煤层气采出水中重金属含量分析

概述了国内外煤层气的开发利用现状,针对煤层气开发过程中采出水的利用价值,结合多个井场采出水的样品实测数据,详细讨论了重金属及其他污染物含量对煤层气采出水利用价值的影响,对其中所含各类污染物质及重金属进行了分类对比分析,提出了煤层气采出水综合利用的处理建议。     

THE EFFECTS OF DEICING SALTS ON WATER CHEMISTRY IN PINHOOK BOG,INDIANA1

ABSTRACT: A five-year study was conducted to identify the effects of road salt intrusion on the water chemistry of Pinhook Bog following operation of an uncovered salt storage pile adjacent to the bog for ten years. A distinct pattern of elevated salt concentrations was observed in the interstitial waters of the surface peat that corresponded to observed alterations in the bog vegetation. Yearly mean salt concentrations as high as 468 mg/l sodium and 1215 mg/l chloride were recorded in the plant root zone of the peat mat. The salt concentrations decreased significantly each year from 1979 to 1981 throughout the impacted area. Some increases of a lesser magnitude occurred in 1982 and 1983. Analysis of salt movements suggested that vertical transport by water movement was responsible for concentration changes. The major declines in salt levels occurred in the spring following snowmelt and heavy precipitation events. Evapotranspiration during periods of drought resulted in the gradual increases in surface peat salt concentrations. Diverted highway runoff was shown to be the major continuing source of sodium chloride contamination and was the likely source of the elevated calcium, magnesium, potassium, bicarbonate, and pH levels also observed in the impacted area.     

Comparison of adsorption models in reservoir simulation of enhanced coalbed methane recovery and CO2 sequestration in coal

Coalbed methane is an important resource of energy. Meanwhile CO₂ sequestration in coal is a potential management option for greenhouse gas emissions. An attractive aspect to this process is that CO₂ is adsorbed to the coal, reducing the risk of CO₂ migration to the surface. Another aspect to this is that the injected CO₂ could displace adsorbed methane leading to enhanced coalbed methane recovery. Therefore, in order to understand gas migration within the reservoir, mixed-gas adsorption models are required. Moreover, coal reservoir permeability will be significantly affected by adsorption-induced coal swelling during CO₂ injection. Coal swelling is directly related to reservoir pressure and gas content which is calculated by adsorption models in reservoir simulation. Various models have been studied to describe the pure- and mixed-gas adsorption on coal. Nevertheless, only the Langmuir and Extended Langmuir models are usually applied in coal reservoir simulations. This paper presents simulation work using several approaches to representing gas adsorption, implemented into the coal seam gas reservoir simulator SIMED II. The adsorption models are the Extended Langmuir model (ELM), the Ideal Adsorbed Solution (IAS) model and the Two-Dimensional Equation of State (2D EOS). The simulations based on one Australian and one American coal sample demonstrated that (1) the Ideal Adsorbed Solution model, in conjunction with Langmuir model as single-component isotherm, shows similar simulation results as the ELM for both coals, with the IAS model representing the experimental adsorption data more accurately than the ELM for one coal and identically with the ELM for the other coal; (2) simulation results using the 2D EOS, however, are significantly different to the ELM or IAS model for both coal samples. The magnitude of the difference is also dependent on coal swelling and the well operating conditions, such as injection pressure.     

Characteristics of coal mine ventilation air flows

Coal mine methane (CMM) is not only a greenhouse gas but also a wasted energy resource if not utilised. Underground coal mining is by far the most important source of fugitive methane emissions, and approximately 70% of all coal mining related methane is emitted to the atmosphere through mine ventilation air. Therefore, research and development on mine methane mitigation and utilisation now focuses on methane emitted from underground coal mines, in particular ventilation air methane (VAM) capture and utilisation. To date, most work has focused on the oxidation of very low concentration methane. These processes may be classified based on their combustion kinetic mechanisms into thermal oxidation and catalytic oxidation. VAM mitigation/utilisation technologies are generally divided into two basic categories: ancillary uses and principal uses. However, it is possible that the characteristics of ventilation air flows, for example the variations in methane concentration and the presence of certain compounds, which have not been reported so far, could make some potential VAM mitigation and utilisation technologies unfeasible if they cannot cope with the characteristics of mine site ventilation air flows. Therefore, it is important to understand the characteristics of mine ventilation air flows. Moreover, dust, hydrogen sulphide, sulphur dioxide, and other possible compounds emitted through mine ventilation air into the atmosphere are also pollutants. Therefore, this paper presents mine-site experimental results on the characteristics of mine ventilation air flows, including methane concentration and its variations, dust loadings, particle size, mineral matter of the dust, and other compounds in the ventilation air flows. The paper also discusses possible correlations between ventilation air characteristics and underground mining activities.     

Enhanced coalbed methane and CO2 storage in anthracitic coals—Micro-pilot test at South Qinshui,Shanxi, China

This paper describes the results of a single well micro-pilot test performed at an existing well in the anthracitic coals of the South Qinshui basin, Shanxi Province, China. A set of reservoir parameters was obtained from the micro-pilot test. The field data was successfully history matched using a tuned reservoir model which accounted for changes in permeability due to swelling and pressure change. Prediction of initial performance showed significant production enhancement of coalbed methane while simultaneously storing the CO₂. The calibrated reservoir model was used to design a multi-well pilot at the site to validate the performance prediction. The design is now completed. The recommendation is to proceed to the next stage of multi-well pilot testing and to demonstrate the enhanced coalbed methane (ECBM) technology.     

山东省区域经济差异时空特征及协调发展研究

定性、定量分析了1998年以来山东省区域经济差异的动态变化特征，运用聚类分析方法把17个地市分为东部和西部，对东西部经济差异进行测度并分析其原因。认为重视效率仍是当前山东省经济发展的主要出发点，同时正视地域差异，发挥区域优势。在继续鼓励东部地区加快发展的同时，对西部地区逐步实行适度倾斜政策，东西结合，在发展中缩小差距，实现协调发展。     

CLIMATE CHANGE: POTENTIAL IMPACTS AND INTERACTIONS IN WETLANDS OF THE UNTTED STATES1

ABSTRACT: Wetlands exist in a transition zone between aquatic and terrestrial environments which can be altered by subtle changes in hydrology. Twentieth century climate records show that the United States is generally experiencing a trend towards a wetter, warmer climate; some climate models suggest that this trend will continue and possibly intensify over the next 100 years. Wetlands that are most likely to be affected by these and other potential changes (e.g., sea‐level rise) associated with atmospheric carbon enrichment include permafrost wetlands, coastal and estuanne wetlands, peat lands, alpine wetlands, and prairie pothole wetlands. Potential impacts range from changes in community structure to changes in ecological function, and from extirpation to enhancement. Wetlands (particularly boreal peat‐lands) play an important role in the global carbon cycle, generally sequestering carbon in the form of biomass, methane, dissolved organic material and organic sediment. Wetlands that are drained or partially dried can become a net source of methane and carbon dioxide to the atmosphere, serving as a positive biotic feedback to global warming. Policy options for minimizing the adverse impacts of climate change on wetland ecosystems include the reduction of current anthropogenic stresses, allowing for inland migration of coastal wetlands as sea‐level rises, active management to preserve wetland hydrology, and a wide range of other management and restoration options.     

CO2 storage and enhanced coalbed methane recovery: Reservoir characterization and fluid flow simulations of the Big George coal,Powder River Basin,Wyoming, USA

Coalbeds are an attractive geological environment for storage of carbon dioxide (CO₂) because CO₂ is retained in the coal as an adsorbed phase and the cost of injection can be offset by enhanced coalbed methane (ECBM) production. This paper presents the findings of a CO₂ storage feasibility study on coalbeds in the Wyodak-Anderson coal zone of the Powder River Basin, Wyoming, USA, using reservoir characterization and fluid flow simulations. A 3D numerical model of the Big George coal was constructed using geostatistical techniques, with values of cleat and matrix permeability and porosity constrained through history-matching of production data from coalbed methane (CBM) wells in the field area.Following history-matching, several ECBM and CO₂ storage scenarios were investigated: shrinkage and swelling of the coal was either allowed or disallowed, a horizontal hydraulic fracture was either placed at the injection well or removed from the model, the number of model layers was varied between 1 and 24, and the permeability and porosity fields were constructed to be either homogeneous or heterogeneous in accordance with geostatistical models of regional variability. All simulations assumed that the injected gas was 100% CO₂ and that the coalbed was overlain by an impermeable caprock. Depending on the scenario, the simulations predicted that after 13 years of CO₂ injection, the cumulative methane production would be enhanced by a factor of 1.5–5. Including coal matrix shrinkage and swelling in the model predicted swelling near the injection well, which resulted in a slight reduction (10%) in injection rate. However, including a horizontal hydraulic fracture in the model at the base of the injection well helped mitigate the negative effect of swelling on injection rate. It was also found that six model layers were needed to have sufficient resolution in the vertical direction to account for the buoyancy effects between the gas and resident water, and that capturing the heterogeneous nature of the coal permeability and porosity fields predicted lower estimates of the storage capacity of the Wyodak-Anderson coal zone.After noting that gravity and buoyancy were the major driving forces behind gas flow within the Big George coal, several leakage scenarios were also investigated, in an effort to better understand the interplay between diffusion and flow properties on the transport and storage of CO₂. The modeling predicted that the upward migration of gas due to the buoyancy effect was faster than the diffusion of CO₂ and therefore the gas rapidly rose to the top of the coalbed and migrated into overlying strata when an impermeable caprock was not included in the model.     

电絮凝＋电氧化法处理山西某区块煤层气采出水研究与实践

山西省某区块煤层气采出水水质均值为COD 170 mg/L,BOD₅29.7 mg/L,氨氮5.36 mg/L,氟化物6.59 mg/L,4个污染物指标超过GB 3838—2002《地表水环境质量标准》Ⅳ类水质限值要求。文章针对该地区煤层气采出水的可生化性差(BOD₅/COD≤20%)、氯离子含量较高等特点,采用“电絮凝+电氧化”法进行中试试验,处理后水质COD≤17 mg/L,氨氮≤0.1 mg/L,氟化物≤1.0 mg/L,试验结果表明:采用该方法可以有效降低COD、氨氮、氟化物等主要污染物指标,使该区块煤层气采出水达到GB 3838—2002标准Ⅳ类水质要求(COD≤30 mg/L、氨氮≤1 mg/L、氟化物≤1 mg/L)。应用中试试验研究成果,采用“双电+保障(过滤)”工艺在该区块建成了煤层气采出水处理示范工程,水处理站建成投运后出水水质稳定,始终满足GB 3838—2002《地表水环境质量标准》Ⅳ类水质要求。     

Coalbed methane reservoir data and simulator parameter uncertainty modelling for CO2 storage performance assessment

Laboratory studies and a number of field pilots have demonstrated that CO₂ injection into coal seams has the potential to enhance coalbed methane (CBM) recovery with the added advantage that most of the injected CO₂ can be stored permanently in coal. The concept of storing CO₂ in geologic formations as a safe and effective greenhouse gas mitigation option requires public and regulatory acceptance. In this context it is important to develop a good understanding of the reservoir performance, uncertainties and the risks that are associated with geological storage. The paper presented refers to the sources of uncertainty involved in CO₂ storage performance assessment in coalbed methane reservoirs and demonstrates their significance using extensive digital well log data representing the Manville coals in Alberta, Canada. The spatial variability of the reservoir properties was captured through geostatistical analysis, and sequential Gaussian simulations of these provided multiple realisations for the reservoir simulator inputs. A number of CO₂ injection scenarios with variable matrix swelling coefficients were evaluated using a 2D reservoir model and spatially distributed realisations of total net thickness and permeability.     

Methane emission from rice paddy soils, aerotolerance of methanogens and global thermal warming

In vitro methane emissions from different rice paddy soils and algal mats were studied under anoxic and atmospheric conditions. Methane production from rice paddy soils cultivating different strains of rice was found to be appreciable under anoxic conditions, but considerably reduced under atmospheric conditions, and dependent on rice cultivars (strains). A contradictory result was obtained with a Gobindabhog cultivated rice field (a strain of rice with aroma), where methane yield under anoxic was greater than that under atmospheric conditions. The results indicated aerotolerance of methanogens or the possible existence of microaerophilic methanogens. The results from algal mats corroborated these findings.Methane has been considered to be an important greenhouse gas contributing significantly to global thermal warming (GTW). Flooded rice paddy fields have been considered to be a most prominent source of abiogenic methane emission, though considerable uncertainty exists regarding the true estimates of methane emission. Factors affecting methane emission and its abatement have been examined. In spite of increasing methane emission, rice cultivation leads to enormous utilization of the green house gas carbon dioxide and release of oxygen to the atmosphere. Thus, the contribution of methane to GTW (from rice paddy cultivation) is more than compensated by carbon dioxide absorption.Appropriate steps have been suggested for the reduction of methane emissions, the most important of which is the restoration of methane sinks.     

CHEMICAL RELATIONSHIPS BETWEEN SURFACE WATER AND THE GROUND IN SOUTH FLORIDA1

ABSTRACT: Analyses of soil and water were made in a stretch of shallow ground north of a cypress head in South Florida. The area is covered with water for part of the year, and it flows slowly southward. The soil is primarily peat formed from the local graminid vegetation during its decay. The top layer consists of a blue-green algal mat whose decay products contribute to the peat also. Collections of soil (including the top layer) were made layer by layer and anlyzed for cations and anions and for ion exchange capacity. The latter appears to be high enough in all layers to account for the ion content within the soil and surrounding waters. It probably is a very important buffer system that retards limestone erosion. CEC values ranged from 20 to 190 meg/100 gm dry soil from bedrock to surface.     

Drainage and utilization of Chinese coal mine methane with a coal–methane co-exploitation model: Analysis and projections

Coal mine methane (CMM) released during coal mining attributes to unsafe working conditions and environmental impact. China, the largest coal producer in the world, is facing problems associated with CMM such as fatal gas accidents and intense greenhouse gas emission along the path to deep mining. Complicated geological conditions featured with low permeability, high gas pressure and gas content of Chinese coal seams have been hindering the coal extraction. To solve these problems, a model of coal–methane co-exploitation is proposed. This model realizes the extraction of two resources with safety ensured and has been successfully applied in Huainan coalfield, China. The current situation of drainage and utilization of CMM in China are diagnosed. Connections between the coal production, methane emissions, drainage and utilization are analyzed. Estimations of future coal production, methane emissions, drainage and utilization are made in a co-exploitation based scenario. The emitted, drained and utilized CMM are projected to reach 26.6, 13.3 and 9.3 billion m³, respectively by adapting the assumption of 3800 million metric tons of coal production by 2020.     

Self-organization theories and environmental management: The case of South Moresby,Canada

This article presents a new approach to the analysis and management of large-scale societal problems with complex ecological, economic, and social dimensions. The approach is based on the theory of self-organizing systems—complex, open, far-from-equilibrium systems with nonlinear dynamics. A brief overview and comparison of different self-organization theories (synergetics, self-organization theory, hypercycles, and autopoiesis) is presented in order to isolate the key characteristics of such systems.The approach is used to develop an analysis of the landuse controversy in the South Moresby area of the Queen Charlotte Islands, British Columbia, Canada. Critical variables are identified for each subsystem and classified by spatial and temporal scale, and discussed in terms of information content and internal/external origin. Eradication of sea otters, introduction of black-tailed deer, impacts of large-scale clearcut logging, sustainability of the coastal forest industry, and changing relations between native peoples and governments are discussed in detail to illustrate the system dynamics of the South Moresby sociobiophysical system. Finally, implications of the self-organizing sociobiophysical system view for regional analysis and management are identified.     

Possible Input of Nitrogen of Visitors’ Origin on a Protected Peatland

The Ozegahara peatland, in the Nikko-Oze National Park in Japan, is ecologically significant because of its oligotrophic environment; it is one of the most strictly preserved areas in the country. The isotope ratio of nitrogen (¹⁵N/¹⁴N) and carbon (¹³C/¹²C) and C/N ratio of peat moss (Sphagnum spp.) and sundew (Drosera rotundifolia) in the peatland were analyzed. The correlation of the isotope ratio with some parameters (sundew population density, number of trapped insects, water level, bog myrtle coverage, and visitor density) was investigated. The nitrogen isotope ratio of sundew showed the most significant covariation with visitor density, where sundew from lunch areas or along busy walkways showed a higher nitrogen isotope ratio. The nitrogen isotope ratio of peat moss covaried, not only with route traffic frequency but also with water level, bog myrtle coverage, and number of trapped insects by sundew, indicating that factors other than the visitor level influence the local nitrogen cycle. This study suggests that the nitrogen imported into the peatland by visitors is a principal factor to be monitored for the maintenance of the natural environment.     

QUALITY OF RUNOFF FROM MINNESOTA PEATLANDS: II. A METHOD FOR ASSESSING MINING IMPACTS1

ABSTRACT The impacts of milled peat mining on runoff quality in northern Minnesota were determined using a multiple watershed approach. The frequency distributions of water quality constituents were used to detect whether runoff from a mined bog differed from that of 15 unmined (control) bogs. Peat mining increased water temperature, suspended sediment, specific conductance and concentrations of acidity, iron, sodium, and nitrogen species, although drinking water standards were not exceeded (α= 0.05). The method presented may be applicable for other nonpoint pollution investigations.     

晋陕蒙接壤地区能源基地战略环境影响评价研究

文章以晋陕蒙接壤区能源基地战略为例对区域战略环境影响评价进行分析和研究。首先对接壤区能源基地战略进行了回顾性地分析和评价,然后对环境影响进行了预测和环境效益分析,最后提出了战略实施的环境保护对策。     

糠醛树脂防砂工艺在临盘油田的应用

针对临盘油田盘河区块地层砂粒细、泥质含量偏高,导致油井实施高压充填防砂后大面积堵塞、小井眼防砂措施有效率偏低两方面的问题,成功试验引进糠醛树脂防砂工艺。2010年初至2011年末,共在临盘油田试验22口井,有效率达86.3%,累计增油13 319.1t。该技术在临盘油田的成功应用,为同类油藏的防砂和开发提供了宝贵的经验和数据,具有重要的理论和实践意义。     

Evaluating coal bed methane investment in China based on a real options model

In this paper, a real options based binominal lattices model for the investment of coal bed methane (CBM) is conducted. CBM prices and market demand are incorporated into the model as the predominant uncertain factors and it is solved by using the bidimensional binominal lattices approach. Then the model is employed to evaluate the investment in CBM projects in China, and the effect of related policies is analyzed. The empirical results demonstrate that the model can be used to offer a better explanation of why the CBM industry has developed slowly in China from an investment perspective. It is found that the current policy environment is not positive enough to attract investment in the CBM industry. Among various factors, CBM prices yield the most significant effect on stimulating investment in CBM development. Increasing the price subsidy is also an effective policy to stimulate investment and promote the development of the CBM industry in China.     

秦皇岛港东港区煤尘污染与气象特征关系分析

本文分析了秦皇岛港东港区煤尘污染与气象条件的关系,分析结果表明,表征煤尘污染的因子总悬浮颗粒物及降尘与自然降水、大风等气象因子具有明显的相关性,并依据分析提出了相应的管理建议。