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Maria Nowakowska Monika Sterzel Krzysztof Szczubiałka 《Journal of Polymers and the Environment》2006,14(1):59-64
Novel water-soluble polymeric photosensitizers based on a natural polymer, naphthalene-modified hydroxyethylcellulose (HENC),
were obtained and used for the photooxidation of cyanide. The reaction leads to the formation of cyanate. The process occurs
via photoinduced electron transfer from CN− to the naphthalene or naphthoquinone polymeric chromophores. The kinetics of the reaction depend on the degree of substitution
of HENC, its concentration, and pH of the solution. The polymers can be easily removed after reaction as prolonged irradiation
leads to their photodegradation. 相似文献
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The photocatalytic degradation of dye Rhodamine B (RhB) in the presence of TiO2 nanostdpe or P25 under visible light irradiation was investigated. The degradation intermediates were identified using Infrared spectra (IR spectra), ^1H nuclear magnetic resonance (^1HNMR) spectra, and gas chromatography-mass spectroscopy (GC-MS). The IR and the ^1HNMR results showed that the large conjugated chromophore structure of RhB was efficiently destroyed under visible light irradiation in both the photocatalytic systems (TiO2 nanostfipe or P25 and Rhodamine B systems). GC-MS results showed that the main identified intermediates were ethanediotic acid, 1,2-benzenedicarboxylic acid, 4-hydroxy benzoic acid and benzoic acid, which were almost the same in the TiO2 nanostdpes and P25 systems. This work provides a good insight into the reaction pathway(s) for the TiO2-assisted photocatalytic degradation of dye pollutants under visible light irradiation. 相似文献
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