatal conductance (g _s ) and xylem water potential (Ψ_xp) on approximately hourly time steps from before dawn to mid-afternoon on 11 August 1996 in watered and unwatered, deep-drawdown plots on gravel soils. P. deltoides responded to abrupt alluvial water table decline with decreased shoot water potential followed by leaf mortality. Ψ_pd and percent leaf loss were significantly related to the magnitude of water table declines. The onset and course of these responses were influenced by short-term variability in surface and ground water levels, acting in concert with physiological and morphological adjustments. Decreases in Ψ_pd corresponded with increases in Ψ_md, suggesting shoot water status improved in response to stomatal closure and crown dieback. Crown dieback caused by xylem cavitation likely occurred when Ψ_pd reached −0.4 to −0.8 MPa. The application of surface irrigation allowed trees to maintain favorable water status with little or no apparent cavitation, even in deep-drawdown plots. Two weeks after the partial canopy dieback and cessation of pumping, g _s and Ψ_xp measurements indicated that water stress persisted in unwatered P. deltoides in deep-drawdown plots.     

PLANNING FOR THE REHABILITATION OF GRAVEL PITS1

ABSTRACT: By field investigations and planning, it is profitable to rehabilitate gravel pits as recreational lakes in urban areas. Some of the important aspects to be considered are topography, soil, surface water and groundwater. A case study is presented and some general guidelines in the rehabilitation process are given. This kind of a use for derelict land is important at the present time as there is a growing demand for recreational lakes in urban areas.     

Nonpoint Source Loading Rates From Selected Land Uses1

ABSTRACT: Loading rates derived from monitoring natural runoff from selected land uses are compared. Land uses selected for evaluation are construction sites, barnyards, and agriculture (dairying). Runoff volumes, sediment, and nutrient fractions were monitored and expressed as areal loadings for comparison purposes. Sediment yield and total phosphorus (total P) loss was directly proportional to runoff (m³/ha). In decreasing order, the loadings for sediment and total P were as follows: construction site > barnyard > general dairying. Runoff from the barnyard area was approximately 10 times higher in soluble phosphorus and ammonium nitrogen than the other land uses under investigation. Areal loss for nitrate nitrogen was highest from the construction site and was attributed to the higher volume of runoff per unit area. Results show that barnyards in a dairying watershed are potentially a major source of sediment and nutrients, especially those dissolved fractions which have the potential for immediate water quality impacts. Relative to general agricultural land, urban construction sites also appear to be a major source of sediment and nutrients. As with barnyard sites, however, the effect of such sites on water quality likely depends on proximity to surface water bodies and other watershed characteristics affecting delivery ratios of contaminants.     

Salt-induced land and water degradation in the Aral Sea basin: A challenge to sustainable agriculture in Central Asia

Expansion of irrigated agriculture in the Aral Sea Basin in the second half of the twentieth century led to the conversion of vast tracks of virgin land into productive agricultural systems resulting in significant increases in employment opportunities and income generation. The positive effects of the development of irrigated agriculture were replete with serious environmental implications. Excessive use of irrigation water coupled with inadequate drainage systems has caused large‐scale land degradation and water quality deterioration in downstream parts of the basin, which is fed by two main rivers, the Amu‐Darya and Syr‐Darya. Recent estimates suggest that more than 50% of irrigated soils are salt‐affected and/or waterlogged in Central Asia. Considering the availability of natural and human resources in the Aral Sea Basin as well as the recent research addressing soil and water management, there is cause for cautious optimism. Research‐based interventions that have shown significant promise in addressing this impasse include: (1) rehabilitation of abandoned salt‐affected lands through halophytic plant species; (2) introduction of 35‐day‐old early maturing rice varieties to withstand ambient soil and irrigation water salinity; (3) productivity enhancement of high‐magnesium soils and water resources through calcium‐based soil amendments; (4) use of certain tree species as biological pumps to lower elevated groundwater levels in waterlogged areas; (5) optimal use of fertilizers, particularly those supplying nitrogen, to mitigate the adverse effects of soil and irrigation water salinity; (6) mulching of furrows under saline conditions to reduce evaporation and salinity buildup in the root zone; and (7) establishment of multipurpose tree and shrub species for biomass and renewable energy production. Because of water withdrawals for agriculture from two main transboundary rivers in the Aral Sea Basin, there would be a need for policy level interventions conducive for enhancing interstate cooperation to transform salt‐affected soil and saline water resources from an environmental and productivity constraint into an economic asset.     

Phosphorus retention and remobilization in vegetated buffer strips: a review

Diffuse pollution remains a major threat to surface waters due to eutrophication caused by phosphorus (P) transfer from agricultural land. Vegetated buffer strips (VBSs) are increasingly used to mitigate diffuse P losses from agricultural land, having been shown to reduce particulate P transfer. However, retention of dissolved P (DP) has been lower, and in some cases VBSs have increased delivery to surface waters. The aims of this review were (i) to develop a conceptual model to enhance the understanding of VBS functioning in terms of DP, (ii) to identify key processes within the model that affect DP retention and delivery, and (iii) to explore evidence for the controls on these processes. A greater understanding in these areas will allow the development of management strategies that enhance DP retention. We found evidence of a surface layer in buffer strip soils that is enriched in soluble P compared with adjacent agricultural land and may be responsible for the reported increased DP delivery. Through increased biological activity in VBSs, plants and microorganisms may assimilate P from particulates retained in the VBSs or native soil P and remobilize this P in a more soluble form. These conclusions are based on a limited amount of research, and a better understanding of biogeochemical cycling of P in buffer strip soils is required.