The effects of alginate microspheres on phytoremediation and growth of Lemna minor in the presence of Cd

Today, the removal of increased amount of contaminant concentrations in nature such as metals, nanoparticles, has become an essential issue to struggle with. In this paper, both the toxic effects of non-essential Cd on Lemna minor in presence of alginate microspheres and metal removal capacity of Cd-exposed L. minor and microspheres were investigated. Three test groups were constructed: group (L) containing Lemna, group (M) containing alginate microsphere and group (L?+?M) containing alginate microsphere and Lemna. Five different levels of Cd concentrations were added into these groups. Estimation models were constructed to estimate Cd removal capacities of L. minor and microspheres, and time-concentration-dependent growth (GRC) rates of both microsphere-containing and non-containing groups were modelled by regression analysis. It was seen that microspheres alone only had no positive or negative effects on Lemna growth. It was observed that, for all test groups the time-dependent growth rate has both increase–decrease trends in general. The toxicity effect of Cd on Lemna growth was reduced by adding microspheres into medium. Furthermore, the results stated that test groups containing only microspheres (M, 0–97.56%) and consortium groups (M?+?L, 0–98.26%) were slightly more successful in Cd removal process compared to Lemna (L) groups (L, 0–97.32%).     

Advanced oxidation treatment of physico-chemically pre-treated olive mill industry effluent

In this study, the applicability of physico-chemical methods was investigated for the pre-treatment of the olive mill effluents prior to the discharge into the common sewerage ending with a municipal wastewater treatment plant. The samples were taken from an olive oil industry operated as three-phase process located in Turkey. Various pre-treatment methods including acid craking, polyelectrolyte and lime additions were applied. Advanced oxidation study using Fenton's process was also investigated following pre-treatment by acid cracking and cationic polyelectrolyte. Acid cracking alone gave satisfactory treatment efficiencies and polyelectrolite additions to the acid-cracked samples enhanced treatment efficiency. Since a complete treatment plant is available at the end of the sewer system, results indicated that the effluents of the investigated industry could be discharged into the municipal sewerage in the case of total chemical oxygen demand (COD_tot), suspended solid (SS) and volatile suspended solid (VSS) concentrations according to the Turkish Water Pollution Control Regulation after pre-treatment with 5 ppm anionic polyelectrolyte following acid cracking. The minimum COD_tot, SS and VSS removals were observed when raw wastewater was pre-treated with lime and the discharge standards to the municipal sewer system could not be met. Advanced oxidation with Fenton's process was applied after acid cracking and cationic polyelectrolyte treatment in order to investigate further reduction in chemical oxygen demand (COD) concentration for minimizing the influence of this industrial discharge on the existing municipal wastewater treatment plant. Results indicated that COD_tot removal increased up to 89% from 74% after Fenton's oxidation for the acid cracked samples in which cationic polyelectrolite (10 ppm) was added.     

Effect of a heavy metal model mixture on biological parameters of rainbow trout <Emphasis Type="Italic">oncorhynchus mykiss</Emphasis>

The effects of a model mixture (HMMM) of seven heavy metals (Cu, Zn, Ni, Cr, Pb, Cd, Mn) on the rainbow trout Oncorhynchus mykiss at all stages of development (embryos, larvae, adults) were investigated based on the annual average concentrations of these metals in cooling waste waters discharging from Ignalina Nuclear Power Plant (Lithuania) into the Drūk?iai lake. According to mortality parameters, the most sensitive to HMMM were larvae, although no significant differences between the sensitivity of embryos and adult fish to HMMM were found. Maximal toxic effect of HMMM was observed during the hatching period. Long-term exposure to sublethal concentrations of HMMM affected embryo development, growth of larvae, their cardio-respiratory and behavioural responses, induced significant changes in morphological, morpho-physiological, physiological and haematological parameters of adult fish. Respiratory responses and growth parameters of fish were found to be the most sensitive to low concentrations of HMMM. Adult fish were capable of detecting and avoiding low, sublethal concentrations of HMMM. Heavy metals in a mixture at low concentrations were more toxic than single ones. According to the background of the damages induced by HMMM, after-effects in a fish organism, as well as in a whole population, can be predicted.     

Photochemical degradation and mineralization of 4-chlorophenol

INTENTION, GOAL, SCOPE, BACKGROUND: Since the intermediate products of some compounds can be more toxic and/or refractory than the original compund itself, the development of innovative oxidation technologies which are capable of transforming such compounds into harmless end products, is gaining more importance every day. Advanced oxidation processes are one of these technologies. However, it is necessary to optimize the reaction conditions for these technologies in order to be cost-effective. OBJECTIVE: The main objectives of this study were to see if complete mineralization of 4-chlorophenol with AOPs was possible using low pressure mercury vapour lamps, to make a comparison of different AOPs, to observe the effect of the existence of other ions on degradation efficiency and to optimize reaction conditions. METHODS: In this study, photochemical advanced oxidation processes (AOPs) utilizing the combinations of UV, UV/H2O2 and UV/H2O2/Fe2+ (photo-Fenton process) were investigated in labscale experiments for the degradation and mineralization of 4-chlorophenol. Evaluations were based on the reduction of 4-chlorophenol and total organic carbon. The major parameters investigated were the initial 4-chlorophenol concentration, pH, hydrogen peroxide and iron doses and the effect of the presence of radical scavengers. RESULTS AND DISCUSSION: It was observed that the 4-chlorophenol degradation efficiency decreased with increasing concentration and was independent of the initial solution pH in the UV process. 4-chlorophenol oxidation efficiency for an initial concentration of 100 mgl(-1) was around 89% after 300 min of irradiation in the UV process and no mineralization was achieved. The efficiency increased to > 99% with the UV/H2O2 process in 60 min of irradiation, although mineralization efficiency was still around 75% after 300 min of reaction time. Although the H2O2/4-CP molar ratio was kept constant, increasing initial 4-chlorophenol concentration decreased the treatment efficiency. It was observed that basic pHs were favourable in the UV/H2O2 process. The results showed that the photo-Fenton process was the most effective treatment process under acidic conditions. Complete disappearance of 100 mgl(-1) of 4-chlorophenol was achieved in 2.5 min and almost complete mineralization (96%) was also possible after only 45 min of irradiation. The efficiency was negatively affected from H2O2 in the UV/H2O2 process and Fe2+ in the photo-Fenton process over a certain concentration. The highest negative effect was observed with solutions containing PO4 triple ions. Required reaction times for complete disappearance of 100 mgl(-1) 4-chlorophenol increased from 2.5 min for an ion-free solution to 30 min for solutions containing 100 mgl(-1) PO4 triple ion and from 45 min to more than 240 min for complete mineralization. The photodegradation of 4-chlorophenol was found to follow the first-order law. CONCLUSION: The results of this study showed that UV irradiation alone can degrade 4-CP, although at very slow rates, but cannot mineralize the compound. The addition of hydrogen peroxide to the system, the so-called UV/H2O2 process, significantly enhances the 4-CP degradation rate, but still requires relatively long reaction periods for complete mineralization. The photo-Fenton process, the combination of homogeneous systems of UV/H2O2/Fe2+ compounds, produces the highest photochemical elimination rate of 4-CP and complete mineralization is possible to achieve in quite shorter reaction periods when compared with the UV/H2O2 process. RECOMMENDATIONS AND OUTLOOK: It is more cost effective to use these processes for only purposes such as toxicity reduction, enhancement of biodegradability, decolorization and micropollutant removal. However the most important point is the optimization of the reaction conditions for the process of concern. In such a case, AOPs can be used in combination with a biological treatment systems as a pre- or post treatment unit providing the cheapest treatment option. The AOP applied, for instance, can be used for toxicity reduction and the biological unit for chemical oxygen demand (COD) removal.     

A fair comparison between the spatial scan and the Besag–Newell Disease clustering tests

Routine surveillance of a large geographic region for clusters of adverse health events, particularly cancers, often involves small area health data, possibly controlling for exposure information. Many different methods have been proposed to test for the presence of geographical clusters. Two of the most popular methods are the spatial scan method proposed by Kulldorff and that using a fixed number of cases within scanning circles proposed by Besag and Newell. Although the second test is very popular, it has some difficulties. While the scan test controls for the multiple testing problem, the Besag and Newell test does not. Additionally, the latter method requires the setting of several tuning parameters whose values affect the test performance and are subjectively chosen by the user. This creates a difficulty to make a fair comparison between the two methods and it explains why there have been few formal studies evaluating their relative performances. In this paper, we modify the Besag and Newell test allowing for the control of the error type I probability and compare its power with respect to that of the spatial scan test. We used data sets from a publicly available simulated benchmark. We found that the two methods have similar results, except for clusters located in sparsely populated regions, where the spatial scan method presented a better performance.     

A baseline study characterizing the municipal solid waste in the State of Kuwait

This paper provides a new reference line for municipal solid waste characterization in Kuwait. The baseline data were collected in accordance with the Standard Test Method for the Determination of the Composition of Unprocessed Municipal Solid Waste (ASTM). The results indicated that the average daily municipal waste generation level is 1.01 kg/person. Detailed waste stream surveys were conducted for more than 600 samples of municipal solid waste (MSW). The waste categories included paper, corrugated fibers, PET bottles, film, organic matter, wood, metal, glass, and others. The results indicated that organic waste dominated the characterization (44.4%), followed by film (11.2%) and then corrugated fibers (8.6%). Analysis of variance (ANOVA) was used to investigate the influence of season and governorate on waste composition. A significant seasonal variation was observed in almost all waste categories. In addition, significant differences in proportions between the current level and 1995 baseline were observed in most waste categories at the 95% confidence level.     

Landscape scale ecological monitoring as part of an EIA of major construction activities: experience at the Turkish section of the BTC crude oil pipeline project

Ecological monitoring is a complementary component of the overall environmental management and monitoring program of any Environmental Impact Assessment (EIA) report. The monitoring method should be developed for each project phase and allow for periodic reporting and assessment of compliance with the environmental conditions and requirements of the EIA. Also, this method should incorporate a variance request program since site-specific conditions can affect construction on a daily basis and require time-critical application of alternative construction scenarios or environmental management methods integrated with alternative mitigation measures. Finally, taking full advantage of the latest information and communication technologies can enhance the quality of, and public involvement in, the environmental management program. In this paper, a landscape-scale ecological monitoring method for major construction projects is described using, as a basis, 20 months of experience on the Baku-Tbilisi-Ceyhan (BTC) Crude Oil Pipeline Project, covering Turkish Sections Lot B and Lot C. This analysis presents suggestions for improving ecological monitoring for major construction activities.     

Afforestation areas defined by GIS in Gölbaşı specially protected area Ankara/Turkey

This paper concentrates on determining the areas for afforestation and the development of conservation strategies and actions in the case where there is high demand for the conservation of a particular land area. The analysis of hydrological landscape structure and of erodibility was prerequisite in the methodological design considering the site-specific natural landscape characteristics of the study area. The Gölba?? Specially Protected Area (SPA) being the case area has many local environmental disturbances, especially with respect to its hydrological system, and the area is beset by increasing demands for its use by the burgeoning human population. It is obviously clear that the present intensive demand for recreational use will be forecasted further increase in the future. The count of rural residences is estimated to increase by 50% over the next decade. This intensive demand shall further strain the carrying capacity of the ecological milieu, which has already suffered to a significant degree because of the present urban and rural activities. The Gölba?? district is located only 20 km from the city center of Ankara, and its surroundings were legally designated to be a Specially Protected Area primarily for the existence of lacustral and fluvial systems where two interconnected lakes exist: Mogan and E?mir Lakes. Essentially, the continuity of the lacustral and fluvial system of Lakes Mogan and E?mir depends on the preservation and improvement of the water sources. However, interconnected surface water bodies of these lakes are actually quite contaminated, and a decline in the water flow from Mogan to E?mir has been observed. For the elaboration of the present method, required conventional maps (at 1/25,000 scale) of topography (for slope analysis) and geology (for erodibility and permeability analysis) were transferred to computer media using AutoCAD® R.14 software. The rectification of the transferred data was done using ERDAS® Imagine 8.3. All data were then transferred into a GIS engine (Arcview® 3.2). This software provided the ability to create, manipulate, analyze and display topologically correct geographic data in digital form. The method proceeded according to the following phases: 1. Analysis of the hydrologic landscape structure; 2. Permeability of the soil structure; 3. Permeability of the geological structure; 4. Conservation zones.     

Speciative determination of Cr (III) and Cr (VI) in dyeing waste water of Dil Creek discharge to Izmit Gulf (Izmit-Kocaeli, Turkey) by ICP-AES

Wastewater pollution in industrial areas is one of the most important environmental problems. Heavy metal pollution, especially chromium pollution in wastewater sources from dyeing and tannery has affected the life on earth. This pollution can affect all ecosystems and human health directly or by food chain. Therefore, the determination of chromium in this study is of great importance. Dil Creek is located in the eastern Marmara region and discharges into the Izmit Gulf. This water source is used for irrigation in agriculture and as drinking water for animals. In this study, a rapid, sensitive and selective method for the speciative direct determination of Cr (III) and Cr (VI) in dyeing waste water samples collected from the nearest station to Izmit Gulf of Dil Creek in May 2006 by inductively coupled plasma-atomic emission spectrometry (ICP-AES) has been developed. An analysis of a given sample is completed in about 15 min for ICP-AES the method. As the result of the chromium analysis, the limit of quantification (LOQ) for the Cr (III), Cr (VI) and total Cr were founded as 0.0111 ± 0.0002 mg/l (RSD, 1.80%), 0.0592 ± 0.0010 mg/l (RSD, 1.70%) and 0.0703 ± 0.0020 mg/l (RSD, 2.84%) respectively. In addition, the general mathematical formula has been developed to calculate the concentration of Cr(III), which can be applied to any other metal species. The result of Cr (VI) analysis indicated that water quality of Creek was IV. class quality according to the inland water classification. In order to validate the applied method, recovery studies were performed.     

Determining the level and cost of sickness presenteeism among hospital staff in Turkey

Objective. This study aimed to determine the associations between sickness presenteeism and socio-demographic factors, perceived health status and health complaints among hospital staff and to calculate the cost burdens and productivity losses attributed to presenteeism. Methods. A cross-sectional study was conducted using 951 hospital staff, including physicians, nurses, midwives, other health personnel and administrative staff working in two hospitals located in K?r?kkale province in Turkey. The health and work performance questionnaire developed by Kessler et al. was revised to measure sickness presenteeism. Results. After performing Student’s t test and a one-way analysis of variance, presenteeism was mostly observed in women, nurse-midwives, young employees, university health staff and health workers with low health status. Average productivity loss and cost of lost productivity per staff member were calculated as 19.92?h/TRY 315.57 for 2 weeks and 478.08?h/TRY 7573.68 for 1 year. Conclusions. The problem of sickness presenteeism is mostly observed in women and nurses. It causes both financial burdens and productivity losses for hospitals. These survey results are thus expected to provide critically important information on presenteeism for decision-makers and healthcare managers.