A study of the elemental leachability and retention capability of compost

In this work a comparison is made between the different approaches that can be taken to evaluate the mobility of elements in compost. The practical consequences of the results obtained are also discussed in terms of methods for cleaning up compost and using compost in environmental remediation. The mobility of potentially toxic elements in compost is evaluated by leaching with four selected eluents, i.e. diluted sulfuric acid, oxalate, citrate and EDTA. In contrast to the chelating agents, diluted sulfuric acid was found to generally have a low leaching capability for removal of heavy metals from compost. This implies that the risk of heavy metal leaching caused by natural rainfall is likely to be low. The results obtained in the leaching experiment were compared with previous results obtained from sequential fractionation. This comparison confirmed that both methods gave similar results for predicting the lability of elements in compost. A non-linear regression analysis of the leaching curves was also conducted. The leaching curves for elements with high lability could be fitted with a two components model. The labile components identified by the kinetic model are approximately in accordance with the fractions obtained from the first step of the sequential extraction method. The kinetic speciation method is shown to be a relatively rapid and simple procedure for compost which gives more information about element lability than simple leaching experiments. The leaching reagents used in this work were not effective enough to be used for cleaning up compost with a high metal content. Compost was however shown to have a high affinity for heavy metals, with the order of affinity of metal for the compost being very similar to that seen for humic acid. Compost may therefore prove to be a good remediation material for metal contaminated waste.     

碘量法测定水中溶解氧有关问题的探讨及改进

碘量法测定溶解氧时,采用NH3·H2O—KI代替NaOH(KOH)—KI固定溶解氧,用H2SO4—H3PO(41+1)混合酸代替H2SO4溶解沉淀,使沉淀沉降速度加快,分界线明显,沉淀溶解也更完全。同时做样品空白实验,校正了氧化还原性物质产生的干扰,对废水有明显的抗干扰能力。通过对蒸馏水、自来水、池塘水、废水进行溶解氧测定,结果均非常满意。     

HNO_3─KI─MIBK萃取／原子吸收光谱法测定固体废物浸提液中的微量银

采用选择性较好的ＨＮＯ３—ＫＩ—ＭＩＢＫ萃取体系对铋渣和尾矿渣浸出液中的痕量银进行预分离富集后，用火焰原子吸收法（ＡＡＳ）进行测定。此法不仅变异系数小（约为３．１％），而且检出限比直接火焰ＡＡＳ法降低两个数量级，达０．５ｎｇ／ｍｌ．另外，还就作品细度对银测定结果的影响原因做了初步探讨。     

合肥地区重金属污染生物监测的初步研究 --以大蜀山铅镉的白鹭监测为例

将合肥地区大蜀山的白（Egretta garzetta）卵和组织样品，用原子吸收法时样品中的Pb、Cd等重金属污染物进行了检测，结果表明，这2种重金属元素在卵和组织中均有不同程度的检出，其中Cd在卵的内容物中残留量较低。而且这2种重金属污染物在鹭卵不同部分的残留量均有差异；同其他地区类似的研究结果相比，合肥地区鹭卵中重金属残留水平相时较高。     

浅析生态园林城市的建设--以重庆市为例

随着社会、经济的快速发展，城市生态环境问题越来越突出，由此人们提出了建设生态园林城市的构想，即实现了人与自然、人与社会的和谐统一，实现了可持续发展的人类聚居地。山水园林城市与生态城市在本质上是一致的。本文以重庆市为例，从自然、经济、社会三个生态亚系统入手，分析了重庆市生态系统的现状，主要是提出目前面临的问题和矛盾，并在此基础上提出重庆市建设山水园林城市的5条途径。     

植物遗传资源保护与利用的市场化机制和国际制度

随着植物物种资源的不断减少和因生物技术迅猛发展对植物遗传资源需求的不断增加 ,植物遗传资源正逐步由公共物品转变为稀缺物品。坚持《生物多样性公约》所确立的遗传资源效益公平分享原则 ,完善现有国际多边体系 ,促进以“遗传编码功能”价值概念和遗传资源保护效应“内部化”与“补偿”方案为基础的植物遗传资源市场化保护与利用机制的形成 ,建立“植物遗传资源交易所”和“生物多样性合作社” ,将有助于提高世界各国尤其是发展中国家保护植物遗传资源的积极性 ,实现全球植物遗传资源的可持续利用     

稀土酞菁锰对表面活性剂(LAS)的催化氧化性能研究

研究了一种新型含稀土酞菁锰(KCeO2MnPcX)催化剂对水中表面活性剂直链烷基苯磺酸钠(LAS)氧化降解的催化性能,讨论了影响催化氧化反应的各种因素,并确定了最佳反应条件。同时初步探讨了这种催化剂对表面活性剂的催化氧化机理,为处理表面活性剂废水提供了新的途径。     

冶金矿山清洁生产审计

通过对姑山矿生产现状的调查研究，确定审计重点为选矿车间，分析了选矿车间存在的问题，提出了清洁生产方案，对方案实施后的经济效益作了分析。     

金属体积成形过程有限元模拟中六面体网格重划技术的研究

针对金属体积成形过程有限元模拟中的网格重划问题 ,提出了基于边界构形的有限元网格重划技术 ,并对其中的一系列技术处理进行了详尽的讨论。将该技术应用于矩形块体镦粗过程的有限元模拟中 ,较好地解决了六面体网格重划问题。     

重庆三峡库区主要生态环境问题与对策

三峡水电站建成后，制约重庆经济可持续发展的关系是生态环境问题，包括三峡库区的水体污染，水土流失与泥沙问题，灾害性地质环境问题，建议建立三峡库区生态环境委员会，实行在市长领导下的环境保护行政领导责任制依法治库，加强生态环境意识教育，建立生态环境保护基金等。