Environmental and health consequences of depleted uranium use in the 1991 Gulf War

Depleted uranium (DU) is a by-product of the 235U radionuclide enrichment processes for nuclear reactors or nuclear weapons. DU in the metallic form has high density and hardness as well as pyrophoric properties, which makes it superior to the classical tungsten armour-piercing munitions. Military use of DU has been recently a subject of considerable concern, not only to radioecologists but also public opinion in terms of possible health hazards arising from its radioactivity and chemical toxicity. In this review, the results of uranium content measurements in different environmental samples performed by authors in Kuwait after Gulf War are presented with discussion concerning possible environmental and health effects for the local population. It was found that uranium concentration in the surface soil samples ranged from 0.3 to 2.5 microg g(-1) with an average value of 1.1 microg g(-1), much lower than world average value of 2.8 microg g(-1). The solid fallout samples showed similar concentrations varied from 0.3 to 1.7 microg g(-1) (average 1.47 microg g(-1)). Only the average concentration of U in solid particulate matter in surface air equal to 0.24 ng g(-1) was higher than the usually observed values of approximately 0.1 ng g(-1) but it was caused by the high dust concentration in the air in that region. Calculated on the basis of these measurements, the exposure to uranium for the Kuwait and southern Iraq population does not differ from the world average estimation. Therefore, the widely spread information in newspapers and Internet (see for example: [CADU NEWS, 2003. http://www.cadu.org.uk/news/index.htm (3-13)]) concerning dramatic health deterioration for Iraqi citizens should not be linked directly with their exposure to DU after the Gulf War.     

Roadless and Low-Traffic Areas as Conservation Targets in Europe

With increasing road encroachment, habitat fragmentation by transport infrastructures has been a serious threat for European biodiversity. Areas with no roads or little traffic (“roadless and low-traffic areas”) represent relatively undisturbed natural habitats and functioning ecosystems. They provide many benefits for biodiversity and human societies (e.g., landscape connectivity, barrier against pests and invasions, ecosystem services). Roadless and low-traffic areas, with a lower level of anthropogenic disturbances, are of special relevance in Europe because of their rarity and, in the context of climate change, because of their contribution to higher resilience and buffering capacity within landscape ecosystems. An analysis of European legal instruments illustrates that, although most laws aimed at protecting targets which are inherent to fragmentation, like connectivity, ecosystem processes or integrity, roadless areas are widely neglected as a legal target. A case study in Germany underlines this finding. Although the Natura 2000 network covers a significant proportion of the country (16%), Natura 2000 sites are highly fragmented and most low-traffic areas (75%) lie unprotected outside this network. This proportion is even higher for the old Federal States (western Germany), where only 20% of the low-traffic areas are protected. We propose that the few remaining roadless and low-traffic areas in Europe should be an important focus of conservation efforts; they should be urgently inventoried, included more explicitly in the law and accounted for in transport and urban planning. Considering them as complementary conservation targets would represent a concrete step towards the strengthening and adaptation of the Natura 2000 network to climate change.     

Policy Cost-effectiveness for Reducing Non-point Agricultural Groundwater Pollution in the UK

A pilot Nitrate Sensitive Areas Scheme was established in 1990 in order to reduce nitrate pollution in heavily polluted areas of the UK through changes in land management. A regression model is derived from field observations which predicts the quantity of nitrate leaching into the groundwater as a function of land use, drainage conditions and fertilizer usage. It is used to explore the cost effectiveness of different land management options for which incentives were provided within the scheme. The most cost effective measures in terms of net exchequer cost per kilogram reduction in nitrogen leached were conversion to grassland with limited restriction on nitrogen fertilization, or conversion to woodland. A basic option involving minor changes to fertilizer practice on arable land was also cost effective but failed to achieve the target nitrate level in groundwater of 50 mg/l. Conversion to grassland with severe restrictions on fertilizer use was less cost effective because higher payments were necessary to encourage uptake by farmers.     

Lead deposited in the cell wall of Funaria hygrometrica protonemata is not stable - A remobilization can occur

The hypothesis that lead (Pb) can be uptake or remobilized from the cell wall (CW) by internalization withlow-esterified pectins (up to 40% - JIM5-P), was studied in tip-growing apical cell of Funaria hygrometrica protonemata. Treatment 4 h with 1 mM PbCl₂ caused marked vesicular traffic intensification and the common internalization of JIM5-P from the CW. Lead bound to JIM5-P was internalized from the CW, together with this compound and entered the protoplast. It showed that Pb deposited in CW is not as safe for plant cell as previously believed.However, pulse-chase experiments (recovering 4 h and 24 h) indicated that CW and its thickenings can function as the final sequestration compartments. In Pb deposition sites, a callose layer occurred. It was localized from the protoplast site, next to Pb deposits separating sequestrated to CW and its thickenings Pb from plasma membrane almost certainly protecting the plant cell from its returning into the protoplast.     

Monitoring of the total content of polycyclic aromatic hydrocarbons (PAHs) in arable soils in Poland

The paper provides comprehensive information on the level of contamination of arable soils in Poland with polycyclic aromatic hydrocarbons (PAHs). Extensive monitoring studies were carried out to determine the content of the 16 priority PAHs in 216 soil samples collected in 2005 throughout arable lands (0-20 cm layer) in Poland. Locations of sampling points reflected the differences in regional industrialisation and urbanisation as well as in the characteristics of soils. The content of Sigma16PAHs ranged from 80 to 7264 microg kg(-1) with a median of 395 microg kg(-1) and with a dominance of 4-6 rings hydrocarbons (74% of total PAHs). Soil properties affected the PAHs content to a limited extend. The organic matter content was the only parameter correlated significantly (although weakly) with the concentrations of Sigma16PAHs; the strength of this relationship was more pronounced in soils with elevated OM content. The various molecular markers pointed to a prevailing pyrogenic origin of the PAHs in Polish arable soils, with minor contribution from liquid fuels combustion and traffic emissions. Two different Polish systems for classification of agricultural soils (providing for the content of Sigma9PAHs and Sigma13PAHs) indicate that the percentage of contaminated arable soils in Poland does not exceed 10%. Multivariate methods enabled an evaluation of spatial trends in Sigma16PAHs concentrations, an identification of regions with very low PAHs content (East part of the country), and a recognition of small industrial/urbanised areas of higher risk.     

Comparative studies on the concentrations of some elements in the urban air particulate matter in Lodz City of Poland and in Milan,Italy

Urban air particulate matter (APM) was collected at two sampling sites in the city of Lodz, Poland in March, May and July 2001. The concentrations of several trace elements (TEs) as well as heavy metals were determined by neutron activation analysis (NAA). It was found that for many elements, the contribution of the blank values arising from the filtering material is very high, especially for glass fiber filters. The results obtained for Lodz were compared to those obtained for Milan, Italy. The data of Lodz are, in general, lower than those found in Milan downtown in the winter season. The influence of three coal-fired power plants located within the city of Lodz on the concentration of trace elements in APM was also considered.     

Pseudomorphs of barite and biogenic ZnS after phyto-crystals of calcium oxalate (whewellite) in the peat layer of a poor fen

Pseudomorphs of barite (BaSO₄) and Cd-rich ZnS after whewellite (CaC₂O₄·H₂O) occur within remnants of Scots pine bark tissues in the peat layer of a poor fen located near a zinc smelter in south Poland. A two-step formation of the pseudomorphs is postulated based on SEM observations: (1) complete dissolution of whewellite, possibly caused by oxalotrophic bacteria, and (2) subsequent bacterially induced precipitation of barite and spheroidal aggregates of ZnS together with galena (PbS) in voids left by the dissolved whewellite crystals. Local increase in pH due to microbial degradation of whewellite, elevated concentrations of Zn(II) and Ba(II) in pore water due to the decomposition of atmospheric particles of sphalerite and barite in the acidic (pH 3.5–3.8) environment, oxidation of S species during drying and rewetting of the peat layer, and subsequent partial reduction of sulfate anions by sulfur-reducing bacteria were all factors likely involved in the crystallization of ZnS and barite in the microenvironment of the post-whewellite voids.     

Application of fuzzy logic to explosion risk assessment

Safety and health of workers potentially being at risk from explosive atmospheres are regulated by separate regulations (ANSI/AIHA in USA and ATEX in the European Union). The ANSI/AIHA does not require risk assessment whereas it is compulsory for ATEX. There is no standard method to do that assessment. For that purpose we have applied the explosion Layer of Protection Analysis (ExLOPA), which enables semi-quantitative risk assessment for process plants where explosive atmospheres occur. The ExLOPA is based on the original work of CCPS for LOPA taking into account an explosion accident scenario at workplace. That includes typical variables appropriate for workplace explosion like occurrence of the explosive atmosphere, the presence of effective ignition sources, activity of the explosion prevention and mitigation independent protection layers as well as the severity of consequences. All those variables are expressed in the form of qualitative linguistic categories and relations between them are presented using expert based engineering knowledge, expressed in the form of appropriate set of rules. In this way the category of explosion risk may be estimated by the semi-quantitative analysis. However, this simplified method is connected with essential uncertainties providing over or under estimation of the explosion risk and may not provide real output data.In order to overcome this problem and receive more detailed quantitative results, the fuzzy logic system was applied. In the first stage called fuzzification, all linguistic categories of the variables are mapped by fuzzy sets. In the second stage, the number of relation between all variables of analysis are determined by the enumerative combinatorics and the set of the 810 fuzzy rules “IF-THEN” is received. Each rule enables determination of the fuzzy risk level for a particular accident scenario. In the last stage, called defuzzification, the crisp value of final risk is obtained using a centroid method. The final result of the risk presents a contribution of each risk category represented by the fuzzy sets (A, TA, TNA and NA) and is therefore more precise and readable than the traditional approach producing one category of risk only. Fuzzy logic gives a possibility of better insights into hazards and safety phenomena for each explosion risk scenario. It is not possible to receive such conclusions from the traditional ExLOPA calculation results. However it requires the application of computer-aided analyses which may be partially in conflict with a simplicity of ExLOPA.The practical example provides a comparison between the traditional results obtained by ExLOPA and by fuzzy ExLOPA methods.