Bioremediation of chlorobenzene-contaminated ground water in an in situ reactor mediated by hydrogen peroxide

New in situ reactive barrier technologies were tested nearby a local aquifer in Bitterfeld, Saxonia-Anhalt, Germany, which is polluted mainly by chlorobenzene (CB), in concentrations up to 450 microM. A reactor filled with original aquifer sediment was designed for the microbiological remediation of the ground water by indigenous bacterial communities. Two remediation variants were examined: (a) the degradation of CB under anoxic conditions in the presence of nitrate; (b) the degradation of CB under mixed electron acceptor conditions (oxygen+nitrate) using hydrogen peroxide as the oxygen-releasing compound. Under anoxic conditions, no definite degradation of CB was observed. Adding hydrogen peroxide (2.94 mM) and nitrate (2 mM) led to the disappearance of CB (ca. 150 microM) in the lower part of the reactor, accompanied by a strong increase of the number of cultivable aerobic CB degrading bacteria in reactor water and sediment samples, indicating that CB was degraded mainly by productive bacterial metabolism. Several aerobic CB degrading bacteria, mostly belonging to the genera Pseudomonas and Rhodococcus, were isolated from reactor water and sediments. In laboratory experiments with reactor water, oxygen was rapidly released by hydrogen peroxide, whereas biotic-induced decomposition reactions of hydrogen peroxide were almost four times faster than abiotic-induced decomposition reactions. A clear chemical degradation of CB mediated by hydrogen peroxide was not observed. CB was also completely degraded in the reactor after reducing the hydrogen peroxide concentration to 880 microM. The CB degradation completely collapsed after reducing the hydrogen peroxide concentration to 440 microM. In the following, the hydrogen peroxide concentrations were increased again (to 880 microM, 2.94 mM, and 880 microM, respectively), but the oxygen demand for CB degradation was higher than observed before, indicating a shift in the bacterial population. During the whole experiment, nitrate was uniformly reduced during the flow path in the reactor.     

Life cycle engineering im Automobilbau

Ecobalance represents the basic principle for an environmental analysis and the starting point for the possibility of achieving improvements. Using the criteria related to both technology and ecology, this method has been expanded upon by IKP/PE and, over the course of many years, has proven to be a satisfactory method for those fields associated with industry and research. Data banks and software systems have been designed and are today applied in industry. An expansion of the holistic balancing to include the ‘social’ dimension is currently being developed by the IKP. Today, ecological decisions in technically and economically-associated areas are continuously being developed which place more emphasis on the preliminary developments than on a purely retrospective analysis. Aside from the continuous, further developments of these types of analysis with regard to never technical questions as well as the integration of newer aspects of optimization based on life cycle information (e.g. production balancing), the goal of further work includes the preparation of process-chain information in the respective in preliminary developments related to the design. The automobile industry consequently plays a significant role here, as was also the case in the initial transformation of methodology which was carried out in the 1990s. Finally, these developments are additionally motivated through the new ordinances presented to be employed throughout the entire EU. The responsibility attributed to a product over the course of its entire lifetime therefore plays a more prominent role. This is also reflected in ordinances like those related to the redemption of old automobiles or in the WEEE of the electronics industry (Directive on Waste Electrical and Electronic Equipment).     

The role of iron nanoparticles on anaerobic digestion: mechanisms,limitations, and perspectives

Environmental Science and Pollution Research - Anaerobic digestion (AD) is the most widely used technology for organic matter treatment. However, multiple types of research have reported on...     

Trichloroethylene (TCE) removal in a single pulse suspension bioreactor

This work describes TCE biotic removal in a single-pulse bioreactor under aerobic conditions. Activated sludge from a wastewater-treatment plant was used for inoculation of the cultivator. The experiment focused on a more detailed verification of microbial composition of mixed heterotrophic culture during pulsed phenol dosage. Attention was given to suppressing eucaryotic organisms, particularly yeasts and fungi, by the addition of cycloheximide. The TCE-removal capacity of the heterotrophic culture, described by kinetic tests, was dependent on pulsed phenol injection and on cyclic addition of phenol and TCE. Maximum TCE degradation was determined in a batch test. It was found that the addition of cycloheximide (an antibiotic against propagation and growth of fungi and yeast) increased the TCE degradation activity of the mixed microbial suspension. A certain residual amount of TCE remained in some of the experiments.