Spatiotemporal Evaluation of Simulated Evapotranspiration and Streamflow over Texas Using the WRF‐Hydro‐RAPID Modeling Framework

This study assesses a large‐scale hydrologic modeling framework (WRF‐Hydro‐RAPID) in terms of its high‐resolution simulation of evapotranspiration (ET) and streamflow over Texas (drainage area: 464,135 km²). The reference observations used include eight‐day ET data from MODIS and FLUXNET, and daily river discharge data from 271 U.S. Geological Survey gauges located across a climate gradient. A recursive digital filter is applied to decompose the river discharge into surface runoff and base flow for comparison with the model counterparts. While the routing component of the model is pre‐calibrated, the land component is uncalibrated. Results show the model performance for ET and runoff is aridity‐dependent. ET is better predicted in a wet year than in a dry year. Streamflow is better predicted in wet regions with the highest efficiency ~0.7. In comparison, streamflow is most poorly predicted in dry regions with a large positive bias. Modeled ET bias is more strongly correlated with the base flow bias than surface runoff bias. These results complement previous evaluations by incorporating more spatial details. They also help identify potential processes for future model improvements. Indeed, improving the dry region streamflow simulation would require synergistic enhancements of ET, soil moisture and groundwater parameterizations in the current model configuration. Our assessments are important preliminary steps towards accurate large‐scale hydrologic forecasts.     

Temperature and feed strategy effects on sulfate and organic matter removal in an AnSBB

The objective of this work was to analyze the interaction effects between temperature, feed strategy and COD/[SO(4)(2-)] levels, maintaining the same ratio, on sulfate and organic matter removal efficiency from a synthetic wastewater. This work is thus a continuation of Archilha et al. (2010) who studied the effect of feed strategy at 30 °C using different COD/[SO(4)(2-)] ratios and levels. A 3.7-L anaerobic sequencing batch reactor with recirculation of the liquid phase and which contained immobilized biomass on polyurethane foam (AnSBBR) was used to treat 2.0 L synthetic wastewater in 8 h cycles. The temperatures of 15, 22.5 and 30 °C with two feed strategies were assessed: (a) batch and (b) batch followed by fed-batch. In strategy (a) the reactor was fed in 10 min with 2 L wastewater containing sulfate and carbon sources. In strategy (b) 1.2 L wastewater (containing only the sulfate source) was fed during the first 10 min of the cycle and the remaining 0.8 L (containing only the carbon source) in 240 min. Based on COD/[SO(4)(2-)] = 1 and on the organic matter (0.5 and 1.5 gCOD/L) and sulfate (0.5 and 1.5 gSO(4)(2-)/L) concentrations, the sulfate and organic matter loading rates applied were 1.5 and 4.5 g/L.d, i.e., same COD/[SO(4)(2-)] ratio (=1) but different levels (1.5/1.5 and 4.5/4.5 gCOD/gSO(4)(2-)). When reactor feed was 1.5 gCOD/L.d and 1.5 gSO(4)(2-)/L.d, gradual feeding (strategy b) showed to favor sulfate and organic matter removal in the investigated temperature range, indicating improved utilization of the electron donor for sulfate reduction. Sulfate removal efficiencies were 87.9; 86.3 and 84.4%, and organic matter removal efficiencies 95.2; 86.5 and 80.8% at operation temperatures of 30; 22.5 and 15 °C, respectively. On the other hand, when feeding was 4.5 gCOD/L.d and 4.5 gSO(4)(2-)/L.d, gradual feeding did not favor sulfate removal, indicating that gradual feeding of the electron donor did not improve sulfate reduction.     

Is aridity restricting deforestation and land uses in the South American Dry Chaco?

In this paper, we explored how aridity influences the regional deforestation and land-use patterns (i.e. crops/pastures) in South American Dry Chaco. To do this, we contrasted land use during last decade (2001–2012) with a spatially explicit aridity index, which we complemented with a crop water balance model. Land-use classifications were performed by considering the temporal variability of NDVI from MODIS satellites, showing that 40 and 60% of deforested land was assigned to crops and pastures, respectively. Results indicate that although the regional deforestation pattern was not associated with the aridity gradient, with drier areas similarly deforested as wetter areas, contrasting differences were observed in the use of this land, with crops mostly located (90%) in wetter areas and pastures evenly distributed across the whole aridity gradient. This research highlighted the strong effect of water limitations on the land-use option after deforestation and may help to set the basis for future land-use planning policies.     

Particulate Organic Matter Composition in A Semi-Enclosed Marine System

Spatial and temporal changes in the biochemical composition of particulate organic matter in a semi-enclosed marine system (Stagnone di Marsala, Mediterranean Sea) were studied, on a monthly basis, from January to December 1994, in order to assess nutritional value of suspended particles for benthic suspension feeders. According to previous findings, the study site displayed a strong oligotrophy. Chlorophyll-a accounted for a very low fraction of the total suspended matter pool (0.1%), whereas at least 75% of POC was of detrital/heterotrophic origin. POC: PON ratio values indicate that bacterioplankton biomass accounted for a significant fraction of the total POC pool, displaying values comparable to those of the phytoplankton biomass (phytoplankton to bacterial biomass ratio was about (1). Temporal and spatial changes in the biochemical composition of particulate organic matter were rather limited and related to its sources, the main of which is represented by detrital particles released by the Posidonia oceanica (L.) beds. the comparison between our results and those encountered in other coastal lagoons indicates that the low abundance of suspension-feeding organisms observed in the study area is related to the “quality depression” of particles due to the dilution of high quality compounds (i.e., biopolymeric carbon) in a largely inorganic matrix. This result leads us to conclude that, to reach the same amount of high quality particulate food, a suspension feeder mollusc in the Marsala lagoon would need to filter a sea water volume around 3 times higher than in other Mediterranean coastal lagoons.     

Radionuclide concentrations in raw and purified phosphoric acids from Brazil and their processing wastes: implications for radiation exposures

Radionuclides from the U and Th natural series are present in alkaline rocks, which are used as feedstock in Brazil for the production of raw phosphoric acid, which can be considered as a NORM (naturally occurring radioactive material). As a result of the purification of raw phosphoric acid to food-grade phosphoric acid, two by-products are generated, i.e., solid and liquid wastes. Taking this into account, the main aim of this study was to evaluate the fluxes of natural radionuclide in the production of food-grade phosphoric acids in Brazil, to determine the radiological impact caused by ingestion of food-grade phosphoric acid, and to evaluate the solid waste environmental hazards caused by its application in crop soils. Radiological characterization of raw phosphoric acid, food-grade phosphoric acid, solid waste, and liquid waste was performed by alpha and gamma spectrometry. The ²³⁸U, ²³⁴U, ²²⁶Ra, and ²³²Th activity concentrations varied depending on the source of raw phosphoric acid. Decreasing radionuclides activity concentrations in raw phosphoric acids used by the producer of the purified phosphoric acid were observed as follows: Tapira (raw phosphoric acid D) > Catal?o (raw phosphoric acids B and C) > Cajati (raw phosphoric acid A). The industrial purification process produces a reduction in radionuclide activity concentrations in food-grade phosphoric acid in relation to raw phosphoric acid produced in plant D and single raw phosphoric acid used in recent years. The most common use of food-grade phosphoric acid is in cola soft drinks, with an average consumption in Brazil of 72 l per person per year. Each liter of cola soft drink contains 0.5 ml of food-grade phosphoric acid, which gives an annual average intake of 36 ml of food-grade phosphoric acid per person. Under these conditions, radionuclide intake through consumption of food-grade phosphoric acid per year per person via cola soft drinks is not hazardous to human health in Brazil. Considering these annual additions of ²³⁸U, ²²⁶Ra, ²³²Th and ⁴⁰K, and since these radionuclide should be homogeneously distributed in the upper 10 cm of soils with an assumed apparent density of 1.5 g/cm³, a maximum increase of 0.19 ± 0.03 Bq kg⁻¹ of soil is expected for ²³⁸U and ²³⁴U. Thus, the addition of solid waste as phosphate fertilizers to Brazilian agricultural soils does not represent a hazard to the ecosystem or to human health.     

Analytical modelling of hydrocarbon pool fires: Conservative evaluation of flame temperature and thermal power

As well known, risk is a combination of probability and consequences of an accident. In analyzing the consequence of accidental hydrocarbon fires and the potential for domino effects, the evaluation of the flame extent and temperature are of the utmost importance. Since the primary effects of pool fires are connected to thermal radiation and issues of interplant/tank spacing employees’ safety zones, firewall specifications are to be addressed on the basis of a proper consequence analysis. By means of real scale experimental tests it was verified that both the thermal power and the flame temperature, T_f, increase as the pool area increases, up to reach maximum values in connection with a “critical pool dimension”. Dealing with pool areas higher than the critical one, experimental results, performed by different researchers at different scales, show a decrease of T_f. An in-depth analysis of the different concurring phenomena connected to a pool fire development allowed identifying the limiting step controlling the flame temperature. In fact, the trend of T_f is mainly determined by the increasing difficulty of oxygen diffusion within the internal bulk of gaseous hydrocarbons. In this article, we propose a novel pool fire modelling approach based on the simplified physical phenomena occurring in a circular turbulent diffusion fire and suitable to provide a theoretical insight into the above-mentioned experimental trends and to obtain the maximum values of the flame temperature and of the thermal power.The geometry of the pool is dictated by the surroundings (i.e., diking) and the analytical models here presented were successfully applied to the common situation of circular pools.However, it must be remarked that the developed model, matching fairly well experimental data for different hydrocarbons, can be applied in modelling similar scenarios characterized by different geometric or environmental conditions (e.g. road and rail tunnel fires).     

Effect of initial excess density and discharge on constant flux gravity currents propagating on a slope

The effect of the upstream conditions on propagation of gravity current over a slope is investigated using three-dimensional numerical simulations. The current produced by constant buoyancy flux, is simulated using a large eddy simulation solver. The dense saline solution used at the inlet is the driving force of the flow. Higher replenishment of the current is possible either by a high inflow discharge or high initial fractional density excess. In the simulations, it is observed that these two parameters affect the flow in different ways. Results show that the front speed of the descending current is proportional to the cube root of buoyancy flux, $(g_o^{\prime } Q)^{1/3}$ , which agrees with the previous experimental and numerical observations. The height of the tail of the current grows linearly in the streamwise direction. Formation of a strong shear layer at the boundary of mixed upper layer and dense lower layer is observed within the body and the tail of the current. Over the tail of the current far enough from the inlet, the vertical velocity and density profiles are compared to the ones from an experimental study. Distance from the bed to the point of maximum velocity increases with an increase in inflow discharge, while it remains practically unchanged with increasing initial fractional excess density in the simulations. Even though the velocity profiles are in good agreement, some discrepancies are observed in fractional excess density profiles among experimental and numerical results. Possible reasons for these discrepancies are discussed. Generally, gravity current type of flows could be expressed in layer-integrated formulation of governing equations. However, layer integration introduces several constants, commonly known as shape factors, to the equations of motion. The values of these shape factors are calculated based on simulation results and compared to the values from experiments and to the favorably used ‘top hat’ assumption.     

Port safety and the container revolution: A statistical study on human factor and occupational accidents over the long period

Several factors can affect occupational accident frequency, namely economical factors, technologies used (low automation, discontinuous operating) job design, organization of work/environmental conditions and human factors. In particular, technological advances in industrial activities can give rise to improvement in productivity and in occupational health and safety, but not necessarily simultaneously. The beginning of the container transport dates back to 50 years ago, but while containerization changed everything, from ships and ports to patterns of global trade, its impact on work injuries was not explored at all. The aim of this paper is to investigate the relationship between work organization, job experience, productivity and occupational accidents, from the starting of the container expansion to nowadays, considering Genoa port (Italy), one of the largest of the Mediterranean Sea. In order to minimize possible reporting biases, such as underreporting or reclassification to a lower level of severity, injury statistics are elaborated starting from data collected directly on-site, from internal accident or medical-aid reports. An in-depth statistical analysis on occupational injuries in the years 1980–2006 is carried out, with reference to frequency indexes, mechanism of injury and material causes. The increase of container-ships traffic and, consequently, the sharp change in port infrastructure involved a rapid modification also in the work organization, with particular reference to the number and characteristics of workforce (decrease from 5783 to nearly 1000 employees and increase of low experience workers from 28% to 74%). The striking high percentage increase of young or low experienced workers in handling container (and performing correlated new tasks) caused a remarkable increase of the risk for occupational injuries. In the studied port, we recorded an increase of the frequency index (injuries per hundred thousand hours worked) from 13.0 to 29.7. It results that the increased expansion of shipping container utilization is not connected to a correspondent human factor safety implementation. Main risk factors are pointed out, revealing an increase of accidents due to transport vehicle (+8.3%) and a reduction of accidents caused by substance or materials (?4.5%). These factors show a statistical significant correlation with the new job tasks. Consideration of these findings may enable managerial solutions and workplace organization interventions for the prevention of injuries and safety performance improvement in port activities.     

Toxicity of new pyrethroid in pest insects Asciamonuste and Diaphania hyalinata,predator Solenopsis saevissima and stingless bee Tetragonisca angustula

There is increasing demand for new products for vegetable pest management. Thus, the aim of this study was to assess the toxicity of pyrethroids with acid moiety modifications to measure the insecticidal activity of these compounds on the lepidopteran vegetable pests Diaphania hyalinata (L.) (Lepidoptera: Pyralidae) and Asciamonuste (Latreille) (Lepidoptera: Pieridae) and evaluate their selectivity for the predatory ant Solenopsis saevissima (F. Smith) (Hymenoptera: Formicidae) and pollinator Tetragonisca angustula (Latreille) (Hymenoptera: Apidae: Meliponinae). Racemic mixtures of five new pyrethroids (30 µg molecule mg^?1 insect body weight) resulted in high (100%) and rapid (stable LD₅₀ after 12 h) mortality in D. hyalinata and A. monuste. In A. monuste, the trans-pyrethroid [12] isomer showed similar toxicity to permethrin. For D. hyalinata, the trans-pyrethroid [9] isomer and cis-pyrethroid [10] isomer were as toxic as permethrin. Due to their low selectivity, these new pyrethroids should be applied on the basis of ecological selectivity principles to minimize impacts on nontarget organisms S. saevissima and T. angustula.