Persistence of polycyclic aromatic hydrocarbons in sediments in the deeper area of the Northern Adriatic Sea (Mediterranean Sea)

The Po Valley is the most important agricultural and industrial area of Adriatic basin. In this area there are several rivers which transport polycyclic aromatic hydrocarbons (PAHs) into the sea via suspended particulate matter. This study describes the persistence of PAHs in the deep and coastal sediments of the Northern Adriatic. Different environmental conditions were studied: salinity, temperature, sunlight, sediment particle size and organic matter in sediment. The average conditions in the deep areas of the Northern Adriatic are: salinity higher than 37, temperature lower than 11 °C, darkness and clayey sediments with a high organic matter content. These conditions increase the persistence of the PAHs in the deep area of the Northern Adriatic.     

Assessment of an Interpretive Program for U.S. Coast Guard Personnel

Abstract: The goal of this research was to measure the effect of a print-based interpretive program on acceptance by U.S. Coast Guard personnel of an endangered-species protection program. We used a within-subjects design to measure changes in eight survey items measuring beliefs about endangered species. There were significant changes in three items. The initial attitude toward endangered species was a strong predictor of subsequent response in a "regression to the mean effect" in which the least change was found in subjects with the highest initial scores on attitude items. Our results suggest that the print-based program was effective at changing the most highly targeted attitudes, but had little effect on more general attitudes.     

Application of laser ablation ICP-MS and traditional techniques to the study of black crusts on building stones: a new methodological approach

Introduction  

In this work, we propose an innovative application of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) as a methodological approach for the chemical characterisation of black crusts on stone monuments, associated with traditional micro-morphological (optical and scanning electron microscopy) and infrared spectroscopic techniques (FTIR).     

BVOC emissions, photosynthetic characteristics and changes in chloroplast ultrastructure of Platanus orientalis L. exposed to elevated CO2 and high temperature

To investigate the interactive effects of increasing [CO₂] and heat wave occurrence on isoprene (IE) and methanol (ME) emissions, Platanus orientalis was grown for one month in ambient (380 μmol mol⁻¹) or elevated (800 μmol mol⁻¹) [CO₂] and exposed to high temperature (HT) (38 °C/4 h). In pre-existing leaves, IE emissions were always higher but ME emissions lower as compared to newly-emerged leaves. They were both stimulated by HT. Elevated [CO₂] significantly reduced IE in both leaf types, whereas it increased ME in newly-emerged leaves only. In newly-emerged leaves, elevated [CO₂] decreased photosynthesis and altered the chloroplast ultrastructure and membrane integrity. These harmful effects were amplified by HT. HT did not cause any unfavorable effects in pre-existing leaves, which were characterized by inherently higher IE rates. We conclude that: (1) these results further prove the isoprene's putative thermo-protective role of membranes; (2) HT may likely outweigh the inhibitory effects of elevated [CO₂] on IE in the future.     

Assessment of the trophic status of four coastal lagoons and one estuarine delta, eastern Brazil

Anthropogenic eutrophication of aquatic ecosystems continues to be one of the major environmental issues worldwide and also of Brazil. Over the last five decades, several approaches have been proposed to discern the trophic state and the natural and cultural processes involved in eutrophication, including the multi-parameter Assessment of Estuarine Trophic Status (ASSETS) index model. This study applies ASSETS to four Brazilian lagoons (Mundaú, Manguaba, Guarapina, and Piratininga) and one estuarine delta (Paraíba do Sul River), set along the eastern Brazilian coast. The model combines three indices based on the pressure–state–response (PSR) approach to rank the trophic status and forecast the potential eutrophication of a system, to which a final ASSETS grade is established. The lagoons were classified as being eutrophic and highly susceptible to eutrophication, due primarily to their longer residence times but also their high nutrient input index. ASSETS classified the estuary of the Paraíba do Sul river with a low to moderate trophic state (e.g., largely mesotrophic) and low susceptibility to eutrophication. Its nutrient input index was high, but the natural high dilution and flushing potential driven by river flow mitigated the susceptibility to eutrophication. Eutrophication forecasting provided more favorable trends for the Mundaú and Manguaba lagoons and the Paraíba do Sul estuary, in view of the larger investments in wastewater treatment and remediation plans. The final ASSETS ranking system established the lagoons of Mundaú as “moderate,” Manguaba as “bad,” Guarapina as “poor,” and Piratininga as “bad,” whereas the Paraíba do Sul River Estuary was “good.”     

An experiment in the electrokinetic removal of copper from soil contaminated by the brass industry

The feasibility of electrokinetic remediation of copper-contaminated soil was evaluated following eight days of electroreclamation. The results indicate that electrokinetic reclamation of Cu is totally ineffective in soil composed primarily of clay minerals and organic matter. The strong absorption of copper by this kind of soil, in our view mainly a result of retention by the clay component, makes it resistant to mobilization by the electrogenerated acidic front as well as by citrates (the competitors of natural chelating agents, i.e., humates). Such conditions, while adverse for the electroremediation process, may cause this kind of soil to act as a natural barrier to the leaching of copper ions.     

Land Management Versus Natural Factors in Land Instability: Some Examples in Northern Spain

The objective of this work is to test a hypothesis formulated on the basis of former results which considers that there might be a “global geomorphic change,” due to activities related to land management and not determined by climate change, which could be causing an acceleration of geomorphic processes. Possible relationships between some geomorphic processes related to land instability (landslides or sediment generation) and potential triggering factors are analyzed in study areas in northern Spain. The analysis is based on landslide inventories covering different periods, as well as the determination of sedimentation rates. Temporal landslide and sedimentation rate trends are compared with different indicators of human activities (land-use change, logging, forest fires) and with potential natural triggers (rainfall, seismicity). The possible influence of the road network in the distribution of landslides is also analyzed. Results obtained show that there is a general increase of both landslide and sedimentation rates with time that cannot be explained satisfactorily by observed rainfall trends and even less by seismicity. Land-use change appears to be by far the main factor leading to land instability, with some changes producing up to a 12-fold increase of landslide rate. A relationship between road network and the spatial distribution of landslides has also been observed. These results do confirm the existence of an acceleration of geomorphic processes in the region, and also suggest that climate-related factors play a limited role in the changes observed.     

Pinus nigra and Pinus pinaster needles as passive samplers of polycyclic aromatic hydrocarbons

Nine polycyclic aromatic hydrocarbons (PAHs) were analysed in pine needles of different ages (from 6 to 30 months) collected from two species, Pinus nigra and Pinus pinaster, in seven sites located along a transect from a suburban to a rural area of Genoa (Italy). In all sites and for both species, concentrations of more volatile PAHs (phenanthrene, anthracene, fluoranthene, pyrene) were higher than those for other less volatile PAHs, which are preferentially sorbed to airborne particulates (benzo[a]anthracene, chrysene, benzofluoranthenes, benzo[a]pyrene). Concentrations of total PAHs found in P. nigra in the rural sites were, on the average, 2.3 times higher than those in P. pinaster growing nearby. In both pine species, concentrations of volatile PAHs increased according to needle age. Annual trends of other PAHs were more variable, with a general decrease in older needles. P. pinaster needles are shown to be more reliable passive samplers, since they are more resistant to plant diseases, and considerable variation in PAH concentration was observed in P. nigra needles with moulds and fungi.     

太湖鼋头渚地区鹭类觅食生境研究

连续 2a实地调查了太湖鼋头渚地区鹭鸟的觅食生境 ,并搜集其雏鸟的反吐物 ,初步掌握了该地区不同鹭鸟对觅食生境的选择与食物组成情况。结果表明 ,无锡鼋头渚地区白鹭与夜鹭主要在鱼塘、湖泊觅食 ,白鹭在湖滨觅食 ,而夜鹭还会到湖中央水面觅食 ;池鹭觅食区域较广 ,主要在鱼塘。鹭群主要的食物类型是鱼类 ,白鹭食物几乎全为鱼类 ,夜鹭 95 %的食物为鱼类 ,兼有少量的蛙类、甲壳类和小型哺乳类动物。