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51.
52.
Grace Pokoo-Aikins Aubrey Heath Ray A. Mentzer M. Sam Mannan William J. Rogers Mahmoud M. El-Halwagi 《Journal of Loss Prevention in the Process Industries》2010,23(3):412-420
The search for cheaper feedstock for use in the production of biofuels such as biodiesel has turned attention to various forms of waste products including animal fats, waste oils and now lipids in sludge. With the potential of obtaining sludge at a reduced cost, free, or possibly with incentives, sewage sludge is being investigated as a potential feedstock for biofuel production. For the extraction of oils from the sewage sludge and the subsequent processing, there are various alternatives that should be designed, analyzed, and screened. In developing and screening these alternatives, it is necessary to have a consistent basis for comparing alternatives based on key criteria. While most of the design studies focus on techno-economic criteria, it is also important to include safety metrics in the multi-criteria analysis. In this work, a detailed economic analysis and a safety evaluation are performed on a process involving extraction of triglycerides and fatty acids, pre-treatment of fatty acids (direct conversion to biodiesel), and transesterification of triglycerides to biodiesel. Four solvents, toluene, hexane, methanol and ethanol, are individually used in the extraction process. The resulting triglycerides and fatty acids from each extraction are modeled in the pre-treatment process. ASPEN Plus software is used to simulate the detailed process. Economic analysis is performed using ASPEN ICARUS, and scale-up of a previously analyzed process is used to estimate the cost of the biodiesel portion of the process. A new safety metric (referred to as the Safety Index “SI”) is introduced to enable comparison of the various solvent extraction processes. The SI is based on solvent criteria as well as process conditions. A case study is presented to demonstrate the insights and usefulness of the developed approach. The results of the techno-economic analysis reveal that of the four solvents used for the initial extraction, hexane and toluene were least costly (2.89 and 2.79 $/gal, respectively). Conversely, the safety analysis utilizing the SI reveals that methanol and ethanol are the safer solvent options. The issue of cost/safety tradeoffs is also discussed. 相似文献
53.
Jaime B. Henning Carolyn J. Stufft Stephanie C. Payne Mindy E. Bergman M. Sam Mannan Nir Keren 《Safety Science》2009,47(3):337-345
Workplace accidents cost organizations and the economy billions of dollars annually, disabling and injuring millions of employees. Employee attitudes toward safety have been shown to relate to safe workplace behavior. In an effort to determine what contributes to stronger employee attitudes toward safety, we examined the relationships between safety attitudes and a wide array of individual differences reflecting preferences and tendencies toward risk and control. Using a sample of 190 engineering and occupational safety students from two universities, we found that agreeableness, conscientiousness, prevention regulatory focus, and fatalism related significantly to all six safety attitudes examined. Regression analyses demonstrated that agreeableness, prevention focus, and fatalism significantly related to safety attitudes when controlling for the other individual differences. This study illustrates the utility of examining individual differences when predicting safety-related attitudes. 相似文献
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Kiran L. Dhanjal‐Adams Marcel Klaassen Sam Nicol Hugh P. Possingham Iadine Chadès Richard A. Fuller 《Conservation biology》2017,31(3):646-656
Conserving migratory species requires protecting connected habitat along the pathways they travel. Despite recent improvements in tracking animal movements, migratory connectivity remains poorly resolved at a population level for the vast majority of species, thus conservation prioritization is hampered. To address this data limitation, we developed a novel approach to spatial prioritization based on a model of potential connectivity derived from empirical data on species abundance and distance traveled between sites during migration. We applied the approach to migratory shorebirds of the East Asian‐Australasian Flyway. Conservation strategies that prioritized sites based on connectivity and abundance metrics together maintained larger populations of birds than strategies that prioritized sites based only on abundance metrics. The conservation value of a site therefore depended on both its capacity to support migratory animals and its position within the migratory pathway; the loss of crucial sites led to partial or total population collapse. We suggest that conservation approaches that prioritize sites supporting large populations of migrants should, where possible, also include data on the spatial arrangement of sites. 相似文献
56.
Wayne S. Meyer Brett A. Bryan David M. Summers Greg Lyle Sam Wells Josie McLean Mark Siebentritt 《Sustainability Science》2016,11(5):733-747
Changing unsustainable natural resource use in agricultural landscapes is a complex social–ecological challenge that cannot be addressed through traditional reductionist science. More holistic and inclusive (or transdisciplinary) processes are needed. This paper describes a transdisciplinary project for natural resource management planning in two regions (Eyre Peninsula and South Australian Murray-Darling Basin) of southern Australia. With regional staff, we reviewed previous planning to gain an understanding of the processes used and to identify possible improvement in plan development and its operation. We then used an envisioning process to develop a value-rich narrative of regional aspirations to assist stakeholder engagement and inform the development of a land use management option assessment tool called the landscape futures analysis tool (LFAT). Finally, we undertook an assessment of the effectiveness of the process through semi-structured stakeholder interviews. The planning process review highlighted the opinion that the regional plans were not well informed by available science, that they lacked flexibility, and were only intermittently used after publication. The envisioning process identified shared values—generally described as a trust, language that is easily understood, wise use of resources, collaboration and inclusiveness. LFAT was designed to bring the best available science together in a form that would have use in planning, during community consultation and in assessing regional management operations. The LFAT provided spatially detailed but simple models of agricultural yields and incomes, plant biodiversity, weed distribution, and carbon sequestration associated with future combinations of climate, commodity and carbon prices, and costs of production. Stakeholders were impressed by the presentation and demonstration results of the software. While there was anecdotal evidence that the project provided learning opportunities and increased understanding of potential land use change associated with management options under global change, the direct evidence of influence in the updated regional plan was limited. This project had elements required for success in transdisciplinary research, but penetration seems limited. Contributing factors appear to be a complexity of climate effects with economic uncertainty, lack of having the project embedded in the plan revision process, limited continuity and capacity of end users and limited after project support and promotion. Strategies are required to minimise the controlling influence that these limitations can have. 相似文献
57.
Xiaobo Chao Yafei Jia F. Douglas Shields Sam S.Y. Wang Charles M. Cooper 《Journal of environmental management》2010,91(7):1456-1466
A three-dimensional water quality model was developed for simulating temporal and spatial variations of phytoplankton, nutrients, and dissolved oxygen in freshwater bodies. Effects of suspended and bed sediment on the water quality processes were simulated. A formula was generated from field measurements to calculate the light attenuation coefficient by considering the effects of suspended sediment and chlorophyll. The processes of adsorption–desorption of nutrients by sediment were described using the Langmuir Equation. The release rates of nutrients from the bed were calculated based on the concentration gradient across the water–sediment interface and other variables including pH, temperature and dissolved oxygen concentration.The model was calibrated and validated by applying it to simulate the concentrations of chlorophyll and nutrients in a natural oxbow lake in Mississippi Delta. The simulated time series of phytoplankton (as chlorophyll) and nutrient concentrations were generally in agreement with field observations. Sensitivity analyses were conducted to demonstrate the impacts of varying suspended sediment concentration on lake chlorophyll levels. 相似文献
58.
59.
van Netten C Brands RH Hoption Cann SA Spinelli JJ Sheps SB 《Environment international》2003,28(7):567-572
An apparent cancer cluster at a police detachment in a coastal British Columbia community was investigated. Police personnel suspected that the detachment building may have been a factor. Police personnel (20 current and 154 previous employees) associated with the detachment since 1963, the date of occupancy, were traced. After all 174 cases were contacted directly, or next of kin in case of death, a total of 16 cases of cancer or suspected cancers were reported. Of these 16, eight cases of cancer were confirmed through a cancer registry. Cancers included testicular, cervical, colon, skin (including melanoma), leukemias and lymphomas with an age range of diagnosis between 22 and 44 years. There was no evidence for an underlying event, factor or condition in the police building that could be attributed to the observed cancer cases. A possible association between these cancers and the use of police traffic radar is discussed. 相似文献
60.
This article focuses on agricultural production in lift irrigation schemes along the White Nile in the Sudan. A comparison is drawn between the theoretical forecast and actual practical experience regarding the feasibility of transferring management from government-run parastatal organizations to private farmer organizations. Although the theoretical model indicates that farmers should be able to cover the cost of managing the river lift irrigation systems, field data show, however, that farmers growing wheat are barely able to break even. Even assuming a doubling of the present wheat yields, the cash surplus earned would only suffice for fuel to operate the pumps. Under these circumstances, it is not surprising that, contrary to government expectations, the private sector has been unenthusiastic about taking over management of White Nile river lift schemes. The lessons that emerge from this study indicate that unplanned and rapid withdrawal of state management can lead to negative results. The transfer of management responsibility for the river pumps does not appear to influence economic performance considerably, which depends on the wider context of the country's economic, political and institutional environment, within which the agricultural sector functions. 相似文献