Effect of chemical amendments on remediation of potentially toxic trace elements (PTEs) and soil quality improvement in paddy fields

Remediation of potentially toxic trace elements (PTEs) in paddy fields is fundamental for crop safety. In situ application of chemical amendments has been widely adapted because of its cost-effectiveness and environmental safety. The main purpose of this research was to (1) evaluate the reduction in dissolved concentrations of cadmium (Cd) and arsenic (As) with the application of chemical amendments and (2) monitor microbial activity in the soil to determine the remediation efficiency. Three different chemical amendments, lime stone, steel slag, and acid mine drainage sludge, were applied to paddy fields, and rice (Oryza sativa L. Milyang 23) was cultivated. The application of chemical amendments immobilized both Cd and As in soil. Between the two PTEs, As reduction was significant (p < 0.05) with the addition of chemical amendments, whereas no significant reduction was observed for Cd than that for the control. Among six soil-related variables, PTE concentration showed a negative correlation with soil pH (r = ?0.70 for As and r = ?0.54 for Cd) and soil respiration (SR) (r = ?0.88 for As and r = ?0.45 for Cd). This result indicated that immobilization of PTEs in soil is dependent on soil pH and reduces PTE toxicity. Overall, the application of chemical amendments could be utilized for decreasing PTE (As and Cd) bioavailability and increasing microbial activity in the soil.     

Use of surrogate species to cost-effectively prioritize conservation actions

Conservation efforts often focus on umbrella species whose distributions overlap with many other flora and fauna. However, because biodiversity is affected by different threats that are spatially variable, focusing only on the geographic range overlap of species may not be sufficient in allocating the necessary actions needed to efficiently abate threats. We developed a problem-based method for prioritizing conservation actions for umbrella species that maximizes the total number of flora and fauna benefiting from management while considering threats, actions, and costs. We tested our new method by assessing the performance of the Australian federal government's umbrella prioritization list, which identifies 73 umbrella species as priorities for conservation attention. Our results show that the federal government priority list benefits only 6% of all Australia's threatened terrestrial species. This could be increased to benefit nearly half (or 46%) of all threatened terrestrial species for the same budget of AU$550 million/year if more suitable umbrella species were chosen. This results in a 7-fold increase in management efficiency. We believe nations around the world can markedly improve the selection of prioritized umbrella species for conservation action with this transparent, quantitative, and objective prioritization approach.     

Linking desorption kinetics to phenanthrene biodegradation in soil

The desorption of polycyclic aromatic hydrocarbons (PAHs) often exhibits a biphasic profile similar to that observed for biodegradation whereby an initial rapid phase of degradation or desorption is followed by a phase of much slower transformation or release. Most investigations to-date have utilised a polymeric sorbent, such as Tenax, to characterise desorption, which is methodologically unsuitable for the analysis of soil. In this study, desorption kinetics of ¹⁴C-phenanthrene were measured by consecutive extraction using aqueous solutions of hydroxypropyl-β-cyclodextrin (HPCD). The data indicate that the fraction extracted after 24 h generally approximated the linearly sorbed, rapidly desorbing fraction (F_rap), calculated using a three-compartment model. A good linear correlation between phenanthrene mineralised and F_rap was observed (r² = 0.89; gradient = 0.85; intercept = 8.20). Hence HPCD extraction (24 h) and first-order three-compartment modelling appear to provide an operationally straightforward tool for estimating mass-transfer limited biodegradation in soil.     

Applying online fleet driver assessment to help identify,target and reduce occupational road safety risks

Many studies have shown that driver attitude and behaviour are important determinants of the likelihood of collision involvement. Knowledge of the Rules of the Road and the perception of hazards are also associated with collision involvement. The aim of this paper is to review the practical application of an online fleet driver assessment program to help identify, target and reduce occupational road safety risks. A large and unique data set collected from online assessment of drivers employed in a UK telecommunications organisation is analyzed. Data was also collected on driver demographics and their driving and collision history. Analysis of the data revealed that attitude, behaviour, knowledge and hazard perception are highly correlated with self-reported collisions. The influence of these variables on collision involvement was assessed using a Poisson regression model. Both attitude and behaviour scores exhibit a statistically significant association with collision involvement, along with other variables such as mileage driven, driver age and personality. The findings lend support to the need to create a safety culture in which driver assessment and improvement is the norm, as well as reducing exposure to risk wherever possible through better ways of working and travelling.     

Dechlorination comparison of mono-substituted PCBs with Mg/Pd in different solvent systems

It is widely recognized that polychlorinated biphenyls (PCBs) are a dangerous environmental pollutant. Even though the use and production of PCBs have been restricted, heavy industrial use has made them a wide-spread environmental issue today. Dehalogenation using zero-valent metals has been a promising avenue of research for the remediation of chlorinated compounds and other contaminants that are present in the environment. However, zero-valent metals by themselves have shown little capability of dechlorinating polychlorinated biphenyls (PCBs). Mechanically alloying the metal with a catalyst, such as palladium, creates a bimetallic system capable of dechlorinating PCBs very rapidly to biphenyl. This study primarily aims to evaluate the effects of solvent specificity on the kinetics of mono-substituted PCBs, in an attempt to determine the mechanism of degradation. Rate constants and final byproducts were determined for the contaminant systems in both water and methanol, and significant differences in the relative rates of reaction were observed between the two solvents.     

Fate and behaviour of phenanthrene in the natural and artificial soils

For the assessment of contaminated soils ecotoxicological tests are used to estimate the bioavailability of contaminants in soil samples. Terrestrial tests reveal the habitat function of soils, and parameters applied in tests involving microorganisms include respiration activity and potential ammonium oxidation. For such tests, the threshold values needed to assess the results have already been established in guidelines ISO 17155 and ISO 15685. In this paper, we discuss about the respiration activity and potential ammonium oxidation results obtained from a wide variety of soils with different physico-chemical properties and levels of contamination. These results show that microbial respiration and potential ammonium oxidation have different sensitivities to various classes of contaminants. We demonstrated that both organic and inorganic contaminants influence potential ammonium oxidation, whereas microbial respiration is predominantly affected by biodegradable organic contaminants. These differences might be useful for more detailed assessments of soil contamination, leading to different recommended actions depending on which parameter is affected.     

Stratospheric Ozone Protection: An EPA Engineering Perspective

Chlorine released into the atmosphere is a major factor in the depletion of the protective stratospheric ozone layer. The Montreal Protocol, as amended in 1990, and the Clean Air Act Amendments of 1990, address the limits and reduction schedules to be placed on chlorine- and bromine-containing chemicals. The status of technical solutions to the problem of chlorofluorocarbons, halons, methyl chloroform, and carbon tetrachloride in the major use areas of refrigeration, foam, aerosols, fire protection, and solvents is discussed here. The discussion includes the cooperative efforts involving academia, industry, U.S. governmental organizations, and other nations who are contributing solutions to these problems.     

Global environmental change: the contribution of social science research to policy in the UK

Research into global environmental change in the United Kingdom, has sought to influence public policy. It has also served to refashion the social sciences themselves, forcing them to consider sustainability as a dimension of all social and economic behaviour. This paper describes the way in which the principle of enhanced sustainability might become a point of reference in social science research. It discusses, some of the lessons that have been learned from the Global Environmental Change Programme and then considers the relationship between this work and research on the environment undertaken within the natural sciences.This paper was presented as a keynote delivery at the Global Forum '94 Conference Towards a sustainable Future: Promoting Sustainable Development, Manchester, UK.     

Combined effects of temperature and salinity on embryos and larvae of the northern bay scallop Argopecten irradians irradians

The combined effects of temperature and salinity on embryonic development and on larval survival and growth to setting size of the northerm bay scallop Argopecten irradians irradians (Lamarck) were studied in the laboratory. A 6x6 complete factorial design was used; temperatures ranged from 10° to 35°C, at 5C° intervals, and salinities ranged from 10 to 35S, at 5S intervals. Response-surface contour diagrams were generated to provide estimates of conditions for optimal responses. Normal development of embryos occurred over a very narrow range of temperature and salinity. Survival of larvae occurred over a wider range of temperature and salinity than did embryonic development or growth of larvae. Satisfactory growth (>70% of the maximum observed value) occurred only at high temperature-high salinity conditions; optimal conditions for survival occurred at similar salinities, but at slightly lower temperatures. Temperatures of 35°C or greater and/or salinities of 10S or less were lethal for all life stages studied. Both salinity and temperature exerted significant effects on development and survival, but temperature was clearly the dominant factor influencing growth. It is suggested that northern bay scallop embryos and larvae be reared at their respective optimal temperature-salinity levels so as to increase efficiency of aquaculture operations.This paper is adapted from a thesis submitted to the College of Fisheries, University of Washington, in partial fulfillment of the requirements for the MS degree. This study was conducted at the NMFS Laboratory in Milford, Connecticut, USA     

瑞典水文变化-气候变化影响模拟

温室效应加剧导致的气候变化将会引起水文系统的变化.随着气候要素的变化,水文变化将会在全球呈现出区域差异性.因此,有必要开展局地和区域尺度上的水文变化影响研究,评价不同区域将会受到怎样的影响.本研究旨在对广泛的瑞典流域上气候变化的水文影响(响应)进行评估.我们采用不同的方法,将气候模型中产生的气候变化信号转换输入到水文模型中.利用瑞典区域气候模拟计划(SWECLIM)生成的区域气候情景,我们进行了几次水文模型模拟研究.得出的基本结论是根据流域的地理位置处于瑞典北部或南部,气候变化对河道水流的分区影响是显著不同的.此外,预测的水文变化不仅与用于确定区域气候模型边界条件的全球气候模型的选择有关,而且与人为气体排放情景的选取有关.