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31.
Zhang B Cox SB McMurry ST Jackson WA Cobb GP Anderson TA 《Environmental pollution (Barking, Essex : 1987)》2008,153(3):658-667
Soil and topical tests were employed to investigate the effect of two N-nitroso metabolites of RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) on earthworm reproduction. The lowest observed effect concentration (LOEC) for cocoon production and hatching was 50mg/kg for both hexahydro-1-nitroso-3,5-dinitro-1,3,5-triazine (MNX) and hexahydro-1,3,5-trinitroso-1,3,5-triazine (TNX) in soil. MNX and TNX also significantly affected cocoon hatching in soil (p<0.001) and in topical tests (p=0.001). The LOECs for cocoon hatching were 1 and 10mg/kg for MNX and TNX in soil, respectively, and 10mg/L in the topical test. Greater than 100mg/kg MNX and TNX completely inhibited cocoon hatching. In soil, the EC20 values for MNX were 8.7 and 8.8mg/kg for cocoon and juvenile production, respectively, compared to 9.2 and 9.1mg/kg for TNX, respectively. The EC20 values for the total number of cocoon hatchlings were 3.1 and 4.7mg/kg for MNX and TNX, respectively, in soil and 4.5 and 3.1mg/L in the topical test. Both MNX and TNX inhibited cocoon production and hatching, suggesting that they may have a negative affect on soil ecosystems at contaminated sites. 相似文献
32.
Analysis of trace dicyandiamide in stream water using solid phase extraction and liquid chromatography UV spectrometry 总被引:1,自引:0,他引:1
An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction. The extraction procedure (including loading, washing, and eluting) used a flow rate of 1.0 mL/min, and dicyandiamide was eluted with 20 mL of a methanol/acetonitrile mixture (V/V = 2:3), followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography–ultraviolet spectroscopy (HPLC–UV). Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge (with activated carbon). Separation was achieved on a ZIC®-Hydrophilic Interaction Liquid Chromatography (ZIC-HILIC) (50 mm × 2.1 mm, 3.5 μm) chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions (R2 > 0.999). Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations (RSDs, n = 3) were below 6.1% with a detection limit of 5.0 ng/mL for stream water samples. 相似文献
33.
Response of Fish and Macroinvertebrate Bioassessment Indices to Water Chemistry in a Mined Appalachian Watershed 总被引:1,自引:0,他引:1
Multimetric indices based on fish and benthic macroinvertebrate assemblages are commonly used to assess the biological integrity
of aquatic ecosystems. However, their response to specific stressors is rarely known. We quantified the response of a fish-based
index (Mid-Atlantic Highlands Index of Biotic Integrity, MAH-IBI) and a benthic invertebrate-based index (West Virginia Stream
Condition Index, WV-SCI) to acid mine drainage (AMD)-related stressors in 46 stream sites within the Cheat River watershed,
West Virginia. We also identified specific stressor concentrations at which biological impairment was always or never observed.
Water chemistry was extremely variable among tributaries of the Cheat River, and the WV-SCI was highly responsive across a
range of AMD stressor levels. Furthermore, impairment to macroinvertebrate communities was observed at relatively low stressor
concentrations, especially when compared to state water quality standards. In contrast to the WV-SCI, we found that the MAH-IBI
was significantly less responsive to local water quality conditions. Low fish diversity was observed in several streams that
possessed relatively good water quality. This pattern was especially pronounced in highly degraded subwatersheds, suggesting
that regional conditions may have a strong influence on fish assemblages in this system. Our results indicate that biomonitoring
programs in mined watersheds should include both benthic invertebrates, which are consistent indicators of local conditions,
and fishes, which may be indicators of regional conditions. In addition, remediation programs must address the full suite
of chemical constituents in AMD and focus on improving linkages among streams within drainage networks to ensure recovery
of invertebrate and fish assemblages. Future research should identify the precise chemical conditions necessary to maintain
biological integrity in mined Appalachian watersheds. 相似文献
34.
Many problems and challenges of ecosystem management currently are driven by the rapid pace and spatial extent of landscape
change. Parks and reserves within areas of high human population density are especially challenged to meet the recreational
needs of local populations and to preserve valued environmental resources. The complex problem of managing multiple objectives
and multiple resources requires an enormous quantity of information, and conceptual models have been proposed as tools for
organizing and interpreting this information. Academics generally prefer a bottom-up approach to model construction that emphasizes
ecologic theory and process, whereas managers often use a top-down approach that takes advantage of existing information to
address more pragmatic objectives. The authors propose a formal process for developing, applying, and testing conceptual models
to be used in landscape monitoring that reconciles these seemingly opposing perspectives. The four-step process embraces the
role of hypothesis testing in the development of models and evaluation of their utility. An example application of the process
to a network of national parks in and around Washington, DC illustrates the ability of the approach to systematically identify
monitoring data that would both advance ecologic theory and inform management decisions. 相似文献
35.
Forest policymakers, public lands managers, and scientists in the Pacific Northwest (USA) seek ways to evaluate the landscape-level
effects of policies and management through the multidisciplinary development and application of spatially explicit methods
and models. The Interagency Mapping and Analysis Project (IMAP) is an ongoing effort to generate landscape-wide vegetation
data and models to evaluate the integrated effects of disturbances and management activities on natural resource conditions
in Oregon and Washington (USA). In this initial analysis, we characterized the spatial distribution of forest and range land
development in a four-county pilot study region in central Oregon. The empirical model describes the spatial distribution
of buildings and new building construction as a function of population growth, existing development, topography, land-use
zoning, and other factors. We used the model to create geographic information system maps of likely future development based
on human population projections to inform complementary landscape analyses underway involving vegetation, habitat, and wildfire
interactions. In an example application, we use the model and resulting maps to show the potential impacts of future forest
and range land development on mule deer (Odocoileus hemionus) winter range. Results indicate significant development encroachment and habitat loss already in 2000 with development located
along key migration routes and increasing through the projection period to 2040. The example application illustrates a simple
way for policymakers and public lands managers to combine existing data and preliminary model outputs to begin to consider
the potential effects of development on future landscape conditions. 相似文献
36.
Christopher J. Yahnke Warren E. Johnson Eli Geffen Deborah Smith Fritz Hertel Michael S. Roy Cristian F. Bonacic Todd K. Fuller Blaire Van Valkenburgh Robert K. Wayne 《Conservation biology》1996,10(2):366-375
The temperate rain forest of Chiloé Island, Chile, is inhabited by an endemic fox ( Dusicyon fulvipes ) first described by Charles Darwin and now designated Darwin's fox. Despite morphological differences, Darwin's fox has been considered only an insular subspecies of the mainland chilla fox ( D. griseus ). This follows the assumption that the island population, with an estimated population of less than 500, has been separated from the mainland chilla fox for only about 15,000 years and may have received occasional immigrants from the mainland. Consequently, this island population has not been protected as endangered or bred in captivity. Recently, a population of Darwin's fox was discovered on the Chilean mainland 600 km north of Chiloé Island. This population exists in sympatry with chilla and possibly culpeo ( D. culpaeus ) foxes, which suggests that Darwin's fox may be reproductively isolated. To clarify the phylogenetic position of Darwin's fox, we analyzed 344 bp of mitochondrial DNA control-region sequence of the three species of Chilean foxes. Darwin's foxes from the island and mainland populations compose a monophyletic group distinct from the two other Chilean fox species. This indicates that Darwin's fox was probably an early inhabitant of central Chile, and that its present distribution on the mainland may be a relict of a once much wider distribution. Our results highlight the ability of molecular genetic techniques to uncover historical relationships masked by recent events, such as local extinctions. The "rediscovery" of Darwin's fox as a distinct species implies that greater significance should be given to the protection of this species and its unique habitat and to documenting the extent of its mainland distribution. 相似文献
37.
This research evaluated the UNC passive aerosol sampler as a tool to measure particle mass concentrations and size distributions. The exposure scenario represented high concentrations and exposure periods of a few hours. Mass concentrations measured with the passive sampler were compared to concentrations measured using both a dichotomous sampler and an aerodynamic particle sizer (APS). In addition, the size distributions measured with the passive sampler were compared to those measured using the APS. Mass concentrations measured using the dichotomous sampler and the APS agreed well. The passive sampler tracked, but tended to overestimate, mass concentrations measured by the other two instruments. Size distributions measured with the passive sampler followed the general pattern of those measured using the APS. Overall, the passive sampler demonstrated both its utility and its limitations in these tests. The concentration measurements and size distributions found using passive samplers were more variable than those of the other instruments, but generally followed the data taken using the other methods. The advantages of low cost and ease of use offset the limitations in data quality with the passive sampler; these advantages are particularly welcome for sampling situations where aerosol properties vary over space or time. 相似文献
38.
Global pilot study for persistent organic pollutants (POPs) using PUF disk passive air samplers 总被引:2,自引:0,他引:2
Harner T Pozo K Gouin T Macdonald AM Hung H Cainey J Peters A 《Environmental pollution (Barking, Essex : 1987)》2006,144(2):445-452
Polyurethane foam (PUF) disks were deployed at global background sites, to test logistical issues associated with a global monitoring network for persistent organic pollutants (POPs). alpha-HCH, exhibited relatively high and uniform concentrations (17-150 pg/m3) at temperate and arctic sites with elevated concentrations associated with trans-Pacific inflow. Concentrations were much lower (<5 pg/m3) in Bermuda, Chile and Cape Grim. Concentrations for gamma-HCH, the main component of lindane, were spatially similar to the alpha-HCH pattern but lower in magnitude (typically, <10 pg/m3). Chlordane concentrations (sum of cis-chlordane, trans-chlordane and trans-nonachlor) were also low (<10 pg/m3). Dieldrin concentrations were in the range 2-25 pg/m3 at most sites but elevated in Bermuda. Back trajectories suggest that advection from Africa and the US may contribute. Endosulfan, a popular current-use pesticide, exhibited highest concentrations ranging from tens to hundreds of pg/m3. There was good agreement between duplicate samplers at each site and PUF disk-derived air concentrations agreed with high volume data. Few logistical/analytical problems were encountered in this pilot study. 相似文献
39.
Wu TH Cañas JE Rainwater TR Platt SG McMurry ST Anderson TA 《Environmental pollution (Barking, Essex : 1987)》2006,144(1):151-157
Seven complete clutches of Morelet's crocodile (Crocodylus moreletii) eggs were collected in northern Belize and examined for organochlorine (OC) pesticide residues. The primary OC detected, p,p-DDE, was found in every egg analyzed (n=175). Other OCs detected included p,p-DDT, p,p-DDD, methoxychlor, aldrin, and endosulfan I. Concentrations of individual OCs ranged from 4 ppb (ng chemical/g egg wet weight) to greater than 500 ppb. A statistical evaluation of p,p-DDE levels in three complete clutches was used to derive the minimum number of eggs needed from a clutch to precisely determine the mean p,p-DDE concentration representative of that clutch. Sample sizes of 8 (80% confidence level) and 11 (90% confidence level) were determined to yield an accurate estimate of contaminant levels in a full clutch of eggs. The statistically recommended sample size of 11 eggs (at 90% confidence level) was successfully tested on the four additional clutches. 相似文献
40.
Major modifications regulating the Tigris River, originated in the 1940s and continuing to the present, have resulted in changes in salinity in the system over time and in different portions of the river course. The increase in salinity is due to decreases in stream discharge due to dams, water management structures such as the Lake Tharthar system, irrigation return flow, and soluble minerals in the basin. This research documents the increase and evaluates the causes of the salinity increase of the river from predevelopment to present using published and previously unavailable data. The predevelopment salinity was under 600 ppm, since 1984 has exceeded the 1000 ppm threshold recommended for drinking water downstream of Amara. A minimum instream flow for the river is calculated at Baghdad and Kut at 185 cubic meters per second (cms), approximately 15% of the mean historical flow of the river, but above the lowest minimum flow recorded at 140 cms. Recommended salinity management options discussed include (1) eliminating Lake Tharthar as a water storage facility, (2) managing saline inflows from tributaries, and (3) employing a minimum instream flow for the river. 相似文献