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41.
Nitrate in groundwater: an isotopic multi-tracer approach 总被引:12,自引:0,他引:12
Widory D Kloppmann W Chery L Bonnin J Rochdi H Guinamant JL 《Journal of contaminant hydrology》2004,72(1-4):165-188
In spite of increasing efforts to reduce nitrogen inputs into groundwater from intensive agriculture, nitrate (NO3) remains one of the major pollutants of drinking-water resources worldwide. Determining the source(s) of NO3 contamination in groundwater is an important first step for improving groundwater quality by emission control, and it is with this aim that we investigated the viability of an isotopic multi-tracer approach (delta15N, delta11B, 87Sr/86Sr), in addition to conventional hydrogeologic analysis, in two small catchments of the Arguenon watershed (Brittany, France). The main anthropogenic sources (fertilizer, sewage effluent, and hog, cattle and poultry manure) were first characterized by their specific B, N and Sr isotope signatures, and compared to those observed in the ground- and surface waters. Chemical and isotopic evidence shows that both denitrification and mixing within the watershed have the effect of buffering NO3 contamination in the groundwater. Coupled delta11B, delta15N and 87Sr/86Sr results indicate that a large part of the NO3 contamination in the Arguenon watershed originates from the spreading of animal manure, with hog manure being a major contributor. Point sources, such as sewage effluents, contribute to the NO3 budget of the two watersheds. 相似文献
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Salps have higher filtration rates than most other holoplankton, and are capable of packaging and exporting primary production
from surface waters. A method of kinematic analysis was employed to accurately measure salp feeding rates. The data were then
used to explain how diverse body morphologies and swimming motions among species and lifecycle stages influence salp feeding
performance. We selected five species, representing a range of morphologies and swimming styles, and used digitized outlines
from video frames to measure body-shape change during a pulse cycle. Time-varying body volume was then calculated from the
digitized salp outlines to estimate the amount of fluid passing through the filtering mesh. This non-invasive method produced
higher feeding rates than other methods and revealed that body volume, pulse frequency and degree of contraction are important
factors for determining volume filtered. Each species possessed a unique combination of these three characteristics that resulted
in comparable filtration (range: 0.44–15.33 ml s−1) and normalized filtration rates (range: 0.21–1.27 s−1) across species. The convergence of different species with diverse morphologies on similar normalized filtration suggests
a tendency towards a flow optimum. 相似文献
45.
Polybrominated diphenyl ethers in domestic indoor dust from Canada, New Zealand, United Kingdom and United States 总被引:8,自引:1,他引:7
Harrad S Ibarra C Diamond M Melymuk L Robson M Douwes J Roosens L Dirtu AC Covaci A 《Environment international》2008,34(2):232-238
Because of the similarities in European and North American dietary exposure, it has been suggested that the order of magnitude higher body burdens in North Americans may be due to international variations in exposure via ingestion of indoor dust. Furthermore, ingestion of indoor dust has been suggested as a possible source of PBDEs in the blood serum of New Zealanders. Hence, polybrominated diphenyl ethers (PBDEs) were measured in domestic indoor dust from: Amarillo/Austin, Texas, US; Birmingham, UK; Toronto, Canada; and Wellington, New Zealand. Concentrations of BDE 209 in two UK samples were - at 520,000 and 100,000 ng g(-1) - the highest ever recorded in a domestic (or office) indoor dust sample. Median concentrations in ng g(-1) were: in Canada 620 and 560 for Sigmatri-hexa-BDEs and BDE 209 respectively; in New Zealand 96, BDE 209 not determined; in the UK 59 and 2,800; and in the US 1600 and 1300. With respect to BDE 209, concentrations were in the order: UK approximately US>Canada. For Sigmatri-hexa-BDEs, the order of concentrations was US approximately Canada>New Zealand approximately UK. Combined with principal component analysis of congener patterns, this suggests that, while North American dusts are contaminated by both Deca- and Penta-BDE commercial formulations, UK dusts are contaminated predominantly by Deca-BDE. The Octa-BDE formulation appears of minimal importance in accordance with available market demand figures. Despite the commercial formulations of PBDEs never having been manufactured in, nor imported into New Zealand, their presence in dusts from that country suggests international trade in PBDE-containing goods is an important pathway effecting their global distribution. 相似文献
46.
Sam Provoost M. Laurence M. Jones Sally E. Edmondson 《Journal of Coastal Conservation》2011,15(1):207-226
In coastal dunes, landscape changes are a rule, rather than an exception. This paper gives an overview of changes in landscape
and vegetation with a focus on the past century. The history of dunes is characterised by phases of sand drift, alternated
with geomorphological stability. The historical development of dune woodland during these stable phases has been documented
for sites all over Europe. Vegetation reconstructions of historical open dune habitats however is very difficult due to limited
preservation of fossil remains. People have drastically altered coastal dune landscapes through centuries of exploitation
and more recently development of the coast. Historical land use has generally pushed vegetation back into a semi-natural state.
During roughly the past century a tendency of increasing fixation and succession is observed on coastal dunes throughout northwest
Europe. Six causes of change are discussed. 1) Changes in land use, mainly abandonment of agricultural practices, have led
to the development of late successional stages such as scrub and woodland. 2) Crashing rabbit populations due to myxomatosis
in the 1950s caused vigorous grass growth and probably stimulated scrub development. 3) A general tendency of landscape fixation
is observed due to both natural and anthropogenic factors. 4) Eutrophication, mainly due to atmospheric nitrogen deposition
is clearly linked to grass encroachment on acidic but also on some calcareous dunes. 5) The impact of climate change on vegetation
is still unclear but probably lengthening of growing season and maybe enhanced CO2 concentrations have led to an acceleration of succession. 6) A general anthropogenisation of the landscape occurs with rapid
spread of non-native species as an important consequence. The reconstruction of a natural reference landscape is considered
largely unattainable because of irreversible changes and the long tradition of human impact, in many cases since the development
of the dunes. Two contradictory elements need reconciliation. First, the general acceleration of succession and scrub and
woodland development in particular is partly caused by a decreased anthropogenic interference in the landscape and deserves
more appreciation. Second, most biodiversity values are largely linked to open, early succession dune habitats and are threatened
by the same tendency. Apart from internal nature management, in which grazing plays an important part, re-mobilisation of
stable, senescent dunes is an important challenge for dune management. 相似文献
47.
Helmi K Skraber S Burnet JB Leblanc L Hoffmann L Cauchie HM 《Environmental monitoring and assessment》2011,179(1-4):163-175
Starting in 2006, a monitoring of Giardia lamblia and Cryptosporidium parvum occurrence was conducted for 2 years in the largest drinking water reservoir of Luxembourg (Esch-sur-S?re reservoir) using microscopy and qPCR techniques. Parasite analyses were performed on water samples collected from three sites: site A located at the inlet of the reservoir, site B located 18 km downstream site A, at the inlet of the drinking water treatment plant near the dam of the reservoir and site C where the finished drinking water is injected in the distribution network. Results show that both parasites are present in the reservoir throughout the year with a higher occurrence of G. lamblia cysts compared to C. parvum oocysts. According to our results, only 25% of the samples positive by microscopy were confirmed by qPCR. (Oo)cyst concentrations were 10 to 100 times higher at site A compared to site B and they were positively correlated to the water turbidity and negatively correlated to the temperature. Highest (oo)cyst concentrations were observed in winter. In contrast, no relationship between the concentrations of (oo)cysts in the reservoir and rain events could be established. Though a correlation has been observed between both parasites and faecal indicators in the reservoir, some discrepancies highlight that the latter do not represent a reliable tool to predict the presence/absence of these pathogenic protozoa. In summer 2007, the maximal risk of parasite infection per exposure event for swimmers in the reservoir was estimated to be 0.0015% for C. parvum and 0.56% for G. lamblia. Finally, no (oo)cysts could be detected in large volumes of finished drinking water. 相似文献
48.
Rubenstein LZ Vivrette R Harker JO Stevens JA Kramer BJ 《Journal of Safety Research》2011,42(6):493-499
Background
Falls are a common, serious, and often unrecognized problem facing older adults. The objective of this study was to provide an initial clinical and statistical validation for a public health strategy of fall risk self-assessment by older adults using a Fall Risk Questionnaire (FRQ).Methods
Adults age 65 + (n = 40) were recruited at a Los Angeles Veterans Affairs (VA) medical facility and at a local assisted living facility. Participants completed the FRQ self-assessment and results were compared to a “gold standard” of a clinical evaluation of risks using the American/British Geriatrics Society guidelines to assess independent predictors of falls: history of previous falls, fear of falling, gait/balance, muscle weakness, incontinence, sensation and proprioception, depression, vision, and medications. For the comparison, we used an iterative statistical approach, weighing items based on relative risk.Results
There was strong agreement between the FRQ and clinical evaluation (kappa = .875, p < .0001). Individual item kappa values ranged from .305-.832. After dropping one FRQ item (vision risk) because of inadequate agreement with the clinical evaluation (kappa = .139, p = .321), the final FRQ had good concurrent validity.Conclusions
The FRQ goes beyond existing screening tools in that it is based on both evidence and clinical acceptability and has been initially validated with clinical examination data. A larger validation with longitudinal follow-up should determine the actual strength of the FRQ in predicting future falls. 相似文献49.
50.
The value of quantitative and qualitative methods of cholinesterase (ChE) analysis in the detection of open neural tube defect (NTD) has been assessed in a prospective survey of 1495 mid-trimester amniotic fluids. Using a quantitative method the mean ChE values were much lower in fluids from pregnancies of normal outcome but it was not possible to discriminate these fluids completely from those associated with NTD pregnancies. particularly when the specimens were contaminated with blood. Similarly, measurement of acetylcholinesterase (AChE) activity alone by three different methods also failed to eliminate the overlap between the two groups. In contrast, polyacrylamide gel electrophoresis revealed only a single band of ChE activity in 1408 out of 1410 fluids from pregnancies with a normal outcome whilst amniotic fluids from all 60 cases of open NTD. 6 out of 7 cases of exomphalos and 3 out of 4 cases of intra-uterine death gave the characteristic second faster-running AChE band. A qualitative gel method which requires the same amount of ChE activity to be loaded from each amniotic fluid is an effective method for pre-natal diagnosis of NTDs. 相似文献