Arsenic poisoning in groundwater: health risk and geochemical sources in Bangladesh

Of the 2508 water samples analyzed in 10 districts of Bangladesh, 51%, on an average, contained arsenic levels of 0.05 to 2.50 mg/l. 95% of nail, 96% of hair, and 94% of urine samples contained arsenic above the normal level. Approximately 3.58 million people out of a total of 17.92 million who are drinking water containing arsenic levels >0.20 mg/l are potentially exposed to high risk of health hazard. Eight thousand and five hundred arsenic patients are identified; they are suffering from various skin lesions, gangrene in leg, skin, lung, bladder, liver, and renal cancer. A big portion of the total population is highly vulnerable to various internal cancers. Lowest arsenic concentration in drinking water producing dermatological disease is found to be 0.103 mg/l. However, the exposure time to develop arsenicosis varies from case to case reflecting its dependence on arsenic level in drinking water and food, nutritional status, genetic variant of human being, and compounding factors. This study has determined the high intensity of fluorescent humic substances in drinking water containing elevated concentrations of arsenic and very low concentrations of heavy metals. The synergistic/antagonistic effect of fluorescent compounds present in drinking water may aggravate the toxicity of arsenic. Geochemical study suggests that arsenic may be released from both reductive dissolution of Fe and Mn (oxy)hydroxide and microbial oxidation of organic matter.     

Fostering Sustainability in Headwaters Country: Using Bioregional and Social Capital Strategies in Support of Sustainability

Many of Canada's ex-urban and rural areas face a daunting array of sustainability challenges. In developing effective sustainability strategies, these areas must rely heavily upon local resources and capacities and existing social capital. Part of the solution for these areas may lie in multi-stakeholder collaborative approaches built on sustainability principles and strategies. These include the engagement and mobilization of civil society networks; the cultivation of strategic partnerships among key stakeholders in civil society, the private sector and government; and long-term local programmes of research, education and advocacy that are supportive of sustainability. This article describes and analyses a Canadian case study—Dufferin County, part of the Headwaters Country region in southern Ontario—in which a multi-stakeholder, civil society based approach to fostering sustainability is currently unfolding. The ideological and theoretical underpinnings of the initiative are explored, key process-oriented and substantive challenges to the approach are analysed and action research strategies are discussed.     

Characteristic levels of heavy metals in sediments and dredged sediments of a municipal creek in the Niger delta, Nigeria

Characteristic levels of metal ions in post dredged sediment and dredged sediments materials of a municipal creek in the Niger Delta show that significant concentrations of heavy metals are found to be accumulated more on the surface (0–15cm depth) of the dredged material as compared to the sub surface (15–30cm) and post dredged sediments. The distribution patterns were in the following order Fe > Mn > Zn > Cu > Pb > Ni > Cd and Fe > Mn > Zn > Pb > Cu > Ni > Cd for the post dredged sediment and dredged sediment materials respectively. The levels of the various metals were far below the EPA screening levels for open water disposal, consequently total levels of heavy metal found in these sediments pose no problem by open-water or upland disposal     

What's wrong with virtual trees? Restoring from stress in a mediated environment

Restorative environments are environments that can help restore depleted attention resources or reduce emotional and psychophysiological stress. These effects have been demonstrated not only in real environments, but also in mediated (projected, broadcasted, etc.) environments. However, the importance of simulation qualities to restoration outcomes has not been systematically studied. The present experiment investigates the importance of immersion in a mediated environment in relation to restoration. Is a projected natural environment more restorative when one is more immersed in it, and hence feels more present in it? The hypothesis was that a more immersive projection would show stronger stress-reducing effects of a mediated restorative environment. After performing a stress-inducing task, participants watched a nature film on either a high or low immersive screen. Physiological measurements (heart period and skin conductance level) were taken throughout the experiment. In addition, we measured self-reported affect and presence using the ITC-Sense of Presence Questionnaire. Significant effects of the screen size manipulation appeared on physiological measures, but not on self-reported affect. The data showed an interaction between screen size and restorative phase on heart period and skin conductance level, indicating stronger restoration for the immersive screen condition over time. We therefore conclude that immersion enhances restorative potential of a mediated natural environment. Self-reported affect did correlate significantly with experienced presence, illustrating the relevance of this experiential counterpart of immersion, although a mediating effect of presence has not yet been established.     

ASSESSMENT OF POSSIBLE IMPACTS OF CLIMATE CHANGE IN AN URBAN CATCHMENT1

ABSTRACT: Stationarity of rainfall statistical parameters is a fundamental assumption in hydraulic infrastructure design that may not be valid in an era of changing climate. This study develops a framework for examining the potential impacts of future increases in short duration rainfall intensity on urban infrastructure and natural ecosystems of small watersheds and demonstrates this approach for the Mission/Wagg Creek watershed in British Columbia, Canada. Nonstationarities in rainfall records are first analyzed with linear regression analysis, and the detected trends are extrapolated to build potential future rainfall scenarios. The Storm Water Management Model (SWMM) is used to analyze the effects of increased rainfall intensity on design peak flows and to assess future drainage infrastructure capacity according to the derived scenarios. While the framework provided herein may be modified for cases in which more complex distributions for rainfall intensity are needed and more sophisticated stormwater management models are available, linear regressions and SWMM are commonly used in practice and are applicable for the Mission/Wagg Creek watershed. Potential future impacts on stream health are assessed using methods based on equivalent total impervious area. In terms of impacts on the drainage infrastructure, the results of this study indicate that increases in short duration rainfall intensity may be expected in the future but that they would not create severe impacts in the Mission/Wagg Creek system. The equivalent levels of imperviousness, however, suggest that the impacts on stream health could be far more damaging.     

HYDROLOGIC MODELING OF A BIOINFILTRATION BEST MANAGEMENT PRACTICE1

ABSTRACT: The goal of this research was to develop a methodology for modeling a bioinfiltration best management practice (BMP) built in a dormitory area on the campus of Villanova University in Pennsylvania. The objectives were to quantify the behavior of the BMP through the different seasons and rainfall events; better understand the physical processes governing the system's behavior; and develop design criteria. The BMP was constructed in 2001 by excavating within an existing traffic island, backfilling with a sand/soil mixture, and planting with salt tolerant grasses and shrubs native to the Atlantic shore. It receives runoff from the asphalt (0.26 hectare) and turf (0.27 hectare) surfaces of the watershed. Monitoring supported by the hydrologic model shows that the facility infiltrates a significant fraction of the annual precipitation, substantially reducing the delivery of nonpoint source pollution and erosive surges downstream. A hydrologic model was developed using HEC‐HMS to represent the site and the BMP using Green‐Ampt and kinematic wave methods. Instruments allow comparison of the modeled and measured water budget parameters. The model, incorporating seasonally variable parameters, predicts the volumes infiltrated and bypassed by the BMP, confirming the applicability of the selected methods for the analysis of bioinfiltration BMPs.     

Leadership self‐efficacy and managers' motivation for leading change

This study develops and tests a leadership model that focuses on managers' motivation for attempting the leadership of change. The construct of leadership self‐efficacy (LSE) is defined, and a measure comprising three dimensions (direction‐setting, gaining followers' commitment, and overcoming obstacles to change) is developed. Based on Bandura's (1986) social cognitive theory, the primary hypothesis is that high LSE managers will be seen by direct reports as engaging in more leadership attempts. Relationships are also proposed between LSE and several factors that are expected to influence this confidence judgment. Managers' organizational commitment and crisis perceptions are modelled as potential moderators of the relationship between LSE and leadership attempts. The model was tested through surveys distributed to managers (n = 150) and their direct reports (n = 415) in a real estate management company and an industrial chemicals firm. Positive relationships (p < 0.05) were found between the first two dimensions of LSE and managers' leadership attempts. An interaction effect involving organizational commitment was discovered for the LSE/overcoming obstacles dimension (p < 0.05). Several positive relationships were found between LSE dimensions and proposed antecedents, including self‐esteem (p < 0.05), subordinates' performance abilities (p < 0.05), and managers' job autonomy (p < 0.05). Copyright © 2002 John Wiley & Sons, Ltd.     

Results from Three Field Tracer Experiments on the Neighbourhood Scale in the City of Birmingham UK

The physical processes governing flow and pollutantdispersion at the neighbourhood scale, a spatial scaleintermediate between the street scale and the city scale, is notwell understood. Furthermore, it is not clear whether a traditional approach using averaged characteristics such as theaerodynamic roughness length is sufficient to predict the concentration field at this scale. To investigate pollutant dispersion in a real urban area, three field experiments were designed within the UK-URGENT programme sponsored by NERC. Theexperiments were performed in the City of Birmingham using a finite duration release of inert, non-toxic and non-depositingtracers, vis. perfluoromethylcyclohexane (PMCH) and perfluoromethylcyclopentane (PMCP). Measurements were taken using air bag samplers placedin an arc at 3.5 km (first experiment) and 1 km (second andthird experiments) from the source; some trap samplers wereplaced outside the main arc in the outskirts of the city. Measurements were analysed in the laboratory using anovel gas-chromatography technique. Data so obtained werecompared with predictions from a simple steady-state modeland a time-dependent model. The concentration-time serieswere very asymmetrical with a sharp rise, a plateau followedby a relatively slow decrease and finally a long-livedplateau above (or possibly very slow decrease to) thebackground level.