TSP-PM10-PM2.5-2型中流量大气颗粒物采集系统的开发和应用

自行开发并研制了TSP-PM10-PM2.5-2型中流量TSP、PM10、PM2.5大气颗粒物采集系统,是目前中国唯一可以采集TSP、PM10、PM2.5样品并提供足够的样品量进行大气颗粒物化学成分分析的中流量大气颗粒物采集器.该系统精心设计和加工的限流孔可以保持完全固定的流量,保证切割粒径的稳定,减小采样的误差并方便操作.该系统已经成功地应用于20多个城市和地区大气颗粒物的监测和研究中,为研究大气颗粒物的污染状况和来源提供了有效的技术手段和支持.     

冷凝吸附法测定痕量挥发性含硫气体

采用冷凝吸附法对痕量挥发性含硫气体的测定进行了研究 ,结果表明自行设计的冷凝吸附装置对于痕量挥发性含硫气体的富集有着良好的效果 ,富集效率可达 94%以上     

垃圾填埋场渗出液中有害成分的研究

研究垃圾填埋场渗出液中的有害成分。渗出液样品用适当的方法处理后 ,用气相色谱 -质谱联用方法和原子发射光谱法进行定性分析。然后用原子吸收分光光度法和反相高效液相色谱法定量测定样品中微量的 Cu、Zn、Pb、Cr、Cd、Hg、苯酚、对甲苯酚、萘、蒽     

哈密地区环境中^220Rn子体α潜能浓度所致居民剂量估算

用ＳｔｒａｎｄｅｎＥ．推荐的测量方法对哈密地区环境空气中２２０Ｒｎ子体α潜能浓度测量结果表明，室内、外平均值分别为５６．１和１０．２（×１０－７Ｊ·ｍ－３）。室内外２２０Ｒｎ／２２２Ｒｎ子体α潜能浓度比值分别为０．８４和０３２。２２０Ｒｎ子体所致居民有效剂量当量为２２８μＳｖ·ａ－１（集体有效剂量当量为０．９×０２ｍａｎ·Ｓｖ）。     

内蒙古某灌域表层土壤六氯环己烷空间分布特征及影响因素

为修复灌区内土壤有机氯农药污染，降低六氯环己烷对土壤环境的危害，对内蒙古某灌域表层土壤进行采样，利用气相色谱测定50个土壤样品中六氯环己烷及其异构体的含量，并利用ArcGIS空间分析技术确定表层土壤中六氯环己烷的分布状况。样本中六氯环己烷的检出率为96%，各样本中六氯环己烷的浓度范围为未检出~23.0 ng/g，平均浓度为4.4 ng/g。4种异构体含量平均值顺序为γ-六氯环己烷>δ-六氯环己烷>β-六氯环己烷>α-六氯环己烷。灌域东北部和西南部残留浓度较高，并由这2个方向向中部地区逐渐递减，表层土壤中的六氯环己烷分布受土壤黏粒量、不同种植种类和灌溉水源的影响较大。虽受人类耕作的影响，但表层土壤中的六氯环己烷污染水平相对较低。     

开展建设项目施工期的环境管理与环境监测

分析了建设项目施工期的环境影响，阐述了开展施工期环境管理与环境监测的必要性，介绍了施工期环境管理的实施手段，施工单位的环境管理制度，施工期环境监测的主要内容及对环境监测部门的要求，建议将施工期的环境管理与环境监测纳入正常的环保管理渠道之中，实现建设项目的全过程环境管理。     

A study of the elemental leachability and retention capability of compost

In this work a comparison is made between the different approaches that can be taken to evaluate the mobility of elements in compost. The practical consequences of the results obtained are also discussed in terms of methods for cleaning up compost and using compost in environmental remediation. The mobility of potentially toxic elements in compost is evaluated by leaching with four selected eluents, i.e. diluted sulfuric acid, oxalate, citrate and EDTA. In contrast to the chelating agents, diluted sulfuric acid was found to generally have a low leaching capability for removal of heavy metals from compost. This implies that the risk of heavy metal leaching caused by natural rainfall is likely to be low. The results obtained in the leaching experiment were compared with previous results obtained from sequential fractionation. This comparison confirmed that both methods gave similar results for predicting the lability of elements in compost. A non-linear regression analysis of the leaching curves was also conducted. The leaching curves for elements with high lability could be fitted with a two components model. The labile components identified by the kinetic model are approximately in accordance with the fractions obtained from the first step of the sequential extraction method. The kinetic speciation method is shown to be a relatively rapid and simple procedure for compost which gives more information about element lability than simple leaching experiments. The leaching reagents used in this work were not effective enough to be used for cleaning up compost with a high metal content. Compost was however shown to have a high affinity for heavy metals, with the order of affinity of metal for the compost being very similar to that seen for humic acid. Compost may therefore prove to be a good remediation material for metal contaminated waste.     

碘量法测定水中溶解氧有关问题的探讨及改进

碘量法测定溶解氧时,采用NH3·H2O—KI代替NaOH(KOH)—KI固定溶解氧,用H2SO4—H3PO(41+1)混合酸代替H2SO4溶解沉淀,使沉淀沉降速度加快,分界线明显,沉淀溶解也更完全。同时做样品空白实验,校正了氧化还原性物质产生的干扰,对废水有明显的抗干扰能力。通过对蒸馏水、自来水、池塘水、废水进行溶解氧测定,结果均非常满意。     

HNO_3─KI─MIBK萃取／原子吸收光谱法测定固体废物浸提液中的微量银

采用选择性较好的ＨＮＯ３—ＫＩ—ＭＩＢＫ萃取体系对铋渣和尾矿渣浸出液中的痕量银进行预分离富集后，用火焰原子吸收法（ＡＡＳ）进行测定。此法不仅变异系数小（约为３．１％），而且检出限比直接火焰ＡＡＳ法降低两个数量级，达０．５ｎｇ／ｍｌ．另外，还就作品细度对银测定结果的影响原因做了初步探讨。     

合肥地区重金属污染生物监测的初步研究 --以大蜀山铅镉的白鹭监测为例

将合肥地区大蜀山的白（Egretta garzetta）卵和组织样品，用原子吸收法时样品中的Pb、Cd等重金属污染物进行了检测，结果表明，这2种重金属元素在卵和组织中均有不同程度的检出，其中Cd在卵的内容物中残留量较低。而且这2种重金属污染物在鹭卵不同部分的残留量均有差异；同其他地区类似的研究结果相比，合肥地区鹭卵中重金属残留水平相时较高。